• Title/Summary/Keyword: High temperature stability

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A Study on Thermal Stability of Unidirectionally Solidified $Al-CuAl_2$ Eutectic Composite (일방향응고시킨 $Al-CuAl_2$공정복합재료의 열적안정성에 관한 연구)

  • Hong, Young-Hwan;Hong, Jong-Hwi
    • Journal of Korea Foundry Society
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    • v.10 no.5
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    • pp.399-407
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    • 1990
  • The effect of thermal cycling and isothermal exposure on the high temperature microstructural stability of unidirectionally solidified $Al-CuAl_2$ eutectic composite has been studied. A coarsening procedures of lamellar eutectic structures were initiated at growth fault region because of diffusion through low angle boundary at this region. It was considered that thermally induced residual stresses produced by thermal cycling were high enough to increase the dislocation density in Al-rich matrix phase. However, it was also considered that dislocations generated by these high thermal stresses were annihilated at high temperature by stress relaxation. Consequently, the thermal cycling up to 1440 cycles between 20 and $520^{\circ}C$ did not affect the microstructural stability.

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Development of PolymerElectrolytes Based on Ionic Liquids forHigh Temperature/Low Humidity PEFC Applications (고온/저가습 고분자전해질 연료전지를 위한 이온성 액체 기반 고분자 전해질막 개발)

  • Sekhon, Satpal Singh;Park, Jin-Soo;Cho, Eun-Kyung;Park, Gu-Gon;Kim, Chang-Soo;Lee, Won-Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.40-43
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    • 2008
  • High temperature polymer electrolyte membranes incorporating ionic liquids (ILs) in different polymers such as commercial fluorinated polymers, sulfonated polymers and recasted nafion have been developed. ILs based on imidazolium cation and different anions possess high ionic conductivity and good thermal stability and have been used in the present study. The membranes containing IL show conductivity ${\sim}10^{-2}S\;cm^{-1}$ above $100^{\circ}C$ under anhydrous conditions and are thermally stable up to $250-300^{\circ}C$. IL acts as a conducting medium in these electrolytes and plays the same role as played by water in fully hydrated nafion membranes. Due to high conductivity and good thermal stability, these membranes are promising materials for PEFCs at higher temperatures under anhydrous conditions.

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Properties of Fire Resistant Finishing Mortar Using Fly Ash and Glass Forming Light Weight Aggregate (플라이애시와 유리 발포 경량골재를 사용한 내화 마감모르타르의 특성)

  • Song, Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.4
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    • pp.374-381
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    • 2015
  • This study is investigating the fire resistant finishing materials composed of fly ash and glass forming light weight aggregate has the high temperature thermal stability. High temperatures such as a fire, cementitious materials beget dehydration and micro crack of cement matrix. From the test result, developed fire resistant finishing materials showed good stability in high temperatures. These high temperature stability is caused by the ceramic binding and low thermal conductivity of glass forming light weight aggregate. Also, alkali activation reaction of fly ash and meta kaolin not showing the decomposition of calcium hydrates. Thus, this result indicates that it is possible to fire resistant finishing light weight mortars.

Improved Temperature Stability in Dielectric Properties of 0.8BaTiO3-(0.2-x)NaNbO3-xBi(Mg1/2Ti1/2)O3 Relaxors

  • Goh, Yumin;Kim, Baek-Hyun;Bae, Hyunjeong;Kwon, Do-Kyun
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.178-183
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    • 2016
  • Ferroelectric relaxor ceramics with $BaTiO_3-NaNbO_3-Bi(Mg_{1/2}Ti_{1/2})O_3$ ternary compositions (BT-NN-BMT) have been prepared by sol-gel powder synthesis and consequent bulk ceramic processing. Through the modified chemical approach, fine and single-phase complex perovskite compositions were successfully obtained. Temperature and frequency dependent dielectric properties indicated typical relaxor characteristics of the BT-NN-BMT compositions. The ferroelectric-paraelectric phase transition became diffusive when NN and BMT were added to form BT based solid solutions. BMT additions to the BT-NN solid solutions affected the high temperature dielectric properties, which might be attributable to the compositional inhomogeneity of the complex perovskite and resulting weak dielectric coupling of the Bi-containing polar nanoregions (PNRs). The temperature stability of the dielectric properties was good enough to satisfy the X9R specification. The quasi-linear P-E response and the temperature- stable dielectric properties imply the high potential of this ceramic compound for use in high temperature capacitors.

