• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.137-138
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• 2017

한반도의 근해는 다양한 해양변화가 있으며, 작전을 수행하는 해군함정, 함재기, 해상운용 비행기, 공군의 전투기, 해안에 위치한 공항 및 비행장 등이 영향을 받는다. 특히 해양환경의 직접적인 영향인 염분은 가스터빈엔진과 같이 고온/고속으로 운용되는 장비에 연료의 황성분과 화학적 변화로 고온부식(Hot Corrosion)이 발생시킨다. 한계값으로 정의 할 수 없지만 염분에 의한 부식은 디미스터(공기흡입구) 높이가 7m 이하일 경우 해상에서 유입되는 염분이 증가하여 부식이 급격하게 증가하였다. 또한 서해보다 동해에서 작전임무를 수행하는 무기체계는 염분도, 풍량, 파고에 의해 비산되는 염분이 상대적으로 많아 부식율이 17% 증가함을 확인하였다. 해상에서 가스터빈엔진을 운용하는 해상무기체계는 염분유입을 최소화하기 위해 해상으로부터 13m이상에서 운용되어야 급격한 고온부식을 최소화 될 것으로 본다.

• Journal of Advanced Marine Engineering and Technology
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• 제28권2호
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• pp.217-227
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• 2004

The bowl in a ship purifier suffers from high stress and high temperature in a detrimental heavy fuel oil environment. Duplex stainless steel(DSS) is a primary material to withstand this harsh condition. Newly-manufactured STS 329 grade DSS has been evaluated by various mechanical and electrochemical test methods. Eight heat treatment(HT) conditions with different temperature and time were applied to the DSS samples to improve corrosion resistance. Microstructure and polarization test results concluded the optimum HT condition was $1.090^{\circ}C$-60 minutes. Confirmation experiments for applying to a real bowl including stress corrosion cracking test exhibited the reproducibility of the optimum HT condition.

• 한국주조공학회지
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• 제40권5호
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• pp.129-133
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• 2020

The outcomes of solution annealing and stress corrosion cracking in cold-worked 316L austenitic stainless steel have been studied using x-ray diffraction (XRD) and the slow strain rate test (SSRT) technique. The good compatibility with a high-temperature water environment allows 316L austenitic stainless steel to be widely adopted as an internal structural material in light water reactors. However, stress corrosion cracking (SCC) has recently been highlighted in the stainless steels used in commercial pressurized water reactor (PWR) plants. In this paper, SCC and inter granular cracking (IGC) are discussed on the basis of solution annealing in a chloride environment. It was found that the martensitic contents of cold-worked 316L stainless steel decreased as the solution annealing time was increased at a high temperature. Moreover, mode of SCC was closely related to use of a chloride environment. The results here provide evidence of the vital role of a chloride environment during the SCC of cold-worked 316L.

• 한국표면공학회지
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• 제30권1호
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• pp.33-43
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• 1997

The effects of process parameters substrate such as substrate current and substrate temperature on the corrosion resistance of ion plated TiN film were investigated. TiN fims were deposited on speed steel on which Ti or Ni hed been previously evaporated. Dense TiN films could be obtained under higher substrate current(1A) and substrate temperature($500^{\circ}C$), whereas TiN films deposited with lower substances current(0.5A) and substrate temperature($300^{\circ}C$) showed porous structure. The corrosion resistances of high speed steel was considerably increased when dense TiN films had been formed on it. The effect of Ti and Ni interlayer on the increase of the corrosion resistance was also significant with dense TiN films, while there was little effect of interlayer on the corrosion resistance when TiN films were porous. the effect of interlayer on the corrosion resistance was more outstanding with Ti then with Ni, because Ti reacts more easily with oxygen to form an oxide layer, and it also shows higher resistance against chlorine containing corrosion media.

• Corrosion Science and Technology
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• 제22권5호
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• pp.351-358
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• 2023

Although many thermal power plants use heat recovery systems, high exhaust gas temperatures are maintained due to corrosion at dew points and ash deposits caused by condensate formation. The dew point of exhaust gas is primarily determined by the concentration of SO₃ and steam, and various experiments and calculation equations have been employed to estimate it. However, these methods are known to be less suitable for exhaust gases with low SO₃ concentrations. Therefore, in this study, since the temperature of the exhaust gas is expected to decrease due to the low-load operation of the coal-fired power plant, sulfuric acid condensation and low-temperature corrosion are anticipated. We aimed to conduct a quantitative evaluation to propose ways to prevent damage by limiting operating conditions and improving facilities. The experimental results showed that the corrosion rate increased linearly with rising temperatures at a certain sulfuric acid concentration. Furthermore, variations in sulfuric acid concentrations generated during the current power plant operation process did not significantly affect the dew point, and the dew point of sulfuric acid under these conditions was observed to be between 120 - 130 ℃.

