• Title/Summary/Keyword: High ozone

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Cascaded H-bridge Multilevel Inverter for High Precision and Linear Control of the Rate of Ozone Yielding

  • Park, Sung-Jun;Kang, Feel-Soon
    • Journal of international Conference on Electrical Machines and Systems
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    • v.2 no.3
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    • pp.321-329
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    • 2013
  • A multilevel inverter employing a cascade transformer is proposed for a silent-discharge-tube ozone generating system. The proposed inverter consists of four full-bridge inverters and fourteen transformers which have a series-connected secondary. It can accurately control the amplitude of the output voltage; hereby, it improves a linear characteristic of the rate of ozone yielding. The power regulation characteristics and operational principle of the proposed system are explained from a practical point of view. High precision ozone generating performance of the proposed multilevel inverter is verified by computer-aided simulations and experiment results.

Numerical Study on the Impact of Meteorological Input Data on Air Quality Modeling on High Ozone Episode at Coastal Region (기상 입력 자료가 연안지역 고농도 오존 수치 모의에 미치는 영향)

  • Jeon, Won-Bae;Lee, Hwa-Woon;Lee, Soon-Hwan;Choi, Hyun-Jung;Kim, Dong-Hyuk;Park, Soon-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.1
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    • pp.30-40
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    • 2011
  • Numerical simulations were carried out to investigate the impact of SST spatial distribution on the result of air quality modeling. Eulerian photochemical dispersion model CAMx (Comprehensive Air quality Model with eXtensions, version 4.50) was applied in this study and meteorological fields were prepared by RAMS (Regional Atmospheric Modeling System). Three different meteorological fields, due to different SST spatial distributions were used for air quality modeling to assess the sensitivity of CAMx modeling to the different meteorological input data. The horizontal distributions of surface ozone concentrations were analyzed and compared. In each case, the simulated ozone concentrations were different due to the discrepancies of horizontal SST distributions. The discrepancies of land-sea breeze velocity caused the difference of daytime and nighttime ozone concentrations. The result of statistic analysis also showed differences for each case. Case NG, which used meteorological fields with high resolution SST data was most successfully estimated correlation coefficient, root mean squared error and index of agreement value for ground level ozone concentration. The prediction accuracy was also improved clearly for case NG. In conclusion, the results suggest that SST spatial distribution plays an important role in the results of air quality modeling on high ozone episode at coastal region.

Application of High-performance Jet Loop Reactor for the Decolorization of Reactive black 5 and Mineralization of Oxalic Acid by Ozone (색도물질과 옥살산의 오존분해를 위한 고효율 Jet Loop 반응기의 적용)

  • Byun, Seok-jong;Geissen, Sven-Uwe;Vogelpohl, Aflons;Cho, Soon-haing;Yoon, Je-yong;Kim, Soo-Myung
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.78-85
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    • 2004
  • As an ozone contactor, we newly adopted HJLR (High-performance Jet Loop Reactor) for the decolorization of Reactive black 5 and the mineralization of oxalic acid, which has been applied exclusively in biological wastewater treatments and well-known for high oxygen transfer characteristics. The ozonation efficiency for organic removals and ozone utilization depending on the mass transfer rate were compared to those of Stirred bubble column reactor, which was controlled by varing energy input in the HJLR and Stirred bubble column reactor. The results were as follows; first, the decolorization rate of Reactive black 5 in the HJLR reactor was nearly proportional to the increasing $k_La$. When the $k_La$ was increased by 25 % from $13.0hr^{-1}$ to $16.4hr^{-1}$, 30 % of the k' (apparent reaction rate constant) was increased from 0.1966 to $0.2665min^{-1}$ (Stirred bubble column; from 0.1790 to $0.2564min^{-1}$). Ozone transfer was found to be a rate-determining step in decolorizing Reactive black 5, which was supported by that no residual ozone was detected in all of the experiments. Second, the mineralization of oxalic acid was not always proportional to the increasing $k_La$ in the RJLR reactor. The rate-determining step for this reaction was OH(OH radical) production with ozone transfer, because residual ozone was always detected during the ozonation of oxalic acid in contrast with Reactive black 5. This result indicates that the increase of $k_La$ in the HJLR reactor is beneficial only when there are in ozone transfer limited regions. In addition, regardless of $k_La$, the mineralization of oxalic acid was nearly accomplished within 60 minutes. It was interpreted as that the longer staying of residual ozone by whirling liquid in the HJLR reactor contributed to an high ozone utilization(83-94%), producing more OR radicals.

