• 한국화재소방학회논문지
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• 제15권1호
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• pp.16-22
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• 2001

석유화학플랜트에서 다량 부산되는 가연성 고체인 PP(Polypropylene) 및 LLDPE(Linear low density polyethylene)의 열적특성과 압력용기를 이용하여 산화제와의 혼촉위험성을 조사하였다. 시차주사열량계 및 열중량 분석기를 이용하여 온도에 따른 발열개시온도 및 중량감소를 조사하였고, PP 및 LLDPE의 혼촉위험성을 살펴보고자 소방법상 제1류 위험물로 분류되고 있는 몇 가지 대표적인 산화성 고체와 혼합하여 무게비에 따른 압력용기 내에서의 혼촉위험성을 조사하였다. 또한 가스농도 측정기를 이용하여 PP 및 LLDPE에 대한 연소생성물의 농도를 측정하였다. DSC분석 결과 열분해에 따른 발열 피크가 PP의 경우 220~$250^{\circ}c$ 부근에서 나타나고 있으며, TGA분석결과 PP 및 LLDPE의 분해온도는 각각 200~$350^{\circ}c$, 300~$500^{\circ}c$ 범위이다. 압력용기 시험에 의한 산화제와 PP 및 LLDPE 분진의 혼촉위험성은 오리피스 직경이 감소할수록, 산화제와의 혼촉 무게비가 증가할수록 그리고 시료의 분해온도와 산화제의 분해온도가 비슷한 경우 흔촉위험성이 크게 나타났다. 또한 시료의 연소가스 분석결과 PP의 경우 LLDPE보다 상당히 많은 양의 일 산화탄소가 발생하는 반면 LLDPE가 PP보다 더 많은 양의 이산화탄소 가스를 발생하였다.

• 한국구조물진단유지관리공학회 논문집
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• 제17권3호
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• pp.118-125
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• 2013

폴리비닐알코올 섬유와 폴리에틸렌 섬유 등의 합성 섬유는 고연성 섬유보강 시멘트 복합재료를 제조하는데 성공적으로 사용되고 있다. 폴리프로필렌 섬유 역시 복합재료를 제조하는데 사용되고 있지만, 고연성을 구현하는 목적보다는 고온에 노출된 콘크리트의 내화 성능 향상 목적으로 사용되고 있다. 이 연구에서는 폴리프로필렌 섬유로 보강된 시멘트 복합재료의 성능을 향상시키는 방법에 대하여 논하고자 한다. 폴리프로필렌 섬유보강 시멘트 복합재료의 성능을 평가하기 위하여 5가지 배합을 결정하였다. 1종 보통포틀랜드시멘트 (OPC)와 OPC를 다량 치환한 플라이애시를 결합재로 사용하였고 물-결합재 비는 0.23~0.25이다. 또한 부피비로 2%의 폴리프로필렌 섬유가 사용되었으며, 연성을 향상시킬 목적으로 폴리스틸렌 비드가 사용되었다. 슬럼프, 밀도, 압축강도, 1축 인장 실험을 포함한 일련의 실험을 수행하였으며, 실험결과, 파괴역학, 마이크로역학, 통계이론을 이용하여 폴리프로필렌 섬유보강 시멘트 복합재료의 성능을 향상할 수 있는 것으로 나타났다.

• 한국의류산업학회지
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• 제23권2호
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• pp.290-296
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• 2021

The effect of draw ratio (8, 10, 12, 14 times) and additive CaCO₃ content (0, 0.5, 1.0, 1.5, 2.0, and 3.0 wt%) on the properties of high-performance PE monofilament was investigated in this study. As the draw ratio increased (8-14 times), the melting enthalpy (ΔHf), crystallinity, specific gravity, and tensile strength increased significantly. However, the draw ratio had little effect on the melting temperature (Tm) and crystallization temperature (Tc). The seawater fastness (stain and fade) of the hydrophobic PE monofilament prepared in this study showed an excellent grade of 4-5 in all draw ratios. To investigate the effect of the additive CaCO₃ content on the properties of high-performance PE monofilament, the draw ratio was fixed at 14 times. It was found that the tensile strength of the PE monofilament sample containing 0.5 wt% of CaCO₃ was much greater compared to the sample without CaCO₃, but the elongation of the sample containing 0.5 wt% of CaCO₃ was much less than the sample with 0 wt% CaCO₃. However, in the case of the sample containing more than 0.5 wt% CaCO₃, the tensile strength slightly decreased and the elongation slightly increased as the CaCO₃ content increased. The seawater fastness (stain and fade) of the hydrophobic PE monofilament showed excellent grades of 4-5, regardless of the amount of additives. From the above results, it was found that the maximum draw ratio of 14 times with an additive of 0.5 wt% CaCO₃ are the optimal conditions for manufacturing high-performance marine fusion materials with various fineness (denier) with high strength and low elongation.

