• Title/Summary/Keyword: High Polymer

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Study on the Strength Characteristics and Flexural Toughness of Steel Fiber Reinforced Polymer Concrete (강섬유 보강 폴리머 콘크리트의 강도특성 및 휨인성에 관한 연구)

  • 김기락;연규석;이윤수
    • Journal of the Korea Concrete Institute
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    • v.11 no.4
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    • pp.137-145
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    • 1999
  • The use of steel fiber reinforced to improve the strength and flexural toughness of concrete is well known, but reinforcement of polymer concrete with steel fibers has been hardly reported till now. Polymer concrete has high strength, durability and freeze-thaw resistance than that of cement concrete, but it has disadvantage such as low flexural toughness. In this paper, the strength characteristics and flexural toughness of steel fiber reinforced polymer concrete are investigated experimentally with various steel fiber aspect ratios($\ell$/d), and contents(vol.%). As the result, the flexural and splitting tensile strengths and flexural toughness were increased aspect ratio, and reach the maximums at a aspect ratio of 50. The relationship between the compressive, flexural and splitting tensile strength were high. And the relationship between flexural strength and strain energy was approximately linear.

Synthesis and Characteristics of Acrylol Borate as New Acrylic Gelator for Lithium Secondary Battery

  • Shin, Hyun-Min;Nguyen, Congtranh;Kim, Byeong-Yeol;Han, Myong-Hee;Kim, Ju-Sung;Kim, Jin-Hwan
    • Macromolecular Research
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    • v.16 no.2
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    • pp.134-138
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    • 2008
  • A novel acrylol borate was designed and synthesized by reacting acrylate monomer and boric acid. The obtained acrylol borate was used as both gelator and anion receptor for the liquid electrolyte in a lithium secondary battery. It was found that the ionic conductivity of the gel polymer electrolyte (GPE) was as high as that of the liquid electrolyte, and the thermal stability of GPE was increased when only 2 wt% acrylol borate was incorporated into the liquid electrolyte. These results suggest that acrylol borate can be used as an effective additive to enhance the thermal stability of the electrolyte without adversely affecting its conductivity. It is believed that the strong complex formation between boron in the gelator and the anion of the salt is responsible for the enhanced thermal stability of the electrolyte solution and the increased ionic conductivity.

Corrosion Protection of Rebars Using High Durability Polymer Cementitious Materials for Environmental Load Reduction (환경부하저감형 고내구성 폴리머 시멘트계 재료를 이용한 철근 부식저감기술)

  • Kim, Wan-Ki;Chung, Seung-Jin
    • KIEAE Journal
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    • v.10 no.5
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    • pp.131-137
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    • 2010
  • The building industry must aim at high-durability and sustainability. A holistic life cycle based approach is recommended to reduce the environmental load. In recent years, technical innovations in the construction industry have advanced to a great extent, and caused the active research and development of high-performance and multifunctional construction materials. Nowadays, various polymer powders have been commercialized to manufacture construction materials in the form of prepackaged-type products, which have rapidly been developed for lack of skilled workmen in construction sites. Recently, terpolymer powders of improved quality have been developed and commercialized as cement modifiers. And, hydrocalumite is a material that can adsorb the chloride ions (Cl-) causing the corrosion of reinforcing bars and liberate the nitrite ions (NO2-) inhibiting the corrosion in reinforced concrete, and can provide a self-corrosion inhibition function to the reinforced concrete. The purpose of this study is to ascertain the self-corrosion inhibition function of polymer-modified mortars using redispersible powders with hydrocalumite. Polymer-modified mortars using VA/E/MMA and VAE redispersible powders are prepared with various calumite contents and polymer-binder ratios, and tested for chloride ion penetration depth, corrosion inhibition. As a result, regardless of the polymer-binder ratio, the replacement of ordinary portland cement with hydrocalumite has a marked effect on the corrosion-inhibiting property of the polymer-modified mortars. Anti-corrosion effect of polymer-modified mortars using VA/E/MMA terpolymer powder with hydrocalumite is higher than that of VAE copolymer powder.

