• Title/Summary/Keyword: Hollow particles

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Low-Temperatrue Synthesis of Mullite Powders by the Emulsion Technique (MgO-Al2O3-SiO2계 요업원료의 제조 및 소결특성 -에멀젼법에 의한 Mullite분체의 저온합성-)

  • 현상훈;이희수;송승룡
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.361-370
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    • 1989
  • Mullite powders were synthesized from the common solution of aluminum sulfate and sodium silicate solutions by the emulsion-hot kerosene technique. The reaction temperature and mechanism for mullitization and the characteristics of synthesized mullite powders were investigated. The effect of Na components introduced from sodium silicate solution on the physical property and microstructure of sintered mullite was also examined. It was proved that mullites were formed at 75$0^{\circ}C$ through the reaction mechanism of Na2O.2.2SiO2+3.3Al2(SO4)3longrightarrow1.1(3Al2O3.2SiO2)+Na2SO4+8.9SO3. Synthetic mullite powders consisted of the compositiion of 3Al2O3.2SiO2 and showed highly agglomeration of hollow spherical particles of 1${\mu}{\textrm}{m}$ diameter. The density and fracture toughness of sintered mullites were somewhat reduced because of the effect of a very small amount of residual Na components.

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Fabrication of Various Carbides with Fibrous and Particulate Shapes by Self-Propagating High Temperature Synthesis Method (자전연소합성법에 의한 여러 가지 섬유상 및 입상 탄화물의 제조)

  • Bang, Hwan-Cheol;Yun, Jon-Do
    • Korean Journal of Materials Research
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    • v.10 no.5
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    • pp.343-349
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    • 2000
  • Fabrication of various carbide fibers from carbon fibers and elementary powders of Ti, Zr, Nb, Zi, W, B, and Mo by self-propagating high temperature synthesis was attempted. It was found the almost pure phase of TiC, ZrC, NbC, SiC, $B_4$C, and $Mo_2$C carbides were successfully produced. The three types of morphologies were ob-served, TiC, ZrC, NbC, and $B_4$C had a hollow-type fibrous shape. SiC had fiber shape consisting of smaller particles and fine whiskers. WC and $Mo_2$C had non-fibrous shapes. The reason for the different morphologies was explained. The formation mechanism of hollow fibers was suggested.

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Effect of Step-aeration on Inorganic Particle Mixtures Filtration in a Submerged Hollow Fiber Microfiltration Membrane (침지식 중공사 정밀여과 분리막에서 무기혼합입자 여과에 대한 단계별 공기세정의 영향)

  • Choi, Youngkeun;Kim, Hyun-Chul;Noh, Soohong
    • Membrane Journal
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    • v.25 no.3
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    • pp.256-267
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    • 2015
  • The goal is to compare two different aeration strategies for a pilot scale operation of submerged microfiltration with respect to the minimization of membrane fouling. A constant aeration (65 L/min) was examined parallel with a step-wise increase in airflow rate (40 to 65 L/min). The airflow rate was stepped to a higher rate every 5 min and the step-aeration cycles were repeated at regular intervals of 15 min. The comparative filtration runs were conducted with synthetic water containing powdered activated carbon (~10 g/L) and/or kaolin (~20 g/L) at a constant flux of 80 LMH. The extent and mechanisms of fouling in the microfiltration were identified by determining hydraulic resistance to filtration and the fouling reversibility after cleaning. Results showed that the step-aeration effectively alleviated fouling in the microfiltration of synthetic water compared to when using constant aeration. A substantial decrease in fouling was achieved by combining with coagulation using aluminum salts regardless of the aeration strategies. The constant aeration resulted in increased pore blocking likely due to increased accumulation of particles on the surface of membrane.

Experimental Study on Electrokinetic Streaming Potential in Micropore Channels of Hollw-Fiber Based on General Helmholtz-Smoluchowski's Principle (일반적 Helmholtz-Smoluchowski 원리에 따른 중공사 미세기공 채널에서의 계면동전기 흐름전위에 관한 실험연구)

