• 한국가스학회지
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• 제26권6호
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• pp.16-23
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• 2022

본 연구에서는 디스크와 인장시험 등을 통해 수소취성에 대한 재료 특성을 평가하고자 하였다. 이를 위해 니켈 당량이 28.5 이상인 합금 조성과, 이와 유사한 상용 합금 조성 2종에 대해 합금을 제조하였고, 각 합금은 진공유도용해로(Vacuum Induction Melting, VIM)에서 개발 합금(이하 #1)과 상용 배관(이하 각각 #2, #3)을 재용해하여 주조재로 제조하였고, 주조 합금은 단조 및 압연하여 판재로 제조하였다. 디스크형태의 시편은 0.1~1000 bar/min의 속도로 수소와 헬륨으로 가압하여 파열압력을 측정하여 수소에 대한 특성을 평가하였고, 전기화학적 방법으로 수소처리한 인장시편과 비교군에 대해 항복강도, 인장강도, 연신률, 단면적 감소율을 확인하였다. 또한 인장시편은 주사전사현미경을 통해 파단면을 확인하였다. 디스크파열시험과 수소처리 한 시편의 인장시험을 통해, 본 연구를 통해 개발된 강종의 경우 상용 강종과 비교하여 유사한 수소취성 특성을 갖고 있음을 확인하였고, 파단면 또한 미세한 두께의 벽개파괴 특성을 보였지만 기계적 강도에 큰 영향을 미치지 않음에 따라 개발된 고질소 스테인리스강은 내수소취성이 우수한 것으로 평가 할 수 있었다.

• 한국압력기기공학회 논문집
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• 제8권1호
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• pp.33-38
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• 2012

A PHE (Process Heat Exchanger) in a nuclear hydrogen system is a key component required to transfer heat energy of $950^{\circ}C$ generated in a VHTR (Very High Temperature Reactor) to a chemical reaction that yields a large quantity of hydrogen. Korea Atomic Energy Research Institute has established a small-scale gas loop for the performance test on VHTR components and recently has manufactured a medium-scale PHE prototype made of Hastelloy-X. A performance test on the PHE prototype is scheduled in the gas loop. In this study, high-temperature structural analysis modeling, and macroscopic thermal and structural analysis of the medium-scale PHE prototype by imposing the established displacement boundary constraints in the previous research were carried out under the gas loop test condition. The results obtained in this study will be compared with performance test results.

• Journal of Advanced Marine Engineering and Technology
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• 제33권7호
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• pp.1034-1043
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• 2009

Hydrogen energy is becoming popular day by day due to its renewability and pollutaaant free natures. Hydrogen gas pressure which is after passing through reciprocating compressor part has high pulsation wave form. A unit, snubber is used as compressor components to reduce the harmful pulsation waveform and to remove the impurities in the hydrogen gas. An experiment has been conducted to investigate the pulsation reduction performance of different arrangement of snubber i.e. snubber array used in reciprocating compression system. Analyzing the snubber array experimental data, it is found that the pressure fluctuations are reduced from 90.1977% ~ 92.6336% with pressure loss 1.5013% ~ 4.9034% for compressor operation at different speed which ensure the good performance of snubber-array as pulsation damper in hydrogen compressing system.

• 한국가스학회지
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• 제27권4호
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• pp.102-109
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• 2023

수소사회 실현에 있어 수요자가 수소를 가장 쉽게 만날 수 있는 시설인 수소충전소의 안전 확보가 중요하다. 수소충전소는 고압의 수소를 저장하는 압축가스설비 등으로 구성되어 있으며, 시설 내 수소 누출로 인한 화재폭발 또는 주변 화재의 영향으로 고압의 압축가스설비가 파열될 위험이 있다. 이에, 한국가스안전공사는 설치단계부터 위험요인을 찾아내 설계에 반영하고 법정 검사를 통한 안전 확보에 만전을 다하고 있다. 본 연구에서는 수소충전소에 설치하는 방호벽의 안전성 효과를 확인하기 위해 방호벽을 이용한 TNT 폭발 실증시험을 실시하고, CFD 프로그램인 FLACS-CFD를 이용하여 실증시험 결과와 비교·검증하였다. 실증시험 및 CFD 해석 결과 방호벽 후단에서 폭발 과압의 감소 효과가 위치에 따라 50 %에서 최대 90 %까지 감소하는 것이 확인되나, 일정거리를 벗어나면 그 효과가 떨어지는 것을 확인하였다. 방호벽의 안전성 검증을 위한 실증시험 및 전산해석 결과는 향후 방호벽 기준 최적화를 위한 제안에 활용하고자 한다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.717-724
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• 2008

Very High Temperature Gas Cooled Reactor (VHTR) has been selected as a high energy heat source for nuclear hydrogen generation, which can produce hydrogen from water or natural gas. A primary hot gas duct (HGD) as a coaxial double-tube type cross vessel is a key component connecting the reactor pressure vessel and the intermediate heat exchanger for the VHTR. In this study, structural sizing methodology for the primary HGD with a coaxial double-tube of the VHTR that produces heat at temperatures in the order of $950^{\circ}C$ was suggested and a structural pre-sizing of it was carried out as an example.

