• Journal of the Korean Ceramic Society
• /
• v.33 no.5
• /
• pp.495-506
• /
• 1996

Monodispersed colloidaly yttria(Y2O3) can be used in a variety of applications such as phosphors. IR transparent materials and fine ceramics. For preparing monodispersed yttria homogeneous precipitation has been regarded as a fovorable method that is monodispersed yttria can be obtained through calcining monodispersed colloidal compound of yttrium (eg:Y(OH)CO3.nH2O)which can be prepared by homogeneous precipitation with urea. It is however still required to find out the quantitative effects of important variables of precipitation such as concentration of yttrium and urea reaction temperature and initial pH of reactant even though homogeneous precipitation of Y3+ with urea has been studied extensively. Among the effects of these variables we investiga-ted 1) the effect of yttrium concentration on the shape and size of precipitate and the reation rate 2) range of yttrium concentration required to make monodispersed colloidal particles 3) the reason for limited concentra-tion range of yttrium and 4) the effect of ultrasonic radiation on the limited concentration.

• Journal of the Korean Ceramic Society
• /
• v.33 no.9
• /
• pp.1031-1037
• /
• 1996

• Journal of Powder Materials
• /
• v.15 no.5
• /
• pp.386-392
• /
• 2008

Silver particles were synthesized from silver nitrate by homogeneous precipitation and chemical reduction methods involving the intermediate silver cyanate. The obtained silver particles were characterized by XRD, SEM, TEM, and BET. Urea which could prevent the agglomeration of the reduced silver particles was used as a homogeneous precipitator. The spherical silver particles with average particle diameter of 100 nm were obtained under the optimum reaction conditions. The optimum synthetic conditions were found as follows: reaction temperature $100^{\circ}C$, reaction time 60 min, concentration of silver nitrate $1{\times}10^{-2}$ mol, urea $5{\times}10^{-3}$ mol, and sodium citrate $8.5{\times}10^{-4}$ mol. The phase of obtained silver particles was crystalline state and the silver particles were relatively dense, which had the surface area of $0.7571\;m^{2}/g$.

• Journal of the Korean Ceramic Society
• /
• v.35 no.11
• /
• pp.1212-1221
• /
• 1998

• Korean Journal of Materials Research
• /
• v.29 no.6
• /
• pp.343-348
• /
• 2019

Structural and mechanical effects of the dynamical precipitation in two copper-base alloys have been investigated over a wide range of deformation temperatures. Basing upon the information gained during the experiment, also some general conclusion may be formulated. A one concerns the nature of dynamic precipitation(DP). Under this term it is commonly understood decomposition of a supersaturated solid solution during plastic straining. The process may, however, proceed in two different ways. It may be a homogeneous one from the point of view of distribution and morphological aspect of particles or it may lead to substantial difference in shape, size and particles distribution. The effect is controlled by the mode of deformation. Hence it seems to be reasonable to distinguish DP during homogeneous deformation from that which takes place in heterogeneously deformed alloy. In the first case the process can be analyzed solely in terms of particle-dislocation-particle interrelation. Much more complex problem we are facing in heterogeneously deforming alloy. Deformation bands and specific arrangement of dislocations in form of pile-ups at grain boundaries generate additional driving force and additional nucleation sites for precipitation. Along with heterogeneous precipitation, there is a homogeneous precipitation in areas between bands of coarse slip which also deform but at much smaller rate. This form of decomposition is responsible for a specially high hardening rate during high temperature straining and for thermally stable product of the decomposition of alloy.

• Journal of the Korean Ceramic Society
• /
• v.33 no.6
• /
• pp.693-699
• /
• 1996

YIG precursor powder was obtained by homogeneous precipitation in chloride salt solution by thermal decom-position of urea. It was found that ferric ions precipitated prior to yttrium ions. The precipitate was minute and spherical in shape. The precipitate formed consisted of the mixture of amorphous and ferric oxyhydroxide. Crystallization of YIG was proceeded by solid state reaction of intermediate YFeO3 and Fe2O3 in the temperature range of 85$0^{\circ}C$ to 140$0^{\circ}C$. Single phase of YIG was obtained by heat-treatment of the powder at 140$0^{\circ}C$ for 6 hrs in air. The powder calcined was molded into pellets and sintered in air. The maximum density of 4,92 g/cm3(95.1% of theoretical density) was obtainable for the pellet sintered at 145$0^{\circ}C$ using the powder calcined at 90$0^{\circ}C$.

