• Title/Summary/Keyword: High Polymer

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Effect of particle size on graphite reinforced conductive polymer composites (입자의 크기에 따른 흑연 보강 전도성 고분자 복합재료의 특성 연구)

  • Heo, S.I.;Yun, J.C.;Oh, K.S.;Han, K.S.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.257-260
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    • 2005
  • Graphite reinforced conductive polymer composites were fabricated by the compression molding technique. Graphite powder was mixed with an phenol resin to impart electrical property in composites. The ratio and particle size of graphite powder were varied to investigate electrical conductivity of cured composites. In this study, graphite reinforced conductive polymer composites with high filler loadings(>66wt.%) were manufactured to accomplish high electrical conductivity. With increasing the loading ratio of graphite powder, the electrical conductivity and flexural strength increased. However. above 80wt.% filler loadings, flexural strength decreased due to lack of resin. Regardless of graphite particle size, electrical conductivity wasn’t varied. On the other hand, with decreasing particle size, flexural strength increased due to high specific surface area.

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Generation of High Pretilt Angle for Nematic Liquid Crystal on Blended Polyimide Surfaces Containing Fluorine Moiety (Fluorine 계열의 폴리머를 함유한 복합 폴리이미드 표면에서의 네마틱 액정의 고 프리틸트 발생)

  • Hwang, Jeoung-Yeon;Lee, Kyung-Jun;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.949-952
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    • 2002
  • The mechanisms of pretilt angle generation for a nematic liquid crystal (NLC) with negative dielectric anisotropy on the blended polyimide (PI) surface containing trifluoromethyl moiety was studied. High LC pretilt angle on the blended polymer surface with F3 was measured and the pretilt angle increased with rubbing strength. However, the low LC pretilt angle on the blended polymer surface with F1 and F2 was measured. The high LC pretilt angle generated is attributable to trifluoromethyl moiety in backbone structure on the blended PI surface. Therefore, the high pretilt angle of NLC can be achieved by using the blended polymer surface.

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High Performance of Printed CMOS Type Thin Film Transistor

  • You, In-Kyu;Jung, Soon-Won
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.17.2-17.2
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    • 2010
  • Printed electronics is an emerging technology to realize various microelectronic devices via a cost-effective method. Here we demonstrated a high performance of p-channel and n-channel top-gate/bottom contact polymer field-effect transistors (FETs), and applications to elementary organic complementary inverter and ring oscillator circuits by inkjet processing. We could obtained high field-effect mobility more than $0.4\;cm^2/Vs$ for both of p-channel and n-channel FETs, and successfully measured inkjet-printed polymer inverters. The performance of devices highly depends on the selection of dielectrics, printing condition and device architecture. Optimized CMOS ring oscillators with p-type and n-type polymer transistors showed as high as 50 kHz operation frequency. This research was financially supported by development of next generation RFID technology for item level applications (2008-F052-01) funded by the ministry of knowledge economy (MKE).

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High efficiency deep blue phosphorescent organic light emitting diodes using a phenylcarbazole type phosphine oxide as a host material

  • Jeon, Soon-Ok;Yook, Kyoung-Soo;Lee, Jun-Yeob
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.188-191
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    • 2009
  • A high efficiency deep blue phosphorescent organic light-emitting diode (PHOLED) was developed using a new wide triplet bandgap host material (PPO1) with a phenylcarbazole and a phosphine oxide unit. The wide triplet bandgap host material was synthesized by a phosphornation reaction of 2-bromo-Nphenylcarbazole with chlorodiphenylphosphine. A deep blue emitting phosphorescent dopant, tris((3,5-difluoro-4-cyanophenyl)pyridine)iridium (FCNIr), was doped into the PPO1 host and a high quantum efficiency of 17.1 % and a current efficiency of 19.5 cd/A with a color coordinate of (0.14,0.15) were achieved in the blue PHOLED. The quantum efficiency of the deep blue PHOLED was better than any other quantum efficiency value reported up to now.

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Convective Heat Transfer of a Paraffin Slurry in a Drag Reducing Carrier Fluid (유동저항 감소유체를 운반유체로 한 파라핀 슬러리의 대류 열전달에 관한 연구)

  • 정동주;최은수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.12
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    • pp.1275-1281
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    • 2001
  • Aqueous polymer solutions are known to have small pressure reduction. Paraffin slurries are known to have high thermal capacity. Paraffin particles are mixed into an aqueous polymer solution to make a new heat transfer fluid having high thermal capacity but low pressure reduction. The heat transfer characteristics of the new slurry was tested in a circular tube having a constant heat transfer boundary condition. The new slurry was found to have high Nusselt numbers as well as high thermal capacity and low pressure reduction in the laminar flow. The trends of the Nusselt numbers along the heating test section were studied for various heating conditions.

