• 제목/요약/키워드: High-$T_c$Phase

검색결과 394건 처리시간 0.03초

2단계 증착법으로 제조된 Pb(Zr, Ti)O$_3$압전 박막의 전기적 특성 및 잔류 응력에 관한 연구 (The Electrical Properties and Residual Stress of Pb(Zr,Ti)O$_3$ Piezoelectric Thin Films fabricated by 2- Step Deposition Method)

  • 김혁환;이강운;이원종;남효진
    • 한국재료학회지
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    • 제11권9호
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    • pp.769-775
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    • 2001
  • High quality PZT piezoelectric thin films were sputter- deposited on$ RuO_2$/$SiO_2$/Si substrates by using 2-step deposition method. As the first step, PZT seed layers were fabricated at a low temperature($475^{\circ}C$ ) to form a pure perovskite phase by reducing the volatility of Pb oxide. and then, as the second step, the PZT films were deposited at high temperatures ($530^{\circ}C$~$570^{\circ}C$) to reduce the defect density in the films. By this method, the pure perovskite phase was obtained at high deposition temperature range ($530^{\circ}C$~$570^{\circ}C$) and the superior electrical properties of PZT films were obtained on $RuO_2$substrate : 2Pr : 60$\mu$C/$\textrm{cm}^2$, $E_c: 60kV/cm, \;J_t: 10^{-6}A/cm^2\; at\; 250kV/cm$. The residual stress of PZT films fabricated by the 2-step deposition method was tensile and below 150MPa. It was attempted to control the residual stress in the PZT films by applying a negative bias to the substrate. As the amplitude of the substrate bias was increased, the residual tensile stress was slightly decreased, however, the ferroelectric properties of PZT films were degraded by ion bombardment.

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다결정 3C-SiC/TiW Ohmic Contact에 관한 연구 (Study for ohmic contact of polycrystalline 3C-SiC/TiW)

  • 온창민;정귀상
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
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    • pp.1311-1312
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    • 2006
  • This paper describes the ohmic contact formation between a TiW film as a contact material deposied by RF magnetron sputter and polycrystalline 3C-SiC films deposied on thermally grown Si wafers. The specific contact resistance (${\rho}_c$) of the TiW contact was measured by using 4he C-TLM. The contact phase and interfacial reaction between TiW and 3C-SiC at high-temperature were also analyzed by XRD and SEM. All of the samples didn't show cracks of the TiW film and any interfacial reaction after annealing. Especially, when the sample was annealed at $800^{\circ}$ for 30min., the lowest contact resistivity of $2.90{\times}10^{-5}{\Omega}{\cdot}cm^2$ of was obtained due to the improved interfacial adhesion.

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Enhanced Densification in Tl-1223/Ag Tapes Prepared Using Pretreated Precursors

  • 정대영;백상민;김봉준;김영철;박기곤
    • Progress in Superconductivity
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    • 제3권2호
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    • pp.198-212
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    • 2002
  • The effects of reacted precursors on phase evolution, microstructure, $J_{c}$ and junctional characteristic of the inter-granular contacts were investigated in Ag-sheathed T1-1223 tapes prepared using three kinds of reacted precursors, and compared to those in the tape prepared using an unreacted precursor The precursors were prepared by heat-treating a mixture of Sr-Ba-Ca-Cu-O, $Tl_2$$O_3$, PbO and $Bi_2$$O_3$ powders at $805^{\circ}C$ (precursor I ), $840^{\circ}C$ (precursor II ) and $905^{\circ}C$(precursor III) for 20 min. Tl-1223 phase content, grain size and J\ulcorner in the tapes appeared to increase in an order of precursors I, II and III Compared to tapes prepared using an unreacted precursor, the tapes prewar ed using precursors II and III revealed reduced pore and impurity densities and an enhanced texture. Also characteristic of inter -granular contacts and fraction of strong-links were improved. The improved properties are attributed to enhanced densification resulting from using the reacted precursors.s.

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분말 사출 성형법으로 제조된 T42 고속도 공구강의 소결 조건에 따른 조직 특성 변화 (The Microstructural Properties Change Owing to the Sintering Condition of T42 High Speed Steel Produced by Powder Injection Molding Process)

