• Transactions of the Korean Society of Mechanical Engineers A
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• v.30 no.8 s.251
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• pp.965-975
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• 2006

High pressure turbine blades are one of the key components in fossil power plants operated at high temperature. The blade is usually made of 12Cr steel and its operating temperature is above $500^{\circ}C$. Long term service at this temperature causes material degradation accompanied by changes in microstructures and mechanical properties such as strength and toughness. Quantitative assessment of reduction of strength and toughness due to high temperature material degradation is required for residual life assessment of the blade components. Nondestructive technique is preferred. So far most of the research of this kind was conducted with low alloy steels such as carbon steel, 1.25Cr0.5Mo steel or 2.25Cr1Mo steel. High alloy steel was not investigated. In this study one of the high Cr steel, 12Cr steel, was selected for high temperature material degradation. Electrochemical polarization method was employed to measure degradation. Strength reduction of the 12Cr steel was represented by hardness and toughness reduction was represented by change of transition temperature, FATT. Empirical relationships between the electrochemical polarization parameter and significance of material degradation were established. These relationship can be used for assessing the strength and toughness on the aged high pressure blade components indirectly by using the electrochemical method.

• Transactions of Materials Processing
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• v.15 no.2 s.83
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• pp.112-117
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• 2006

Sliding wear mechanism of a high nitrogen austenitic 18Cr-18Mn-2Mo-0.9N steel has been investigated. Dry sliding wear tests of the steel were carried out at various loads of IN-10N under a constant sliding speed condition of 0.15m/s against AISI 52100 bearing steel balls. Solution ($1050^{\circ}C$) and isothermal aging ($900^{\circ}C$) heat treatments were performed on the steel and the effect of the heat treatments on the wear was investigated. Wear rates of the solution-treated steel specimen remained low until 5N load, and then increased abruptly at loads above 5N. The rates of isothermally aged specimens were low and increased gradually with the applied load. Worn surfaces, their cross sections, and wear debris of the steel specimens were examined with a scanning electron microscopy. Phases of the heat-treated specimen and the wear debris were identified using XRD. The transformed phase underneath a sliding track was investigated and analyzed using a TEM. Effects of the phase transformation during the wear and $Cr_{2}N$ precipitates formed during the isothermal aging on the wear of the austenitic steel were discussed.

• Journal of Welding and Joining
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• v.15 no.4
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• pp.154-165
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• 1997

Abrasive wear characteristics of high Cr white cast iron-based hardfacing were investigated using the rubber wheel abrasion wear test method according with the ASTM G65-85. Mild steel was also tested for comparison with high Cr cast iron hardfacing. Wear experiments, where the applied force, wheel revolution rate and abrasive powder feed rate were selected as test valuables, were planned and analyzed by response surface method to evaluate wear statistically and quantitatively. Weight loss of high Cr cast iron hardfacing was mostly affected by the applied force and wheel revolution rate, and little by the powder feed rate. Weight loss of mild steel was greatly affected by the wheel revolution rate and powder feed rate, and slowly and steadily increased with the applied force. Abrasive wear mechanism of high Cr cast iron and mild steel was discussed in the light of the wear test results.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2006.05a
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• pp.421-424
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• 2006

High nitrogen steels (HNS) exhibit both high strength and ductility during tensile deformation. In the present study the Fe-18Cr-14Mn-4Ni-0.9N high nitrogen steel was heat treated at $1000^{\circ}C$ and $1100^{\circ}C$ to produce $Cr_2N$ precipitates in austenite matrix and full austenite microstructures, respectively. Tensile tests of the heat treated specimens were performed at two different strain rates of 0.05/sec and 0.00005/sec. Each tensile curve of the specimens could be well characterized by the the modified Ludwik equation. Plastic deformation of the steel was adequately represented by the four parameters of the modified Ludwik equation. At 0.05/s strain rate, the specimen with the $Cr_2N$ precipitate exhibited higher strength than the full austenite specimen, while the full austenite specimen showed better mechanical properties at 0.00005/s strain rate. It was found that the $Cr_2N$ precipitates influences deformation behavior of the high nitrogen steel significantly.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2005.10a
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• pp.105-108
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• 2005

Sliding wear mechanism of a high nitrogen austenitic 18Cr-18Mn-2Mo-0.9N steel has been investigated. Dry sliding wear tests of the steel were carried out at various loads of 1N-10N under a constant sliding speed condition of 0.15m/s against AISI 52100 bearing steel balls. Solution $(1050^{\circ}C)$ and isothermal aging $(900^{\circ}C)$ heat treatments were performed on the steel and the effect of the heat treatments on the wear were investigated. Wear rates of the solution-treated steel specimen remained low until 5N, and then increased abruptly at loads above 5N. The rates of isothermally aged specimens were low and increased gradually with the applied load. Worn surfaces, their cross sections, and wear debris of the steel specimens were examined with a scanning electron microscopy. Phases of the heat-treated specimen and the wear debris were identified using XRD. Phases transformed underneath the sliding track during the wear were investigated and analyzed using TEM. Effects of the phase transformation during the wear and $Cr_2N$ precipitates formed during the isothermal aging on the wear of the austenitic steel were discussed.

