• Title/Summary/Keyword: High ozone

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Analysis of Time Series Models for Ozone Concentration at Anyang City of Gyeonggi-Do in Korea (경기도 안양시 오존농도의 시계열모형 연구)

  • Lee, Hoon-Ja
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.5
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    • pp.604-612
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    • 2008
  • The ozone concentration is one of the important environmental issue for measurement of the atmospheric condition of the country. This study focuses on applying the Autoregressive Error (ARE) model for analyzing the ozone data at middle part of the Gyeonggi-Do, Anyang monitoring site in Korea. In the ARE model, eight meteorological variables and four pollution variables are used as the explanatory variables. The eight meteorological variables are daily maximum temperature, wind speed, amount of cloud, global radiation, relative humidity, rainfall, dew point temperature, and water vapor pressure. The four air pollution variables are sulfur dioxide $(SO_2)$, nitrogen dioxide $(NO_2)$, carbon monoxide (CO), and particulate matter 10 (PM10). The result shows that ARE models both overall and monthly data are suited for describing the oBone concentration. In the ARE model for overall ozone data, ozone concentration can be explained about 71% to by the PM10, global radiation and wind speed. Also the four types of ARE models for high level of ozone data (over 80 ppb) have been analyzed. In the best ARE model for high level of ozone data, ozone can be explained about 96% by the PM10, daliy maximum temperature, and cloud amount.

Characteristics of near-surface ozone distribution

  • Kim, Yoo-Keun;Lee, Hwa-Woon;Kim, Jae-Hwan;Moon, Yun-Seob;Song, Sang-Keun
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.3
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    • pp.127-137
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    • 2000
  • This study presents an analysis of the characteristics of vertical ozone distribution near the surface using ozonesonde data(l995 to 1998), plus surface ozone and meteorological data from the Pohang region. These features were examined in detail using three case studies. The first related to episodes of high surface ozone concentrations during the Spring season when the frontogenesis between the high and low pressure associated with the upper-level jet stream was found to be located near the surface. The second was a 5-day winter period(l3 -17 December, 1997) in the Pohang province when the hourly concentrations exceeded 90 ppb on several occasions owing to low-level jets(LLJs) induced by a nocturnal stable layer. Accordingly, this explains why the high surface ozone concentrations occurred at night as the ozone was transported across the zone by a strong wind speed( over 12.5 ms .1). The third case study was ozone enhancement due to photochemical reactions. In this case, the maximum concentration of ozone exceeded 60 ppb in the summer(23 -28 August, 1997). When an ozone peak appeared within the boundary layer, the occurrence frequency of a low-level jet due to the nocturnal stable layer was about 77%, similarly the occurrence frequency of a near-surface ozone peak relative to the appearance of an LLJ was about 76%. Accordingly, there is clearly a close correlation between the occurrence of LLJs and near-surface ozone peaks.

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A study on high ozone concentration in Shiwha.Banwol industry complex using photochemical air pollution model- Analysis of meteorological characteristics - (시화.반월단지지역의 고농도 오존일에 대한 광화학모델 적용 연구 - 기상특성에 대한 분석 -)

  • An, Jae-Ho
    • Journal of the Korean Solar Energy Society
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    • v.31 no.5
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    • pp.47-59
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    • 2011
  • The purpose of this paper is to simulate the high ozone concentration in Shiwha Banwol indusrial complex. High pollution episodes (ozone alert) of this area are the results of geographical location and its air pollutants emission. This research has used meteorological model (RAMS) and photochemical air pollution Model (CIT model). As first step of the evaluate of this combined model system simulations are done in terms of meteorological characteristics like wind fields, PBL-height, etc.. Numerical simulations are carried out with real meteorological synoptic data on June. 24-25, 2010. In comparison with real measurement and another research the model reflects well local meteorological phenomena and shows the possibility to be utilized to analyse the pollutant dispersion over irregular terrain region. The high ozone concentration is deeply correlated to the ambient air temperature, wind speed and solar radiation. Local meteorological phenomena like sea-land breeze impact on horizontal dispersion of ozone. This analysis of meteorological characteristics can, in turn, help to predict their influences on air quality and to manage the high ozone episodes.

