• Journal of Korean Society for Atmospheric Environment
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• v.24 no.E2
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• pp.74-82
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• 2008

We have examined seasonal and annual means of clear-sky solar noon and daily erythemal ultraviolet-B irradiances measured in Anmyeon. The intensity of the EUV-B irradiance is mainly dependent on solar zenith angle (SZA) and total ozone amounts on clear day conditions. The daily maximum occurs near solar noon time and the highest monthly accumulated EUV-B is seen in July in Anmyeon. The maximum daily variation occurs in June and July due to precipitation and clouds. The 7-year trend of EUV-B irradiance shows that it is slightly increasing. Additionally, we could confirm that aerosol effects such as Asian Dust decreases the EUV-B irradiance reaching the ground surface by 35% to 60%. For more than 45% of the summer days, EUV-B irradiacne was high enough that the UV index registered higher than category Extremely High. This information will be very important for evaluation of the UV index for prevention of both skin cancer and ecosystem damages as well as to understand UV climatology over the Korean Peninsula.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.25 no.7
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• pp.83-91
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• 2011

Even if smoke, fumes, mist or dust particles are removed by electrostatic precipitators (ESPs), the occurrence of ozone, which is harmful to human body, has to be severely restricted in the indoor environments of hospitals, offices, and workshops. Therefore, the two-stage ESP generating positive corona at the ionizer is typically used because it creates less ozone than the two-stage ESP generating negative corona at the ionizer. In order to predict the collection performance and the optimal design of the two-stage ESP applied to positive high-voltage, particle concentration is experimentally investigated in this paper. In addition, particle motion within the collector section is also numerically analyzed. The positive corona discharge current of the ionizer is found to be affected by the applied voltage in the collector section but less so by the particle concentration. Particle concentration shows a minimum near the high voltage electrode of the collector section. The minimum value of the collection efficiency is almost proportional to gas velocity. When the collector length decreases, the minimum value of the collection efficiency increases. Charged particles entering the collector region are linearly deflected towards the grounded plate by an electric field. From the above experimental and numerical results, two empirical equations on the concentration ratio and the collection efficiency are derived, and are in good agreement with the experimental data.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 1998.10a
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• pp.1-1
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• 1998

Advanced (Chemical) oxidation processes (AOP) differ from most conventional ones in that hydroxyl radical(OH.) is considered to be the primary oxidant. Hydroxyl radicalcan react non-selectively with a great number of organic and inorganic chemicals. The typical rate constants of true hydroxyl radical reactions are in the range of between 109 to 1012 sec-1. Many processes are possible to generate hydroxyl radical. These include physical and chemical methods and their combinations. Physical means involves the use of high energy radiation such as gamma ray, electron beam, and acoustic wave. Under an applied high energy radiation, water molecules can be decomposed to yield hydroxyl radicals or aqueous electrons. Chemical means include the use of conventional oxidants such as hydrogen peroxide and ozone, two of the most efficient oxidants in the presence of promoter or catalyst. Hydrogen peroxide in the presence of a catalyst such as divalent iron ions can readily produce hydroxyl radicals. Ozone in the presence of specific chemical species such as OH- or hydrogen peroxide, can also generate hydroxyl radicals. Finally the combination of chemical and physical means can also yield hydroxyl radicals. Hydrogen peroxide in the presence of acoustic wave or ultra violet beam can generate hydroxyl radicals. The principles for hydroxyl radical generation will be discussed. Recent case studied of AOP for water treatment and other environmental of applications will be presented. These include the treatment of contaminated soils using electro-Fenton, lechate treatment with conventional Ponton, treatment of coal for sulfur removal using sonochemical and the treatment of groundwater with enhanced sonochemical processes.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.6
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• pp.759-771
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• 2004