• 한국주조공학회지
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• 제24권4호
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• pp.209-216
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• 2004

High silicon cast irons(HSCI) with the high acid resistance have been used for the prevention of acid corrosion occurring in various structures under acid conditions. However, the HSCI is only known as one of materials which have high acid resistance, but few work has dealt with this material in domestic. Therefore, in this study, the acid resistance of various cast irons with alloying elements and melting conditions have been examined, and studied the influences of the matrix structures, mechanical properties and morphologies of graphite. The results obtained in this study are as follows : In case of melting temperature, the mechanical properties of specimen manufactured with high temperature of $1650^{\circ}C$ showed higher value because the inclusion and impurity were removed. In case of pouring temperature, the mechanical properties of specimen fabricated below $1350^{\circ}C$ of pouring temperature showed higher value because the amount of gas absorption from atmosphere decreased during the solidification time. The corrosion rate decreased with increase in Si content. On the other hand, Mn addition appeared an opposite trend with Si.

• 플랜트 저널
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• 제4권2호
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• pp.60-65
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• 2008

As the operating conditions in a supercritical oxidation reactor are set in high temperature with high pressure causing a reactor suffering from the harsh circumstances. It means the reactor adopts itself with Fe-Cr alloy in acidic atmosphere with low pH value and Ni alloy in basic atmosphere with high pH value due to its superior corrosion resistance. The study, whose target waster water is pertinent to the latter part, has selected Ni alloy such as ostenite type stainless steel 304 and 316, superstainless steel AL6XN, Inconel 625, MAT 21, and titanium Gr. 5 in order to measure corrosion resistance against those samples under the same conditions of temperature and pressure applied for a supercritical oxidation reactor. The result shows the identifiable difference in corrosion resistance by observing the surface states through a scanning probe microscope as well as measuring the weight loss through making the samples above deposited in wastewater for two-week and four-week stay. The purpose of this corrosion experiment is to identify the most corrosion-resistant material among sample species pre-selected according to pH concentration of wastewater in pursue of applying for a reactor exposed to the extreme corrosion environment. It is because such a reactor made of a verified material enables to safeguard a stable operation under the supercritical wastewater processing facility.

• 한국표면공학회지
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• 제40권5호
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• pp.219-224
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• 2007

The corrosion characteristics of Fe-18Cr-10Ni steels were studied between $600^{\circ}C$ and $1000^{\circ}C$ in Ar+(0.2, 1)%$SG_2$ gas for up to 300 hr in order to employ Fe-18Cr-10Ni steels in the coal-fired power plants. The corrosion resistance of Fe-18Cr-10Ni steels was good due mainly to the high amount of Cr, which formed $Cr_2O_3$ from the initial corrosion stage. Fe in the steels corroded to mainly $Fe_2O_3$ and $Fe_3O_4$. Ni was not susceptible to corrosion under the current corrosion condition. Relatively thin, single-layered scales formed.

• Corrosion Science and Technology
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• 제20권6호
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• pp.367-372
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• 2021

The effect of carbon addition on the general corrosion behavior of high-chromium cast iron (HCCI) was studied by a scanning electron microscope with energy dispersive spectroscopy (SEM-EDS) or electron back-scattered diffraction (EBSD), or electrochemical polarization techniques in 0.1 mol dm^-3 H₂SO₄ + 0.05 mol dm^-3 HCl at room temperature. The addition of 2.1-2.8 wt% carbon to HCCI increased the fraction of eutectic austenite and eutectic carbide phases, while that of HCCI decreased the fraction of the primary austenitic phase. Potentiostatic polarization of the HCCI at -0.35 V_SSCE or 0.0 V_SSCE resulted in preferential general corrosion of the primary austenitic or eutectic austenitic phases, respectively. The decrease in corrosion current density and the shift in noble corrosion potential direction with increasing carbon content in the HCCI indicated that the fraction and the chemical composition of austenitic (primary and eutectic) and carbide phases were strongly related to the general corrosion behavior of the HCCI.

• 방사성폐기물학회지
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• 제3권1호
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• pp.31-40
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• 2005

발전소 내 방사화 부식생성물의 대부분을 차지하고 있는 니켈 페라이트계 부식생성물을 모사 발생시키기 위한 고온 고압용 장치를 제작하여 연구를 수행하였다. 배관형 포집기를 이용한 부식생성물 발생장치로부터 방사화 부식생성물과 가장 유사한 부식생성물을 얻을 수 있었다. 발전소에서 입자성 부식생성물이 발생되는 원리인 온도에 따른 용해도 차이를 구현하기 위하여 270$\^{circ}$C에서 부식반응이 일어나 상대적으로 높은 온도를 가진 포집용 장치에 부식생성물이 포집되도록 장치를 제작하였으며 , 발생된 부식생성물은 주사전자현미경 관찰과 EDAX를 통한 조성분석으로 그 특성을 관찰하였다. 부식생성물은 포집 된 위치 에 따라서 침상 형태의 산화물과 결정 형태의 산화물로 나뉘었으며, 조성 분석 결과 결정 형태의 부식생성물이 니켈 페라이트로서 발전소에서 발생되는 입자성 부식생성물과 유사한 것을 알 수 있었다.