Effect of Surface Ozone on Vegetation in Korea - Preliminary Study on Early Foliage of Robinia pseudo-acacia - (한국의 지면 오존이 식생에 미치는 영향에 관한 연구 - 아까시나무 조기낙엽 현상과 관련성 검토 예비 연구 -)

  • Cho, Seog-Yeon
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.1
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    • pp.29-38
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    • 2007
  • Recently, the tropospheric ozone has gained a global attention for its adverse effect on vegetation as well as its contribution to the global warming. Although a number of studies have been carried out for the urban ozone, the effect of ozone on vegetation is still largely unknown in Korea. The present work aimed at performing the first evaluation of forest damage by ozone using the national air monitoring data from the year 2000 to the year 2005. Moreover, it also explored the relevance of adverse effect of ozone to the recent events on leaf chlorosis of black locust, Robinia pseudo-acacia, leading to early foliage widely observed in Korea since 2001. In the nineties, forest damages caused by ozone such as leaf chlorosis occurred in Europe and North America and led to invoke comprehensive field and laboratory studies. As a result, AOT40, implying the accumulated dose over a threshold 40 ppb, was developed to assess the forest damage by ozone. 19 air monitoring stations were selected across Korea to calculate AOT40 from the year 2000 to the year 2005. The calculated AOT40 generally increased during April and May and reached the maximum after May. The increase of AOT40 diminished substantially from the mid-June as the rainy season started. The calculated AOT40 in the nine rural sites from the year 2002 to th ε year 2005 ranged from 6.8 to 29.4 ppm-hr. And all the AOT40 at th ε year 2005 exceeded the critical value of 10 ppm-hr for forest damage. Morevoer the calculated AOT40 of Korea appeared higher than the AOT40 of Europe in the year 2004/2005 and comparable to the AOT40 of China in the year 2000. Despite the high levels of the calculated AOT40 since the year 2001 and the consistency of time of seasons between high AOT40 values and occurrence of chlorosis of black locust, further studies are required to conclude that the chlorosis of black locust occurred from the year 2001 to the year 2005 were resulted from a damage by ozone.

A Study on the Effect of Cumulus Parameterization and Microphysics on Ozone Simulations during Long-range Transport Process over Northeast Asia (동북아 장거리 수송 과정에서 적운 모수화 및 미세물리과정이 오존 모사농도에 미치는 영향 연구)

  • Kang, Jeong-Eon;Kim, Cheol-Hee
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.2
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    • pp.135-151
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    • 2013
  • This study has been carried out to analyze the sensitivity of ozone concentrations by employing different options of cumulus parameterization schemes (CPSs) and microphysics schemes in MM5 models. These sensitivity tests were applied to long-range transport case of higher ozone over Northeast Asia. Employed CPS schemes are Betts-Miller (BM), Grell (GR), Kain-Fritsch2 (KF2), Anthes-Kuo (AK), None scheme (grid scale physics only), and four microphysics used here are Simple ice, Reisner1, Reisner2, Schultz scheme in MM5. We chose two cases of high ozone long range transport case by employing both concentrations ozone level and backward trajectory model. The results showed that modeled ozone concentrations indicated about 10% differences among CPSs. Of the all options, GR and KF2 (for CPS), and Rersiner-1 and Resiner-2 (for microphysics) showed relatively good and stable variations against ensemble mean values. For both CPS and microphysics schemes, the difference of precipitation arising from different parameterization schemes was significant by itself, but the resultant ozone variations showed only marginal. But the cloud fraction differences arising from different parameterization schemes showed better correlation with ozone variations than precipitation differences, indicating that the photochemical ozone generation variations is more dominant by cloud fraction than wet removal process for high and long-ranged transported ozone cases over Northeast Asia.

Numerical Simulation of Ozone using UAM-V on Summer Episode in the Costal Urban Area, Busan (UAM-V를 이용한 부산지역 고농도 오존사례 수치모의)

  • 김유근;오인보;황미경
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.1
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    • pp.1-11
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    • 2003
  • Temporal and horizontal distributions of surface ozone concentrations covering the Busan metropolitan area were simulated by UAM -V (The Variable grid Urban Airshed Model) that was run with meteorological inputs taken from MM5 for ozone episode day (18 July 1999). UAM-V underestimated the daily maximum ozone con-centration about 14 ppb on average at all monitoring sites within Busan area comparing with observed value. but the correlation between observed and simulated values showed quite significant (R = 0.896, p< 0.01 on average). Higher concentrations of ozone occurred near the city center and industrial areas (western side of city) with high levels of anthropogenic source in the morning, and transport of ozone and its precursors by sea breeze developed in the afternoon contributed to elevated ozone levels in downwind rural areas. Particalarly in slightly downwind area of city center, the highest daily maximum ozone concentration ($\geq$120 ppb) was simulated by UAM-V at 1400 LST. Consequently, local environments including emission distributions and land -sea breeze circulation influenced ozone distributions in the Busan metropolitan area.