Estimation and Variation of an Exposed Population of a Vulnerable Group to High Ozone Episodes (고농도 오존발생시 취약계층 노출 인구 현황 및 변화)

  • Kang, Jae-Eun;Bang, Jin-Hee;Oh, In-Bo;Kim, Yoo-Keun
    • Journal of Environmental Science International
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    • v.23 no.4
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    • pp.697-705
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    • 2014
  • The exposed population of a vulnerable group to high ozone episodes (exceeding 60 ppb/8h) was estimated in Busan metropolitan city from 2000 to 2010. The frequency of high ozone days at monitoring sites and the number of the population aged over 65 were used to calculate the accumulated (total, seasonal, and yearly) number of the exposed older population (EOP) to high ozone episodes during the study period based on administrative areas, by interpolation and zonal mean methods in ArcGIS software. The older population in this city had increased significantly from 2000 to 2010 (representing over 10% of the total population in 2010). The vulnerable areas (e.g. the eastern area of the city) of the EOP to high ozone episodes were different from the areas with frequent high ozone episodes (e.g., the western area) due to the increase of the older population in particular areas. The difference was more significant in spring than in any other season, and in 2010 than in previous years (2000 and 2005).

A Study on the Characteristics of Antecedent Meteorologic Conditions on High Ozone Days in Busan (부산지역 고농도 오존일의 선행 기상 특성 연구)

  • Do, Woo-Gon;Jung, Woo-Sik
    • Journal of Environmental Science International
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    • v.24 no.8
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    • pp.993-1001
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    • 2015
  • Comparing to the other air pollutants like $SO_2$, CO, the number of exceedance of the ozone national ambient air quality standard(NAAQS) and the ozone warning increased recently in Busan. The purpose of this study is to find out the preliminary symptoms for high ozone days in Busan area. In order to find out the preliminary symptoms, the hourly ozone data at air quality monitoring stations and the hourly meterological parameters at Busan regional meteorological 2007 to 2013 were used for the analysis. Averaged daily max ozone concentration was the highest(0.055 ppm) at Noksan and Youngsuri in the ozone season from 2007 to 2013. The horizontal distributions of daily max. ozone including all stations in Busan at high ozone days(the day exceeding 0.1 ppm of ozone concentration at least one station) were classified from two to five clusters by hierarchial cluster analysis. The meteorological variables showing strong correlation with daily max. ozone were the daily mean dew point temperature, averaged total insolation, the daily mean relative humidity and the daily mean cloud amount. And the most frequent levels were $19-23^{\circ}C$ in dew point temperature, $21-24 MJ/m^2$ in total insolation on the day before, $2.6-3.0 MJ/m^2$ on the very day, 67-80% in relative humidity and 0-3 in cloud amount.

A Study on Photoresist Strip Process using DIO3 (오존수를 이용한 감광막 제거 공정에 관한 연구)

  • Chai, Sang-Hoon;Son, Young-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1143-1148
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    • 2004
  • In this study, photoresist stripping in semiconductor or LCD (liquid crystal display) fabrication processes using DIO, was investigated. In order to obtain the high PR stripping efficiency of DIO. we have developed new ozone-generating system with high ozone concentration and ozone-resolving system with high contact ratio. In this study, we obtained ozone gas concentrations of 11 % by new ozone-generating system, ozone-resolving efficiency of 99.5 % and maximum solubility of 130 ppm in deionized water. We applied the newly designed equipments to photoresist stripping processes and obtained similar results to SPM(sulfuric-peroxide mixture) process characteristics.

Evaluation of the Effect of Regional Pollutants and Residual Ozone on Ozone Concentrations in the Morning in the Inland of the Kanto Region

  • Kiriyama, Yusuke;Shimadera, Hikari;Itahashi, Syuichi;Hayami, Hiroshi;Miura, Kazuhiko
    • Asian Journal of Atmospheric Environment
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    • v.9 no.1
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    • pp.1-11
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    • 2015
  • Increasing ozone concentrations are observed over Japan from year to year. One cause of high ozone concentration in the Kanto region, which includes areas inland from large coastal cities such as metropolitan Tokyo, is the transportation of precursors by sea breezes. However, high ozone concentrations are also observed in the morning, before sea breezes approach inland areas. In this point, there would be a possibility of residual ozone existing above the nocturnal boundary layer affects the ozone concentration in the following morning. In this study, we utilized the Weather Research and Forecasting model and the Community Multiscale Air Quality model to evaluate the effect of regional precursors and residual ozone on ozone concentrations over the inland Kanto region. The results show that precursors emitted from non-metropolitan areas affected inland ozone concentrations more than did precursors from metropolitan areas. Moreover, calculated results indicate downward transportation of residual ozone, resulting in increased concentration. The residual ozone was also affected by precursors emitted from non-metropolitan areas.

