• Title/Summary/Keyword: High nitrogen concentration

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Evaluation on Design Factors of Electrolytic Flotation Reactor by Measuring Polarization Curve (분극곡선 측정을 통한 전해부상조의 설계인자 평가)

  • Lim, Bong-Su;Jin, Jing-Zhu;Choi, Chan-Soo
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.244-250
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    • 2007
  • This study was carried out to obtain the optimum design factors for an eletrolytric flotation reactor. When the effluent of the leachate treatment facility was treated under the condition of 10 volts, 30 minutes, at the Al-Al electrode system; COD removal efficiency was 45%, and total phosphorus removal efficiency was 98%. The high removal efficiency was caused by the fact that phosphate was removed by leaching $Al^{3+}$ from two electrodes. The leachate containing high ammonium nitrogen concentration was treated by a batch test under the condition of 60 minutes reaction time and added chloride ion; ammonium nitrogen removal efficiency was 89%. This high efficiency was affected by added chloride ion to wastewater. To find the optimum current density and voltage of the leachate containing chloride ion (ratio of $Cl^-/NH_4-N$ is 11) a electrochemical polarization curve was used. These values were found to be $4.5mA/cm^2$ and about 2.1 V, respectively. When C-Al electrode system was used at a batch test, the total nitrogen removal efficiency was increased by 1.8 to 3.3 times, compared to Al-Al electrode system due to high $Cl_2$ gas production.

Preparation of AlN thin films on silicon by reactive RF magnetron sputtering (RF 마그네트론 스퍼터링을 이용한 Si 기판상의 AlN 박막의 제조)

  • 조찬섭;김형표
    • Journal of the Semiconductor & Display Technology
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    • v.3 no.2
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    • pp.17-21
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    • 2004
  • Aluminum nitride(AlN) thin films were deposited on silicon substrate by reactive RF magnetron sputtering without substrate heating. We investigated the dependence of some properties for AlN thin film on sputtering conditions such as working pressure, $N_2$ concentration and RF power. XRD, Ellipsometer and AES has been measured to find out structural properties and preferred orientation of AlN thin films. Deposition rate of AlN thin film was increased with an increase of RF power and decreased with an increase of $N_2$ concentration. AES in-depth measurements showed that stoichiometry of Aluminium and Nitrogen elements were not affected by $N_2$ concentration. It has shown that low working pressure, low $N_2$ concentration and high RF power should be maintained to deposit AlN thin film with a high degree of (0002) preferred orientation.

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Advanced Treatment of Wastewater from Food Waste Disposer in Modified Ludzack-Ettinger Type Membrane Bioreactor

  • Lee, Jae-Woo;Jutidamrongphan, Warangkana;Park, Ki-Young;Moon, Se-Heum;Park, Chul
    • Environmental Engineering Research
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    • v.17 no.2
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    • pp.59-63
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    • 2012
  • This paper proposes a modified Ludzack-Ettinger (MLE) type membrane bioreactor (MBR) as a method of treatment for wastewater from food waste disposer. Micro-membrane filtration allows for an extremely low concentration of suspended solids in the effluent. The effluent of the reactor in question is characterized by a relatively high level of non-biodegradable organics, containing a substantial amount of soluble microbial products and biomass. Results obtained in this paper by measurement of membrane fouling are consistent with biomass concentration in the reactor, as opposed to chemical oxygen demand (COD). The MLE process is shown to be effective for the treatment of wastewater with a high COD/N ratio of 20, resulting in are markedly high total nitrogen removal efficiency. Denitrification could be improved at a higher internal recycle ratio. Despite the low concentration of influent phosphorus, the phosphorus concentration of the outflow is seen to be relatively high. This is because outflow phosphorous concentration is related to COD consumption, and the process operates at along solids retention time.