The Daily Ozone Concentrations at Gwanak and City Hall: Measurement Data between 1996 and 2000 (관악과 시청의 요일별 오존 농도 : 1996∼2000년 측정자료)

  • 김정화;김용표
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.5
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    • pp.611-619
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    • 2003
  • Characteristics of the ozone concentrations in Seoul were analyzed for the data between May and September from 1996 to 2000. Observation data from 27 stations in Seoul are used. Among the results from 27 stations, representative results from 2 stations (City hall and Gwanak representing downtown and background areas of Seoul, respectively) are presented. The 24-hour average ozone concentrations of Gwanak (28.6 ppb) are higher than City hall (14.9 ppb). The 24-hour average ozone concentrations on Sunday are higher than other days at both sites. During weekday, the 24-hour average ozone concentrations on Wednesday are higher than other days. Although the mean of the I-hour daily maximum ozone concentrations at Gwanak is higher than City hall, the . ozone concentrations above 95th percentile at City hall are higher than Gwanak. As a result, the number of days on which the 1 - hour ozone concentration exceeding 100 ppb and 120 ppb at Gwanak (17 and 3) are lower than City hall (29 and 9). To sum up, both sites are VOCs limited region and the mean ozone concentration in Gwanak is higher because of the lower N0$_2$ concentration. But high ozone cases occur more frequently in City hall when conditions are right.

Effects of Atmospheric Ozone on the Rice Blast Pathogen Pyricularia grisea

  • Hur, Jae-Seoun;Kim, Ki-Woo;Kim, Pan-Gi;Yun, Sung-Chul;Park, Eun-Woo
    • The Plant Pathology Journal
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    • v.16 no.1
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    • pp.19-24
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    • 2000
  • The direct effects of acute $\textrm{O}_3$ on the growth, sporulation and infection of Pyricularia grisea, rece blast pathogen, were investigated to understand the interactions between ozone and the pathogen. Acute exposure of 200 nl $\textrm{l}^{-1}$ ozone for 8 h significantly reduced conidia germination on water atar. Ozone exposure of 200 nl $\textrm{l}^{-1}$ for 8h per day for 5 days had no effect on increase in colony diameter, but severely damaged actively growing aerial mycelia. However, the damage to mycalia was recovered during the following 16 h exposure of unpolluted air. Conidial production was also stimulated by the acute ozone exposure for 5 days. The conidia exposed to the acute ozone for 5 days normally germinates but slightly reduce appressoria formation on rice leaf. However, the conidia produced by artificial stimulation under the same ozone concentration for 10 days showed significant reduction in appressorea for mation on a hydrophobic film. This study suggests that the acute ozone could ingibit appressoria formation as well as vegetative growth of the pathogen, resulting in decrease in rece blast development in the field during summer when high ozone episodes could occur occasionally.

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The Characteristics of the Complex Discharge Type Ozonizer using Applied Voltage of a Inverse-Polarity and a Screw Type Electrode (역극성 전압인가와 나사형 전극을 이용한 복합방전형 오존발생기의 특성)

  • Song, Hyun-Jig
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.9
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    • pp.80-85
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    • 2011
  • In this paper, complex discharge type ozonizer with a screw type electrode has been designed and manufactured for environmental improvement using low power and high efficency ozoniazer. The complex discharge type ozonizer is equipped with three electrodes{central electrode(CE), internal electrode(IE) and external electrode(EE)}. Ozone of the complex discharge type ozonizer is generated by superposition of silent discharge and surface discharge in discharge space as a screw type CE and IE are respectively applied to AC high voltage of inverse-polarity has $180[^{\circ}]$ phase difference, EE is common electrode. In this time, when oxygen has been used as supplied gas, the maximum values of ozone concentration, ozone generation and ozone yield were obtained as 8,334[ppm], 3,249[mg/h] and 65.3[g/kwh].

Effect of Ozone Treatment on Growth of Microorganisms Contaminated Ginseng Powders (오존처리가 인삼분말에 오염시킨 미생물의 생육에 미치는 영향)

  • 곽이성;노길봉;장진규;최강주
    • Journal of Food Hygiene and Safety
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    • v.10 no.1
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    • pp.45-51
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    • 1995
  • Ozone treatment was applied to ginseng powder for the improving hygienic quality of ginseng powder. A bacterial strain was isolated form ginseng powder contaminated. The strain designated as GT4, was identified as Escherichia coli species by IMVIC test method. Ozone inhibited strongly total bacteria and coliforms in ginseng powder(initial concentration 103/g) at 0.35 ppm. High ozone concentration reduced death time of the total bacteria in ginseng powder. However, ozone treatment caused significant degradation in saponins of ginseng powder. Ozone treatment also caused a increase in Hunter's color L value and decrease in a and b values of ginseng powder.

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