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Synthesis of Ultra-long Hollow Chalcogenide Nanofibers

  • 좌용호
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.3.1-3.1
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    • 2011
  • Nanoengineered materials with advanced architectures are critical building blocks to modulate conventional material properties or amplify interface behavior for enhanced device performance. While several techniques exist for creating one dimensional heterostructures, electrospinning has emerged as a versatile, scalable, and cost-effective method to synthesize ultra-long nanofibers with controlled diameter (a few nanometres to several micrometres) and composition. In addition, different morphologies (e.g., nano-webs, beaded or smooth cylindrical fibers, and nanoribbons) and structures (e.g., core-.shell, hollow, branched, helical and porous structures) can be readily obtained by controlling different processing parameters. Although various nanofibers including polymers, carbon, ceramics and metals have been synthesized using direct electrospinning or through post-spinning processes, limited works were reported on the compound semiconducting nanofibers because of incompatibility of precursors. In this work, we combined electrospinning and galvanic displacement reaction to demonstrate cost-effective high throughput fabrication of ultra-long hollow semiconducting chalcogen and chalcogenide nanofibers. This procedure exploits electrospinning to fabricate ultra-long sacrificial nanofibers with controlled dimensions, morphology, and crystal structures, providing a large material database to tune electrode potentials, thereby imparting control over the composition and shape of the nanostructures that evolved during galvanic displacement reaction.

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중공단면 고강도 철근 콘크리트 교각의 연성거동에 관한 실험적 연구 (Ductility performance of hollow-section reinforced concrete piers using high-strength reinforcing bars)

  • 오병환;박대균;조근호;신용석
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.730-733
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    • 2004
  • Three Hollow RC piers were tested under a constant axial load and a cyclically reversed horizontal loadto investigate the structural behavior of hollow RC piers using the high strength concrete and the high strength rebars. The test variables include concrete compressive strength, steel strength, and steel ratio. The test results indicate that RC piers using the high strength concrete and high strength rebars exhibit ductile behavior and appropriate seismic performance, in compliance with the design code. The present study allows more realistic application of high strength rebars and concrete to RC piers, which will provide enhanced durability as well as more economy.

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3차원 경사크랙을 가진 중공축의 응력확대계수산정 (Computation of stress Intensity Factors of Hollow Cylinder with Three Dimension Inclination Cracks)

  • 이종선
    • 한국생산제조학회지
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    • 제8권1호
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    • pp.21-27
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    • 1999
  • In this study, stress intensity factors KI, KII, KIII are existing at the same time to a hollow cylindrical bar of three dimension inclination crack. In order to investigate by experimentally the effect of the inclination angle $\psi$ of crack, artificial inclination cracks in the circumferential direction are put in the surface of a hollow cylindrical bar made by the epoxy-resin. Experimentally, stress analysis methods of stress intensity factors were proposed. But, suitable method are the caustic method and the photoelastic stress freezing method. The mixed mode of KI, and KII, were determined by the photoelastic method of the classical approach method and the FORTRAN language program of the used smallest square method.

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공초점 현미경을 이용한 물체표면 형상측정에 관한 연구 (A Study on the Con-focal Microscope for the Surface Measurements)

  • 강영준;송대호;유원재;백성훈
    • 한국정밀공학회지
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    • 제20권5호
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    • pp.73-81
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    • 2003
  • In case of hollow cylinder extrusion using porthole die, the effects of extrusion parameters-temperature, the speed of extrusion, the shape of the die and mandrel-on metal flow in porthole die extrusion of aluminum have been investigated. However, there have been few studies about condenser tube extruded by porthole die. Original metal flow of condenser tube by porthole die extrusion is similar to hollow cylinder extrusion but the estimation of metal flow for extrusion parameters is different. For example, variation of chamber length in hollow extrusion only affects the welding pressure, however, the welding chamber length in condenser tube extrusion influences to the welding pressure as well as the deflection of mandrel. This study was designed to evaluate metal flow, welding pressure, extrusion load, tendency of mandrel deflection according to angular variation in the bottom of chamber in porthole die. Estimation was carried out using finite element method in as non-steady state. Analytical results can provide useful information the optimal design of porthole die.

Assay of In Vivo Chromium with a Hollow-fiber Dialysis Sensor

  • Ly, Suw-Young;Yoo, Hai-Soo;Jung, Min-Ki;Ko, Kwang-Hee;Kim, Byung-Jin;Lee, Ki-Chul;Choi, Byung-Min
    • Toxicological Research
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    • 제26권3호
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    • pp.233-236
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    • 2010
  • The analytical in vivo chromium ion was searched for using a voltammetric hollow-fiber dialysis sensor via square wave stripping voltammetry (SW), cyclic voltammetry (CV), and chronoamperometry. Under optimum parameters, the analytical results indicated linear working ranges of 50~400 mg/l CV and $10{\sim}80\;{\mu}g/l$ SW within a 30-sec accumulation time. The analytical detection limit (S/N) was $6.0\;{\mu}g/l$. The developed method can be applied to in vivo tissues and in ex vivo toxicity assay, as well as to other materials that require chromium analysis.

