• 제목/요약/키워드: Hole injection layer

검색결과 197건 처리시간 0.023초

유기발광 소자의 수송층 두께 변화에 따른 발광효율 연구 (Study of OLED luminescence efficiency by Hole Transport layer change)

  • 이정호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.1002-1006
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    • 2004
  • The studies on OLED(Organic Light-Emitting Diode) materials and structures have been researched in other to improve luminescence efficiency of OLED. Electrons and holes are injected into the devices, transported across the layer and recombine to form excitons, their profiles are sensitive to mobility velocity of electrons and holes. A suggested means of improving the efficiency of LEDs would be to balance the injection of electrons and holes into light emission layer of the device. In this paper, we demonstrate the difference of velocity between hole and electron by experiments, and compare with a data of simulation and experiment changing hole carrier transport layer thickness, so we get the optimal we improve luminescence efficiency. We improve understanding of the various luminescence efficiency through experiments and numerical analysis of luminescence efficiency in the hole carrier transport layer's thicknes.

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정공 주입층 Copper(II)-phthalocyanine의 결정 변화에 따른 유기발광소자의 발광특성연구 (EL Properties of OLEDs with Different Crystal Structures of Hole Injection Layers of Copper(II)-phthalocyanine)

  • 임은주;이기진;한우미;이정윤;차덕준;이용산;김진태
    • 한국전기전자재료학회논문지
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    • 제16권2호
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    • pp.113-119
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    • 2003
  • We report the electrical properties of copper(II)-phthalocyanine(Cu-Pc) as a hole injaction layer in organic light-emitting diode (OLED). OLEDs were constructed by the following material structure : indium tin oxaide (ITO)/ CuPc/ triphenyl-diamine (TPD)/ tris-(8-hydroxyquinoline)aluminum (Alq3)/4-(Dicyanomethlene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM)/ Al. we observed that the change of recombination zone by using a DCM detection thin layer (6 ${\AA}$) in a Alq$_3$ emitting layer. layer. Recombination zone was moved toward the cathode as the hole mobility increased due to the heat-treatment temperature of cupc layer increased.

Synthesis of Conjugated Polymers with Fluorene and Biphenylamine and Application to PLED Devices

  • Park, Eun-Jung;Kwon, Hyeok-Yong;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.458-460
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    • 2008
  • Four kinds of copolymers with fluorene and biphenylamine units were synthesized by palladium-catalyzed polycondensation reaction. These polymers were characterized in terms of their UV/Visible and photoluminescence (PL) properties in solution and film state. These polymers were also studied as a hole transporting material in the polymer light emitting diode (PLED) devices.

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정공수송층의 변화에 따른 청색 유기 발광 소자의 특성 (Characteristics on the Variation of Hole transporting layer of Blue organic light-emitting diodes)

  • 김구영;박정현;서지훈;이금희;윤승수;김영관
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.434-435
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    • 2007
  • We have demonstrated the characteristics on the variation of hole transporting layer in blue organic light-emitting diodes (OLEDs) using new blue fluorescent emitter. We fabricated two types of hole transporting layer structures that one is 4,4',4"-Tris(N-(2-naphthyl)-N-phenyl-amino)-triphenylamine (2-TNATA) of $600{\AA}$ as a hole injection layer, N,N'-diphenyl-N,N'- (2-napthyl)-(1,1'-phenyl)-4,4'-diamine (NPB) of $200{\AA}$ as a hole transporting layer and another device is NPB of $500{\AA}$ without the 2-TNATA. The devices without the 2-TNATA showed improved characteristic of the luminance and efficiency.

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정공 주입층 및 수송층에 따른 고분자 유기발광다이오드의 특성 연구 (The Properties of Hole Injection and Transport Layers on Polymer Light Emitting Diode)

  • 신상배;장호정
    • 마이크로전자및패키징학회지
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    • 제14권4호
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    • pp.37-42
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    • 2007
  • 본 연구에서는 ITO/PEDOT:PSS/PFO:MEH-PPV/LiF/Al의 구조를 갖는 고분자 유기발광다이오드를 제작하여 정공 주입층으로 사용되는 PEDOT:PSS의 두께 변화와 PVK 정공 수송층을 도입하여 ITO/PEDOT:PSS/PVK/PFO:MEH-PPV/LiF/Al 구조를 갖는 고분자 유기발광 다이오드를 제작하여 정공수송층이 유기발광다이오드의 전기 광학적 특성에 미치는 영향에 대하여 조사, 비교하였다. 실험에 사용된 모든 유기물은 플라즈마 처리된 ITO/glass 기판위에 스핀 코팅법으로 도포하였다. 정공 주입층인 PEDOT:PSS 두께를 약 80 nm에서 50 nm로 감소한 경우 PLED 소자의 휘도는 약 $220cd/m^2$ 에서 $450cd/m^2$으로 크게 증가하였다. 이러한 결과는 정공 주입층의 두께가 감소할수록 ITO 전극에서 발생한 정공이 보다 쉽게 발광막으로 전달되기 때문이다. 또한 PVK 정공 수송층을 도입한 PLED소자에서 최대 전류밀도와 휘도는 $268mA/cm^2$$540cd/m^2$ (at 12V)의 값을 각각 나타내었다. PVK 정공 수송층이 도입되지 않은 소자에 비해 전류밀도는 약 14%, 휘도는 약 22%의 특성개선을 나타내었다.

