• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.560-567
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• 2023

This study is part of the research on fire-resistant materials to prepare for changing fire behavior, oyster shell and egg shell, which are natural calcium carbonate materials, were substituted as fine aggregates. The purpose of this study was to evaluate the strength and fire resistance performance according to the substitution rate, and to provide data for use as fire resistance material. Oyster shells and egg shells were substituted with 10~50 % of the fine aggregate, respectively, and tested for strength and Simplified heating according to the KS test method. Although the strength of OS was measured to be higher than that of ES, the backside temperature was also measured to be higher. As a result, it is recommended to use fireproof boards with OS where strength performance is required, such as explosive fires, Where high fire resistance performance is required, such as high-temperature fires over 1000 ℃, fireproof boards with ES can be selected according to the application.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.5
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• pp.535-548
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• 2023

The intermittent nature of renewable energy is a challenge to overcome for safety and stable performance in water electrolysis systems linked to renewable energy. Oxygen removal using the catalyst is suitable for maintaining the oxygen concentration in hydrogen below the explosive level (4%) even in intermittent power supply. Metals such as Pd, Pt, and Ni are expected to be effective materials due to their hydrogen affinity. The oxygen removal performance was compared under high hydrogen concentration conditions by loading on γ-Al₂O₃ with high reactivity and large surface area. The characteristics of the catalyst before and after the reaction were analyzed through X-ray diffraction, transmission electron microscope, H₂-temperature programmed reduction, X-ray photoelectron spectroscope, etc. The Pd catalyst that showed the best performance was able to lower 2% oxygen to less than 5 ppm. Changes in catalyst characteristics after the reaction indicate that oxygen vacancies are related to oxygen removal performance and catalyst deactivation.

• Explosives and Blasting
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• v.41 no.4
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• pp.17-28
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• 2023

Recently, the utilization of underground space for research facilities and resource development has been on the rise, expanding development from shallow to deep underground. The establishment of deep underground spaces necessitates a thorough examination of rock stability under conditions of elevated stress and temperature. In instances of greater depth, the stability is influenced not only by the geological structure and discontinuity of rock but also by the propagation of ground vibrations resulting from earthquakes and rock blasting during excavation, causing stress changes in the underground cavity and impacting rock stability. In terms of blasting engineering, empirical regression models and numerical analysis methods are used to predict ground vibration through statistical regression analysis based on measured data. In this study, single-hole blasting was conducted, and the pressure of the blast hole and observation hole and ground vibration were measured. Based on the experimental results, the blast pressure blasting vibration at a distance, and the response characteristics of the tunnel floor, side walls, and ceiling were analyzed.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.65-65
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• 2012

Copper zinc tin sulfide ($Cu_2ZnSnS_4$, CZTS) is a very promising material as a low cost absorber alternative to other chalcopyrite-type semiconductors based on Ga or In because of the abundant and economical elements. In addition, CZTS has a band-gap energy of 1.4~1.5eV and large absorption coefficient over ${\sim}10^4cm^{-1}$, which is similar to those of $Cu(In,Ga)Se_2$(CIGS) regarded as one of the most successful absorber materials for high efficient solar cell. Most previous works on the fabrication of CZTS thin films were based on the vacuum deposition such as thermal evaporation and RF magnetron sputtering. Although the vacuum deposition has been widely adopted, it is quite expensive and complicated. In this regard, the solution processes such as sol-gel method, nanocrystal dispersion and hybrid slurry method have been developed for easy and cost-effective fabrication of CZTS film. Among these methods, the hybrid slurry method is favorable to make high crystalline and dense absorber layer. However, this method has the demerit using the toxic and explosive hydrazine solvent, which has severe limitation for common use. With these considerations, it is highly desirable to develop a robust, easily scalable and relatively safe solution-based process for the fabrication of a high quality CZTS absorber layer. Here, we demonstrate the fabrication of a high quality CZTS absorber layer with a thickness of 1.5~2.0 ${\mu}m$ and micrometer-scaled grains using two different non-vacuum approaches. The first solution-processing approach includes air-stable non-toxic solvent-based inks in which the commercially available precursor nanoparticles are dispersed in ethanol. Our readily achievable air-stable precursor ink, without the involvement of complex particle synthesis, high toxic solvents, or organic additives, facilitates a convenient method to fabricate a high quality CZTS absorber layer with uniform surface composition and across the film depth when annealed at $530^{\circ}C$. The conversion efficiency and fill factor for the non-toxic ink based solar cells are 5.14% and 52.8%, respectively. The other method is based on the nanocrystal dispersions that are a key ingredient in the deposition of thermally annealed absorber layers. We report a facile synthetic method to produce phase-pure CZTS nanocrystals capped with less toxic and more easily removable ligands. The resulting CZTS nanoparticle dispersion enables us to fabricate uniform, crack-free absorber layer onto Mo-coated soda-lime glass at $500^{\circ}C$, which exhibits a robust and reproducible photovoltaic response. Our simple and less-toxic approach for the fabrication of CZTS layer, reported here, will be the first step in realizing the low-cost solution-processed CZTS solar cell with high efficiency.

• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.321-330
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• 2011

Recently, the effects of high temperature and fiber content on the residual mechnical properties of high-strength concrete were experimentally investigated. In this paper, residual mechanical properties of concrete with water to cement (w/c) ratios of 0.55, 0.42 and 0.35 exposed to high temperature are compared with those obtained in fiber reinforced concrete with similar characteristics ranging from 0.05% to 0.20% polypropylene (PP) fiber volume percentage. Also, factors including pre-load levels of 20% and 40% of the maximum load at room temperature are considered. Outbreak time, thermal strain, length change, and mass loss were tested to determine compressive strength, modulus of elasticity, and energy absorption capacity. From the results, in order to prevent the explosive spalling of 50 MPa grade concretes exposed to high temperature, more than 0.05 vol. % of PP fibers is needed. Also, the cross-sectional area of PP fiber can influence the residual mechanical properties and spalling tendency of fiber reinforced concrete exposed to high temperature. Especially, the external loading increases not only the residual mechanical properties of concrete but also the risk of spalling and brittle failure tendency.

• Journal of Aerospace System Engineering
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• v.13 no.2
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• pp.34-42
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• 2019

The existence of different thermodynamic properties results in various undesirable effects, such as thermal deformation and residual stress, in heat-welding processes. The solid-state junction, by using explosive or electromagnetic forces, i.e., high-velocity impact welding without employing heat is advantageous in joining materials with different thermodynamic properties. In the solid-state junction, the joining is performed within a short time, a high velocity and large deformations are accompanied by interfacial surfaces. The numerical analysis models play an important role in the understanding of the mechanism of high-velocity impact welding. However, in the analysis of high velocity and large deformations, the conventional Lagrangian method has low reliability due to the occurrence of entanglements. In this study, high-velocity impact welding between Cu and CP-Ti with different thermodynamic properties was performed using a un-gridded numerical method, SPH (Smoothed Particle Hydrodynamics), and interfacial morphology occurred. As a result of the analysis, the interfacial morphology was confirmed and the compared degree of shape (straight, vortex), period, length, and so on appeared differently depending on the relationship between the parameters (impact angle and speed).

• Journal of the Korea Institute of Building Construction
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• v.21 no.5
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• pp.483-493
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• 2021

Urban overcrowding has created an explosive supply and demand for high-rise buildings. High-rise buildings are contributing to enhancing the image of the city by serving as focal points, but due to the stack effect, malfunction of elevator doors, difficulties in opening and closing the doors and windows of the outer wall, smoke and odors spreading to the upper floors, noise, energy loss, fire and pollutants have been causing various unexpected problems such as rapid spread of fire. This study classified high-rise buildings according to their vertical zoning, analyzed the causes of and solutions to the stack effect, and derived design and construction methods. Through the initial plan to block the outside air and securing airtightness through precise construction, we sought ways to secure the airtightness inside and outside the building by actively blocking the airflow from the lower floors. In addition, the facility solution can be a measure to reduce the specific phenomena caused by the stack effect, but it should only be applied to the minimum extent because the potential for secondary damage is high. This study emphasized the need for systematic stack effect management by suggesting design and construction measures for each vertical zoning of the causes and countermeasures of the stack effect. It is expected that this study will be helpful not only for design and construction, but also for building maintenance.

• Journal of KIISE:Information Networking
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• v.30 no.5
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• pp.581-594
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• 2003

Recently, a location management is being more important in mobile communication systems due to an explosive increase of mobile users. Current systems have used a concept of location area. Based on this concept, a mobile user performs a location update whenever it moves into a new location area. However, this scheme can not avoid unnecessary location updates when a mobile user moves around with high movement rate as compared to call arrival rate. That results in tremendous location management cost. To overcome this drawback, our proposal divides service areas into two sets: One is a set of areas that mobile users move with high speed and another is a set of areas that they move with low speed. After establishing these two sets, this paper employs different location tracking schemes for each sets. Generally, most mobile users with high speed have a low CMR and a regular direction until they arrive at their destination. Using such the moving behavior, systems can predict a mobile user's next location area in advance. When the mobile user moves into the predicted location, our proposal does not perform a location update. Thus, it can reduce overall location management cost. The Markov model is used to analyze the performance of our proposal. Using the model, this paper compares our proposal with IS-41 and TLA. The analytic results show that as CMR grows lower, an overall cost of our proposal becomes less, particularly if a mobile user frequently moves into the specific location are predicted by mobile systems. Also, our proposal has a better performance than other two schemes when the communication cost between HLR and VLR is high.

