• 제목/요약/키워드: High temperature shock, Low temperature shock

검색결과 81건 처리시간 0.024초

ZrB2-SiC 세라믹스의 미세구조와 기계적 물성에 미치는 B4C 첨가효과 (Effect of B4C Addition on the Microstructures and Mechanical Properties of ZrB2-SiC Ceramics)

  • 채정민;이성민;오윤석;김형태;김경자;남산;김성원
    • 한국세라믹학회지
    • /
    • 제47권6호
    • /
    • pp.578-582
    • /
    • 2010
  • $ZrB_2$ has a melting point of $3245^{\circ}C$ and a relatively low density of $6.1\;g/cm^3$, which makes this a candidate for application to ultrahigh temperature environments over $2000^{\circ}C$. Beside these properties, $ZrB_2$ is known to have excellent resistance to thermal shock and oxidation compared with other non-oxide engineering ceramics. In order to enhance such oxidation resistance, SiC was frequently added to $ZrB_2$-based systems. Due to nonsinterability of $ZrB_2$-based ceramics, research on the sintering aids such as $B_4C$ or $MoSi_2$ becomes popular recently. In this study, densification and high-temperature properties of $ZrB_2$-SiC ceramics especially with $B_4C$ are investigated. $ZrB_2$-20 vol% SiC system was selected as a basic composition and $B_4C$ or C was added to this system in some extents. Mixed powders were sintered using hot pressing (HP). With sintered bodies, densification behavior and high-temperature (up to $1400^{\circ}C$) properties such as flexural strength, hardness, and so on were examined.

초고온용 ZrB2-계 세라믹스의 치밀화와 물성 (Densification and Properties of ZrB2-based Ceramics for Ultra-high Temperature Applications)

  • 김성원;김형태;김경자;서원선
    • 한국정밀공학회지
    • /
    • 제29권3호
    • /
    • pp.273-278
    • /
    • 2012
  • $ZrB_2$ has a melting temperature of $3245^{\circ}C$ and a low density of $6.1\;g/cm^3$, which makes this a candidate for application to ultra-high temperature over $2000^{\circ}C$. Beside these properties, $ZrB_2$ has excellent resistance to thermal shock and oxidation compared with other non-oxide engineering ceramics. This paper reviewed briefly 2 research examples, which are related to densification and properties of $ZrB_2$-based ceramics for ultra-high temperature applications. In the first section, the effect of $B_4C$ addition on the densification and properties of $ZrB_2$-based ceramics is shown. $ZrB_2$-20 vol.% SiC system was selected as a basic composition and $B_4C$ or C was added to this system in some extents. With sintered bodies, densification behavior and hightemperature (up to $1400^{\circ}C$) properties such as bending strength and hardness are examined. In the second section, the effect of the SiC size on the microstructures and physical properties is shown. $ZrB_2$-SiC ceramics are fabricated by using various SiC sources in order to investigate the grain-growth inhibition and the mechanical/thermal properties of $ZrB_2$-SiC.

커튼월 스팬드럴용 진공유리의 열파손에 대한 비교실험 (A Comparative Experiment on Thermal Stress Failure of Vacuum Glazing applied in Curtain Wall at Spandrel area)

  • 김승철;윤종호;신우철;안정혁
    • KIEAE Journal
    • /
    • 제16권3호
    • /
    • pp.121-128
    • /
    • 2016
  • Purpose: The vacuum glazing should constantly retain the gap in vacuum state to maintain high thermal performance. To do so, pillars are used to prevent the glazing from clinging to each other by the atmospheric pressure and therefore surface of the vacuum glazing is consistently affected by residual stress. The vacuum glazing could be applied to curtain wall systems at spandrel area to fulfill a rigorous domestic standard on U-value of the external wall. However, this can lead to high glazing temperature increase by heat concentration at a back panel and finally thermal stress breakage. This study experimentally determined weakness of the vacuum glazing systems on the thermal stress breakage and investigated effect of the residual stress. Method: The experiment first built two scale-down mock-up facilities that replicate the spandrel area in curtain wall, and then installed single low-e glass and vacuum glazing respectively. The two mock-up facilities were exposed to outside to induce the thermal stress breakage. Result: The experiment showed that the temperature occurred the thermal stress breakage was $114.4^{\circ}C$ for the single low-e glass and $118.9^{\circ}C$ for the vacuum glazing respectively. The result also showed the vacuum glazing reached the critical point earlier than the single low-e glass, which means that the vacuum glazing has high potential to occur the thermal shock breakage. In addition, the small temperature difference between two glazing indicates that the residual stress scarcely affects breakage of the vacuum glazing.