Fabrication of a Micromachined Metal Thin-film Type Pressure Sensor for High Overpressure Tolerance and Its Characteristics (과부하 방지용 마이크로머시닝 금속 박막형 압력센서의 제작과 그 특성)

  • Kim, Jae-Min;Lim, Byoung-Kwon;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05a
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    • pp.192-196
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    • 2002
  • This paper describes on the fabrication and characteristics of a metal thin-film pressure sensor based on Cr strain-gauges for harsh environment applications. The Cr thin-film strain-gauges are sputter-deposited onto a micromachined Si diaphragms with buried cavity for overpressure protectors. The proposed device takes advantages of the good mechanical properties of single-crystalline Si as diaphragms fabricated by SDB and electrochemical etch-stop technology, and in order to extend the operating temperature range, it incorporates relatively the high resistance, stability and gauge factor of Cr thin-films. The fabricated pressure sensor presents a low temperature coefficient of resistance, high-sensitivity, low non-linearity and excellent temperature stability. The sensitivity is 1.097~1.21 $mV/V{\cdot}kgf/cm^2$ in the temperature range of $25{\sim}200^{\circ}C$ and the maximum non-linearity is 0.43 %FS.

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Effect of Sintering Temperature on Electrical Properties and Stability of Zn-Pr-Co-Cr-Tb-Based Varistors (Zn-Pr-Co-Cr-Tb계 바리스터의 전기적 특성 및 안정성에 소결온도가 미치는 영향)

  • Nahm, Choon-Woo
    • Korean Journal of Materials Research
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    • v.17 no.6
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    • pp.298-302
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    • 2007
  • The electrical properties and its stability of Zn-Pr-Co-Cr-Tb-based varistors were investigated for different sintering temperatures. As the sintering temperatures increased, the varistor voltage decreased in the range of $705.2{\sim}299.1$ V/mm, the nonlinear coefficient decreased in the range of $42.4{\sim}31.7$, and the leakage current was in the range of $1.0{\sim}1.7\;{\mu}A$. The stability of electrical characteristics increased with the increase of sintering temperature. The varistors sintered at $1350^{\circ}C$ marked the high electrical stability, with $%\Delta$ $V_{1mA}=+0.1%,\;%\Delta{\alpha}=+3.2%$, and $%{\Delta}I_L=+117.6%$ for DC accelerated aging stress state of $0.95V_{1mA}/150^{\circ}C/24\;h$.

Sintering Temperature Effect on Electrical and Dielectric Stability of ZPCCL-Based Varistors (소결온도가 ZPCCL계 바리스터의 전기적, 유전적 안정성에 미치는 영향)

  • Nahm, Choon-Woo
    • Korean Journal of Materials Research
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    • v.16 no.8
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    • pp.466-472
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    • 2006
  • The electrical, dielectric properties, and its stability of ZPCCL-based varistors were investigated for different sintering temperatures in the range of $1230{\sim}1300^{\circ}C$. As the sintering temperatures increased, the varistor voltage decreased in the range of $777.9{\sim}108$ V/mm, the nonlinear coefficient decreased in the range of $77.9{\sim}7.1$, and the leakage current increased in the range of $0.3{\sim}50.6\;{\mu}A$. The stability of electrical and dielectric characteristics was obtained from sintering temperature of $1260^{\circ}C$. the varistors sintered at $1260^{\circ}C$ marked the high electrical and dielectric stability, with $%{\Delta}{V_{1mA}=+1.9%,\;%{\Delta}{\alpha}=-10.6%,\;%{\Delta}I_L=+20%\;and\;%{\Delta}tan\;{\delta}=+9.9%$ for DC accelerated aging stress state of $0.95V_{1mA}/150^{\circ}C$/24 h.