• Corrosion Science and Technology
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• v.20 no.6
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• pp.373-383
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• 2021

The effect of Cr addition to high Mn steel on flow-accelerated corrosion (FAC) behavior in a neutral aqueous environment was evaluated. For comparison, two types of conventional ferritic steels (API X70 steel and 9% Ni steel) were used. A range of experiments (electrochemical polarization and impedance tests, weight loss measurement, and metallographic observation of corrosion scale) were conducted. This study showed that high Mn steel with 3% Cr exhibited the highest resistance to FAC presumably due to the formation of a bi-layer scale structure composed of an inner Cr enriched Fe oxide and an outer Mn substituted partially with Fe oxide on the surface. Although the high Mn steels had the lowest corrosion resistance at the initial corrosion stage due to rapid dissolution kinetics of Mn elements on their surface, the kinetics of inner scale (i.e. Cr enriched Fe oxide) formation on Cr-bearing high Mn steel was faster in dynamic flowing condition compared to stagnant condition. On the other hand, the corrosion scales formed on API X70 and 9% Ni steels did not provide sufficient anti-corrosion function during the prolonged exposure to dynamic flowing conditions.

• Nuclear Engineering and Technology
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• v.31 no.6
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• pp.561-571
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• 1999

Microstructure and mechanical properties of five Cr-Mo steels for nuclear industry applications have been investigated. Transmission electron microscopy, energy dispersive spectrometer, differential scanning calorimeter, hardness, tensile, and impact test were used to evaluate the Cr and W effect on the microstructure and mechanical properties. Microstructures of Cr-Mo steels after tempering are classified into three types : bainitic 2.25Cr-lMo steel, martensitic Mod.9Cr-lMo, HT9M, and HT9W steels, and dual phase HT9 steel. The majority of the precipitates were found to be M$_{23}$C$_{6}$ carbides. As minor phases, fine needle-like V(C,N), spherical NbC, fine needle-like Cr-rich Cr$_2$N, and Cr-rich M$_{7}$C$_3$were also found. Addition of 2wt.% W in Cr-Mo steels retarded the formation of subgrain and dissolution of Cr$_2$N precipitates. Hardness and ultimate tensile strength increased with increasing Cr content. Though Cr content of HT9W steel was lower than that of HT9 steel, the hardness of HT9W was higher due to the higher W content. W added HT9W steel had the highest ultimate tensile strength above $600^{\circ}C$. But impact toughness of W added steel (HT9W) and high Cr steel (HT9) was low.w.w.

• Journal of Power System Engineering
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• v.14 no.6
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• pp.29-34
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• 2010

As the steam temperature of fossil power plant boiler is increasing, the use of 9Cr-1Mo high alloy material is prevalent and it is needed to investigate the characteristics of low cycle fatigue for high alloy and austenite stainless steel that has used up to recently. As a result of test, in 9Cr-1Mo high alloy steel, the relation of strain and fatigue life is non-linear and the crack mode of low cycle fatigue is brittle but in the austenite stainless steel, that of strain and fatigue life is linear and the crack mode of low cycle fatigue is ductile. Comparing the fatigue life between high alloy and austenite stainless steel, there is no consistent characteristics as to strains. But the fatigue life of 9Cr-1Mo steel is longer by 25% than that of STS304 stainless steel in the relatively low, 0.3% strain. In the other strain, the fatigue life of two materials is similar.

• Journal of Surface Science and Engineering
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• v.55 no.6
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• pp.448-459
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• 2022

Generally, steel is the most commonly used in the industry because of good strength, processability and cost-effectiveness. Steel can be surface-treated such as coating or used as an alloy by adding elements such as Cr, Ni, Zr, and Al to increase corrosion resistance. However, even if steel is used in same environment corrosion resistance is sharply lowered when it is exposed to a high temperature for a fixed or extended period of time due to an overload or other factors. In particular, the use of hot-dip aluminized plated steel, which is used in high-temperature atmospheres, is increasing due to the surface Al₂O₃ oxide film. This steel necessitates an urgent solution as issues of corrosion resistance limitations often appear. It is an important issue that not only cause analysis but also the research for the surface treatment method that can be solved. Thus, in this study, Cr in which it is expected to be effective in corrosion resistance and heat resistance attempted to deposit on hot dip aluminized plated steel with PVD sputtering. And it was possible to present the surface treatment application of various types of industrial equipment exposed to high temperature and basic design guidelines for use by confirming the corrosion resistance of hot dip Al-Si plated steel with Cr film deposited at high temperature.

• Proceedings of the KSME Conference
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• 2000.11a
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• pp.99-104
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• 2000

This paper describes the high temperature creep characteristics for virgin material of 9Cr1MoVNb steel using small punch creep(SP-Creep) test technique which is developing recently. In addition, the several results of SP-Creep test are compared with that of 2.25Cr- 1Mo steel which is widely used as boiler materials and that of conventional uniaxial creep test. The obtained SP-Creep curves show the creep behaviors of three regimes like that obtained from conventional uniaxial creep test, and SP-Creep properties are definitely depended on applied load and test temperature. The correlation of SP-Creep rate and creep rupture life with applied load has been determined like the correlation between creep rate/rupture life and stress in uniaxial creep test, and also is satisfied with Power law. The creep rupture times of newly 9Cr1MoVNb steel are higher than those of 2.25Cr1Mo steel at the same creep temperature and applied loading condition, and the decrease extent of creep rupture life with loads is very lower compared with 2.25Cr1Mo steel.