This study analyzed concentrations of volatile organic compounds (VOCs) produced from incineration of plastic wastes at $600^{\circ}C$. The plastic wastes used in this study included polyethyleneterephthlate (PETE), high density polyethylene (HOPE), polyvinyl chloride (PVC), low density polyethylene (LOPE), polypropylene (PP), polystyrene (PS) and other. Plastic wastes were heated from room temperature upto $600^{\circ}C$ providing the compressed air inside of a small-scale electric furnace for 90 minutes and then they were oxidized (incinerated) for 60 minutes at $600^{\circ}C$ maintaining the same air supply. VOCs emitted from the incineration process were sampled using an air sampling pump and Tedlar air bags for 150 minutes and then the components and concentrations of the VOCs were analyzed by a GC-MS. The most prominent chemical structure of the VOCs obtained from the incineration process of the HOPE, LOPE and PP, which include ethylene groups in their main chains, was identified as aliphatic hydrocarbons such as 1-hexene. However, aromatics such as benzene were major chemical structure from the incineration of PETE, PVC and PS which include benzene rings in their main chains. This study estimated the total VOC production from the incineration of the plastic wastes based on the real plastic waste production and the emission factors. 64% and 27% of the total VOC emissions consisted of aliphatic hydrocarbons and aromatics, respectively, which have double bonds within their molecular structure and thus a high ground level ozone formation potential.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.6
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• pp.633-640
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• 2008

In this research, the $3.6m^3/day$ scale pilot plant consisting preozonation, coagulation, flocculation, and ceramic membrane processes was operated for long term period to evaluate the validity of ceramic membrane filtration process for treating lake water containing high concentration manganese. The higher concentration of dissolved manganese($Mn^{2+}$) was effectively oxidized to the bigger insoluble colloidal manganese ($MnO^2$) by 1~2 mg/L ozone. The colloidal manganese reacted with coagulant (poly aluminium chloride, PAC) and then formed the big floc. Ceramic membrane rejected effectively manganese floc during membrane filtration. Dissolved organic carbon(DOC) removal was dependent upon $Mn^{2+}$ concentration. While average $Mn^{2+}$ concentration was 0.43 and 0.85 mg/L in raw water, DOC removal rate in preozonation was 26.5 and 13.5%, respectively. The decrease rate of membrane permeability was faster without preozonation than with preozonation while membrane fouling decreased with NOM oxidation by ozone. In conclusion, raw water containing high concentration of manganese can be effectively treated in preozonation-coagulation-ceramic membrane filtration system.

• Textile Coloration and Finishing
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• v.23 no.2
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• pp.76-82
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• 2011

Ultra High molecular weight polyethylene(UHMWPE) films were photooxidized by UV/ozone irradiation. Reflectance of the irradiated films decreased in the low wavelength regions of visible light, indicating destructive interference of visible light due to roughened surface. The UV treatment developed the nano-scale roughness on the UHMWPE films surface, which increased by two-fold from 82.6 to 156.6nm in terms of peak-valley roughness. The UV irradiation caused the oxygen content of the UHMWPE film surface to increase. Water contact angle decreased from $83.2^{\circ}$ to $72.9^{\circ}$ and surface energy increased from 37.8 to 42.6mJ/$m^2$ with increasing UV energy. The surface energy change was attributed to significant contribution of polar component rather than nonpolar component indicating surface photooxidation of UHMWPE films. The increased dyeability to cationic dyes may be due to the photochemically introduced anionic and dipolar dyeing sites on the film surfaces.

• Journal of the Korean Wood Science and Technology
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• v.8 no.3
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• pp.64-76
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• 1980

Fig. 8 summarizes the present status of high yield pulp production and the directions of research on modification. A thick line indicates pulping process presently in use. As mentioned previously, one kind of modification is to introduce hydrophilic groups onto the pulp. Still unsolved is whether or not the introduction of hydrophilic groups should be restricted to lignin only. Goring (28) reported that middle lamella lignin has fewer phenolic hydroxyl groups than cell wall lignin and suggested that such a difference in the lignin may be useful in the removal of middle lamella lignin. The introduction of hydrophilic groups onto pulp may not be enough to modify high yield pulp. The removal of some portion of carbohydrate may be also necessary from the standpoint of softening of pulp fibers. There is no information at what lignin and carbohydrate, and how much should be removed. The combination with synthetic high polymers may also be important in modifying high yield pulp. Prof. C. Schuerch of the State University of New York who was a visiting professor at the University of Tokyo in 1974, mentioned that the hydrophilicity of lignin would be promoted, if phenolic hydroxyl or carboxyl groups could be introduced into the aromatic nucleus of lignin. If this were possible. this process would also mean a pulp yield of more than 100%. This idea is just one example of the expectation made possible through lignin chemistry. Instead of the introduction of hydrophilic group, the oxidative degradation of aromatic nucleus of lignin may also be useful in promoting the hydrophilicity of pulp. In this case, ozone may be an excellent chemical. However, there are a lot of problems to be solved such as homogeneity of reaction and selectivity of ozone for lignin. The above ideas are summarized in Fig. 9. There are many problems to be solved in the production of an excellent high yield pulp which is comparable to chemical pulp. The information from wood chemistry hopefully will elucidate some of the problems mentioned above.

