• 제목/요약/키워드: High-pressure experiment

검색결과 985건 처리시간 0.032초

초임계수에서 Cephradine 산화반응속도 (Fundamental Kinetics of Cephradine Oxidation in Supercritical Water)

  • 김영권;김인배
    • 한국환경보건학회지
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    • 제30권2호
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    • pp.133-139
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    • 2004
  • The objective of this study was to investigate the destruction efficiency and to determine the fundamental parameters of oxidation kinetics under the supercritical water(SCW) condition. Target material was cephradine, toxic and antibiotic material, in the pharmaceutical wastewater. For this purpose, the effect of reaction temperature and oxidant were investigated on the destruction efficiency of cephradine. And the oxidation kinetics of cephradine was derived by using a empirical power-law model. The experiment was carried out in a cylindrical batch reactor made of Hastelloy C-276 which was endurable high temperature and pressure. The destruction efficiency of cephradine increased with increment of the temperature and reaction time. Also the type of oxidants was effected and oxidants(Air and $H_2O$$_2$) were enhanced the destruction efficiency. The global oxidation kinetics for cephradine has led to two rate expressions according to type of oxidant. - In the presence of air oxidant: Rate=k. $e^{-Ea}$RT/(Ceph.)$^{1.0}$ ( $O_2$)$^{0.51}$$\pm$0.05(k=3.27${\times}$$10^{5}$ sec. Ea=63.25 kJ/mole) - In the presence of $H_2O$$_2$ oxidant : Rate=kㆍ $e^{-Ea}$RT/(Ceph.)$^{1.0}$ ($H_2O$$_2$)$^{0.62}$$\pm$0.02(k=2.76${\times}$$10^4$/sec. Ea=47.65 kJ/mole)ole))

불평등 전계 하에서의 침전극 가공상태에 따른 SF6혼합가스의 방전특성 (Discharge Characteristics of SF6 Mixture Gases due to Processing Status of needle electrode under Non-Uniform Fields)

  • 고연성;서호준;이동희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.198-199
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    • 2006
  • AC spark discharge voltage of SF6/C02and SF6/N2 containing various mixed rate in volume percent (1, 5 and 10%) of SF6 in non-uniform fields are investigated. The needle to plane electrode gap spacing was 5 and 10 mm, and the gas pressure was varied within the range of 0.1${\sim}$0.7 MPa. We have observed a N-characteristic typical for the electronegative gases even in gas mixtures of 1% SF6 with CO2 and N2 as buffer gases. Especially, the materials of the needle electrode affect the insulation properties of the gas mixtures drastically. On the contrary to the case of needle electrodes made by mild steel or high carbon steel, the N-characteristics are hardly perceived in the case of stainless steel needle in this experiment.

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고강도 알루미늄 합금의 Fretting Fatigue에 관한 연구 (A Study on Fretting Fatigue of High Strength Aluminum Alloys)

  • 이학선;김상태;최성종;양현태;김재경;이동석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.168-173
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    • 2004
  • Fretting is a kind of surface degradation mechanism observed in mechanical components and structures. The fretting damage decrease in 50-70% of the plain fatigue strength. This may be observed in aircraft, automobile and nuclear power plant used in special environment and various loading conditions. In the present study, the characteristics of the fretting fatigue are investigated using the two aluminum alloy(Al2024-T3511 and Al7050-T7451). Through the experiment, it is found that the fretting fatigue strength of the Al7050-T7451 alloy decreased about 50% from the plain fatigue strength, while the fretting fatigue strength of the Al2024-T3511 alloy decreased about 45%. The tire track was widely observed in fracture surface area of oblique crack which was induced by contact pressure. These results can be the basic data to the structural integrity evaluation of aluminum alloy subjected to fretting damage.

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PF 열교환기를 적용한 공조기의 성능에 대한 실험연구 (Experimental Study on Performance of Air-conditioner with PF Heat Exchanger)

  • 서동남;엄유식;박경만;이상재;김대훈;권영철
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 동계학술발표대회 논문집
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    • pp.525-530
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    • 2008
  • In the present study, the cooling performances of the air-conditioner applied the fin-tube and aluminum PF heat exchangers have been experimentally investigated by using the calorimeter. The experiment is carried out in the conditions of the standard temperature and the low temperature. Fin type of PF heat exchanger is a triangler and squarer form. PF heat exchanger has smaller refrigerant weight and larger capacity and COP han the fin-tube heat exchanger. The performance of PF-2 heat exchanger with the squarer in is more excellent than that of PF-1 heat exchanger with the triangler fin. The high pressure of PF heat exchanger decreases about 7%, compared to the fin-tube heat exchanger. Also, CSPF of the fin-tube and PF heat exchanger is evaluated.