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모의시험에서 정공 주입층 물질 AF의 에너지 갭이 OLED의 전기적 특성에 미치는 영향 (Effect on Electrical Characteristics of OLEDs According to Energy Gap for HIL of Amorphous Fluoropolymer Materials by Simulation)

  • 한현석;김정식;김원종;이종용;소병문;김태완;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.33-33
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    • 2010
  • Electrical properties of organic light-emitting diodes (OLEDs) were simulated by S.co's program. The OLEDs have stable operating parameters, high luminance, and high efficiency in simulation. The AF stands for amorphous fluoropolymer in simulation, and it was used as a hole-injection layer. In the five structure of OLEDs, an AF layer is sandwiched between the hole-transport layer and the ITO layer to increase the external quantum efficiency. By considering organic light-emitting diodes using an optimal energy gap of AF, it could contribute to the improvement of the efficiency of the device in the simulation.

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Effects of PEDOT:PSS Buffer Layer in a Device Structure of ITO/PEDOT:PSS/TPD/Alq3/Cathode

  • Ahn, Joon-Ho;Lee, Joon-Ung
    • Transactions on Electrical and Electronic Materials
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    • 제6권1호
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    • pp.25-28
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    • 2005
  • We have investigated the effects of hole-injection buffer layer in organic light-emitting diodes using poly(3,4-ethylenedioxythiophene):poly(stylenesulfonate)(PEDOT:PSS) in a device structure of $ITO/PEDOT:PSS/TPD/Alq_{3}/cathode$. Polymer PEDOT:PSS buffer layer was made by spin casting method. Current-voltage, luminance-voltage characteristics and efficiency of device were measured at room temperature with a variation of cathode materials; Al, LiF/Al, LiAl, and Ca/Al. The device with LiF/Al cathode shows an improvement of external quantum efficiency approximately by a factor of ten compared to that of Al cathode only device. Our observation shows that cathode is important in improving the efficiency of the organic light-emitting diodes.

다층구조 Organo-lanthanide OLED의 전기적 특성 (Electrical Properties of Multi-layer Organo-lanthanide OLEDs)

  • 하미영;김소연;문대규
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 학술대회 및 기술세미나 논문집 디스플레이 광소자
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    • pp.83-84
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    • 2006
  • ITO/4, 4', 4"-tris (N -3 - methylphenyl - N - phenyl - amino) - triphenylamine, [m-MTDATA] / Terbium Iris - (1 - phenyl - 3 - methyl - 4 - (tertiarybutyryl) - pyrazol - 5 - one) triphenylphosphine oxide [$(tb-PMP)_3Tb-(Ph_3PO)$] / Mg:Ag devices were made to investigate its electrical and light emission properties. The thickness of m-MTOATA layer was varied from 0 to 80 nm. There was a threshold thickness for the sufficient hole injection. The insertion of 20 nm thick m-MTDATA layer between ITO and Tb-complex resulted in the right shift of current-voltage curve because of the insufficient hole injection. The low operating voltage can be obtained above the 40 nm of m-MTDATA layer. The insertion of m-MTDATA induced the increase of the background in the electroluminescence spectrum which was dependent on the current density of the devices.

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Polymeric hole-injection layer for high-efficiency and long-lifetime in organic light-emitting diodes

  • Choi, Mi-Ri;Han, Tae-Hee;Woo, Seong-Hoon;Lim, Kyung-Geun;Yun, Won-Min;Kwon, Oh-Kwan;Park, Chan-Eon;Shin, Hoon-Kyu;Hur, Dal-Ho;Shin, Kyoung-Hwan;Jang, Jyong-Sik;Lee, Tae-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.781-783
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    • 2009
  • We achieved high efficiency and long lifetime in small-molecule organic light-emitting diodes using a blend of polyaniline-based conducting polymer and a perfluorinated ionomer as a hole injection layer (HIL). The HIL formed by single spin coating greatly enhanced the surface work function and thus the hole injection from the anode, which resulted in great improvement in device luminous efficiency. We find that the solution processed HIL outperforms the conventional vacuum-deposited small molecule HIL in terms of the device performance.

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유기 능동 소자 제작을 위한 신소재 연구 (A Study on New Materials for Organic Active Devices)

  • 이성재;임성택;신동명;최종선;이후성;김영관;손병청
    • 한국응용과학기술학회지
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    • 제17권3호
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    • pp.174-177
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    • 2000
  • The effect of a-sexithiophene(${\alpha}-6T$) layers on the light emitting diode (LED) were studied. The ${\alpha}-6T$ was used for a buffer layer in electroluminescent (EL) devices. Enhanced carrier (hole) injection and improved emission efficiency were observed. Carrier injection characteristics were investigated as a function of ${\alpha}-6T$ later thickness. The efficiency of the electroluminescence was proportional to the thickness of ${\alpha}-6T$ layer. The highest efficiency was observed 600A of ${\alpha}-6T$ later, which was about 1.5 times higher than that of device without ${\alpha}-6T$ later. The device with a-6T showed an operation voltage lowered by 2V. The ${\alpha}-6T$ layer can substitute hole blocking layer, and control charge injection properties.