• Proceedings of the IEEK Conference
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• 2001.06e
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• pp.237-240
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• 2001

There are several electricity applied sterilizers such as sterilizer with high frequency, sterilizer with ozone, sterilizer with high voltage, and so on. Those sterilizers feature “because there is no chemical process, there is no secondly environmental pollution” At the power conversion part, AVS and ZCS methods have been used that it results in reduced switching loss, miniaturized size, and lightened weight. Besides, the current in the device is smaller than that of existing method. Thus, it is expected that the cost of sterilization process, when quality of the device is measured by power consumption, will be reduced.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.4
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• pp.378-386
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• 2014

The use of bus stop in the center lane has reduced the emissions of exhaust gas on the road due to the improvement of the traffic speed but has caused a health problem for the citizens who are waiting for the bus in the platform, and thus the air pollution control of bus stop in the center lane is emerging as a more important part. This study was conducted to investigate the air pollution degree for the center lane-bus stops in four regions using mobile air measuring vehicle, and to evaluate the characteristics of air pollution by comparing with the data measured at the urban air monitoring site close to the bus stops. In addition, the correlation analysis was performed to analyze the impact to neighboring region by vehicle exhaust gas. The regional mean concentration of nitrogen dioxide in the center lane-bus stops ranged from 0.025 to 0.043 ppm which shows from 2.5 times to 5.3 times higher than the values of urban air monitoring site selected as a control group. The regional mean concentration of ozone in the center lane-bus stops ranged from 0.023 to 0.034 ppm which shows from 3% to 28% lower than the values of urban air monitoring site selected as a control group. The concentrations of nitrogen dioxide and ozone for the sampling regions did not exceed one hour-air quality environmental standard (0.1 ppm). The mean concentration of particulate matter for four center lane-bus stops was $28{\mu}g/m^3$ which shows about 27% higher than the values of urban air monitoring site selected as a control group, and that of particulate matter did not exceed one day-air quality environmental standard ($100{\mu}g/m^3$). In the results of correlation analysis between data from center lane-bus stops and data from urban air monitoring sites, the correlation coefficient (r) of nitrogen dioxide was relatively low as 0.316 to 0.416, and the correlation coefficient was high as the distance was close and vice versa. However, the correlation coefficient of ozone ranged from 0.167 to 0.658 and the correlation coefficient was high as the distance was far and vice versa.

• International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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• v.21 no.1
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• pp.31-46
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• 1993

A radiative transfer model with two-stream/delta-Eddington approximation has been developed to calculate the vertical distributions of atmospheric heating rates and radiative fluxes. The performance of the model has been evaluated by comparison with the results of ICRCCM (Intercomparison of radiative codes in climate models). It has been demonstrated that the presented model has a capability to calculate the solar radiation not only accurately but also economically. The characteristics of ultraviolet-B radiation (UV-B; 280-320nm) are examined by comparison of relation between the flux at the top of atmosphere and that at the surface. The relation of UV-B is quadratic due to the strong ozone absorption in this band. Also, the dependence of the UV-B radiation on the stratospheric ozone depletion and stratospheric aerosol haze due to volcanic eruption on the stratospheric ozone depletion and stratospheric aerosol haze due to volcanic eruption has been tested with various solar zenith angles. The surface UV-B increases as the solar zenith angle increases. The existence of stratospheric aerosols causes an increase in the planetary albedo due to the aerosols' backscattering. The planetary albedo with aerosol's effect has been increases as the solar zenith angle is not sensitive. It may be caused by the fact that the aerosols' scattering effect becomes saturated with the relatively long path length in a large solar zenith angle. Finally, the regional impact of stratospheric aerosols due to volcanic eruption on the intensity of UV-B radiation at the surface has been estimated. A direct effect is that the flux is diminished at the low latitudes, while it is enhanced in the high latitudes by the aerosols' photon trap or twilight effect. In the high latitudes, both aerosols' scattering and ozone absorption have strong and opposite impacts to the surface UV-B radiation is located at the mid-latitudes during spring season in both hemispheres.