초음파 처리조의 구조에 따른 살균효과 연구 (Research on Ultrasonic Sterilization Effect of Treatment Equipments)

  • 이양래;김현세;백민혁
    • 한국생산제조학회지
    • /
    • 제22권5호
    • /
    • pp.818-823
    • /
    • 2013
  • In the process of sterilization during the manufacture of beverages, both the treatment time and the temperature influence the beverage taste and flavor. Therefore, to improve the beverage quality, a nonthermal sterilization method is preferred to a high-temperature one. A nonthermal method, ultrasonic treatment by shock waves from cavitation, has been known to have a sterilizing effect. In this study, to observe the effect of ultrasonic frequency and treatment time on beverage quality, batch type ultrasonic equipment was fabricated and tested. Further, to evaluate the applicability of this ultrasonic method to an in-situ process, flow type ultrasonic heptagonal equipment was fabricated and then used to perform a sterilization experiment. Subsequently, the sterilizing effect was measured under ultrasonic and low-temperature ($55^{\circ}C$) treatments. Based on the obtained results, ultrasonic sterilization technology that can be applied for treatments at flow rates of up to 3 L/min was developed.

온도변화에 따른 담배나방 유충 지방체의 유전자 발현 비교 분석 (Comparison of Gene Expression in Larval Fat Body of Helicoverpa assulta in Different Temperature Conditions)

  • 차욱현;김광호;이대원
    • 한국응용곤충학회지
    • /
    • 제57권3호
    • /
    • pp.165-175
    • /
    • 2018
  • 곤충은 넓은 범위의 온도영역에 사는 것으로 알려져 있으나, $40^{\circ}C$가 넘는 고온이나 빙결온도 이하의 저온에서는 생존이 어렵다. 본 연구는 사육온도 조건이 다른 환경에서 대사중심 조직인 지방체의 유전자 발현을 분석하기 위해, 온도조건을 달리하여 담배나방을 저온 사육충 ($3{\sim}10^{\circ}C$), 고온 사육충 ($35^{\circ}C$)로 나누고 상온 사육충 ($25^{\circ}C$)을 대조구로 사용하여 전사체 분석을 수행하였다. 저온에서 특이적으로 높은 발현을 보인 유전자는 표피단백질, ${\Delta}9$ 불포화효소, 글리세롤 3-인산 탈수소효소이며, 저온에서 발현이 낮아진 유전자는 키틴 합성효소, catalase, UDP-당전이 효소이다. 고온에서 특이적으로 높은 발현을 보인 유전자는 과산화물제거효소, metallothionein 2, phosphenolpyruvate carboxykinase, 트레할로스 운반단백질이었다. 고온에서 높고 저온에서 낮은 대조적 발현을 보인 유전자는 열충격단백질, glutathione peroxidase이었다. 이들 온도 특이적이거나 대조적 발현을 보이는 유전자는 기후변화에 관련한 특이마커로 활용이 가능할 것으로 사료된다.

초고온 소재용 ZrB2계 복합소재의 제조 (Fabrication of ZrB2-based Composites for Ultra-high Temperature Materials)

  • 김성원;채정민;이성민;오윤석;김형태;남산
    • 한국분말재료학회지
    • /
    • 제16권6호
    • /
    • pp.442-448
    • /
    • 2009
  • $ZrB_2$-based composites are candidate materials for ultra-high temperature materials (UHTMs). $ZrB_2$ has become an indispensable ingredient in UHTMs, due to its high melting temperature, relatively low density, and excellent resistance to thermal shock or oxidation. $ZrB_2$ powders are usually synthesized by solid state reactions such as carbothermal, borothermal, or combined carbothermal reaction. SiC is added to this system in order to enhance the oxidation resistance of $ZrB_2$. In this study, $ZrB_2$?based composites were successfully synthesized and densified through two different processing paths. $ZrB_2$ or $ZrB_2$ 25 vol.%SiC was fully synthesized from oxide starting materials with reducing agents after heat treatment at 1400$^{\circ}C$. Besides, $ZrB_2$?20 vol.%SiC was fully densified with $B_4C$ as a sintering additive after hot pressing at 1900$^{\circ}C$. The synthesis mechanism and the effect of sintering additives on densification of $ZrB_2$ ?SiC composites were also discussed.

Potential Efficacy of Multiple-shot Long-pulsed 1,064-nm Nd:YAG in Nonablative Skin Rejuvenation: A Pilot Study

