• 대한한의학방제학회지
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• 제17권2호
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• pp.53-63
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• 2009

Objective : To compare the contents of heavy metals, residual pesticides and sulfur dioxide before/after a decoction. Methods : The heavy metal contents before/after a decoction were measured by Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and mercury analyzer. In order to analyze pesticides in 4 samples we used simultaneous multi-residue analysis of pesticides by GC/ECD, which was followed by GC/MSD analysis to confirm the identity of the detected pesticide in each sample. In addition, the contents of sulfur dioxide ($SO_2$) were performed by Monier-Williams distillation method. Results: 1. The mean values of heavy metal contents (mg/kg) for the samples were as follows: Jaeumganghwa-tang (before decoction - Pb; 1.190, Cd; 0.184, As; 0.099 and Hg; 0.028, after decoction - Pb; .033, Cd; 0.003, As; 0.005 and Hg; 0.001), Yukmijiwhang-tang (before decoction - Pb; 0.484, Cd; 0.133, As; 0.053 and Hg; 0.009, after decoction - Pb; 0.065, Cd; 0.008, As; 0.007 and Hg; not detected), Bojungikgi-tang (before decoction - Pb; 0.863, Cd; 0.197, As; below 0.016 and Hg; 0.011, after decoction - Pb; 0.071, Cd; 0.009, As; 0.004 and Hg; 0.001) and Ssangwha-tang (before decoction - Pb; 1.511, Cd; 0.212, As; 0.094 and Hg; 0.016, after decoction - Pb; 0.029, Cd; 0.006, As; 0.005 and Hg; 0.0004). 2. Contents (mg/kg) of sulfur dioxide ($SO_2$) before a decoction in Jaeumganghwa-tang, Yukmijiwhang-tang and Ssangwha-tang exhibited 22.7, 107.3 and 5.5, respectively. However, contents of sulfur dioxide after a decoction in all samples were not detected. 3. Contents (mg/kg) of residual pesticides before/after a decoction in all samples were not detected. Conclusion : These results will be used to establish a criterion of heavy metals, residual pesticides and sulfur dioxide.

• 대한한의학회지
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• 제30권4호
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• pp.108-117
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• 2009

Objective: To compare the contents of heavy metals, residual pesticides and sulfur dioxide before/after a decoction. Methods: The heavy metal contents before/after a decoction were measured by inductively-coupled plasma atomic emission spectrometer (ICP-AES) and mercury analyzer. In order to analyze pesticides in 5 samples we used simultaneous multi-residue analysis of pesticides by GC/ECD, which was followed by GC/MSD analysis to confirm the identity of the detected pesticide in each sample. In addition, the contents of sulfur dioxide ($SO_2$) were performed by Monier-Williams distillation method. Results: 1. The mean values of heavy metal contents (mg/kg) for the samples were as follows: Sipjeondaebo-tang (before decoction - Pb; 1.163, Cd; 0.257, As; 0.080 and Hg; 0.016, after decoction - Pb; 0.059, Cd; 0.007, As; 0.006 and Hg; 0.0003), Palmul-tang (before decoction - Pb; 1.181, Cd; 0.242, As; 0.152 and Hg; 0.014, after decoction - Pb; 0.067, Cd; 0.008, As; 0.008 and Hg; 0.0003), Sagunja-tang (before decoction - Pb; 1.285, Cd; 0.283, As; 0.063 and Hg; 0.012, after decoction - Pb; 0.047, Cd; 0.009, As; 0.004 and Hg; not detected) and Samul-tang (before decoction - Pb; 1.025, Cd; 0.169, As; 0.099 and Hg; 0.013, after decoction - Pb; 0.065, Cd; 0.007, As; 0.010 and Hg; 0.001). 2. Contents (mg/kg) of residual pesticides before/after a decoction were not detected in any samples. 3. Contents (mg/kg) of sulfur dioxide ($SO_2$) before a decoction in Sipjeondaebo-tang, Palmul-tang, Sagunja-tang and Samul-tang exhibited 5.0, 6.0, 14.0 and 6.9, respectively. However, contents of sulfur dioxide after a decoction were not detected in any samples. Conclusion: These results will be used to establish a criterion for heavy metals, residual pesticides and sulfur dioxide.