연료전지 버스용 (200kW급) 막가습기 개발 (Development of Membrane Humidifier for Fuel Cell Bus (200kW))

  • 이무석;강충석;윤영서;김경주;윤준기
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.471-473
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    • 2006
  • An object of the present study is to provide a hollow fiber membrane humidifier capable of improving the humidification efficiency while lowering the pressure loss, and is suitably usable for PEMFC(Polymer Electrolyte Membrane Fuel Cell). The performance of PEMFC is decisively dependent on the humidity of the electrolyte membrane(fluorinated membrane) and a humidifier plays an important role in moisturizing electrolyte membrane. Especially this humidifier is adaptable for lower price to promote the commercialization of fuel cell vehicles and is passive type to be power free and to be volumetrically optimized. In this research, we propose the substitutes for the expensive fluorinated materials and the optimum dry-jet wet spinning conditions of hollow fiber membrane to get the fuel cell humidifier. In addition to that we established the standard method of evaluating the moisturizing performance of the humidifier of various materials.

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Hollow cathode discharge에서 자발적 진동의 광검류 신호 측정 (Observation of spontaneous oscillation of optogalvanic signal in a hollow cathode discharge)

  • 이준회
    • 한국진공학회지
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    • 제12권1호
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    • pp.51-54
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    • 2003
  • 아르곤 방전 기체의 음 글로우 영역에서 자발적 직동의 광검류 신호를 관찰하였다. 자발적 진동의 광검규 신호는 3 mA 보다 낮은 땅선 전류에서 나타난다. 준안정 준위의 인자 밀도 변화와 1s-2p 전이의 방출 세기를 동시에 측정한 결과, 자발적 진동 신호를 발생시키는 메커니즘 중의 한 가지는 느린 전자의 충돌에 의한 준안정 준위 원자의 단계적 이온화이다.

Genetic algorithm optimization of precast hollow core slabs

  • Sgambi, Luca;Gkoumas, Konstantinos;Bontempi, Franco
    • Computers and Concrete
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    • 제13권3호
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    • pp.389-409
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    • 2014
  • Precast hollow core slabs (HCS) are technically advanced products in the precast concrete industry, widely used in the last years due to their versatility, their multipurpose potential and their low cost. Using three dimensional FEM (Finite Element Method) elements, this study focuses on the stresses induced by the prestressing of steel. In particular the investigation of the spalling crack formation that takes place during prestressing is carried out, since it is important to assure the appropriate necessary margins concerning such stresses. In fact, spalling cracks may spread rapidly towards the web, leading to the detachment of the lower part of the slab. A parametric study takes place, capable of evaluating the influence of the tendon position and of the web width on the spalling stress. Consequently, after an extensive literature review on the topic of soft computing, an optimization of the HCS is performed by means of Genetic Algorithms coupled with 3-D FEM models.

A356 중공 주조 샤시 부품에서의 국부적인 인장 변형 특성에 미치는 미세 조직 분석 (Microstructural Analysis of Local Tensile Deformation Characteristics in A356 Hollow Sand Cast Chassis Part)

  • 김재중;고영진;임종대
    • 한국자동차공학회논문집
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    • 제18권6호
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    • pp.1-6
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    • 2010
  • Aluminum rear lower arm is designed for luxury sedan and manufactured by hollow sand casting in the present study. Here we present the relationship between local microstructure and coupon tensile test in the rear lower arm. The characteristics of the local tensile deformation are supposed to be dependent upon Si distribution and DAS (dendrite arm spacing). Si distribution affects the yield strength and DAS affects the elongation of local area in the part, respectively.

기공 형성제 조절과 소결 온도의 변화가 다공질 지르코니아 세라믹스의 미세구조 및 강도에 미치는 영향 (Effect of Pore Formers and Sintering Temperatures on Microstructure and Bending Strength of the Porous Zirconia Ceramics)

  • 이은정;송인혁;하장훈;한유동;김양도
    • 한국분말재료학회지
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    • 제18권6호
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    • pp.502-509
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    • 2011
  • In this study, a novel-processing route for fabricating microcellular zirconia ceramics has been developed. The proposed strategy for making the microcellula zirconia ceramics involved hollow microspheres as pore former. Compared to conventional dense microspheres pore former, well-defined pore structured zirconia ceramics were successfully fabricated. Effects of hollow microsphere content and sintering temperature on microstructure, porosity, pore distribution, and strength were investigated in the processing of microcellular zirconia ceramics.