• 한국지반신소재학회논문집
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• 제3권2호
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• pp.23-29
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• 2004

폐기물 매립지 최종복토의 주요 기능중 하나는 매립지 내부로 우수의 침투를 억제하는 것이다. 이러한 기능을 담당하는 차단층은 폐기물 관리법상 다짐점토층(45cm)의 단독포설이나 다짐점토층(30cm)상부에 HDPE를 복합으로 포설하도록 되어 있다. 그러나 바닥층 사면부에서와 같이 최종복토층 끝단 사면부에서 다짐점토층의 포설이 어렵다는 문제점이 있다. 따라서 본 연구에서는 토목합성물질 사이에 차수성이 뛰어난 벤토나이트를 삽입한 토목합성수지점토라이너(Geosynthetic Clay Liner; GCL)를 다짐점토층 대신 적용하여 최종복토 끝단 사면부에서 차단층으로서의 적용가능성을 평가해 보고자 HELP 분석과 사면에서의 안정성 검토, 환경적 내구성 검토를 수행하였다. 그 결과 GCL이 기존의 다짐점토층보다 안정된 결과를 나타내고 있어 GCL을 최종복토의 차단층으로서 사용하도록 제안하고자 한다.

• 한국건축시공학회지
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• 제20권3호
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• pp.245-252
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• 2020

합성수지 거푸집은 내부식성이 우수한 경량의 고밀도 폴리에틸렌(HDPE)를 재료로 사용한다. 합성수지 거푸집의 전과정 평가를 위하여 ISO FDIS 13352에서 요구하는 시스템 경계를 만족하도록 공정 흐름도를 고려하였다. 이에 따라 고려된 시스템 경계는 Cradle-to- Product shipmen이다. 고려된 시스템 경계에서 투입 에너지원, 사용재료, 운송수단, 제작공정 등으로부터 산정한 전과정 목록(LCI) 데이터베이스를 분석하였다. 합성수지 거푸집의 LCI 데이터 분석으로 부터 환경부의 환경영향평가지수 방법론에 기반하여 분류화, 정규화, 특성화 및 가중치 과정을 거쳐 환경영향평가를 수행하고, 그 결과는 유로폼의 환경영향 평가값과 비교하였다. 실험결과, 전용횟수를 고려한 CO₂ 배출량은 유로폼 대비 2배 이상의 전용성을 갖는 합성수지 거푸집이 약 32 % 가량 낮았다. 이는 합성수지 거푸집 사용은 유로폼 대비 자재 생산을 1/2로 줄일 수 있으며, CO₂ 배출량 저감으로 이어질 수 있다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.378.2-378.2
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• 2016

Biosensors currently suffer from severe non-specific adsorption of proteins, which causes false positive errors in detection through overestimation of the affinity value. Overcoming this technical issue motivates our research. Polyethylene glycol (PEG) is well known for its ability to reduce the adsorption of biomolecules; hence, it is widely used in various areas of medicine and other biological fields. Likewise, amine functionalized surfaces are widely used for biochemical analysis, drug delivery, medical diagnostics and high throughput screening such as biochips. As a result, many coating techniques have been introduced, one of which is plasma polymerization - a powerful coating method due to its uniformity, homogeneity, mechanical and chemical stability, and excellent adhesion to any substrate. In our previous works, we successfully fabricated plasmapolymerized PEG (PP-PEG) films [1] and amine functionalized films [2] using the plasma enhanced chemical vapor deposition (PECVD) technique. In this research, an amine functionalized PP-PEG film was fabricated by using the plasma co-polymerization technique with PEG 200 and ethylenediamine (EDA) as co-precursors. A biocompatible amine functionalized film was surface characterized by X-ray photoelectron spectroscopy (XPS) and Fourier-transform infrared spectroscopy (FT-IR). The density of the surface amine functional groups was carried out by quantitative analysis using UV-visible spectroscopy. We found through surface plasmon resonance (SPR) analysis that non-specific protein adsorption was drastically reduced on amine functionalized PP-PEG films. Our functionalized PP-PEG films show considerable potential for biotechnological applications such as biosensors.

• Maxillofacial Plastic and Reconstructive Surgery
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• 제18권2호
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• pp.177-183
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• 1996

With the increasing esthetic requirement in orthognathic surgeries, midfacial corrective surgeries were developed to improve the paranasal depression. Augmentation with autogenous bones has long been the standard in facial reconstruction, however limited graft availability, donor site morbidity, and difficulties in 3-dimensional shaping were led to limited use. Porous high density polyethylene$(Medpor{(R)})$ was introduced in the 1970s as an alloplastic implants. It can be used in various size and shapes, and shortend operation time. The purpose of this study is to determine, by means of cephalometrics, the degree of long term stability and gaining of the overlying soft tissue thickness. The results were as followings : 1. There was no evidence of foreign body reaction, infection, and tissue necrosis. 2. $(Medpor{(R)})$ implants had an advantage of clinical use ; easy to contour and adapt to obtain a precise 3-dimensional construction. 3. Cephalometric study of 16 cases of paranasal augmentation revealed an overall increase of soft tissue thickness of approximately 82.1% in 6-months following. 4. The successful results could be obtained under the aseptic handling.