• 한국식품영양과학회지
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• 제22권4호
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• pp.484-488
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• 1993

본 연구는 전라북도내 서해안 농촌지역 저수지나 강에서 서식하는 붕어의 중금속 함량을 측정하여 다음과 같은 결과를 얻었다. 1 . Hg, Cu의 함량은 동림저수지에서 0.0167ppm, 0.1094ppm으로 가장 낮았고 As의 함량은 지산저수지 에서 0.0018ppm, 만경강에서 0.0012ppm으로 검출되었으나 다른 지역에서는 검출되지 않았다. Pb은 탑천강에서 0.3536ppm, Cd은 동림저수지에서 0.1094ppm, Mn은 만경강에서 2.9059ppm, Zn은 동진강에서 14.3096ppm으로 가장 낮았다. 2. Hg, Pb의 함량은 지산저수지에서 0.0407ppm, 0.6593pm으로 가장 높았고 Cd은 옥구 저수지에서 0.1935ppm, Cu는 탑천강에서 0.3792ppm, Mn은 동림저수지에서 6.9335ppm, Zn은 가천강에서 48.1615ppm으로 가장 높았다. 3. FAO/WHO의 최대허용량과 비교할 때 모두가 훨씬 낮았지만 그 안전성 여부는 다른 식품과 연관시켜 판단되어야 할 문제라고 생각된다. 4. 중금속 함량 측정을 주로 서해안 지역에 위치하고 있는 담수어중 가장 많은 붕어만을 채취하여 측정하였는데 앞으로는 여러 종류의 담수어와 더불어 계절별로 또 전라남북도 지방과 함께 계속 연구를 하고자 한다.

• 한국식품영양학회지
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• 제18권3호
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• pp.254-264
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• 2005

This study was conducted to estimate the contents of heavy metals 'Hg, Cd, Pb, As, Zn, Cu, Cr, Mn' in some vegetables which were produced in Korea. The levels of heavy metals were determined using a mercury analyzer, an ICP(inductively coupled plasma spectrometer) and an AAS(atomic absorption spectrophotometer) after wet digestion. The values of heavy metals "mean(mini.~maxi.)" ppm(mg/kg) in some vegetables(raw of perilla leaf, chard, small water dropwort, water dropwort, kale, bud of aralia, pumpkin(round type) and pumpkin(long type) were as follows : Hg : 0.0021(0.0006~0.0054)mg/kg, Cd : 0.0035(ND*~0.0377)mg/kg, Pb : 0.0191(0.0023~0.0928)mg/kg, As : 0.0757(ND~0.5294)mg/kg, Zn : 2.6299(0.4478~6.8567)mg/kg, Cu : 1.0261(0.2046~8.9417)mg/kg, Cr : 0.1535 (0.0240~0.4982)mg/kg, Mn : 3.2476(0.3283~9.8280)mg/kg. This results showed that Mn was generally simillar to previous reports and Cd, Hg, Pb were lower than other reseaches, but As was little higher or Zn, Cu, Cr were higher than the levels of those reported contents in some vegetables on domestic supermarkets in Korea, Although tolerable limit of Hg and Cd is not in a regulation of WHO/FAO, these mean levels(Pb, As, Zn, Cu) are lower than recommended levels of WHO/FAO, Pb "0.1~2.0" mg/kg, As "1.0" mg/kg, Zn "5.0" mg/kg and Cu "0.1~50"mg/kg from vegetables in 'the tolerable contents of food' by the FAO/WHO, therefor some vegetables has set to evaluate their safeties.