Optimum Semi-Continuous Cultivation of Chlorella sp. FC-21 for Production of Biomass: Light Emitting Diodes as a Light Source and High Concentrations of Nitrogen and Phosphate in Culture Media (지속적 바이오매스 생산을 위한 클로렐라 반연속 배양 연구: 발광다이오드(Light Emitting Diode) 광원 및 고농도 인과 질소를 함유한 배지 사용 효과를 중심으로 한 연구)

  • Choi, Boram;Lim, Junhyuk;Lee, Jaekeun;Lee, Taeyoon
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.8
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    • pp.523-527
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    • 2012
  • This study was performed to determine optimum conditions of semi-continuous cultivation of chlorella sp. FC-21 cultivated under red light emitting diode (LED). Semi-continuous cultivation was conducted using red LED because red LED was found to be the best light source for chlorella sp. FC-21. During cultivation, phosphate and nitrogen were quickly diminished where cell concentration of chlorella was inversely proportional to the concentrations of phosphate and nitrogen in culture solution. To increase the period of dilution of culture solution, additional amounts of phosphate and nitrogen were inserted in the culture solution to increase the concentrations of phosphate and nitrogen. The cell concentrations of chlorella increased in the modified culture, but cell diameter was diminished as the dilution of culture was periodically conducted. When considered the cell concentration and cell diameter during the cultivation, amount of biomass produced was maintained constant.

Identification of QTLs Associated with Physiological Nitrogen Use Efficiency in Rice

  • Cho, Young-Il;Jiang, Wenzhu;Chin, Joong-Hyoun;Piao, Zhongze;Cho, Yong-Gu;McCouch, Susan R.;Koh, Hee-Jong
    • Molecules and Cells
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    • v.23 no.1
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    • pp.72-79
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    • 2007
  • Demand for low-input sustainable crop cultivation is increasing to meet the need for environment-friendly agriculture. Consequently, developing genotypes with high nutrient use efficiency is one of the major objectives of crop breeding programs. This study was conducted to identify QTLs for traits associated with physiological nitrogen use efficiency (PNUE). A recombinant inbred population (DT-RILs) between Dasanbyeo (a tongil type rice, derived from an indica ${\times}$ japonica cross and similar to indica in its genetic make-up) and TR22183 (a Chinese japonica variety) consisting of 166 $F_8$ lines was developed and used for mapping. A frame map of 1,409 cM containing 113 SSR and 103 STS markers with an average interval of 6.5 cM between adjacent marker loci was constructed using the DT-RILs. The RILs were cultivated in ordinary-N ($N-P_2O_5-K_2O=100-80-80kg/ha$) and low-N ($N-P_2O_5-K_2O=50-80-80kg/ha$) (100 kg/ha) conditions. PNUE was positively correlated with the harvest index and grain yield in both conditions. Twenty single QTLs (S-QTLs) and 58 pairs of epistatic loci (E-QTLs) were identified for the nitrogen concentration of grain, nitrogen concentration of straw, nitrogen content of shoot, harvest index, grain yield, straw yield and PNUE in both conditions. The phenotypic variance explained by these S-QTLs and E-QTLs ranged from 11.1 to 44.3% and from 16.0% to 63.6%, respectively. The total phenotypic variance explained by all the QTLs for each trait ranged from 35.8% to 71.3%, showing that the expression of PNUE and related characters depends signify- cantly upon genetic factors. Both S-QTLs and E-QTLs may be useful for marker-assisted selection (MAS) to develop higher PNUE genotypes.