Characterization of Ozone Distributions in Pohang: Measurement Data during 2002~2006 (포항지역 오존농도의 분포 특성: 2002~2006년 측정자료)

  • Lim, Ho-Jin;Lee, Yong-Jik
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.1
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    • pp.50-62
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    • 2011
  • Temporal trends and spatial distributions of ozone concentrations in Pohang were investigated using data measured at 4 air quality monitoring stations (i.e., Daedo, Jukdo, Jangheung, and Desong) during 2002-2006. The monthly mean ozone concentrations were highest during April and June and decreased during July and August, which follows the typical trend in the Northeast Asia region. The high springtime ozone concentration might have been strongly influenced by the enhanced photochemical ozone production of accumulated precursors during the winter under increased solar radiations. In July and August, ozone levels were decreased by frequent and severe precipitation that caused lower mean monthly solar radiation and efficient wash-out of ozone precursors. This suggests that precipitation is extremely beneficial in the aspect of ozone pollution control. High ozone concentrations exceeding 80ppb dominantly occurred in May and June during the late afternoon between 16:00~17:00. Ozone concentrations were higher in Jangheung and Daesong relative to Daedo and Jukdo, whereas total oxidants $(O_3+NO_2)$ were higher in Jangheung and Daedo. In the suburban area of Daesong, ozone concentrations seem to be considerably higher than those in urban sites of Daedo and Jukdo due to lower ozone loss by NO titration with lower local NO level.

A High Efficiency Ozone Generation Using a Electrode-edge Discharge and a Dielectric-Barrier Discharge (전극연면방전(電極沿面放電)과 유전체장벽방전(誘電體障壁放電)을 공용(共用)한 고효율(高效率) 오존발생(發生))

  • Choi, Jae-Gu;Moon, Jae-Duk
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1410-1412
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    • 1995
  • A high efficiency ozone generation using both of a electrode-edge discharge and a dielectric-harrier discharge from a modified silent type ozone generator has been proposed and studied for small scale applications. It is found that the output ozone concentration of the proposed generator depended greatly upon the air gap spacing and the applied power frequency and voltage on the ozone generation. The ozone generator showed higher ozone concentration than the same size of the ceramic type surface ozone generator(Masuda type one). And, it is found that the generator had a potential to be used as an ozone generator for small scale applications.

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Influences of Mesh Shapes and Interspacings on Ozone Generation Characteristics (그물방전극 형상과 방전공격이 오존생에 미치는 영향)

  • Park, Seung-Lok;Lee, Jae-Chan;Moon, Jae-Duk;Jung, Sung-Jin
    • Proceedings of the KIEE Conference
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    • 2000.07e
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    • pp.29-32
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    • 2000
  • Ozone has been widely applied to many industrial fields because of its strong oxidation effects. Therefore, the studies have been progressed for the effective and high concentration of one generation. The silent or surface discharge have been mainly used for high concentration ozone generation until now. But these two types of ozone generators have shortcomings to be improved. In this study, the ozone generator which improved the shortcomings of above two type of ozone generators was proposed and manufactured for high concentration ozone generation. And the proposed ozone generator could generate the surface and barrier discharge simultaneously. For this purpose, a mesh type discharge electrodes were proposed and the experiments were fulfilled as a function of the widths and spacings of mesh electrodes and gap spacings between the dielectric barrier and mesh electrode. When the width of mesh electrode[WM] and spacing of mesh electrode[SM] are 0.3[mm] and 0.8[mm] respectively, the maximum ozone concentration of 2.96[vol%] was obtained at 5.6[kV], 830[mA], gap spacing (S)=0.65[mm].

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