• 대한원격탐사학회지
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• 제29권2호
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• pp.243-251
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• 2013

본 연구는 인공위성과 지상 원격탐사 자료를 이용하여 동북아 지역에서 발생하는 황사현상의 중장거리 이동에 따른 광학적 특성 변화를 분석하였다. 동북아시아 지역의 Aerosol Robotic Network(AERONET)의 선포토미터 관측 지점 중에 황사의 발원지로 Dunhuang과 Inner-Mongolia, 발원지에 근접한 풍하측 지점으로 Yulin과 Beijing, 그리고 장거리 이동 지점으로 한국의 Anmyon과 Gosan, 일본의 Noto, 이렇게 7곳을 선정하여 자료를 분석하였다. 황사의 발생 및 이동 경로를 파악하기 위하여 자외선 원격탐사 기법을 사용하는 인공위성인 Ozone Monitoring Instrument(OMI) 관측자료를 활용하였다. 발원지에서의 단산란알베도는 440 nm에서 0.90에서 0.96 사이의 값으로 높았으나 풍하측이나 장거리 이동 지역에서는 그 값이 감소하였다. 또한, 파장에 따른 단산란알베도 값의 차이는 발원지에서는 높게 나타났으나 이동된 지역에서는 그 차이가 감소하였다. 이러한 장거리 이동에 따른 황사의 광흡수 특성의 변화는 이동 중 탄소입자와 같은 대기 오염물질과의 혼합으로부터 기인하는 것으로 판단된다.

• 대한환경공학회지
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• 제32권3호
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• pp.296-308
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• 2010

Peroxone 공정은 정수처리 공정에서 기존의 염소와 오존 공정들의 여러 가지 한계점들을 극복할 수 있는 공정이다. 과산화수소와 오존에 의해 생성되는 OH 라디칼은 다양한 유기성 오염물질들에 대해 빠른 산화분해 및 높은 제거효율을 나타낸다. Peroxone 공정을 운영하는데 있어 주요 과제는 OH 라디칼 생성을 저해시키는 또는 생성된 OH 라디칼을 소모시키는 scavenger들과 공존할 때 peroxone 공정의 효율을 높일 수 있는 방안을 강구하는 것이다. Bromate와 같은 무기성 산화 부산물의 생성을 최소화할 수 있는 방안과 peroxone 공정 처리 후 염소 소독시 생성되는 염소 소독부산물들의 생성을 보다 저감할 수 있는 방안에 대해서도 많은 연구가 필요하다. 또한, 수중에 잔류하는 과산화수소에 대한 문제이다. 잔류 과산화수소를 on-line으로 측정할 수 있는 정밀한 측정장비의 개발 및 보급이 우선되어야 peroxone 공정의 운영에 있어서 안전성이 확보될 수 있다. 이러한 과제들이 해결이 된다면 peroxone 공정은 보다 다양한 목적으로 정수처리에 효율적으로 적용될 수 있을 것이다.

• 한국환경과학회지
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• 제16권12호
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• pp.1463-1468
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• 2007

Emission of methyl bromide(MeBr) of soil fumigant was implicated in stratospheric ozone depletion. To determine the environmental fate for 1,3-dichloropene(1,3-D) of alternatives fumigants for MeBr, this paper researched the transformation for 1,3-D in water and soil. Half lives of cis-1,3-D in water with first-order kinetics are 9.9day and 1.7day at $25^{\circ}C\;and\;40^{\circ}C$, half lives of trans-1,3-D are 8.6day and 1.5day at $25^{\circ}C\;and\;40^{\circ}C$, respectively. Transformation for 1,3-D in water at high temperature faster then at low temperature. Hydrolysis for 1,3-D in water are unaffected at $pH\;2.5{\sim}pH\;10.0$, but hydrolysis for 1,3-D at pH 11.5 higher then at $pH\;2.5{\sim}pH\;10.0$. Half lives of cis-1,3-D in soil are 11.5day and 7.7day at 3% and 10% of soil moisture, half lives of trans-1,3-D are 9.9day and 6.9day at 3% and 10% of soil moisture, respectively. Transformation for 1,3-D in water increased with increasing soil moisture. Transformation for trans-1,3-D isomer are more rapid then cis-1,3-D isomer in water and soil. This research has identified that transformation for 1,3-dichloropropene are affected by temperature, pH, soil moisture, and isomer of cis and trans in water and soil.