Variations in carbon and nitrogen stable isotopes and in heavy metal contents of mariculture kelp Undaria pinnatifida in Gijang, southeastern Korea

  • Shim, JeongHee;Kim, Jeong Bae;Hwang, Dong-Woon;Choi, Hee-Gu;Lee, Yoon
    • ALGAE
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    • v.32 no.4
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    • pp.349-357
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    • 2017
  • Korean mariculture Undaria pinnatifida was collected during the months of January, February, March, and December of 2010, as well as from January of 2011 to investigate the changes in the carbon and nitrogen stable isotope ratios (${\delta}^{13}C$ and ${\delta}^{15}N$) and heavy metal with respect to it growth and to identify the factors that influence such changes. The blades of U. pinnatifida showed ${\delta}^{13}C$ and ${\delta}^{15}N$ in the range (mean) of -13.11 to -19.42‰ (-16.93‰) and 2.99 to 7.57‰ (4.71‰), respectively. Among samples with the same grow-out period, those that weighed more tended to have higher ${\delta}^{13}C$ suggesting a close association between the carbon isotope ratio and growth rate of U. pinnatifida. Indeed, we found a very high positive linear correlation between the monthly average ${\delta}^{13}C$ and the absolute growth rate in weight ($r^2=0.89$). Nitrogen isotope ratio tended to be relatively lower when nitrogen content in the blade was higher, probably due to the strengthening of isotope fractionation stemming from plenty of nitrogen in the surrounding environment. In fact, a negative linear correlation was observed with the nitrate concentration in the nearby seawaters ($r^2=0.83$). Concentrations of Cu, Cd, Pb, Cr, Hg, and Fe in the blades showed a rapid decrease in their concentration per unit weight in the more mature U. pinnatifida. Specifically, compared to adult samples, Cu, Hg, and Pb were concentrated by 30, 55, and 73 folds, respectively, in the young blades. Therefore, U. pinnatifida tissue ${\delta}^{13}C$ is as an indirect indicator of its growth rate, while ${\delta}^{15}N$ values and heavy metal concentrations serve as tracers that reflect the environmental characteristics.

Advanced Water Treatment of High Turbidity Source by Hybrid Process of Photocatalyst and Alumina Microfiltration: Effect of Organic Matters at Nitrogen Back-flushing (광촉매 및 알루미나 정밀여과 혼성공정에 의한 고탁도 원수의 고도정수처리: 질소 역세척시 유기물의 영향)

  • Park, Jin Yong;Sim, Sung Bo
    • Membrane Journal
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    • v.22 no.6
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    • pp.441-449
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    • 2012
  • Effect of humic acid (HA) with periodic nitrogen back-flushing was investigated in hybrid process of alumina microfiltration and photocatalyst for drinking water treatment. It was compared and investigated with the previous results of microfiltration water back-flushing or ultrafiltration nitrogen back-flushing in viewpoints of membrane fouling resistance ($R_f$), permeate flux (J), and total permeate volume ($V_T$). As results, the trends of membrane fouling were different depending on nitrogen or water back-flushing, and depending on ultrafiltration or microfiltration made with the same material. Also, the nitrogen back-flushing using microfiltration was more effective membrane fouling inhibition than ultrafiltration, and the nitrogen back-flushing was more effective than water back-flushing using the same microfiltration membrane. Turbidity treatment efficiencies were almost constant independent of HA concentration, but HA treatment efficiency was the maximum at HA 10 mg/L. From this results, it was shown that the treated water HA quality increased as increasing HA concentration, but HA could be removed the most effectively by photocatalyst beads adsorption and photo-oxidation at HA 10 mg/L.

Experimental Study on the Soot Formation Characteristics of Alkane-based Single Fuel Droplet (알케인계 단일 연료 액적의 Soot 생성 특성에 관한 실험적 연구)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.22 no.2
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    • pp.80-86
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    • 2017
  • The soot formation characteristics of various alkane-based single fuel droplets were studied in this work. Also, This study was performed to provide the database of the soot behavior and formation of alkane-based single fuel droplet. The experimental conditions were set to 1.0 atm of ambient pressure ($P_{amb}$), 21% of oxygen concentration ($O_2$) and 79% of nitrogen concentration ($N_2$). Combustion and soot formation of single fuel droplet was visualized by visualization system with high speed camera. At the same time, ambient pressure, oxygen concentration and nitrogen concentration were maintained by ambient condition control system. Soot formation characteristics was analyzed and compared on the basis of intensity ratio ($I/I_0$) of background image. The results of toluene fuel droplet showed the largest soot generation. Soot volume fraction ($f_v$) was almost the same under the identical fuel types regardless of various initial droplet diameter ($d_0$) since thermophoretic flux was not much changed under the same ambient conditions.

