• Title/Summary/Keyword: Host materials

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Fabrication and Characterization of Orange Polymer Light Emitting Diodes by Concentration of MEH-PPV (MEH-PPV의 농도에 따른 황색 고분자 유기발광다이오드의 제작과 특성평가)

  • Jeon, Chang-Duk;Shin, Sang-Baie;Gong, Su-Choel;Park, Hyung-Ho;Jeon, Hyeong-Tag;Chang, Ho-Jung
    • Proceedings of the KAIS Fall Conference
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    • 2008.05a
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    • pp.184-185
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    • 2008
  • 본 연구에서는 ITO/PEDOT:PSS//PFO:MEH-PPV/LiF/Al 구조를 갖는 고분자 유기발광다이오드를 제작하여 발광 도펀트인 MEH-PPV의 농도에 따른 황색 PLED 소자의 전기 광학적 특성에 대하여 조사하였다. MEH-PPV의 농도를 각각 6, 7, 8, 9, 10 wt% 로 변화시켜 소자를 평가한 결과 9 wt%의 농도에서 가장 우수한 전기 및 광학적 특성을 보였으며, 16 V의 인가전압에서 약 630 cd/$m^2$의 휘도 특성과 256 mA/$cm^2$의 전류밀도 특성이 관찰되었다. 또한 10 wt%의 소자에서는 오히려 낮은 광학적 특성이 관찰되어 9 wt%에서 도펀트의 농도가 포화됨이 관찰되었고, 제작된 소자의 색좌표 (CIE coordiante)는 모든 소자에서 (x, y = 0,49, 0.49)로 거의 동일하게 나타났다.

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Study on the Characteristics and Fabrication of Organic Light Emitting Devices Using the Synthesised Phosphorescent Metal Complexes (인광특성이 있는 금속 착물의 합성과 그 물질을 이용한 소자 제작 및 소자 특성 평가)

  • Kim, Young-Kwan;Sohn, Byoung-Chung;Kim, Jun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.2
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    • pp.97-102
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    • 2002
  • Recently, the phosphorescent organic light-emitting devices (OLEDs) have been extensively studied for their high internal quantum efficiency. In this study, we synthesised several phosphorescent metal complexes, and certified their composition using NMR. We also investigated the characteristics of the phosphorescent OLEDs with the green emitting phosphor, $Ir(ppy)_{3}$. The devices with a structure of indium-tin-oxide(ITO)/N,N'-diphenyl-N,N'-(3-methylphenyI}-1,1'-biphenyl-4,4'-diamine (TPD)/metal complex doped in host materials/2,9-dimethyl-4,7-diphenyl-l,10-phenanthroline(BCP)/tris (8-hydroxyquinolinato) Aluminum($Alq_{3}$)/Li:Al/Al was fabricated, and its electrical and optical characteristics were studied. By changing the doping concentration of tris(2-phenylpyridine)iridium ($Ir(ppy)_{3}$), we fabricated several devices and investigated their characteristics.

ROLE OF SOILS IN THE DISPOSAL OF NUCLEAR WASTE

  • Lee, S.Y.
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.3
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    • pp.251-268
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    • 1986
  • Selecting a site for the safe disposal of radioactive waste requires the evaluation of a wide range of geologic, mineralogic, hydrologic, and physicochemical properties. Although highly diverse, these properties are in fact interrelated. Site requirements are also diverse because they are influenced by the nature of the radionuclides in the waste, for example, their half-lives, specific energy, and chemistry. A fundamental consideration in site selection is the mineralogy of the host rock, and one of the most ubiquitous mineral groups is clay minerals. Clays and clay minerals as in situ lithologic components and engineered barriers may playa significant role in retarding the migration of radionuclides. Their high sorptivity, longevity (stability), low permeability, and other physical factors should make them a very effective retainer of most radionuclides in nuclear wastes. There are, however, some unanswered questions. For example, how will their longevity and physicochemical properties be influenced by such factors as radionuclide concentration, radiation intensity, elevated temperatures, changes in redox condition, pH, and formation fluids for extended periods of time? Understanding of mechanisms affecting clay mineral-radionuclide interactions under prevailing geochemical conditions is important; however, the utilization of experimental geochemical information related to physicochemical properties of clays and clay-bearing materials with geohydrologic models presents a uniquely challenging problem in that many assessments have to be based on model predictions rather than on experiments. These are high-priority research investigations that need to be addressed before complete reliance for disposal area performance is made on clays and clay minerals.