• Journal of the Korean Society for Precision Engineering
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• v.25 no.6
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• pp.108-115
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• 2008

The wear on engine valve and seat insert is one of the most important factors affecting engine performance. The engine valve and seat insert must be able to withstand the severe environment that is created by: high temperature exhaust gases generated while the engine is running, rapid movement of the valve spring, high pressure generated in the explosive process. In order to study such problems, a simulator has been developed to generate and control high temperatures and various speeds during motion. The wear simulator is considered to be a valid simulation of the engine valve and seat insert wear process with various speeds during engine activity. This work focused on the test of various degrees of wear on four different exhaust valve materials such as HRV40, HRV40-FNV (face nitrided valve), STL #32, STL #6,. Throughout all tests performed in this study, the outer surface temperature of the seat insert was controlled at $350^{\circ}C$, the cycle number was $4.0{\times}10^6$, the test load was 6860 N, the fuel was LPG the test speed was 20 Hz (2400 RPM) and the seat insert material was HVS1-2. The mean (standard deviation) maximum roughness of the exhaust valve and seat insert was $25.44\;(3.16)\;{\mu}m$ and $27.53\;(3.60)\;{\mu}m$ at the HRV40, $21.58\;(2.38)\;{\mu}m$ and $25.94\;(3.07)\;{\mu}m$ at the HRV40-FNV, $36.73\;(8.98)\;{\mu}m$ and $61.38\;(7.84)\;{\mu}m$ at the STL #32, $73.64\;(23.80)\;{\mu}m$ and $60.80\;(13.49)\;{\mu}m$ at the STL #6, respectively. It was discovered that the maximum roughness of exhaust valve was lower as the high temperature hardness of the valve material was higher under the same test conditions such as temperature, test speed, cycle number, test load and seat insert material. The set of the HRV40-FNV exhaust valve and the HVS1-2 seat insert showed the best wear resistance.

• Economic and Environmental Geology
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• v.5 no.4
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• pp.187-209
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• 1972

Drilling position is one of the most important factors affecting on the blasting effects. There has been many reports on several blasting factors of burn-cut by Messrs. Brown and Cook, but in this study the author tried to compare drilling positions of burn-cut to pyramid-cut, and also to correlate burn-cut effects of drilling patterns, not being dealt by Prof. Ito in his theory, which emphasized on dynamical stress analysis between explosion and free face. According to former theories, there break out additional tensile stress reflected at the free face supplemented to primary compressive stress on the blasting with one-free-face. But with these experimented new drilling patterns of burn-cut, more free faces and nearer distance of each drilling holes make blasting effects greater than any other methods. To promote the above explosive effect rationary, it has to be considered two important categories under-mentioned. First, unloaded hole in the key holes should be drilled in wider diameter possibly so that it breaks out greater stress relief. Second, key holes possibly should have closer distances each other to result clean blasting. These two important factors derived from experiments with, theories of that the larger the dia of the unloaded hole, it can be allowed wider secondary free faces and closes distances of each holes make more developed stress relief, between loaded and unloaded holes. It was suggested that most ideal distance between holes is about 4 clearance in U. S. A., but the author, according to the experiments, it results that the less distance allow, the more effective blasting with increased broken rock volume and longer drifted length can be accomplished. Developed large hole burn-cut method aimed to increase drifting length technically under the above considerations, and progressive success resulted to achieve maximum 7 blasting cycles per day with 3.1m drifting length per cycle. This achievement originated high-speed-drifting works, and it was also proven that application of Metallic AN-FO on large hole burn-cut method overcomes resistance of one-free-face. AN-FO which was favored with low price and safety handling is the mixture of the fertilizer or industrial Ammonium-Nitrate and fuel oil, and it is also experienced that it shows insensible property before the initiation, but once it is initiated by the booster, it has equal explosive power of Ammonium Nitrate Explosives (ANE). There was many reports about AN-FO. On AN-FO mixing ratio, according to these experiments, prowdered AN-FO, 93.5 : 6.5 and prilled AN-FO 94 : 6, are the best ratios. Detonation, shock, and friction sensities are all more insensitive than any other explosives. Residual gas is not toxic, too. On initation and propagation of the detonation test, prilled AN-FO is more effective than powered AN-FO. AN-FO has the best explosion power at 7 days elapsed after it has mixed. While AN-FO was used at open pit in past years prior to other conditions, the author developed new improved explosives, Metallic AN-FO and Underwater explosive, based on the experiments of these fundmental characteristics by study on its usage utilizing AN-FO. Metallic AN-FO is the mixture of AN-FO and Al, Fe-Si powder, and Underwater explosive is made from usual explosive and AN-FO. The explanations about them are described in the other paper. In this study, it is confirmed that the blasting effects of utilizing AN-FO explosives are very good.