• Bulletin of the Korean Chemical Society
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• 제30권2호
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• pp.409-414
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• 2009

Novel binol aldehydes derivatized at 2' hydroxy position with both uryl and acetamide groups (2), and diuryl groups (3) have been synthesized. Both were designed for streospecific binding and chirality conversion of general dipeptides with support of multiple hydrogen bonding donor sites in the receptors. The receptors, 2 and 3, converted the chirality of N-terminal amino acids of peptides such as Ala-Gly, Met-Gly, Leu-Gly and His-Gly with stereoselectivity on D-form over L-form. The stereoselectivity ratios were in the range of 5-11, somewhat higher than those of the binol receptor with mono uryl group (1). The DFT calculation at the B3LYP/6-31G$^*$//MPWB1K/6-31G$^*$ level revealed that 3-D-Ala-Gly was 2.2 kcal/mol more stable than 3-L-Ala-Gly. The considerable steric hindrance between the methyl group of the alanine and the imine CH moiety of the receptor seems to be the main contributing factor for the thermodynamic preference.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.293-300
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• 2018

Reduced graphene oxide (rGO) nanosheets were patterned with poly[benzodithiophene-bis(decyltetradecyl-thien) naphthothiadiazole] (PBDT-DTNT) and poly[bis(triiso-propylsilylethynyl) benzodithiophene-bis(decyltetradecyl-thien) naphthobisthiadiazole] (PBDT-TIPS-DTNT-DT) and used in photovoltaics. Conductive patternings changed via surface modification of rGO; because polymers encountered a high hindrance while assembling onto grafted rGO. The best records were detected in indium tin oxide (ITO):poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS):PBDTDTNT/rGO:PBDT-DTNT:LiF:Al devices, i.e., short current density $(J_{sc})=11.18mA/cm^2$, open circuit voltage $(V_{oc})=0.67V$, fill factor (FF) = 62% and power conversion efficiency (PCE) = 4.64%. PCE increased 2.31 folds after incorporation of PBDT-DTNT into thin films. Larger polymer assemblies on bared-rGO nanosheets resulted in greater phase separations.

• 한국환경과학회지
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• 제23권9호
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• pp.1563-1572
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• 2014

The autecology of the Zostera marina and Z. japonica was studied in populations growing in the same locality (Sagumi Bay, southwestern coast of Korea). Environmental factors and plant characteristics were examined monthly from August 2008 to September 2011. Along intertidal zone, Z. japonica (0.1-0.5 m above mean lower low water, MLLW) occurred above Z. marina (0.5-2.5 m MLLW). Tidal exposure at low tide during day was the highest in the spring and the lowest in the summer. Underwater Irradiance showed seasonal fluctuation that was the highest in spring and summer caused by tidal pattern. Strong seasonal patterns in water temperature appeared to control the seasonal variations in morphology, biomass and leaf growth. The seasonal pattern of Z. japonica resembled that of the Z. marina in morphological characteristics, above-and below-ground biomass, whereas it differed in shoot density and leaf elongation. Despite some similarities in seasonal growth patterns, the patterns of Z. japonica were lagged by 2 month of Z. marina. Seasonal variation in the above biomass of Z. marina was caused by changes in density and plant size, whereas that of Z. japonica was mainly caused by changes in shoot density. Zostera marina was more sensitive to high temperatures than Z. japonica, and the increasing water temperature during the summer became the factor that inhibits the growth of the Z. marina. Zostera Japonica, there is no clear change according to the amount of the light. It is because its habitat locates above that of Zostera marina so that the amount of the light that is necessary to growth is enough and in this condition, any preventing factor does not seem to work at all. Although underwater light getting into Zostera marina's habitat is very low level and there is no any hindrance to the survival of them, it prevents them from their productivity a bit.

• 디지털융복합연구
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• 제10권9호
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• pp.59-72
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• 2012