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The Study of Religious Medical Treatment in the Canonical Scripture of Daesoon Jinrihoe in Korea (韓國大巡真理會《典經》之宗教醫療研究)

  • Chung, Yun-ying
    • Journal of the Daesoon Academy of Sciences
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    • v.39
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    • pp.249-274
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    • 2021
  • The aim of this article is to investigate the religious medical treatments performed by Kang Jeungsan as recorded in The Canonical Scripture, the main scripture of the Korean new religion, Daesoon Jinrihoe. The unity of mind and body is the core principle underlying Kang Jeungsan's religious medical treatments. He believed treating the mind of his patients was more important and necessary than treating their diseases. As such, he believed the only way to treat critical illness was to keep preserve the mind-body unity of his patients. Massage was a physical therapy often used by Kang Jeungsan. The medicinal materials that he commonly used were the Four-substance Decoction (四物湯 samultang), Minor Bupleurum Decoction (小柴胡湯 soshihotang), quince (木瓜 mokgwa *Pseudocydonia sinensis; not papaya), and rehmannia (生地黃 saengjihwang). Kang Jeungsan's religious medical treatments were characteristic of Daoist healing methods. His Daoist style healing methods included multiple techniques such as treating diseases through correcting Qi, exorcising malevolent entities, transferring diseases to a different host, removing a disease through the changing of clothes, pouring medicine into the ground, combining the usage of talisman and incantations, and treating the common people. Among these techniques, Jeungsan's pouring medicine into the ground was especially innovative.

Evaluation of dissolution characteristics of magnetite in an inorganic acidic solution for the PHWR system decontamination

  • Ayantika Banerjee ;Wangkyu Choi ;Byung-Seon Choi ;Sangyoon Park;Seon-Byeong Kim
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1892-1900
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    • 2023
  • A protective oxide layer forms on the material surfaces of a Nuclear Power Plant during operation due to high temperature. These oxides can host radionuclides, the activated corrosion products of fission products, resulting in decommissioning workers' exposure. These deposited oxides are iron oxides such as Fe3O4, Fe2O3 and mixed ferrites such as nickel ferrites, chromium ferrites, and cobalt ferrites. Developing a new chemical decontamination technology for domestic CANDU-type reactors is challenging due to variations in oxide compositions from different structural materials in a Pressurized Water Reactor (PWR) system. The Korea Atomic Energy Research Institute (KAERI) has already developed a chemical decontamination process for PWRs called 'HyBRID' (Hydrazine-Based Reductive metal Ion Decontamination) that does not use organic acids or organic chelating agents at all. As the first step to developing a new chemical decontamination technology for the Pressurized Heavy Water Reactor (PHWR) system, we investigated magnetite dissolution behaviors in various HyBRID inorganic acidic solutions to assess their applicability to the PHWR reactor system, which forms a thicker oxide film.

First report of seven unrecorded bambusicolous fungi in Korea

  • Sun Lul Kwon;Minseo Cho;Changmu Kim;Jae-Jin Kim
    • Journal of Species Research
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    • v.13 no.2
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    • pp.111-126
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    • 2024
  • Korean bamboo forests encompass 22,067 hectares and are dominated by Phyllostachys species. These forests serve as vital ecosystems, providing nourishment and habitat for diverse flora, fauna, and microorganisms. Among these inhabitants, various fungal species have been documented worldwide, displaying ecological roles as saprobes, parasites, and symbionts within or outside the bamboo host. However, a comprehensive study of bambusicolous fungi within the Korean bamboo ecosystem remains a critical gap in our knowledge. In this study, we conducted an extensive survey of bamboo materials collected from various bamboo forests and subsequently undertook fungal isolation. Primary identification of bambusicolous fungi was achieved through analysis of the internal transcribed spacer (ITS) region. As a result, we identified seven previously unrecorded bambusicolous fungal species (Fusarium bambusarum, Fusicolla violacea, Macroconia gigas, Neopestalotiopsis camelliae-oleiferae, Neopestalotiopsis iberica, Neopestalotiopsis longiappendiculata, and Thyridium punctulatum). Phylogenetic analysis using protein-coding genes appropriate for each taxon and morphological observation were conducted to ensure accurate identification. This study contributes to our understanding of fungal diversity within bamboo forests in Korea.