• 동아시아식생활학회지
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• 제15권4호
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• pp.465-474
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• 2005

This study was conducted to estimate the contents of heavy metals 'mercury(Hg), cadmium(Cd), lead(Pb), arsenic(As), zinc(Zn), copper(Cu), chrome(Cr) and manganese(Mn)' in root vegetables which were produced in Korea. The levels of heavy metals were determined using a mercury analyzer, an ICP(inductively coupled plasma spectrometer) and an AAS(atomic absorption spectrophotometer) after wet digestion. The values of heavy metals 'mean(minimum-maximum)' mg/kg(ppm) in root vegetables (radish, turnip, carrot, ginger, edible burdock, taro, Chinese yam, east indian lotus) were as follows ; Hg : 0.0019(0.0002${\~}$0.0062), Cd : 0.0088(ND${\~}$0.0402), Pb : 0.021(ND${\~}$0.1070), As : 0.0401(ND${\~}$0.1732), Zn : 1.865(0.4186${\~}$6.9319), Cu : 0.648 (0.1826${\~}$4.0172), Cr : 0.121(0.0132${\~}$1.2030), and Mn : 2.730(0.0477${\~}$10.0468) mg/kg. These results showed that Hg were generally similar to and Cd was lower but Ph, As, Zn, Co, Mn were little higher than the levels of those reported contents in root vegetables on retail markets in Korea. Although the tolerable limit of Cd and Hg is not set in a regulation of WHO/FAO, the tested mean levels(Pb, As, Zn, Cu) were lower than the regulated ones of WHO/FAO, Pb '0.1-2.0', As '1.0', Zn '5.0', and Cu 0.1${\~}$50 mg/kg from vegetables. Therefore, root vegetables sold in the retail markets were evaluated as safe in terns of the heavy metal contents.

• Toxicological Research
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• 제28권2호
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• pp.93-98
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• 2012

This study has attempted to establish an analysis method through validation against heavy metals in the body (Pb, Cd and Hg) using ICP-MS and Gold amalgamation and find out the relevance between heavy metal and Alzheimer's disease after analyzing the distribution of heavy metal concentration (Pb, Cd and Hg) and correlations between a control group and Alzheimer's disease group. In this study, Pb and Cd levels in the blood and serum were validation using ICP-MS. For analysis of Hg levels in the blood and serum, the gold amalgamation-based 'Direct Mercury Analyzer' has been used. According to an analysis on the heavy metal concentration (Pb, Cd and Hg concentration) in the blood, Cd concentration was high in the Alzheimer's disease group. In the serum, on the contrary, Pb and Hg were high in the Alzheimer's disease group. For analysis of correlations between heavy metal levels in the blood and serum and Alzheimer's disease, t-test has been performed. Even though correlations were observed between the blood lead levels and Alzheimer's disease, they were statistically insignificant because the concentration was higher in a control group. No significance was found in Cd and Hg. In the serum, on the other hand, no statistical significance was found between the heavy metal (Pb, Cd and Hg) and Alzheimer's disease. In this study, no statistical significance was observed between heavy metal and decrease in cognitive intelligence. However, it appears that a further study needs to be performed because the results of the conventional studies were inconsistent.

• 분석과학
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• 제19권4호
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• pp.342-351
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• 2006

서울시내에 유통 중인 대형어류 17종 89건에 대하여 원자흡광광도계(AAS) 및 수은분석기 등을 이용하여 납, 카드뮴, 수은, 크롬, 구리, 비소 함량을 근육, 간 및 아가미 등의 부위별로 분석하였다. 그 결과를 요약하면 다음과 같다($Mean{\pm}SD$, mg/kg). 어종별 평균 중금속 함량은 Hg $0.08{\pm}0.01mg/kg$, Pb $0.17{\pm}0.32mg/kg$, Cd $0.34{\pm}0.07mg/kg$, Cr $0.05{\pm}0.05mg/kg$, Cu $1.14{\pm}0.13mg/kg$, As $0.24{\pm}0.22mg/kg$ 이었다. 부위별 유해 중금속의 전체적인 측정치를 살펴보면 중금속과 어종에 상관없이 간의 측정치가 가장 높게 나타났다. 나라별 중금속을 비교한 결과 Hg, Pb, Cu는 뉴질랜드산, Cd, As는 노르웨이산, Cr은 국내산 어류의 평균함유량이 다른 나라 어류보다 다소 높은 측정치를 보였으나, 자연함량수준으로 오염의 가능성은 없다고 생각된다. 기준초과로 검출된 어종은 일본에서 수입된 황돔으로 두 건이었다. 어류의 간과 근육 부위 중금속 함량 간의 상관관계는 Hg (r=0.989, p<0.01), Pb (r=0.978, p<0.01), Cd (r=0.991, p<0.01), Cu (r=0.998, p<0.01), As (r=0.198, p<0.05)에서 상관관계를 나타냈으며, Cr (r=0.082)은 유의적 상관관계가 인정되지 않았다.