The Electro-Chemical Treatment for Nitrogen Removal of Metal Finishing Wastewater (질소제거를 위한 금속표면처리폐수의 전기화학적 처리)

  • Sim, Joo-Hyun;Seo, Hyung-Joon;Kim, Dae-Hwan
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.190-196
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    • 2007
  • This study examined the nitrate removal efficiency which uses an electrowinning, and also analyzed the nitrate removal efficiency under a variety of operating conditions such as nitrate concentrations, pH, current densities, electrodes, reducing agents in order to determine optimal conditions. In addition, the multi-step electro-chemical process test has been also analyzed. During the electrowinning, the identical Zn-Zn and Pt-Ti electrodes in the insoluble oxidation electrode(Pt) has shown the highest nitrate removal efficiency in the 100 mg $NO_3^{-}$ -N/L concentration. In the concentration of 150 mg $NO_3^{-}$ -N/L, the efficiency of the Zn-Zn electrode were 70~85%, and that of Pt-Ti electrode were 40~50% without any change of pH. In the high concentration of 500 and 1,000 mg $NO_3^{-}$ -N/L, the higher the concentration, the more decrease of its nitrate removal efficiency decreased. However, the energy consumed for nitrogen removal increased when the nitrate concentration was high. As a result of the multi-step electro-chemical process test, We chose the Test 4. Because the first, most of the zinc consumed from 1 step was recovered from over the 2 step. The second, amount of consumption anode decreased with insoluble anode Pt from over the 2 step. And the third, Zn cathode increased the possibility of reusing Zn deposited. In view of the results so far achieved, the multi-step electro-chemical process would be applied to treat nitrogen involved in metal finishing wastewater.

Effects of dietary protein level on growth performance and nitrogen excretion of dairy heifers

  • Zhang, Bin;Wang, Chong;Liu, He;Liu, Jianxin;Liu, Hongyun
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.3
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    • pp.386-391
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    • 2017
  • Objective: Protein supplementation is costly and can result in excess nitrogen (N) excretion. The objective of this study was to evaluate the effects of feeding different levels of dietary protein on average daily gain, body size, rumen fermentation, and nitrogen excretion of 8 to 10 month-old Holstein heifers. Methods: Thirty-six Holstein heifers were divided into 12 blocks according to age ($273{\pm}6.2d$) and were randomly assigned to diets containing a low (10.2% dry matter [DM]), medium (11.9% DM), or high (13.5% DM) level of dietary crude protein (CP). All diets contained approximately 70% roughage and 30% concentrate with similar dietary metabolizable energy (ME) content (2.47 Mcal/kg). Results: Dry matter intake did not differ among the treatments, and average daily gain increased with the increasing dietary protein, 0.79, 0.95, 0.97 kg/d for low, medium, and high group, respectively. Body height increased linearly with increasing dietary CP but no other significant differences in body dimensions were found among the treatments. The increased ratios of dietary CP improved the rate of rear teat length growth remarkably (p<0.05). There was no difference in rumen pH or ruminal major volatile fatty acid (acetate, propionate, and butyrate) concentration among the 3 diets, but rumen ammonia-N concentration increased with the higher dietary CP (p<0.05). Increasing N intake led to increased total N excretion; urinary N excretion was significantly increased (p<0.05) but fecal N excretion was similar among the treatments. Conclusion: These data suggest that the diet containing 11.9% CP (ME 2.47 Mcal/kg) could meet the maintenance and growth requirements of 9 to 11 month-old Holstein heifers gaining approximately 0.9 kg/d.