LATE RECONSTRUCTION OF PARTIALLY-RESECTED MANDIBLE AFTER REMOVAL OF AMELOBLASTOMA OF THE MANDIBLE (하악골 부분절제술후 이물성형재료에 의한 즉시재건술이 실패된 예에서 양측 장골뼈와 Miniplate Osteosynthesis 를 이용하여 재건시킨 법랑아세포종 치험 1예)

  • Park, Hyung-Sik;Kim, Sun-Yong;Kwon, Joon-Ho;Lee, Sang-Hye
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.12 no.1
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    • pp.171-179
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    • 1990
  • This is a report on a case of delayed reconstruction after partial mandibularectomy for Ameloblastoma involving symphysis and bodies of the mandible by using of two large pieces of corticocancellous bone blocks obtained from both iliac crests. The authors failed immediate reconstruction with two kinds of Alloplasts(metal, methylmethacrylate) at two times of trial due to known infection and suggestive poor histocompatibility of materials aginst the host who has been suffered from long-term and active pulmonary tuberculosis. However we could get success late reconstruction of this problem-occured and curved area with two pieces of large corticocancellous blocks by using of miniplate osteosynthesis and biphasic external pin fixation. From our experience we are obtained some results as follows : 1. Alloplastic graft materials seemed to be dangerous to maintain successfuly in patient who has a long-term debilitating disease as a active pulmonary tuberculosis. 2. Biphasic external skeletal pin fixation appliance gave many advantages such as maintain functional position of the remained bodies and condyles of the mandible after removal of failed alloplasts and during control of inflammation of this area, assist supportive roles to fix and maintain bone grafts during healing, allow mandibular movement during healing and so offer to conduct normal functional stimuli to bone grafts during osteogenesis etc. 3. Bony union was successful between not only normal bones and grafted bones but also grafted bone pieces even though we used two pieces of large blocks of corticocancellous bone for graft. 4. Miniplate osteosynthesis was not affect any adverse effects to bone grafts but offered good role of fixation and maintenance for bone grafts.

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Fabrication and characteristics for the organic light emitting device from single layer poly(N-vinylcarbazole) (단층 poly(N-vinylcarbazole) 유기물 전기발광 소자의 제작 및 특성)

  • 윤석범;오환술
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.11
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    • pp.55-61
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    • 1998
  • Organic light emitting devices from a single layer thin film with a hole transport polymer, poly(N-vinylcarbazole) (PVK) doped with 2-(4-bi phenyl)-5-(4-t-butyl-phenyl) -1,3,4-oxadiazole (Bu-PBD) as electron transporting molecules and Coumurine 6(C6), 1,1,4,4-tetraphenyl-1,3-butadiene (TPB), Rhodamine B as a emitter dye were fabricated. The sing1e layer structure and the use of soluble materials simplify the fabrication of devices by spin coating technique. The active layer consists of one polymer layer that is simply sandwiched between two electrodes, indium-tin oxide (ITO), and aluminum. In this structure, electron and hole inject from the electrodes to the PVK : Bu-PBD active layer. Respectively, Blue, green and orange colored emission spectrum by the use of TPB, C6, Rhodamine B dye emitted at 481nm, 500nm and 585nm were achieved during applied voltages. PVK materials can be useful as the host polymer to be molecularly doped with other organic dyes of the different luminescence colors. And EL color can be tuned to the full visible wavelength.