  • 도경록;최성현;권영삼;조권구;안인섭
    • 한국분말재료학회지
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    • 제17권4호
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    • pp.312-318
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    • 2010
  • High speed steels (HSS) were used as cutting tools and wear parts, because of high strength, wear resistance, and hardness together with an appreciable toughness and fatigue resistance. Conventional manufacturing process for production of components with HSS was used by casting. The powder metallurgy techniques were currently developed due to second phase segregation of conventional process. The powder injection molding method (PIM) was received attention owing to shape without additional processes. The experimental specimens were manufactured with T42 HSS powders (59 vol%) and polymer (41 vol%). The metal powders were prealloyed water-atomised T42 HSS. The green parts were solvent debinded in normal n-Hexane at $60^{\circ}C$ for 24 hours and thermal debinded at $N_2-H_2$ mixed gas atmosphere for 14 hours. Specimens were sintered in $N_2$, $H_2$ gas atmosphere and vacuum condition between 1200 and $1320^{\circ}C$. In result, polymer degradation temperatures about optimum conditions were found at $250^{\circ}C$ and $480^{\circ}C$. After sintering at $N_2$ gas atmosphere, maximum hardness of 310Hv was observed at $1280^{\circ}C$. Fine and well dispersed carbide were observed at this condition. But relative density was under 90%. When sintering at $H_2$ gas atmosphere, relative density was observed to 94.5% at $1200^{\circ}C$. However, the low hardness was obtained due to decarbonization by hydrogen. In case of sintering at the vacuum of $10^{-5}$ torr at temperature of $1240^{\circ}C$, full density and 550Hv hardness were obtained without precipitation of MC and $M_6C$ in grain boundary.

고온초전도체를 이용한 마이크로파 전력분배기의 소형화 개발 (Miniaturized Development of Microwave Power Divider Using High-Tc Superconductors)

  • 정동철;유병화;곽민환;강광용;한병성
    • 전기학회논문지P
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    • 제58권3호
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    • pp.334-338
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    • 2009
  • In this paper, We report the miniaturization of superconducting microwave power dividers based on lumped element equivalent circuits. To do this, we analyzed a conventional branch-type power divider by using an ABCD matrix under even and odd mode excitation. Then, we calculated each lumped element impedance throughout this analysis of a transmission line matrix. Also we simulated our equivalent circuits made of lumped elements by using a full wave analysis, em Sonnet. Our deign of microwave power divider based on simulated results was fabricated on high-$T_c$ superconducting thin films deposited on MgO substrate. Experimental results were reported in terms of bandwidth, center frequency, and phase difference between $S_{21}$ and $S_{31}$. We confirm that our design will be useful in the future microwave power systum.

Cu-35%Sn 합금의 일방향 열처리에서 출현하는 미세조직 (Microstructural Evolution in the Unidirectional Heat Treatment of Cu-35%Sn Alloys)

  • 최광진;지태구;박장식
    • 열처리공학회지
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    • 제16권6호
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    • pp.320-328
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    • 2003
  • A specimen of Cu-35%Sn alloy has been subjected to the unidirectional heat treatment in an attempt to examine the evolution of microstructures under varying thermal conditions. The specimen was cast in the form of a cylinder 10 mm in diameter and 200 mm in length, which was then installed in the temperature gradient field established inside a vertical tube furnace. The furnace temperature was adjusted to make the upper part at $750^{\circ}C$ and bottom end part at $300^{\circ}C$ of the specimen. The experiment was terminated by dropping it into water after the 30 minutes holding at given temperature. By the rapid cooling, the high temperature phases, ${\gamma}$ and ${\zeta}$, were retained at ambient temperature with some of ${\gamma}$ phase transformed to ${\varepsilon}$ phase, especially at the grain boundaries of ${\gamma}$ phase. The presence of ${\varepsilon}$ phase was found to determine the nature of phase transformations of the ${\zeta}$ phase undergoes upon cooling. In the close area of the ${\varepsilon}$ phase, ${\varepsilon}$ phase grew separately out of ${\zeta}$, and adds to the preexisting ${\varepsilon}$ whereas in areas away from ${\varepsilon}$, both ${\delta}$ and ${\varepsilon}$ grew simultaneously out of ${\zeta}$, and formed a lamella eutectoid structure. The transformation to ${\delta}$ was found to occur only in slow cooling. The hardness on each phase showed that the retained phases, ${\gamma}$ and ${\zeta}$, could be plastically deformed without brittle fracture while the phases, ${\varepsilon}$ and ${\delta}$, were too brittle to be deformed.

