• Macromolecular Research
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• 제17권7호
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• pp.506-515
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• 2009

We synthesized a series of polystyrene derivatives containing various side chain terminal moieties, such as phenoxymethyl, 4-methoxyphenoxymethyl, 4-fluorophenoxymethyl, 4-methylphenoxymethyl, and 4-trifluoromethoxyphenoxymethyl groups, using polymer analogous reactions, in order to investigate the effect of the side group on their liquid crystal (LC) alignment behaviors. The polymers containing 4-fluorophenoxymethyl, 4-methylphenoxymethyl, or 4-trifluoromethoxyphenoxymethyl side groups had lower surface energy values and the LC cells fabricated using the unrubbed films of these polymers showed homeotropic LC alignment behavior. The LC cells fabricated using the rubbed films of the polymers containing phenoxymethyl or 4-fluorophenoxymethyl groups showed homogeneous planar LC alignment behavior in which the LCs were aligned perpendicular to the rubbing direction. This homogeneous planar and perpendicular alignment behavior was ascribed to the favorable anisotropic interactions between the LC molecules and the side groups preferentially oriented perpendicular to the rubbing direction.

• Transactions on Electrical and Electronic Materials
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• 제7권6호
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• pp.301-304
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• 2006

We studied the nematic liquid crystal (NLC) aligning capabilities using the new alignment material of the SiC (Silicon Carbide) thin film. The SiC thin film exhibits good chemical and thermal stability. The good thermal and chemical stability make SiC an attractive candidate for electronic applications. A vertical alignment of nematic liquid crystal by atomic beam exposure on the SiC thin film surface was achieved. The about $87^{\circ}$ of stable pretilt angle was achieved at the range from $30^{\circ}\;to\;45^{\circ}$ of incident angle. Consequently, the vertical alignment effect of liquid crystal electro-optical characteristic by the atomic beam alignment method on the SiC thin film layer can be achieved.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 춘계학술대회 논문집 디스플레이 광소자 분야
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• pp.62-65
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• 2005

We studied the nematic liquid crystal (NLC) alignment capability by the Ultraviolet (UV) alignment method on a-C:H thin-films, and investigated electro-optical performances of the UV aligned twisted nematic (TN)-liquid crystal display (LCD) with the UV exposure on a-C:H thin film surface. A good LC alignment by UV irradiation on a-C:H thin-film surfaces was achieved. Monodomain alignment of the UV aligned TN-LCD can be observed. The good electro-optical (EO) characteristics of the UV aligned TN-LCD was observed with oblique UV exposure on the a-C:H thin film surface for 1min.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 D
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• pp.1815-1817
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• 1999

In this paper, the generation of high pretilt angle in nematic liquid crystal (NLC) by dipping effect on three kinds of the rubbed polyimide (PI) surface was investigated. The generated pretilt angle of NLC increases due to dipping effect before rubbing treatment on two kinds of the rubbed PI surface with side chain. The generated pretit angle in NLC by using dipping effect after rubbing treatment on PI surface with short side chain is high compared to the PI surface with long side chain. The generated pretit angle of the positive type NLC $(\Delta{\varepsilon}>0)$ is higher as than that of the negative type NLC $({\Delta}{\varepsilon}<0)$ by using dipping effect before rubbing treatment on homeotropic layer. The generated pretilt angle of NLC is attributed to perpendicular component of permittivity ${\varepsilon}_{\perp}$ of NLC on rubbed PI surface.