• Korean Chemical Engineering Research
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• 제48권4호
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• pp.540-543
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• 2010

가스 중에 포함되어 있는 질소산화물을 안전하게 처리하기 위하여 저온 플라즈마 반응기를 제작하여 반응기내에 공급되는 반응물질의 유량과 방전주입전력량에 대한 장치의 특성을 실험적으로 조사하고, 유효성을 검정하였다. 반응가스는 $NO/N_2$ 혼합가스와 $N_2/O_2$ 혼합가스를 이용하여 초기 NO 농도를 설정하고, 유속을 1~4 l/min으로 공급하였다. 반응물질의 유량이 증가할 때 NO의 감소율이 낮고, 방전주입전력이 높을 때 NO의 분해가 용이하였다. 또한 반응물질의 지연시간이 길고 방전주입전력이 높을수록 NO의 분해에너지 효율이 높았으며, 유량이 많고 방전 주입 전력량이 증가할수록 오존의 생성량이 증가하였다.

• 설비공학논문집
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• 제6권4호
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• pp.439-452
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• 1994

One of the chlorofluorocarbon compounds. R-12 deplete atmospheric ozone. It leads to international agreement to reduce CFC production. R-134a has similar thermodynamic properties to CFC-12. It has zero ODP(Ozone Depletion Potential). This Paper focuses on the lubricating oils for using with R-134a PAGs(Polyalkylene Glycol's) and esters are primary lubricants that are now being tested for use with R-134a Because of extreme polarity of R-134a. there are many problems in the selection of lubricating oil. This investigation analyzes compressor working conditions and calculates wear parts friction for simulation testing. Miscibility and material compatibility is proved by sealed glass tests. Friction was tested on the closed type pin on disk wear tester. This equipment simulates actual refrigerating compressor. Environment controlled test made more reliable result than field test Conventional oils(mineral oils, Alkylbenzene, PAO(Polyalpha Olefin) are immiscible with R-134a. PAGs and ester oils are miscible with R-134a. Friction coefficient is similar to conventional system(mineral oil/R-12 systems) at operating condition. At start & stop condition, PAGs/R-134a system has high friction coefficient. It provide reliable result on the lubricity, miscibility, material compatibility of R-134a with these new lubricants. It suggests proper selection of refrigeration oil that may improve compressor durability of performance.

• 한국환경농학회지
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• 제27권4호
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• pp.406-412
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• 2008

Biogas plant with anaerobic digestion is receiving high attention as a facility for both livestock waste treatment and electric power generation. Objective of this study was to perform life cycle assessment (LCA) of a biogas plant which incorporates swine and food waste (7:3) as source materials for biogas production. In addition, the biogas production process was compared with the prevalent composting method as a reference in the aspects of green house gas (GHG) reduction potential and environmental impact. The biogas method was capable of reducing 52 kg $CO_2$ eq. emission per ton of swine/food waste, but the composting process was estimated to emit 268 kg $CO_2$ eq. into air. The biogas method was evaluated as more beneficial to the environment by mitigating the impact on abiotic depletion potential (ADP), global warming potential (GWP), ozone depletion potential (ODP), eutrophication potential (EP), and photochemical ozone creation potential (POCP), but not to acidification potential (AP).

• 한국대기환경학회지
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• 제22권1호
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• pp.63-71
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• 2006

An automated carbonyl measurement system was constructed. Atmospheric carbonyl compounds were extracted onto DNPH containing collection solution while flowing through a glass coil. Each carbonyl species was separated on a HPLC column and quantified by UV absorption detector. Using this system, carbonyl compounds were continuously measured at the campus of Korea University in Seoul, Korea during June, 2005. Sampling resolution was 30 minutes and the detection limit of HCHO was 0.19 ppbv. Also, $\O_{3}$, it's precursors, and meteorological parameters were measured. The maximum, minimum, average, and median concentrations of HCHO during the whole experiment was 35.8 ppbv, 1.4 ppbv, 11.7 ppbv, and 9.3 ppbv respectively. Formaldehyde showed a distinct diurnal variation with a broad maximum around 13 $\sim$ 15, which was 1 $\sim$ 3 hours ahead of an ozone maximum. During a couple of days, however, HCHO concentrations were kept high through the night or increased concomitantly with NOx in the morning. These results imply that HCHO was mainly produced from the photochemical oxidation of VOCs, but local emission sources couldn't be ruled out. The differences between daily maximum and minimum of $O_{3}$ and HCHO were calculated for 11 days of June, when typical diurnal variations were observed for the two species. A strong positive correlation was found between $\Delta O_{3}$ and $\Delta HCHO$ and the average mole ratio of $\Delta HCHO$ to $\Delta O_{3}$ was 2.6. It indicates that formaldehyde played a key role in $\Delta O_{3}$ production as an indicator species in Metropolitan Seoul during June, 2005.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.172-172
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• 2016