• 박물관보존과학
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• 제12권
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• pp.53-58
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• 2011

국립중앙박물관이 소장하고 있는 고구려 개마총 여인행렬 벽화편에 사용된 안료의 성분 분석을 수행하였다. 분석은 비파괴 성분분석기인 X-선 형광분석기(XRF)를 사용하여 안료의 성분 원소를 확인하였다. 분석결과 벽화의 채색안료 중 적색에는 진사/주(HgS)와 산화철이 사용되었으며 흑색에는 먹, 백색에는 연백이 사용되었다. 얼굴 부분은 진사/주와 연백을 혼합하여 채색하거나 경우에 따라 채색하지 않았을 가능성이 높았다.

• 한국식품영양학회지
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• 제15권1호
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• pp.64-69
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• 2002

To know a degree of pollution in agricultural products cultivated around 4 unworked mines located in Chollanam-Do, we investigated a concentration of heavy metal and trace metal to provide the basic data for its residual limits. 28 samples of seven kinds of agricultural products(lettuce, onion, potato, radish, pepper, pumpkin, bean) collected from 4 unworked mines located in Chollanam-Do in 2001 were analyzed by Mercury Analyzer for mercury and Atomic Absorption spectrophotometer for Pb, As, Cd, Cu, Mn, and Zn. Hg contents were detected N.D. ∼trace level(0.01 ppm and less) and As content were detected N.D. ∼ 0.029 lpm but most of same)leE were not detected. Cd contents were detected N.D∼0.124 ppm. The results of Hg, As, Pb and Cd content showed that for all the 7 species of agricultural products studied, none have accumulated levels dangerous enough to Pose health problems. The average contents of Cu were 3.070 ∼ 7.825 ppm in bean, the Mn were 3.688 ∼23.935 ppm in lettuce ailed the Zn were 5.690 ∼21.171 ppm in bean, respectively.

• 한국식품과학회지
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• 제37권3호
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• pp.329-333
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• 2005

본 연구는 국내 유통 중인 인삼 및 인삼제품류 8종 100건에 대하여 중금속 함량을 조사 평가하고자 수행하였다. 유도결합 플라즈마분광기(ICP), 원자흡광광도계(AAS) 및 수은분석기 둥을 이용하여 납, 카드뮴 등 중금속을 측정하였다. 인삼(n=30) 중 납 등 중금속 함량은 다음과 같았다[min-mak(mean), 단위 mg/kg]. Hg은 0.002-0.02(0.007), Pb은 0.018-0.39(0.106), Cd은 0.004-0.413(0.106), As는 불검출 -0.094(0.013), Cu는 0.24-5.5(3.2), Mn 3.18-50.4(20.09), Zn은 0.76-44.27(13.42). 또한 인삼제품류 (n=70)에 대한 중금속 함량은 다음과 같았다[min-max(mean), 단위 mg/kg]. Hg은 0.0001-0.002(0.001), Pb은 0.001-0.133(0.017), Cd는 불검출 -0.181(0.008), Cu는 불검출 -1.1(0.13), Mn 0.73-30.15(1.61), Zn은 0.02-13.42(1.02). 본 연구결과, 우리나라 국민의 인삼 및 인삼제품류를 통한 수은, 납, 카드뮴 섭취량은 FAO/WHO에서 설정한 잠정주간섭취허용량의 0.003%, 0.01%, 0.02%로 매우 낮게 나타났다.