  • 전명석;조홍일
    • Membrane Journal
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    • v.12 no.1
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    • pp.41-50
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    • 2002
  • The streaming potential generated by the electrokinetic flow within electric double layer of charged microchannel is applied to determine the zeta potential of hollow-fiber membrane pore by using the general Helmholtz-Smoluchowski equation. The streaming potential is know to provide a useful real-time information on the surface property and the interaction between pore and particles in actual situations and physicochemical conditions. The influence of physicochemical parameters upon the filtration with hollow-fibers has been examined with an in-situ and simultaneously monitoring the streaming potential as well as permeate flux. In particular, the present study examined an experimental method to identify the effect of cake layer which can vary according to the axial position of a hollow-fiber and the progress of membrane fouling by measuring the position-dependent streaming potential. As the latex concentration increases, the permeate flux decreased but the streaming potential increased. The growth of cake layer has been mire developed with increasing latex concentration, however, the effect of surface charges of latexes deposited on the membrane surface leads to increase the streaming potential. With increasing ionic concentration of KCI, both the permeate flux and the streaming potential decrease. The increase of ionic concentration provides a compact cake layer due to the shrinkage of Debye length and the decreased streaming potential results from the weakened ionic flows owing to a thin diffusive double layer.

Numerical Simulations on Combustion Considering Propellant Droplet Atomization and Evaporation of 500 N Class Hydrogen Peroxide / Kerosene Rocket Engine (500 N급 과산화수소/케로신 로켓엔진의 추진제 액적 분무와 증발을 고려한 연소 수치해석)

  • Ha, Seong-Up;Lee, Seon-Mi;Moon, In-Sang;Lee, Soo-Yong
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.10
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    • pp.862-871
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    • 2012
  • The numerical simulations on 500-N class rocket engine using 96% hydrogen peroxide and kerosene have been conducted, considering atomization, evaporation, mixing and combustion of its propellants. The grid containing 1/6 part of combustion chamber has been generated and it is assumed that 3 kinds of liquid-phase propellants (kerosene, hydrogen peroxide and water) were injected as hollow cone spray pattern, using Rosin-Rammler function for distribution of droplet diameter. For the calculation of combustion the eddy-dissipation model was applied. Owing to small size of combustion chamber and large specific heat / latent heat of hydrogen peroxide and water the propulsion characteristics were highly influenced by the size of droplet particles, and in this analysis the engine with droplet particles of 30 micron in average has shown the best propulsion performance.

A Study on Rolling Friction Characteristics of Magneto-Rheological Elastomer under Magnetic Fields (자기장 영향에 따른 자기유변탄성체의 구름 마찰 특성 연구)

  • Lian, Chenglong;Lee, Kwang-Hee;Kim, Cheol-Hyun;Lee, Chul-Hee
    • Tribology and Lubricants
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    • v.30 no.4
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    • pp.234-239
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    • 2014
  • Magneto-rheological elastomer (MR elastomer) is a smart material, because it has mechanical properties that change under a magnetic field. An MR elastomer changes its stiffness characteristics when the inner particles (iron particles) align along the direction of a magnetic field. There has been much research to make use of this characteristic to control vibration issues in various mechanical systems, such as for mounting systems in the automotive field, home appliances, etc. Furthermore, the friction and wear properties of MR elastomer have been studied, as these relate to the durability of the material needed to meet engineering requirements. Rolling friction (or rolling resistance) is one of these friction properties, but has not yet been studied in the context of MR elastomers. In this study, an MR elastomer is fabricated in the shape of a hollow cylinder to evaluate the rolling friction characteristic under a magnetic field. The test apparatus is setup and a strain gauge is used to calculate the rolling resistance under test conditions. Permanent magnets are used to supply the magnetic field during tests. The load and rolling speed conditions are also considered for the tests. The test results show that rolling friction characteristic has a different trend under different magnetic field, load, and rolling speed conditions. It is assumed that the stiffness change of an MR elastomer under a magnetic field has an effect on the rolling friction characteristic of the MR elastomer. For the future work, the rolling friction characteristics of MR elastomers will be controlled by adjusting the strength of the magnetic field using electromagnets.

Engineering Characteristics of Diatom Modified Soil Mixture (Diatom 혼합토의 공학적 특성)

  • Kim, Kyu-Sun
    • Journal of the Korean Geotechnical Society
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    • v.28 no.5
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    • pp.77-84
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    • 2012
  • The engineering characteristics of natural sediments containing diatom microfossils have been investigated for their abnormal deformation and strength behavior for a few decades. The presence of disk or hollow shape diatoms causes low compressibility, high hydraulic conductivity, and high shear strength of sediments. Some of these unusual differences show the characteristic of diatom owing to the interlocking of large interparticle porosity and angular particles. This phenomenon implies the possible use of diatom as modification materials to change the engineering performance of soil mixtures. This paper describes the engineering characteristics of diatom-kaolin mixture to investigate the engineering properties of diatom modified soils using conventional geotechnical tests and elastic and electromagnetic wave propagation tests. Experimental test results show the performance improvement by increasing diatom contents and the performance degradation by the breakage of interlocking between diatom particles under high effective stress.