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커먼레일 디젤기관에서 분사전략에 따른 성능 및 배출가스에 관한 연구 (A Study on Characteristics of Performance and Emission by CRDI Engine's Injection Strategy)

  • 엄동섭;고동균;나완용;이성욱
    • 한국분무공학회지
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    • 제16권3호
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    • pp.134-139
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    • 2011
  • Recent research has focused on engine combustion technology as well as application of after-treatment in order to comply with emission regulation. However, it is much more efficient way to control emissions from engine itself and furthermore research on engine control will provide the direction of after-treatment technology in future. Furthermore, emission standard regulation for passenger diesel vehicles has been stringent compared to others and nano-particles will be included in EURO6 regulation in Europe and similar emission standard will be introduced in Korea. A 3.0 liter high speed diesel engine equipped with by CRDI system of 160MPa injection pressure, and an intake/exhaust system of V type 6 cylinder turbo-intercooler was applied. The injection duration and injection quantity, pilot injection types which are related to CRDI and air/fuel ratio control applied by EVGT were changed simultaneously. Standard experiment procedure constituted dilution apparatus and CPC system to collect nano-particles and these test results were compared with regulated materials of CO, HC, NOx and investigated their relations and characteristics of nano-particles.

능선형상의 유전체 구조를 갖는 AC-PDP의 Xe 함량 변화에 대한 발광특성 (Luminous Characteristics of AC-PDP with Ridged Dielectric Layer in Various Xe Contents)

  • 남문호;김정민;최시영
    • 대한전자공학회논문지SD
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    • 제41권8호
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    • pp.25-30
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    • 2004
  • 본 논문에서는 방전유지전극사이에 유전체 공극이 존재하는 능선형상의 상판구조를 제안하였다. 이 구조는 상판의 방전 유지 전극사이 강한 전계를 이용하여 동작전압을 감소시킬 수 있고 이로 인한 Xe의 주입비율을 증가시켜 휘도 및 발광효율을 향상시킬 수 있는 구조이다. 실험에서는 6인치 테스트 패널을 사용하였으며 기체 압력을 450 torr로 유지하면서 Xe 함량을 10 %, 15 %, 20 %, 30 %, 50 %로 변화하여 실험하였다. 실험결과, 10 %의 동일한 Xe 기체를 주입한 결과, 제안된 구조를 적용할 경우, 방전개시전압과 방전유지전압이 각각 79 V, 74 V 감소하였으며 10 %의 Xe을 주입한 일반적인 구조와 50 %의 Xe을 주입한 제안된 구조의 휘도와 발광효율 비교에서 본 논문에서 제안한 구조가 비슷한 구동전압 범위에서 일반적인 구조에 비하여 효율은 50.9 % 향상되었고, 휘도는 33 % 향상됨을 알 수 있었다.

Robust Design of Main Control Valve for Hydraulic Pile Hammer Flexible Control System

  • Guo, Yong;Hu, Jun Ping;Zhang, Long Yan
    • International Journal of Fluid Machinery and Systems
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    • 제9권1호
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    • pp.28-38
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    • 2016
  • The flexible control system for hydraulic pile hammer using main control valve is present to the requirement of rapidly reversing with high frequency. To ensure the working reliability of hydraulic pile hammer, the reversing performance of the main control valve should commutate robustness to various interfere factors. Through simulation model built in Simulink/Stateflow and experiment, the effects of relative parameters to reverse performance of main control are analyzed and the main interfere factors for reversing performance are acquired. Treating reverse required time as design objects, some structure parameters as control factors, control pressure, input flow and gaps between spool and valve body as interfere factors, the robust design of the main control valve is done. The combination of factors with the strongest anti-jamming capability is acquired which ensured the reliability and anti-jamming capability of the main control valve. It also provides guidance on design and application of the main control valve used in large flow control with interferes.