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Beta glucan: Heath benefits of optimal ingredients via the mixture ratio of rice bran and Sarcodon aspratus

  • Seo, Yu-Ri;Kim, Hye-Been;Cheong, Kyu-Min;Lim, Ki-Taek
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.101-101
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    • 2017
  • Beta-glucan is a polymerized polysaccharide on beta-1,3 chemical bonds. It has the main pharmacological action of various anticancer mushrooms and is colorless and odorless. In addition, it enhances phagocytosis of macrophages against mycobacterium tuberculosism and increases resistance of host against food poisoning bacteria. Owing to these advantages, beta-glucan was used in various health supplement foods such as immune boosters, hypotensive agent and hypoglycemic agent. Our study was aimed to investigate the effective components of beta-glucan, which was optimized via the contents of Sarcodon aspratus and rice bran. First, the mixture ratio condition of Sarcodon aspratus and rice bran were respectively 10:0, 7:3, 5:5, 3:7, and 0:10. The raw materials were fabricated using hot water extraction method. Distilled water of 100 mL was added to the raw material and extracted. After the extraction processed, the content of effective components was analyzed. The absorbance of beta-glucan was measured using a beta-glucan kit (Megazyme, (1-3) (1-4) BETA-D-GLUCAN ASSAY KIT). The absorbance analysis was repeated three times for accurate analysis. After the extracts were lyophilized, the yields of extracted raw materials according to the mixture ratio conditions of Sarcodon aspratus and rice bran (10:0, 7:3, 5:5, 3:7, and 0:10) were respectively 33.1%, 34.5%, 35.3%, 30.7%, and 24.3%. The absorbance was 1.52, 1.47, 1.50, 1.79, and 1.56, respectively. As a result, the optimum ratio of beta-glucan is 3:7 at Sarcodon aspratus and rice bran. This study suggested that the optimal amount of beta-glucan could be used as a health supplement foods and food additive such as immune boosters, hypotensive agent and hypoglycemic agent. However, the new condition (temperature, time) of hot water extraction to maximize the content of beta-glucan could be considered, could be necessary to compare with the existing extracts.

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The Characteristics of PEO-Based Composite Electrolyte added functionalized SiO_2$ Filler and (3-cyanopropyl)methylsiloxane cyclics. (기능성 실리카 filler와 (3-cyanopropyl)methylsiloxane cyclics를 가소제로 이용해 제조되어진 PEO-Based 전해질의 특성 연구)

  • 이재필;김정남;문희수;이승원;이영식;서동학;김인수;박종완
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.214-214
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    • 2003
  • 고체 고분자 전해질에 대한 연구는 1979년 wright와 Armand에 처음 시작된 이래로 지난 20여년간 연구가 계속적으로 지속되고 있다. 전지의 적용되기 위해 전해질이 갖추어야 할 조건중에 이온전도도가 상온에서 10-4 S/cm 이상의 전도도를 나타내야 하지만 지금까지 연구되고 있는 여러 고체 고분자 전해질은 이런 조건을 만족시키지 못하고 있는 실정이다. 본 연구에서는 이런 상온에서의 이온 전도성을 향상시키기 위해 여러 종류의 실리카와 세라믹 계열의 첨가제를 첨가하여 이온전도성의 향상을 꾀하고자 하였다. 본 연구에서는 고체 고분자 전해질의 host polymer로써 분자량 400,000 의 Polyethylene oxide를 사용하였으며 Lithuim salt로는 Lithium (bisperfluroethylsulfonyl)imide(3M)를 기본적으로 사용하였다. 여기에 가소제의 역활로써 (3-cyanopropyl)methylsiloxane cyclics를 첨가하였고 표면그룹이 CH3와 OH기로 이루어진 기능성 나노 실리카를(<11nm)이용하여 함량별 전기 화학적 특성 및 기본 물성을 측정하였다. 기본적으로 이 네 가지 물질을 유기용매 Acetonitril에 잘 용해하여 Solid Casting방법으로 80-100 마이크로의 복합고분자 전해질을 제조하였다. Homogeneous하고 uniform한 필름 제조하기 위해 9$0^{\circ}C$에서 열처리를 24h 동안 실시하였다. 제조되어진 복합고분자전해질은 XRD를 통하여 결정성을 조사하였고 DSC를 이용하여 유리 전이온도 및 결정화도를 조사하였다. 복합고체고분자의 전기화학적 성질을 평가하기 위해 blocking electrode를 제작하여 임피던스 스펙트로 스코피를 이용하여 이온전도성을 측정하였다. 또한 복합 고분자 전해질의 온도의존성에 대해서도 조사하였다. 또한 실제 전지의 작동구간에서의 전해질의 안정성을 확인하기 위해 LSV를 측정하였고. Li metal을 사용하여 non-blocking electrode를 제작하여 복합고분자 전해질과의 계면저항을 측정하였다.

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