A Study on the Effect of Automotive Engine Performance by Using Carbon Nano Colloid Cooling Water (탄소나노콜로이드 냉각수를 사용하여 자동차 엔진성능의 향상에 관한 연구)

  • Yi, Chung-Seob;Lee, Byung-Ho
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.5
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    • pp.134-142
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    • 2011
  • Although combustion is essential in most energy generation processes, it is one of the major causes of air pollution. Exhaust pipes with circular fin were designed to study the effect of cooling the recirculated exhaust gases (EGR) of Diesel engines on the chemical composition of the exhaust gases and the reduction in the percentages of pollutant emissions. The gases examined in this study were oxides of nitrogen (NOx), carbon dioxide ($CO_2$) and carbon monoxide (CO). In addition, $O_2$ concentration in the exhaust was measured. The designs adopted in this study were about exhaust pipes with solid and hollow fins around them direct surface force measurement in water using a nano size colloidal probe technique. The direct force measurement between colloidal surfaces has been an essential topic in both theories and applications of surface chemistry. As particle size is decreased from micron size down to true Carbon nano Colloid size (<10 nm), surface forces are increasingly important. Nano particles at close proximity or high solids loading are expected to show a different behavior than what can be estimated from continuum and mean field theories. The current tools for directly measuring interaction forces such as a surface force apparatus or atomic force microscopy (AFM) are limited to particles much larger than nano size. This paper use Water and CNC fluid at normal cooling system of EGR. Experimental result showed all good agreement at Re=$2.54{\times}10^4$ by free convection and Re=$3.36{\times}10^4$ by forced air furnace.

Characteristics of Carbonaceous Particles Derived from Coal-fired Power Plant and Their Reduction (석탄 화력발전소에서 발생하는 미연분의 특성분석 및 저감방법)

  • Park, Ho-Young;Kim, Young-Ju;Yu, Geun-Sil;Kim, Chun-Kun;Kim, Dong-Hun
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.10
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    • pp.1065-1073
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    • 2006
  • The unturned carbon in fly ash, recently occurred in the coal-fired Yong Hung power station, caused some problems in ash utilization and boiler efficiency. This paper describes the analysis of unburned carbon and six coals, some tests performed at Yong Hung Boiler, and the results of combustion modification for the reduction of unburned carbon in fly ash. From the physical and chemical analysis of unburned carbon in fly ash, most particles were turned out to be hollow cenosphere and agglomerated soot particles. The sooting potential from six coals used in the plant were investigated with CPD(Chemical Percolation Devolatilization) model. The results showed that the higher potential was presented to Peabody, Arthur, Shenhua coals rather than other coals. It was necessary to measure the coal flow rates at each coal feeding pipe for four burner levels since they affect the extent of mixing of soot with oxidant, in turn, the oxidation rate of soot particles. The unbalance in coal flow rate was found in several coal pipes. We successfully reduced unturned carbon in ash by increasing the excess air and changing the SOFA's yaw angle.

A Study on Membrane Fouling by Flux and Linear Velocity in Coagulation/Ultrafiltration Membrane System (응집·한외여과 조합공정에서 플럭스와 선속도가 막오염에 미치는 영향에 관한 연구)

  • Moon, Seong-Yong;Lee, Sang-Hyup;Kim, Seung-Hyun;Yoon, Cho-Hee
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.4
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    • pp.429-436
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    • 2005
  • A coagulation/ultrafiltration membrane hybrid system was operated to treat river water with capacity of $0.06m^3/d$. The impact on membrane fouling by flux and linear velocity was investigated. It is known that pressure increase is proportional to flux increase. However, pressure increase was much faster than theoretical value in the pilot plant test. So it was suggested that flux was on important factor in ultrafiltration of continuous operation. Membrane fouling was decreased when linear velocity was increased. This phenomenon was found more obviously without coagulation. With the combination of coagulation and sedimentation, membrane fouling was not reduced conspicuously. Big particles formed during coagulation and sedimentation were destroyed by feed and circulation pumping, which resulted in little effect on membrane fouling reduction. The degree of destruction was similar at various linear velocities. In this study, the hollow fiber membrane was used and the system was operated in pressure type module. In case of the system used in this study, membrane fouling has been affected lightly by linear velocity variation when coagulation pretreatment was applied.