Simulation and Characteristic Measurement with Sputtering Conditions of Triode Magnetron Sputter

  • Kim, Hyun-Hoo;Lim, Kee-Joe
    • Transactions on Electrical and Electronic Materials
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    • 제5권1호
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    • pp.11-14
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    • 2004
  • An rf triode magnetron sputtering system is designed and installed its construction in vacuum chamber. In order to calibrate the rf triode magnetron sputtering for thin films deposition processes, the effects of different glow discharge conditions were investigated in terms of the deposition rate measurements. The basic parameters for calibrating experiment in this sputtering system are rf power input, gas pressure, plasma current, and target-to-substrate distance. Because a knowledge of the deposition rate is necessary to control film thickness and to evaluate optimal conditions which are an important consideration in preparing better thin films, the deposition rates of copper as a testing material under the various sputtering conditions are investigated. Furthermore, a triode sputtering system designed in our team is simulated by the SIMION program. As a result, it is sure that the simulation of electron trajectories in the sputtering system is confined directly above the target surface by the force of E${\times}$B field. Finally, some teats with the above 4 different sputtering conditions demonstrate that the deposition rate of rf triode magnetron sputtering is relatively higher than that of the conventional sputtering system. This means that the higher deposition rate is probably caused by a high ion density in the triode and magnetron system. The erosion area of target surface bombarded by Ar ion is sputtered widely on the whole target except on both magnet sides. Therefore, the designed rf triode magnetron sputtering is a powerful deposition system.

PLIF 및 자발광 계측을 이용한 이중선회 가스터빈 연소기에서 연소불안정 모드 연구 (A Study of Combustion Instability Mode in Dual Swirl Gas Turbine Combustor by PLIF and Chemiluminescence Measurement)

  • 최인찬;이기만
    • 한국연소학회지
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    • 제19권1호
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    • pp.29-38
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    • 2014
  • This paper described an experimental investigations of combustion instability mode in a lean premixed dual swirl combustor for micro-gasturbine system. When such the instability occurs, a strong coupling between pressure oscillations and unsteady heat release excites a self-sustained acoustic wave which results in a loud, annoyed sound and may also lead a structural damage to the combustion chamber. The detailed period of flame behavior and heat release in combustion instability mode have been examined with high speed OH and CH-PLIF system and $CH^*$ chemiluminescence measurement, flame tomography with operated at 10 kHz and 6 kHz each. Experiment results suggest that unstable flame behavior has a specific frequency with 200 Hz and this frequency is accords with about 1/2 sub-harmonic of combustor resonance frequency, not fundamental frequency. This is very interesting phenomenon that have not reported yet from other previous works. Therefore, when a thermo-acoustic instability with Rayleigh criterion occurs, the fact that the period of heat release and flame behavior are different each other was proposed for the first time through this work.

Liquid Chromatographic Determination of Etofenprox Residues in Foods with Mass-Spectrometric Confirmation

  • Lee, Young-Deuk;Kwon, Chan-Hyeok;Kwon, Ki-Sung
    • 한국환경농학회지
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    • 제30권4호
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    • pp.432-439
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    • 2011
  • BACKGROUND: An official analytical method was developed to determine etofenprox residues in agricultural commodities using high-performance liquid chromatography (HPLC). METHODS AND RESULTS: The etofenprox residue was extracted with acetone from representative samples of five raw products which comprised rice grain, apple, mandarin, cabbage, and soybean. The extract was then serially purified by liquid-liquid partition and Florisil column chromatography. For rice and soybean samples, acetonitrile/n-hexane partition was additionally coupled to remove nonpolar lipids. Reversed phase HPLC using an octadecylsilyl column was successfully applied to separate etofenprox from co-extractives. Intact etofenprox was sensitively detected by ultraviolet absorption at 225 nm. Recovery experiment at the quantitation limit validated that the proposed method could apparently determine the etofenprox residue at 0.02 mg/kg. Mean recoveries from five crop samples fortified at three levels in triplicate were in the range of 93.6~106.4%. Relative standard deviations of the analytical method were all less than 10%, irrespective of crop types. A selected-ion monitoring LC/mass spectrometry with positive atmospheric-pressure chemical ionization was also provided to confirm the suspected residue. CONCLUSION(s): The proposed method is simple, rapid and sensitive enough to be employed in routine inspection or monitoring of agricultural products for the etofenprox residue.