• Title/Summary/Keyword: High dielectric properties

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Analysis of Conductivity Variation and Conduction Mechanism in Bulk NiO Based on Sintering Conditions

  • Ju-Hyeon Lee;Tae-Soo Yeo;Wook Jo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.4
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    • pp.418-421
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    • 2023
  • Multilayer Ceramic Capacitors (MLCCs) are essential passive components in the electronics industry, known for their high capacitance due to the multilayer structure comprising inner electrodes and dielectric layers. Nickel electrodes are commonly used in MLCCs as the inner electrodes, and to prevent oxidation during the co-firing of the dielectric layers with nickel electrodes, reducing atmosphere is required. However, reducing atmosphere sintering can also induce a reduction of the dielectric, necessitating precise control of oxygen partial pressure. To explore the possibility of using oxide electrodes that do not require reducing atmosphere sintering, we analyze the electrical properties of nickel oxide (NiO) as a potential candidate. As a preliminary study on its use as an alternative inner electrode, the correlation between microstructure and electrical properties of bulk NiO under different sintering conditions was investigated to gain insights into the conduction mechanisms of the material.

Electrorheological Properties of Anhydrous ER Suspensions Based on Phosphated Cellulose (인산처리 셀룰로오스를 첨가한 비수계 ER 유체의 전기유변학적 특성)

  • 안병길;최웅수;권오관;문탁진
    • Tribology and Lubricants
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    • v.14 no.2
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    • pp.1-9
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    • 1998
  • The electrorheological (ER) behavior of suspensions in silicone oil of phosphated cellulose particles (average particle size 17.77 ${\mu}{\textrm}{m}$) was investigated at room temperature with electric fields up to 2.5 KV/mm. In this paper, for development of anhydrous ER suspensions using at wide temperature range, we would like to know fundamental understandings on the ER activity. As a first step, the anhydrous ER suspensions dispersed the phosphated cellulose particles were measured, and not only the electrical characteristics such as dielectric constant, current density and electrical conductivity but also the rheological properties on strength of electric field and quantity of dispersed phase were studied. From the experimental results, the anhydrous ER suspensions dispersed phosphated cellulose particles showed a stable current density and very high performance of ER effect $(\tau/\tau_0=1030)$ on the 2.5 KV/mm and the dynamic yield stress $(\tau_y)$ was in exponential proportion to the strength of electric fields.

The electrical characteristics of STO dielectric thin films for application of DRAM capacitor. (DRAM 캐패시터 응용을 위한 STO 유전체 박막의 전기적인 특성)

  • 이우선;오금곤;김남오;손경춘;정창수;정용호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.291-294
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    • 1998
  • The objective of this study is to deposited the preparation of STO dielectric thin films on Ag/barrier-mater/Si(N-type 100) bottom electrode using a conventional rf-magnetron sputtering technique with a ceramic target under various conditions. It is demonstrated that the leakage current of films are strongly dependent on the atmosphere during deposition and the substrate temperature. The resistivity properties of films deposited on silicon substrates were very high resistivity. Capacitance of the films properties were the highest value(1000pF) and dependent on substrate temperature.

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The Structure, Surface Morphology and Electrical Properties of ZrO2 Metal-insulator-metal Capacitors (ZrO2 MIM 캐패시터의 구조, 표면 형상 및 전기적 특성)

  • Kim Dae Kyu;Lee Chongmu
    • Korean Journal of Materials Research
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    • v.15 no.2
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    • pp.139-142
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    • 2005
  • [ $ZrO_2$ ] gate dielectric thin films were deposited by radio frequency (rf)-magnetron sputtering and its structure, surface morphology and electrical peoperties were studied. As the oxygen flow rate increases, the surface becomes smoother. The experimental results indicate that a high temperature annealing is desirable since it improves the electrical properties of the $ZrO_2$ gate dielectric thin films by decreasing the number of interfacial traps at the $ZrO_2/Si$ interface. The carrier transport mechanism is dominated by the thermionic emission.

The effect of sintering temperature on the electrical properties of ZnO ceramics (ZnO세라믹스의 소결온도가 전기적 특성에 미치는 영향)

  • 김용혁;이덕출
    • Electrical & Electronic Materials
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    • v.8 no.1
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    • pp.40-47
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    • 1995
  • Electrical properties of ZnO ceramics based on Bi oxide was investigated in relation to sintering temperature. In the temperature range >$1150^{\circ}C$ to >$1350^{\circ}C$ the grain size increased from 9.mu.m to 20.mu.m when the sintering temperature was raised. The leakage current in the low voltage range increased as the potential barrier decreases, which is caused by increasing the grain size at high temperature. The dielectric characteristics of the ZnO ceramics was also affected by sintering temperature. Large dielectric constant was attributed, to the grainboundary layer of polycrystalline ZnO ceramics and decreasing grainboundary width. The variation of breakdown voltage with sintering temperature was attributed to the change of the donor concentration in the ZnO grain and grain size. The results showed that breakdown voltage increased decreasing grain size and donor concentration. Nonohmic coefficient was associated with the lower breakdown voltage per grainboundary layer due to the grain growth and higher donor concentration.