MR Brake를 이용한 공압근육매니퓰레이터의 지능제어 (Performance Improvement of Pneumatic Artificial Muscle Manipulators using Magneto-Rheological Brake)

  • 안경관;;안영공
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2005년도 춘계학술대회논문집
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    • pp.572-575
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    • 2005
  • A novel pneumatic artificial muscle actuator (PAM actuator), which has achieved increased popularity to provide the advantages such as high strength and high power/weight ratio, low cost, compactness, ease of maintenance, cleanliness, readily available and cheap power source, inherent safety and mobility assistance to humans performing tasks, has been regarded during the recent decades as an interesting alternative to hydraulic and electric actuators. In order to realize satisfactory control performance, a variable damper Magneto Rheological Brake (MRB), Is equipped to the Joint of the manipulator. Superb mixture of conventional PID controller and a phase plane switching control method brings us a novel controller. This proposed controller is appropriate for a kind of plants with nonlinearity, uncertainties and disturbances. The experiments were carried out in practical PAM manipulator and the effectiveness of the proposed control algorithm was demonstrated through experiments, which had proved that the stability of the manipulator can be improved greatly in a high gain control by using MRB with phase plane switching control method and without regard for the changes of external inertia loads.

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고출력 브러시레스 직류전동기 개발 (The development of BLDG motor with high power density)

  • 최태인;공영경;김현철;김창림;송종환;홍성영;김병섭;정용배;최경호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 A
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    • pp.394-396
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    • 1999
  • ADD has developed a special BLDCM(brushless d.c. motor) that has small size and high power density. The model of BLDCM is like that of advanced nation. Design, production and test carried out by ADD and HYOSUNG Corp.. We simulated back EMF of phase, inductance of line and eddy current loss of rotor after we tested the motor at 80 Kw. According to analysis we have established the performance of 100Kw power recently. There are the same results that we designed.

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가공열처리에 의한 고강도 Al-Cu-Li-Ag-Mg-Zr 합금의 기계적 성질 개선 (Improvement of Mechanical Properities in Al-Cu-Li-Ag-Mg-Zr Alloys by Thermomechanical Treatement)

  • 유정희;남궁일;이오연;김동건
    • 열처리공학회지
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    • 제5권2호
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    • pp.103-110
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    • 1992
  • This study is aimed to investigate the effect of various thermomechanical treatments($T_6$, $T_8$ and ITMT) on the microstructure and mechanical properties of an Al-Cu-Li-Ag-Mg-Zr alloy (Weldalite 049) which has been known to strong natural aging response, good weldablity and high strength in $T_6$ sand $T_8$ temper. This experiment was performed by means of differential scaning calorimetry, tensile test, optical and transmission electron microscopy. The tensile strength in the peak aged condition shows 620, 650 MPa in $T_6$ and $T_8$(40% cold work), respectively. Also, The tensile strength is increased with cold working in $T_8$ but decreased at 60% cold working. However, the tensile strength of the intermediate thermomechanical treated speciman(ITMT) is lower than that of $T_6$ temper about 20% but the elongation is higher than two times. It might be predicted that the ITMT is effective processing to improve the toughness of this alloy. In $T_6$, $T_8$ and ITMT, the major strengthening phase is $T_1(Al_2CuLi)$ phases. and the fine $T_1$ phase which are homogeneously precipited in matrix was observed much more in $T_8$ than $T_6$ and ITMT.

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Oxalate 침전법의 의한 Li$_{1+x}$ Co$_{y}$ Mn$_{2-y}$ $O_4$spinel의 합성 및 고온특성 (Synthesis and high Temperature properties of Li$_{1+x}$ Co$_{y}$ Mn$_{2-y}$ $O_4$spinel prepared by oxalate precipitation)

  • 김세호;이병우
    • 한국결정성장학회지
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    • 제10권3호
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    • pp.239-244
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    • 2000
  • $LiMn_2$$O_4$Spine에 Li 과량 및 Mn 대신 Co를 일부 치환시킨 $_{1+x}$ Co$_{y}$ Mn$_{2-y}$ $O_4$(0$\leq$x$\leq$0.2,y=0,1/9,1/6) spinel에 대한 합성온도 결정, 상의 생성 등 고온 상평형에 대해 연구하였다. 고온 합성에 따른 제 2상의 생성을 방지하기 위해 저온합성이 가능한 습식화학적 합성법중 하나인 oxalate 침전법을 사용하여 $600^{\circ}C$ 이하에서 단일상의 spinel로 합성하였다. 이렇게 합성된 분말에 대해 TG-DTA분석 및 고온에서 급냉한 분말에 대한 XRD분석을 통해 질량(산소)의 증감에 연관된 가역적인 상전이 온도인 $T_1$, $T_2$$T_{2'}$ 들을 확인하였으며, 첨가된 Li의 양과 치환된 Co의 양에 따른 격자상수, 상전이 온도의 변화, 고온상의 안정성 등에 대해 연구하였다. 본 연구를 통해 Li$_{1+x}$ Co$_{y}$ Mn$_{2-y}$ $O_4$spinel의 합성온도 및 냉각속도 둥 합성과정 결정에 필요한 결과들을 얻을 수 있었다.

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