The International Maritime Organization(IMO) adopted the International Convention for the Control and Management of Ships' Ballast Water and Sediments in 2004 to prevent the transfer of aquatic organisms via ballast water. Forty ballast water treatment systems were granted final approval. A variety of techniques have been developed for ballast water treatment including UV treatment, indirect or direct electrolysis, ozone treatment, chemical compounds and plasma-arc method. In particular, using plasma and ozone nano-bubble treatments have been attracted in the fields. However, these treatment systems have a problem such as remained toxic substance, demand for high power source, low efficiency, ets. In this paper, we present our strilization results obtained from membrane type electrolytic-reduction treatment system The core of an electrolysis unit is an electrochemical cell, which is filled with pure water and has two electrodes connected with an external power supply. At a certain voltage, which is called critical voltage, between both electrodes, the electrodes start to produce hydrogen gas at the negatively biased electrode and oxygen gas at the positively biased electrode. The amount of gases produced per unit time is directly related to the current that passes through the electrochemical cell. From the results, we could confirm the sterilization effect of bacteria such as S. aureus, E. Coli and demonstrate the mechanism of sterilization phenomena by electrolytic-reduction treatment system.

• 한국식품저장유통학회지
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• 제10권4호
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• pp.447-453
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• 2003

얼룩과는 배 재배중에 사용하는 봉지 종류에 따라 수확시발생률이 다른데 흡습성과 투기성이 불량한 이중 봉지인 신문 봉지를 사용한 경우 수확시 발생률이 75%로 가장 높았으며 저온 저장중에는 습도가 높을수록 많이 발생하여 저장 180일까지 폴리에틸렌 필름 밀봉구에서 54～100% 까지 발생하였다 또한 수확 시기가 늦어질수록 얼룩과 발생이 많아져 관행 수확기보다 일주일 빠른 9월 하순에 수확한 배보다 10월 초순이나 10월 중순에 수확한 배는 저장중에 각각 1.5, 2.4배나 높은 발생률을 보였고 저장중 폴리에틸렌 필름두께에 따라서는 얼룩과 발생률이 차이가 없었다. 얼룩과의 발현 원인이 미생물로 추정되어 과피에서 분리균을 채취, 배양하여 형태적으로 관찰한 결과, 원인균은 Gloeodes pomigena와 유사한 균으로 추정되었다. 저온 저장고 내에서 0.1～0.5ppm의 오존 가스를 처리하면 저장 180일까지 얼룩과가 전혀 발생하지 않았으며 얼룩과 발생 이후에 오존 가스를 처리해도 얼룩과의 진전을 막을 수 있었다.

• 센서학회지
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• 제30권5호
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• pp.309-313
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• 2021

Organic semiconductors have received tremendous attention for their research because of their tunable electrical and optical properties that can be achieved by changing their molecular structure. However, organic materials are inherently unstable in the presence of oxygen and moisture. Therefore, it is necessary to develop moisture and air stable semiconducting materials that can replace conventional organic semiconductors. In this study, we developed a NiO_x thin film through a solution process. The electrical characteristics of the NiO_x thin film, depending on the thermal annealing temperature and UV-ozone treatment, were determined by applying them to the hole injection layer of an organic light-emitting diode. A high annealing temperature of 500 ℃ and UV-ozone treatment enhanced the conductivity of the NiO_x thin films. The optimized NiO_x exhibited beneficial hole injection properties comparable those of 1,4,5,8,9,11-hexaazatriphenylene hexacarbonitrile (HAT-CN), a conventional organic hole injection layer. As a result, both devices exhibited similar power efficiencies and the comparable electroluminescent spectra. We believe that NiO_x could be a potential solution which can provide robustness to conventional organic semiconductors.