Exploring the Flexural Bond Strength of Polymer-Cement Composition in Crack Repair Applications (균열 보수용 폴리머 시멘트 복합체의 휨접착강도에 관한 연구)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.1
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    • pp.23-34
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    • 2024
  • This research aims to assess the flexural bonding efficacy of polymer-cement composites(PCCs) in mending cracks within reinforced concrete(RC) structures. The study involved infilling PCCs into cement mortar cracks of varying dimensions, followed by evaluations of enhancements in flexural adhesion and strength. The findings indicate that the flexural bond performance of PCCs in crack repair is influenced by the cement type, polymer dispersion, and the polymer-to-binder ratio. Specifically, the use of ultra-high early strength cement combined with silica fume resulted in an up to 19.0% improvement in flexural bond strength compared to the application of ordinary Portland cement with silica fume. It was observed that the augmentation in flexural strength of cement mortar filled with PCCs was significantly more dependent on the depth of the crack rather than the width. Furthermore, PCCs not only acted as repair agents but also as reinforcement materials, enhancing the flexural strength to a certain extent. Consequently, this study concludes that PCCs formulated with ultra-high early strength cement, various polymer dispersions, silica fume, and a high polymer-to-binder ratio ranging from 60% to 80% are highly effective as maintenance materials for crack filling in practical settings.

Effect of Nano-sized Silicas in HPDLC Based on PUA

  • Kim, Eun-Hee;Woo, Ju-Yeon;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1212-1215
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    • 2004
  • Diffraction modes of holographic grating were fabricated with polyurethane acrylates(PUA). Two types of silica (AEROSIL 200 and AEROSIL R812) were added to reduce the shrinkage of polymer matrix. It was founded that shrinkage of PUA composite film was reduced with the addition of silica. HPDLC based PUA/silica composite also showed high diffraction efficiency. The morphology of the resultant gratings was analyzed by using scanning electron microscopy(SEM) and Tg of the polymer matrix by dynamic mechanical thermal analysis(DMTA).

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Development of Polymer Mortar Guide Block for the Blind Handicapped People (폴리머 복합재료를 이용한 유도 블럭의 개발)

  • 이기원;연규석;이윤수;지경용
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1999.10c
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    • pp.330-335
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    • 1999
  • The objective of this stu요 was to develop a polymer mortar guide block for the blind handicapped people. A high strength and a long durability polymer concrete using unsaturated polyester resin was used to developed the block and to improve the exiting cement mortar guide bloc. Physical and mechanical properties of the polymer mortar guide block were investigated with respect to absorptivity, impact strength, bending strength compared to those of the conventional cement guide block. The polymer mortar guide block was proven to have properties , indication that the block have better industrial applications.

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An ionic liquid incorporated gel polymer electrolyte for double layer capacitors

  • Perera, Kumudu S.;Prasadini, K.W.;Vidanapathirana, Kamal P.
    • Advances in Energy Research
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    • v.7 no.1
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    • pp.21-34
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    • 2020
  • Energy storage devices have received a keen interest throughout the world due to high power consumption. A large number of research activities are being conducted on electrochemical double layer capacitors (EDLCs) because of their high power density and higher energy density. In the present study, an EDLC was fabricated using natural graphite based electrodes and ionic liquid (IL) based gel polymer electrolyte (GPE). The IL based GPE was prepared using the IL, 1-ethyl-3-methylimidazolium trifluoromethanesulfonate (1E3MITF) with the polymer poly(vinyl chloride) (PVC) and the salt magnesium trifluoromethanesulfonate (Mg(CF3SO3)2 - MgTF). GPE was characterized by electrochemical impedance spectroscopy (EIS), DC polarization test, linear sweep voltammetry (LSV) test and cyclic voltammetry (CV) test. The maximum room temperature conductivity of the sample was 1.64 × 10-4 Scm-1. The electrolyte was purely an ionic conductor and the anionic contribution was prominent. Fabricated EDLC was characterized by EIS, CV and galvanostatic charge discharge (GCD) tests. CV test of the EDLC exhibits a single electrode specific capacitance of 1.44 Fg-1 initially and GCD test gives 0.83 Fg-1 as initial single electrode specific discharge capacitance. Moreover, a good stability was observed for prolonged cycling and the device can be used for applications with further modifications.

Strength Properties of Ultrarapid-Hardening polymer-Modified Concrete with Fiber (섬유 혼입 초속경 폴리머 시멘트 콘크리트의 강도 특성)

  • Joo, Myung-Ki;Noh, Byung-Chul;Kim, Young-Sang;Choi, Kyu-Hyung;Choi, Yong-Son
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.749-752
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    • 2008
  • The effects of fiber content on strength properties of ultrarapid-hardening polymer-modified concretes with fiber. As a result, the compressive and flexural strengths of ultrarapid-hardening polymer-modified concretes with fiber increase with increasing of fiber content. In particular, the ultrarapid-hardening polymer-modified concretes with a polymer-cement ratio of 20% and a fiber content of 0.08% provide approximately two times higher flexural strength than unmodified concretes. Such high strength development is attributed to the high tensile strength of polymer and fiber and the improved bond between cement hydrates and aggregates because of the addition of polymer and fiber.

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