이 연구는 수사경찰의 조직역량이 조직몰입에 미치는 영향을 실증적으로 분석하는데 목적을 두었다. 연구의 목적을 달성하기 위하여 조직역량에 대한 개념을 정립하고 수사경찰의 조직역량이 조직몰입에 미치는 영향에 대한 인식과 그 상관관계를 검증하기 위한 지표를 설정하기 위해서 경영학과 행정학의 선행연구들을 검토하여 실증적 연구를 위한 이론적 배경을 구축하였다. 조직역량이 조직몰입에 미치는 영향에 관한 이론적 배경을 중심으로 조사연구를 설계하였으며 따라서 관련 선행연구와 문헌조사 및 공식통계 자료의 분석, 조사대상 집단의 설문조사 항목을 변수화하여 SPSS Window 18.0통계패키지를 이용하여 통계분석을 실시하였다. 수사경찰의 조직역량이 조직몰입에 영향을 미치는 것은 당연함에도 불구하고 지금까지 이 분야에 대한 연구는 매우 부족한 실정이다. 이 연구는 수사경찰의 조직역량이 조직몰입에 미치는 영향의 분석을 통해 궁극적으로는 수사경찰이 사회질서유지에 기여할 수 있는 효율적인 조직을 설계하고 유지하고자 하는데 그 목적이 있다.

• 미생물학회지
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• 제50권3호
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• pp.239-244
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• 2014

ErmSF는 macrolide 항생물질인 tylosin을 생성하는 Streptomyces fradiae가 보유한 4개의 항생제 내성인자 단백질 중 하나로 23S rRNA의 $A_{2058}$에 dimethylation 시킴으로써 항생제가 부착되는 것을 막음으로써 그 내성을 일으킨다. ErmSF는 다른 Erm 단백질과는 달리 긴 N-terminal end region을 가지고 있어서 그 역할을 알아보기 위해 1-38번째의 아미노산을 제거한 결손변이 단백질을 고안하고 대장균에서 발현하여 그 활성을 in vivo와 in vitro에서 관찰하였다. 결손변이 단백질을 발현하는 대장균은 결손에 의한 활성저하에 기인하여 야생형 단백질을 발현하는 대장균에 비하여 항생제에 대한 내성이 손상된 것을 관찰하였다. 세포 외 in vitro에서의 활성은 야생형 ErmSF에 비하여 약 20%가 손상된 것으로 나타났다. 이렇게 관찰된 활성의 저하는 결손 변이에 의한 활성화 부위에서 일어난 결손에 의한 것이라기 보다는 기질의 부착 또는 생성물의 효소에서의 이탈 과정이 손상되어서 나타나는 것으로 사료된다.

• 한국산학기술학회논문지
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• 제18권4호
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• pp.428-437
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• 2017

최근 지자체는 난개발과 도시경관 저해, 기존 관련법에 따른 제어한계등의 과제를 해결하기 위해서 각 지역의 특성에 맞는 추진전략을 수립하고 있다. 이를 위해서 사업승인을 위한 별도 기준을 마련하여 경관, 색채, 외관, 층수계획등을 준수하도록 유도하고 있다. 층수계획은 도시경관과 계획밀도 및 외부공간의 질을 결정하는 중요한 인자이고 지구여건에 따라 매우 다른 양상을 나타내는 변화요인이다. 또한 각 지구의 용적률이나 건설호수에 따른 지하주차장 설치비율, 녹지율 등에 따라 매우 다른 경향을 보이는 주요인자이다. 그러나 지자체는 지역특성을 감안하지 않고 일률적으로 저층화 지향의 층수를 규제하여 지구특성을 살리지 못하고 있다. 따라서 본 연구에서는 지구별 사례분석과 가배치안 검토를 통하여 각 지표간 상관관계를 규명하여 다음과 같은 결론에 도달하였다. 첫째, 관련법과 제도에 밀도지표제, 평균층수제, 주거환경성능제 등을 도입해 융통성을 확보하여야 한다. 둘째, 계획초기부터 인접불럭 또는 도시까지 개념을 확대하는 광역적인 계획기법을 개발하여야 한다. 셋째, 지역별 특화전략 수립과 권장형의 규제방안 등 규제완화 조치를 시행하여야 한다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.137.1-137.1
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• 2010

For Indonesia, sustainable energy supply is an important factor to preserve the stable economic growth. One important strategy is development of renewable energy, which has not been fully exploited yet. The paper examines the potency of renewable energy in Indonesia. Currently, biomass composes 23% of total primary energy supply, while geothermal and hydropower has a combined share of 3%. But according to the overall potency of renewable energy, hydropower is found to have the highest available resource of 76 GW, followed by biomass and geothermal by 49.81 GW and 28.53 GW, respectively. Although the solar radiation is only at modest level ($4.80kWh/m^2/day$), the tropical all year sunlight can boost the competitiveness of solar photovoltaic and thermal application. As for wind energy, the average speed of 3-6 m/s requires the development of low speed wind turbine. The examination of electricity and petroleum product prices through international comparison for non-OECD countries shows fifth lowest price level for both of petroleum products and electricity for industrial use. As for household electricity price, Indonesia is placed the second among all the countries compared. The energy subsidy and price structure are examined in detail because it could be a source of hindrance to renewable energy promotion. The examination of renewable energy potency in this study could provide insights about recent development of renewable energy in Indonesia. As an outcome of policy examination, the price comparison analysis suggests Indonesia to reduce or even remove the energy subsidies in the long run. These findings can be utilized to formulate effective policies for renewable energy promotion.