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Effects of Temperature on Tribological Properties of Polymer Material (온도 조건에 따른 폴리머 소재의 트라이볼로지 특성 연구)

  • Chi-Yoon An;Dae-Eun Kim
    • Tribology and Lubricants
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    • v.39 no.6
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    • pp.262-267
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    • 2023
  • Research to replace metal mechanical elements with polymer materials has recently accelerated. However, polymers exhibit less favorable mechanical properties than metal materials, and are often easily worn-out owing to frictional heat when their mechanical elements contact while in relative motion. Therefore, research on the polymer tribological properties is required to employ polymer materials in mechanical elements operating under harsh conditions. In this study, we examine the effect of mechanical part operating temperatures on the material friction and wear characteristics of polymer materials. We conduct ball-on-disk friction tests under dry conditions at various temperatures, using a metal ball with high hardness and a polymer as the counter surface. Each test is repeated at least three times to ensure the reliability of the test results. Before the friction test, we analyze the surface hardness and roughness of each polymer specimen; after the friction test, we use a three-dimensional confocal microscope to compare and analyze the polymer specimen wear characteristics. Based on this study, we systematically elucidate the polymer material tribological characteristics. This information should be useful for selecting and utilizing polymer materials at various temperatures.

High performance of inverted polymer solar cells

  • Lee, Hsin-Ying;Lee, Ching-Ting;Huang, Hung-Lin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.61.2-61.2
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    • 2015
  • In the past decades, green energy, such as solar energy, wind power, hydropower, biomass energy, geothermal energy, and so on, has been widely investigated and developed to solve energy shortage. Recently, organic solar cells have attracted much attention, because they have many advantages, including low-cost, flexibility, light weight, and easy fabrication [1-3]. Organic solar cells are as a potential candidate of the next generation solar cells. In this abstract, to improve the power conversion efficiency and the stability, the inverted polymer solar cells with various structures were developed [4-6]. The novel cell structures included the P3HT:PCBM inverted polymer solar cells with AZO nanorods array, with pentacene-doped active layer, and with extra P3HT interfacial layer and PCBM interfacial layer. These three difference structures could respectively improve the performance of the P3HT:PCBM inverted polymer solar cells. For the inverted polymer solar cells with AZO nanorods array as the electronic transportation layer, by using the nanorod structure, the improvement of carrier collection and carrier extraction capabilities could be expected due to an increase in contact area between the nanorod array and the active layer. For the inverted polymer solar cells with pentacene-doped active layer, the hole-electron mobility in the active layer could be balanced by doping pentacene contents. The active layer with the balanced hole-electron mobility could reduce the carrier recombination in the active layers to enhance the photocurrent of the resulting inverted polymer solar cells. For the inverted polymer solar cells with extra P3HT and PCBM interfacial layers, the extra PCBM and P3HT interfacial layers could respectively improve the electron transport and hole transport. The extra PCBM interfacial layer served another function was that led more P3HT moving to the top side of the absorption layer, which reduced the non-continuous pathways of P3HT. It indicated that the recombination centers could be further reduced in the absorption layer. The extra P3HT interfacial layer could let the hole be more easily transported to the MoO3 hole transport layer. The high performance of the novel P3HT:PCBM inverted polymer solar cells with various structures were obtained.

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Synthesis and Characterization of High Molecular Weight Biodegradable Polyoxalate (고분자량 생분해성 폴리옥살레이트의 합성과 특성분석)

  • Kim, Se-Ho;Yoo, Han-Na;Khang, Gil-Son;Lee, Dong-Won
    • Polymer(Korea)
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    • v.34 no.6
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    • pp.547-552
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    • 2010
  • Biodegradable polymers have gained enormous attentions in the pharmaceutical and biomedical applications, especially in drug delivery. In this work, we report the synthesis and characteristics of high molecular weight polyoxalate with ~75000 Da. Hydrolytic degradation kinetics and degradation products were characterized by nuclear magnetic resonance and gel permeation chromatography. Polyoxalate is a semicrystalline and thermally stable polymer with a glass transition temperature of ${\sim}35^{\circ}C$, which is suitable for drug delivery applications. The hydrophobic nature of polyoxalate allows it to be formulated into nanoparticles and encapsulate drugs using a conventional oil-in-water emulsion/solvent displacement method. Polyoxalate nanoparticles also exhibited excellent cytotoxicity profiles. It can be suggested that polyoxalate has great potential for numerous biomedical and pharmaceutical applications.

The application study on the super flowing the polymer based cement mortar (초유동화 폴리머시멘트몰탈의 실용화연구)

  • 손형호;이종열
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.04a
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    • pp.36-41
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    • 1995
  • Recently, as the problems according to the deteriorated structure were gathering sterength, there were required the advent of the high peformance for polymer ceme at compostie in building constrution devision. The polymer cement mortar was developed for improvements of the various problems in ordinary cement mortar. finishing method using the super flowing polymer-based self levelling mortar for concrete slab and floor.

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