• Journal of Information Display
• /
• v.1 no.1
• /
• pp.35-41
• /
• 2000

Manganese-doped $Zn_2SiO_4$ phosphors well known as a green emitter with high luminescence efficiency were prepared by the homogeneous precipitation method, and their photoluminescence properties under vacuum-ultraviolet (VUV) excitation were investigated. $Zn_2SiO_4$:Mn phosphors obtained by this method have exhibited a high luminance of property and a spherical shape of particles. In particular, the green emission intensity of zinc orthosilicate prepared as containing around 2 mole% of manganese was much stronger than that of the commercial $Zn_2SiO_4$:Mn phosphor, while the decay time was longer. However, addition of $Al^{3+}$ and $Li^+$ into $Zn_2SiO_4$:Mn composition has significantly diminished the decay time of the phosphor without much degradation of the emission intensity.

• The Korean Journal of Quaternary Research
• /
• v.24 no.1
• /
• pp.1-10
• /
• 2010

The Indian summer monsoon behaved an abnormal way in 2002 and as a result there was a large deficiency in precipitation (especially in July) over a large part of the Indian subcontinent. For the study of deficient monsoon of 2002, a recent version of the NCAR regional climate model (RegCM3) has been used to examine the important features of summer monsoon circulations and precipitation during 2002. The main characteristics of wind fields at lower level (850 hPa) and upper level (200 hPa) and precipitation simulated with the RegCM3 over the Indian subcontinent are studied using different cumulus parameterization schemes namely, mass flux schemes, a simplified Kuo-type scheme and Emanuel (EMU) scheme. The monsoon circulation features simulated by RegCM3 are compared with the NCEP/NCAR reanalysis and simulated precipitation is validated against observation from the Global Precipitation Climatology Centre (GPCC). Validation of the wind fields at lower and upper levels show that the use of Arakawa and Schubert (AS) closure in Grell convection scheme, a Kuo type and Emanuel schemes produces results close to the NCEP/NCAR reanalysis. Similarly, precipitation simulated with RegCM3 over different homogeneous zones of India with the AS closure in Grell is more close to the corresponding observed monthly and seasonal values. RegcM3 simulation also captured the spatial distribution of deficient rainfall in 2002.

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.43 no.4
• /
• pp.57-68
• /
• 2001

It is matter of common knowledge to give impetus to the water resources development to cope with increasing demand and supply for the water utilization project including agricultural living and industrial water owing to the economic and civilization development in recent years. Regional design rainfall is necessary or the design of the dam reservoir levee and drainage facilities for the development of various kinds of essential waters including agricultural water. For the estimation of the regional design rainfall classification of the climatologically an geographically homogeneous regions should be preceded preferentially This study was mainly conducted to derive the optimal regionalization of the precipitation data which can be classified by the climatologically and geographically homogeneous regions all over the regions except Cheju and Wulreung islands in Korea. A total of 65 rain gauges were used to regional analysis of precipitation. Annual maximum series for the consecutive durations of 1, 3, 6, 12, 24, 36, 48 and 72hr were used for various statistical analysis. Both K-means clustering and mean annual precipitation methods are used to identify homogeneous regions all over the regions. Nine and five homogeneous regions for the precipitation were classified by the K-means clustering and mean annual methods, respectively. Finally, Five homogeneous regions were established by the trial and error method with homogeneity test using statistics of $\chi$$^2$ distribution.

• The Korean Journal of Quaternary Research
• /
• v.22 no.1
• /
• pp.13-22
• /
• 2008

The Indian summer monsoon behaved in an abnormal way in 2002 and as a result there was a large deficiency in precipitation (especially in July) over a large part of the Indian subcontinent. For the study of deficient monsoon of 2002, a recent version of the NCAR regional climate model (RegCM3) has been used to examine the important features of summer monsoon circulations and precipitation during 2002. The main characteristics of wind fields at lower level (850 hPa) and upper level (200 hPa) and precipitation simulated with the RegCM3 over the Indian subcontinent are studied using different cumulus parameterization schemes namely, mass flux schemes, a simplified Kuo-type scheme and Emanuel (EMU) scheme. The monsoon circulation features simulated by RegCM3 are compared with the NCEP/NCAR reanalysis and simulated precipitation is validated against observation from the Global Precipitation Climatology Centre (GPCC). Validation of the wind fields at lower and upper levels shows that the use of Arakawa and Schubert (AS) closure in Grell convection scheme, a Kuo type and Emanuel schemes produces results close to the NCEP/NCAR reanalysis. Similarly, precipitation simulated with RegCM3 over different homogeneous zones of India with the AS closure in Grell is more close to the corresponding observed monthly and seasonal values. RegcM3 simulation also captured the spatial distribution of deficient rainfall in 2002.