• Bulletin of the Korean Chemical Society
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• v.24 no.4
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• pp.489-493
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• 2003

2-Mercaptobenzothiazole was used as a highly selective and efficient carrier for the uphill transport of silver ion through a chloroform bulk liquid membrane. In the presence of thiosulfate ion as a suitable metal ion acceptor in the receiving phase, the amount of silver transported across the liquid membrane after 180 min was 90 ± 3.0%. The selectivity and efficiency of silver ion transported from aqueous solutions containing equimolar mixtures of $Zn^{2+}, Cu^{2+}, Co^{2+}, Ni^{2+}, Cd^{2+}, Pb^{2+}, Bi^{3+}, Fe^{2+}, Fe^{3+}, Pd^{2+}, Mn^{2+}, Hg^{2+}, Sn^{2+}, Ca^{2+}, Mg^{2+}, K^+, Na^+ and Li^+$ were investigated.

• Textile Coloration and Finishing
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• v.25 no.1
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• pp.13-17
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• 2013

A new assembly derived from 2,3-dibromo-5,6,7,8-tetrafluoroquinizarin and sodium diethyl-carbamodithiolate, was prepared as an efficient $Fe^{3+}$ colorimetric chemosensor with high selectivity over other cations $Fe^{3+}$, $Na^+$, $Mg^{2+}$, $Pb^{2+}$, $Cd^{2+}$, $Ni^{2+}$, $Ca^{2+}$, $Cu^{2+}$, $Hg^{2+}$, $Zn^{2+}$ : from the dark blue to brown color change that is visible by eyes. This assembly produced large bathochromic shift of 228 nm in the presence of $Fe^{3+}$ compared with the corresponding absorption maximum of the parent dye.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3749-3754
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• 2013

Two 3D isomorphous and isostructural complexes, namely, $[Zn(BDOA)(bpy)(H_2O)_2]_n$ (1) and $[Cd(BDOA)-(bpy)(H_2O)_2]_n$ (2); (BDOA = Benzene-1,4-dioxyacetic acid, bpy = 4,4'-bipyridine) were synthesized under hydrothermal conditions and characterized by means of elemental analyses, thermogravimetric (TG), infrared spectrometry, and single crystal X-ray diffraction. Complexes 1 and 2 crystallize in the triclinic system, space group P-1 and each metal ion in the complexes are six-coordinated with the same coordination environment. In the as-synthesized complexes, $BDOA^{2-}$ anions link central metal ions to form a 1D zigzag chain $[-BDOA^{2-}-Zn(Cd)-BDOA^{2-}-Zn(Cd)-]_{\infty}$, whereas bpy pillars connect metal ions to generate a 1D linear chain $[-bpy-Zn(Cd)-bpy-Zn(Cd)-]_{\infty}$. Both infinite chains are interweaved into 2D grid-like layers which are further constructed into a 3D open framework, where hydrogen bonds play as the bridges between the adjacent 2D layers. Luminescent properties of complex 1 showed selectivity for $Hg^{2+}$ ion.

• Applied Chemistry for Engineering
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• v.1 no.2
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• pp.140-146
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• 1990

Polydimethylsiloxane(PDMS) containing [N, N'-bis (3- (salicylidene amino) propyl) amine Co(II)] (Co(saldpt)) as a fixed oxygen carrier was synthesized. UV-visible spectra of the membrane demonstrated that Co(saldpt) binded molecular oxygen specificaaly and reversibly. From time lag method experiment, it was found that both oxygen permeability and diffusibity increase with decreasing upstream pressure, while solubility maintain nearly constant. The maximum oxygen permeability and oxygen selectivity over nitrogen obtained was 18.6 barrer and 4, respectively, at 25 mmHg and $40^{\circ}C$ from the the PDMS membrane containing 1 wt% of Co(saldpt). Facilitation behavior was explained in terms of the dual sorption model.