• JSTS:Journal of Semiconductor Technology and Science
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• 제1권2호
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• pp.95-102
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• 2001

Hafnium oxide thin films for gate dielectric were deposited at $300^{\circ}C$ on p-type Si (100) substrates by plasma enhanced chemical vapor deposition (PECVD) and annealed in $O_2$ and $N_2$ ambient at various temperatures. The effect of hydrogen treatment in 4% $H_2$ at $350^{\circ}C$ for 30 min on the electrical properties of $HfO_2$for gate dielectric was investigated. The flat-band voltage shifts of $HfO_2$capacitors annealed in $O_2$ambient are larger than those in $N_2$ambient because samples annealed in high oxygen partial pressure produces the effective negative charges in films. The oxygen loss in $HfO_2$films was expected in forming gas annealed samples and decreased the excessive oxygen contents in films as-deposited and annealed in $O_2$ or $N_2$ambient. The CET of films after hydrogen forming gas anneal almost did not vary compared with that before hydrogen gas anneal. Hysteresis of $HfO_2$films abruptly decreased by hydrogen forming gas anneal because hysteresis in C-V characteristics depends on the bulk effect rather than $HfO_2$/Si interface. The lower trap densities of films annealed in $O_2$ambient than those in $N_2$were due to the composition of interfacial layer becoming closer to $SiO_2$with increasing oxygen partial pressure. Hydrogen forming gas anneal at $350^{\circ}C$ for samples annealed at various temperatures in $O_2$and $N_2$ambient plays critical role in decreasing interface trap densities at the Si/$SiO_2$ interface. However, effect of forming gas anneal was almost disappeared for samples annealed at high temperature (about $800^{\circ}C$) in $O_2$ or $N_2$ambient.

• 한국수소및신에너지학회논문집
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• 제19권5호
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• pp.439-444
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• 2008

The heat capacity and pressure drop of $CO_2$ and coolant in a multi-tube type gas cooler were investigated experimentally. The main components of the refrigerant loop are a receiver, a $CO_2$ compressor, a mass flow meter, an evaporator and a multi-tube type gas cooler as a test section. The mass flowrate of $CO_2$ and coolant were varied from 0.06 to 0.075 [kg/s], respectively and the cooling pressure of gas cooler were from 8 to 10 [MPa]. The heat capacity of $CO_2$ in the test section is increased with the increment in mass flowrate of coolant, the cooling pressure and mass flowrate of $CO_2$. The pressure drop of $CO_2$ is decreased with the decrease in mass flowrate of coolant and $CO_2$, but decreased with increase in cooling pressure of $CO_2$. The heat capacity of $CO_2$ per unit heat transfer area of gas cooler is greatly high. Therefore, in case of the application of $CO_2$ at the multi-tube type gas cooler, it is expected to carry out the high-efficiency, high-performance and compactness of gas cooler.

• 한국수소및신에너지학회논문집
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• 제32권3호
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• pp.189-195
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• 2021

A compressed hydrogen tank is to be repressurized to 40 bar by being connected to a high-pressure line containing hydrogen at 50 bar and 25℃. Hydrogen filling time and the corresponding hydrogen temperature has been estimated when the filling process stopped according to several thermodynamic models. During the process of cooling the hydrogen tank, hydrogen temperature and pressure vs. time estimation was performed using Aspen Dynamics. Filling time, hydrogen temperature after filling hydrogen gas, cooling time and the final tank pressure after tank filling process have been completed according to the thermodynamic models are almost same.

• 한국수소및신에너지학회논문집
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• 제20권6호
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• pp.471-478
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• 2009

The specific some types of compressors are appropriate for a use in hydrogen gas station. Metal diaphragm type of hydrogen compressor is one of them, which can satisfy the critical requirements of maintaining gas purity and producing high pressure over 850 bar. The objective of this study is to investigate an characteristics of compression through two-way Fluid-Structure-Interaction (FSI) analysis as bulk modulus and initial volume of oil independently varies. Deflection of diaphragm, oil density, gas and oil pressure were analyzed during a certain period of compression process. According to the analysis results, bulk modulus and initial volume remarkably affected deflection of diaphragm, oil density, gas and oil pressure. The highest gas pressure were attained with the highest bulk modulus of $7e^9\;N/m^2$ and the lowest initial oil volume of 80 cc.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2850-2855
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• 2008

Very High Temperature Reactor (VHTR) has been selected as a high energy heat source for a nuclear hydrogen generation. The VHTR heat is transferred to a thermo-chemical hydrogen production process through an intermediate loop. Both Process Heat Exchanger and sulfuric acid evaporator provide the coupled components between the VHTR intermediate loop and hydrogen production module. A small scaled Compact Nuclear Hydrogen Coupled Components test loop is developed to simulate the VHTR intermediate loop and hydrogen production module. Main objective of the loop is to screening the candidates of NHDD (Nuclear Hydrogen Development and Demonstration) coupled components. The operating condition of the gas loop is a temperature up to $950^{\circ}C$ and a pressure up to 6.0MPa. The thermal and fluid dynamic design of the loop is dependent on the structures that enclose the gas flow, especially primary side that has fast gas velocity. We designed and constructed a small scale sulfuric acid experimental system which can simulate a part of the hydrogen production module also.