• Journal of Radiation Protection and Research
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• 제26권2호
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• pp.67-71
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• 2001

극저준위 방사능측정시스템의 백그라운드에 영향을 주는 중성자를 차폐하기 위한 차폐체를 설계하였다. 중성자 차폐방법은 고 밀도 폴리에틸렌을 이용하여 고속중성자를 감속한 후 $B_4C$를 이용하여 감속된 열중성자를 흡수하는 방법을 이용하였다. 몬테카를로 모사방법인 MCNP4B 코드를 이용하여 계산한 결과 고 밀도 폴리에틸렌의 두께가 10 cm 일 때 열중성자속이 최대가 되는 것으로 나타났으며 감속된 중성자의 흡수는 용제에 자연상태의 $B_4C$ 분말을 30 w% 섞을 경우 2 mm의 두께에서 94%의 중성자 흡수가 일어나는 것으로 나타났다. 또한 몬테카를로 모사를 통한 계산결과의 타당성 여부를 조사하기 위하여 중성자 차폐실험 장치를 제작하여 실험 결과와 비교하였으며, 비교 결과 실험값과 일치하는 것으로 나타났다.

• Archives of Plastic Surgery
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• 제37권5호
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• pp.639-643
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• 2010

Purpose: Cryptotia is a congenital deformity in which the upper third of the auricle is buried under the temporal skin. It is rare in Caucasians, yet it is more common in Asians. Although a variety of methods to treat cryptotia have been introduced, there is still no acceptable single procedure that can successfully manage this deformity in its entity. We present a triangular V-Y advancement flap and rhomboid flap for correcting cryptotia that can overcome the diverse shortcomings of the conventional methods. Methods: This operative method was used to correct 18 auricles in patients ranging in age from 4 to 33 years. A triangular flap was prepared over the auricle by making a skin incision according to Ohmori's method. Then a rhomboid flap with a side length of about 8 to 10 mm that sets the lower portion as a pedicle in the anterior region was prepared to supplement the contracted portion of the helix. The cartilage deformity was corrected by the banner flap or the radiating cartilage incisions with cartilage graft or high density polyethylene graft. Results: We have treated 16 patients with severe cryptotia using this method and have obtained good aesthetic results. All cases showed widened scaphoid fossa and smooth triangular fossa of antihelix. There were no major postoperative complications, such as necrosis or infection of the flaps. Conclusion: Correction of cryptotia using the triangular V-Y advancement flap and rhomboid flap is useful a method for certain conditions, when a severe contraction of the helix is present.

• Korea-Australia Rheology Journal
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• 제14권1호
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• pp.33-45
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• 2002

Recent results obtained for the port-pom model and the constitutive equations with time-strain separability are examined. The time-strain separability in viscoelastic systems Is not a rule derived from fundamental principles but merely a hypothesis based on experimental phenomena, stress relaxation at long times. The violation of separability in the short-time response just after a step strain is also well understood (Archer, 1999). In constitutive modeling, time-strain separability has been extensively employed because of its theoretical simplicity and practical convenience. Here we present a simple analysis that verifies this hypothesis inevitably incurs mathematical inconsistency in the viewpoint of stability. Employing an asymptotic analysis, we show that both differential and integral constitutive equations based on time-strain separability are either Hadamard-type unstable or dissipative unstable. The conclusion drawn in this study is shown to be applicable to the Doi-Edwards model (with independent alignment approximation). Hence, the Hadamardtype instability of the Doi-Edwards model results from the time-strain separability in its formulation, and its remedy may lie in the transition mechanism from Rouse to reptational relaxation supposed by Doi and Edwards. Recently in order to describe the complex rheological behavior of polymer melts with long side branches like low density polyethylene, new constitutive equations called the port-pom equations have been derived in the integral/differential form and also in the simplifled differential type by McLeish and carson on the basis of the reptation dynamics with simplifled branch structure taken into account. In this study mathematical stability analysis under short and high frequency wave disturbances has been performed for these constitutive equations. It is proved that the differential model is globally Hadamard stable, and the integral model seems stable, as long as the orientation tensor remains positive definite or the smooth strain history in the flow is previously given. However cautious attention has to be paid when one employs the simplified version of the constitutive equations without arm withdrawal, since neglecting the arm withdrawal immediately yields Hadamard instability. In the flow regime of creep shear flow where the applied constant shear stress exceeds the maximum achievable value in the steady flow curves, the constitutive equations exhibit severe instability that the solution possesses strong discontinuity at the moment of change of chain dynamics mechanisms.