Microstructure and High Temperature Strength of Rapidly Solidified Al-8wt%Fe Alloy (급속응고된 Al-8wt%Fe 합금의 미세조직 및 고온강도)

  • 최병준
    • Journal of Powder Materials
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    • v.5 no.3
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    • pp.192-198
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    • 1998
  • Microstructure and mechanical properties were examined on rapidly solidified Al-8wt%Fe alloy. High temperature strength test was also undertaken, and it is shown that the refinement in microstructure resulting from extremely rapid cooling rates gives rise to improved high temperature strength, but the elongation to fracture of this material decreases with increasing temperature, particularly in the temperature range up to 30$0^{\circ}C$. Specimens heat-treated for 100 hrs were analyzed with TEM micrographs to understand the thermal stability of this material.

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Thermal Stability Enhanced Ge/graphene Core/shell Nanowires

  • Lee, Jae-Hyeon;Choe, Sun-Hyeong;Jang, Ya-Mu-Jin;Kim, Tae-Geun;Kim, Dae-Won;Kim, Min-Seok;Hwang, Dong-Hun;Najam, Faraz;Hwang, Seong-U;Hwang, Dong-Mok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.376-376
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    • 2012
  • Semiconductor nanowires (NWs) are future building block for nano-scale devices. Especially, Ge NWs are fascinated material due to the high electrical conductivity with high carrier mobility. It is strong candidate material for post-CMOS technology. However, thermal stability of Ge NWs are poor than conventional semiconductor material such as Si. Especially, when it reduced size as small as nano-scale it will be melted around CMOS process temperature due to the melting point depression. Recently, Graphene have been intensively interested since it has high carrier mobility with single atomic thickness. In addition, it is chemically very stable due to the $sp^2$ hybridization. Graphene films shows good protecting layer for oxidation resistance and corrosion resistance of metal surface using its chemical properties. Recently, we successfully demonstrated CVD growth of monolayer graphene using Ge catalyst. Using our growth method, we synthesized Ge/graphene core/shell (Ge@G) NW and conducted it for highly thermal stability required devices. We confirm the existence of graphene shell and morphology of NWs using SEM, TEM and Raman spectra. SEM and TEM images clearly show very thin graphene shell. We annealed NWs in vacuum at high temperature. Our results indicated that surface melting phenomena of Ge NWs due to the high surface energy from curvature of NWs start around $550^{\circ}C$ which is $270^{\circ}C$ lower than bulk melting point. When we increases annealing temperature, tip of Ge NWs start to make sphere shape in order to reduce its surface energy. On the contrary, Ge@G NWs prevent surface melting of Ge NWs and no Ge spheres generated. Furthermore, we fabricated filed emission devices using pure Ge NWs and Ge@G NWs. Compare with pure Ge NWs, graphene protected Ge NWs show enhancement of reliability. This growth approach serves a thermal stability enhancement of semiconductor NWs.

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The Study on the Surface Properties of Concrete Tile According to the Autoclave Curing (오토클레이브 양생에 따른 콘크리트 마감재의 표면특성에 관한 연구)

  • Choi Sun-Mi;Jung Ji-Yong;Jung Eun-Hye;Kawg Eun-Gu;Kim Jin-man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.77-80
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    • 2005
  • The surface of concrete tiles is weak in moisture that it occurrenced efflorescence, but in the former study we found that it is possible to ensure moisture stability of concrete surface by autoclaving. So this study is to discuss the moisture stability and Physical Properties of high-strength glossy concrete according to time and temperature of autoclave curing. As the results, by increasing time and temperature of autoclave curing, compressive strength and surface hardness increased and glossiness decreased. In the case to 3 hour and $180^{\circ}C$ of autoclave curing, there is not effloescences in mosture stability test.

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