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Research of Degradation Properties on Stator Coil of Traction Motor (견인전동기 고정자 코일의 열화특성 연구)

  • Jang, Dong-Uk;Byun, Yeun-Sub;Wang, Jong-Bae;Park, Hyun-June;Kim, Gil-Dong;Han, Young-Jae
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1430-1432
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    • 2001
  • In this paper, 200-class insulation system for form-wound stator coils is designed for form-wound stator coils is designed for AC traction driven with VVVF inverter. Model coils are made to embody all essential elements representing a winding insulation system and structure. Acceleration degradation for model coils is applied exposure to heat(235$^{\circ}C$). In order to investigate the condition of the coils and to determine their insulation reliability, high voltage test and the dielectric properties such as dielectric loss and capacitance are performed. Also, partial discharge measurement is investigated for internal defects.

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Effect of Annealing on the Dielectric Properties and Microstructures of Thin Tantalum Oxide Film Deposited with RF Reactive Sputtering

  • Lee, Gyeong-Su;Nam, Kee-Soo;Chun, Chang-Hwan;Kim, Geun-Hong
    • ETRI Journal
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    • v.13 no.2
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    • pp.21-27
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    • 1991
  • Effects of annealing on the dielectric properties and microstructures of thin tantalum oxide film(25nm) deposited on p-type Si substrate with rf reactive magnetron sputtering were investigated. The leakage current density was remarkably reduced from $10^-8$ to $10^-12$ A/$\mum^2$at the electric field of 2MV/cm after rapid thermal annealing(RTA) in $O_2$at $1000^{\circ}C$, while little leakage reduction was observed after furnace annealing in $O_2$ at $500^{\circ}C$. The structural changes of thin tantalum oxide film after annealing were examined using high resolution electron microscope(HREM). The results of HREM show that substantial reduction in the leakage current density after the RTA in $O_2$ can be attributed to crystallization and reoxidation of the thin amorphous tantalum oxide film.

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A Study of development on Mica/Epoxy Composite (2) (마이카/ 에폭시 복합재료의 개발에 관한 연구(2))

  • Park, Chung-Hoo;Jeung, Eun-Shik;Kim, Ki-Beom
    • Proceedings of the KIEE Conference
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    • 1987.11a
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    • pp.216-219
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    • 1987
  • Dielectric and Mechanical Properties of Mica flake/ Epoxy Composite are investigated. The Mica content is about 50 wt % and its thickness is about $240{\mu}m$. The finished Mica flake/Epoxy Composite contains about 0.1-1.0 wt % of aminosilane coupling agent. Ruby Mica filler and high temperature curing Epoxy resin are used. From the viewpoint of dielectric and mechanical properities. the optimum properties is obtained for the sample post cured at $130^{\circ}C$ for 5 h ours after curing at $80^{\circ}C$ for 2 hours and with 0.5 weight % silane coupling agent.

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Dielectric Properties of Glass Fiber Reinforced Epoxy Composites by Cure under Pressure (가압 겔화법에 의한 에폭시 복합 재료의 유전적 특성)

  • 곽영순;신중홍;박정후
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.38 no.4
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    • pp.292-297
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    • 1989
  • To achieve fiber/resin reinforced composites with high quality (void-free, uniform compaction), a basic understanding of the principal factors related to a thermal cycle to cure the matrix and a pressure to compact the system is necessary. In this paper, some dielectric and mechanical properties of glass cloth reinforced epoxy composites are measured as a function of fabrication conditions, where the time that the pressure is applied to the sample during the cure process is controlled. Both the tensile strength and frequency characteristics of the sample are improved significantly when the pressure is applied at the start point of gelling.

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Nanocomposite magnetic powder materials using mechanochemical Synthesis

  • Soh, Dae-Wha;Mofa, N.N.;Keteguenov, T.A.;Mansurov, Z.A.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.585-587
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    • 2002
  • The materials showing high structure dispersity are developed on the quartz base and they are obtained by mechano-chemical technology. Depending on the processing conditions and subsequent applications the materials produced by mechano-chemical reaction show concurrently magnetic, dielectric and electrical properties. The obtained magnetic-electrical powders classified by aggregate complex of their features as segnetomagnetics, contain a dielectric material as a canγing nucleus, particularly the quartz on that surface one or more layers of different compounds are synthesized having thickness up to 10~50 nm and showing magnetic, electrical and other properties.

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