• Journal of Radiation Protection and Research
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• 제18권1호
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• pp.53-61
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• 1993

홀수 핵종인 $^{75}As$의 핵 구조를 분광학적 방법으로 연구하기 위하여 $^{75}Se$의 전자 포획에 의하여 방출되는 감마선에 대해 단일 감마선 측정과 감마-감마 동시측정 실험을 하였다. 본 실험에서 구한 각 상관관계 계수는 $A_{22}=-0.452{\pm}0.017,\;A_{44}=0$이고 279.5keV 전이 감마선에 대한 혼합비는 ${\delta}=-0.586{\pm}0.017$을 얻었다. 또한 낮은 준위에서의 에너지의 상대 강도를 정확히 측정한 후 이를 이용하여 환산 행렬 요소들을 계산한 후 단일 입자 모형의 관점에서 hindrance factor를 구했다. 그 결과 279.5 keV 감마 전이의 다중극도는 74.44%의 Ml 전이와 25.56%의 E2 전이를 포함한 혼합 전이이며 5/2 준위의 밴드구조를 $f_{5/2}$ proton준위에 바탕을 둔 1/2 [310]으로 결정하였다.

• 상하수도학회지
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• 제22권2호
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• pp.259-265
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• 2008

Generally speaking, there are two widely used methods of Nitrogen removal from waste water: 1) nitrification using autotrophic microorganisms, and 2) denitrification using heterotrophic microorganisms. The C/N ratio is an important factor of the denitrification process. In this case, if methanol is added to increase the lacking organic matter, a high economic cost is incurred and methanol is left in the processed water. In an effort to fix these issues, autotrophic denitrification through the use of Hydrogen, Iron and Sulfur is being studied, and among those Sulfur is cheaper and carries out denitrification effectively, and therefore is being studied the most. In this study, after cultivating T. denitrificans, the presence of T. denitrificans was determined and the effectiveness of denitirification via T. denitrificans was studied. In order to find out about the inhibition of T. denitrificans from the loading of organic matter, this shows that the greater the loading of organic matter, the more the denitrification ability of T. denitrificans is hindered. In order to research the hindrance of T. denitrificans resulting from the loading of $NO_3{^-}-N$, these results show that concentrations less than 100mg/L per 100mL of gel volume do not hinder T. denitrificans. In order to research the optimization of denitrification resulting from T. denitrificans, three 500mL samples of Sulfur granules were prepared: 1) one with only T. denitrificans attached (Mode I), 2) one with both T. denitrificans and active sludge attached (Mode II), and 3) one with only active sludge attached (Mode III). The results showed that autotrophic denitrification using S from Mode I was the most active.

• 한국물환경학회지
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• 제25권6호
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• pp.902-909
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• 2009

With various reservoirs, dams and reduction of water velocity in downstream, rivers in Korea often have characteristics of accumulation of pollutants. Therefore, the main focus of water quality modeling in Korea needs to be shifted from DO to algae and organic matter. Moreover the structures of water quality models should be modified to have capability of simulating BOD which is a key factor of total water pollution load management in Korea as laboratory experiment BOD (Bottle $BOD_5$). In the SWAT model which is one of the widely used water quality models in Korea, the channel water quality module is using main algorithm of the QUAL2E model which has limitations in simulating algae, organic matter and Bottle BOD5 etc. To overcome this hindrance, in this study, the improved channel water quality module of the SWAT model (Q-SWAT) was proposed by linking the algorithms of the QUAL-NIER model which was developed based on the QUAL2E model to the SWAT model. The algorithms estimating the increase of internal organic matter by fractionization algal metabolism process and calculating Bottle $BOD_5$ were added and the results of proposed model were compared to those of the original SWAT model. The results of comparison test are showing that more accurate BOD values can be obtained with the Q-SWAT model and it is anticipated that the Q-SWAT model can be used as an effective tool of decision support through the water quality simulation and long term pollution source analysis.