  • Kim, Young-Koo;Lee, Hae-Jin;Kim, Jihee
    • Medical Lasers
    • /
    • 제9권2호
    • /
    • pp.159-165
    • /
    • 2020
  • Background and Objectives The ultimate goal in current skin rejuvenation practice is to achieve a good result with minimal pain and downtime. Nonablative skin rejuvenation (NSR) is one technique. The efficacy of the long-pulsed 1064 nm Nd:YAG laser (LPNDY) has not been assessed in NSR. Materials and Methods Three target areas were selected (bilateral cheeks and glabellar region) in six volunteer subjects. A LPNDY with an integral skin temperature monitor delivered three stacked shots to each target area (1064 nm, 12 mm spot, 13 J/cm2, 1 Hz) without any skin cooling or anesthesia. The skin temperature was recorded before, during, and after each set of shots using the system monitor and in real-time using a high-sensitivity (±0.001℃) near-infrared video camera. The skin reaction was observed with the naked eye, and pain and discomfort were assessed by the subjects during and after treatment. Results The subjects reported a mild feeling of heat with no discomfort during or after the test treatments. Mild erythema was observed around the treatment areas, without noticeable edema. A series of three ascending skin temperature stepwise peaks, with a decrease in skin temperature towards the baseline after the third shot, was observed consistently. The mean temperatures for shots 1, 2, and 3 for the cheeks were 39.5℃, 42.0℃, and 44.4℃, respectively, and for the glabella, 40.8℃, 43.9℃, and 46.2℃, respectively. Similar ranges were indicated on the system integral temperature monitor. Conclusion A set of three stacked pulses with the LPNDY at a low fluence achieved ideal dermal temperatures to achieve some dermal remodeling but without any downtime or adverse events. The temperature data from the integral thermal sensor matched the video camera measurements with practical accuracy for skin rejuvenation requirements. These data suggest that LPNDY would satisfy the necessary criteria to achieve effective NSR, but further studies will be needed to assess the actual results in clinical practice.

Cr2O3-MgO-Y2O3 첨가에 따른 뮬라이트 세라믹스의 기계적 성질 (Effect of Cr2O3-MgO-Y2O3 Addition on Mechanical Properties of Mullite Ceramics)

  • 임진현;김시연;여동훈;신효순;정대용
    • 한국전기전자재료학회논문지
    • /
    • 제30권12호
    • /
    • pp.762-767
    • /
    • 2017
  • Mullite ($3Al_2O_3{\cdot}2SiO_2$) has emerged as a promising candidate for high-temperature structural materials due to its erosion resistance, chemical and thermal stabilities, relatively low thermal expansion coefficient, excellent thermal shock and creep resistances, and low dielectric constant. However, since the pure mullite sintering temperature is as high as $1,600{\sim}1,700^{\circ}C$, there is an increasing need for a sintering additive capable of improving the strength characteristics while lowering the sintering temperature. Herein we have tried to obtain the optimal sintering additive composition by adding MgO, $Cr_2O_3$, and $Y_2O_3$ to mullite, followed by sintering at $1,325{\sim}1,550^{\circ}C$ for 2 h. With additives of 2 wt% of MgO, 2 wt% of $Cr_2O_3$, 4 wt% of $Y_2O_3$, A density of $3.23g/cm^3$ was obtained for the sintered body at $1,350^{\circ}C$ upon using 2 wt% MgO, 2 wt% $Cr_2O_3$, and 4 wt% $Y_2O_3$ as additives. The three-point flexural strength of that was 275 MPa and the coefficient of thermal expansion (CTE) was $4.15ppm/^{\circ}C$.

생물막을 이용한 상수 원수에서의 암모니아 제거 특성 (Ammonia Removal Characteristics of Biolfilm Reactor)

  • 신항식;임경호;이상민
    • 상하수도학회지
    • /
    • 제10권1호
    • /
    • pp.78-84
    • /
    • 1996
  • The presence of ammonia, usually in the form of ammonium ion ($NH_4{^+}$), can enhance bacterial growth m the distribution system and make the production of drinking water more costly if ammonium must be removed to ensure good disinfection. Removal of ammonia by biological oxidation could be economical which prevents excess chlorine dosage In this research, effects of hydraulic retention time (HRT) and media type on the ammonia removal efficiencies of submerged biofilm reactor were investigated. The biofilm reactors combined the characteristics of high biological solids capture efficiency and good hydraulic control. The results indicate that biofilms can remove over 77 percent of the ammonia with HRT of longer than 2 hr even at low temperature ranging from 14.6 to $16.6^{\circ}C$. The HRT has a significant effect on nitrification. The overall nitrification and efficiency of ammonia removal increase with increasing HRT. It has also been observed that when the fibrous media was used, the ammonia removal, nitrification rate and endurance to shock improved.

  • PDF

Upwind 방법을 이용한 무딘물체 주위의 화학적 비평형 비점성 유동장의 수치 해석 (Numerical Analysis of Nonequilibrium Chemically Reacting Inviscid flow over Blunt-bodies Using Upwind Method)

  • 서정일;송동주
    • 한국전산유체공학회:학술대회논문집
    • /
    • 한국전산유체공학회 1997년도 추계 학술대회논문집
    • /
    • pp.99-105
    • /
    • 1997
  • A finite-difference method based on conservative supra characteristic method type upwind flux difference splitting has been developed to study the nonequilibrium chemically reacting inviscid flow. For nonequilibrium air, NS-1 species equations were strongly coupled with flowfield equations through convection and species production terms. Inviscid nonequilibrium chemically reacting air mixture flows over Blunt-body were solved to demonstrate the capability of the current method. At low altitude flight conditions the nonequilibrium air models predicted almost the same temperature, density and pressure behind the shock as equilibrium flow: however, at high altitudes they showed substantial differences due to nonequilibrium chemistry effect. The new nonequilibrium chemically reacting upwind flux difference splitting mettled can be extended to viscous flow and multi-dimensional flow conditions.

  • PDF