• 제목/요약/키워드: Hexagonal-Ferrite

검색결과 70건 처리시간 0.029초

염을 이용한 Sr 페라이트의 분말합성과 그의 자성특성 (Synthesis of Sr-Ferrite by a Molten Salt Flux and Its Magnetic Properties)

  • 김정식;김시동
    • 한국세라믹학회지
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    • 제42권10호
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    • pp.672-677
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    • 2005
  • In this study we prepared the Sr-ferrite powders and magnet by a molten salt method using the (NaCl+KCl) salt mixture. Starting materials of $Fe_{2}$$O_{3}$ and Sr$Co_{3}$ were mixed as the molar ratio of 5.70:1, and 0.08 mol$ \% $ $Al_{2}$$O_{3}$, 0.10 mo1$ \% $ Si$O_{2}$ and 0.12 mo1$ \% $ CaO were added as additives. Sr-ferrite powders synthesized at the reaction temperatures of 800$\∼$1200$ ^{\circ}C $ showed the typical M-type hexagonal ferrite phase, and hexagonal plate-like morphology with uniform distribution of 1$\∼$3 $\mu$m particle size. The bulk density of the sintered Sr-ferrite magnet prepared with powders by the molten salt method showed the maximum density of 4.82 g/$cm^{3}$ at the sintering temperature of 1200$^{\circ}C $. The maxima of remanent flux density (Br, 45 emu/g) and coercive force (iHc, 3.75 kOe) occurred at the sintering temperatures of 1150$ ^{\circ}C$ and 1200$^{\circ}C $.

Propylene Oxide를 이용한 졸-겔법에 의한 MO·Fe12O18 (M/Ba, Sr) 나노 분말의 합성과 물리적 특성 (Synthesis and Physical Properties of MO·Fe12O18 (M/Ba and Sr) Nanoparticles Prepared by Sol-Gel Method Using Propylene Oxide)

  • 이수진;최석범;곽형섭;백승욱
    • 공업화학
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    • 제17권4호
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    • pp.420-425
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    • 2006
  • Propylene oxide (PPO)를 gelation agent로 한 졸-겔법으로 입자가 균일하고 자기적 특성이 우수한 $MO{\cdot}Fe_{12}O_{18}$ (M/Ba and Sr)의 구조식을 가지는 M-type hexagonal ferrite를 제조하였다. 본 방법으로 얻은 졸-겔용액은 매우 안정적인 분산상태를 보이며, $Fe^{3+}$의 겔화가 진행되고, 생성된 $Fe_2O_3$의 표면에서 $Ba^{2+}$ 또는 $Sr^{2+}$의 겔화가 진행되는 것으로 설명될 수 있어서, +3가 이하의 금속이라도 +3가 이상의 금속 존재 하에는 겔화가 가능한 것을 확인하였다. 또한, 기존 방법과 비교하여 값싼 원료를 사용하며, 반응 시간도 1 min 이내로 짧아지는 장점이 있다. 본 제조법으로 얻어진 분말은 기왕에 발표된 문헌 값과 비교하면 $150^{\circ}C$ 이상 낮은 열처리 온도에서 최고의 자기적 특성을 나타냈으며, 향상된 자기적 특성을 보였다. Sr-ferrite의 경우 최대포화자화 값 74.4 emu/g, 보자력 값 6198 Oe을, Ba-ferrite의 경우도 최대포화자화 값 68.1 emu/g, 보자력 값 5155 Oe을 보였다. 이들은 기존에 발표된 문헌 값과 비교하면 각각 10%와 5% 이상 증가된 보자력 값을 나타내어, 고밀도 자기기록재료에 적합함을 확인하였다. 제조된 분말은 1차 건조 분말의 경우 3~5 nm의 입자들이 응집된 50 nm 정도의 구형입자가 생성되고, 열처리 후에는 500 nm 정도의 고른 크기를 가진 육각판상형 입자가 생성된다.

THE COMPLEX PERMEABILITY AND MATCHING FREQUENCY OF FERRITE MICROWAVE ABSORBER

  • Shin, Jae-Young;Oh, Jae-Hee
    • 한국자기학회지
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    • 제5권5호
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    • pp.800-804
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    • 1995
  • The complex permeability dispersions and the microwave absorbing phenomena are investigated in ferrite microwave absorber. The complex permeability of NiZn ferrite, NiZnCo ferrite, and Y-type hexagonal ferrite were measured in 200MHz-14GHz range. Two types of resonances, the domain wall and the spin rotational resonance, were observed. With a ferrite particle with a diameter of about $1\;\mu\textrm{m}$, only spin rotational resonance were observed. The theoretical matching frequency is determined by plotting the measured complex permeability locus on the impedance matching solution map. One or two impedance matching phenomena are observed in the ferrite absorbers according to their complex permeability loci on the impedance matching solution map. The first matching frequency, found in the ferrite-rubber composites, which was higher than that of spin rotational resonance, increased with spin rotational resonance frequency.

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수열합성에 의한 Ba-Ferrite의 형성조건 (Conditions for the Formation of Ba-Ferrite by Hydrothermal Synthesis)

  • 이경희;이병하;윤갑중
    • 한국세라믹학회지
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    • 제22권5호
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    • pp.61-65
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    • 1985
  • This stud deals with the conditions for the Formation of Ba-Ferrite by Hydrothemal synthesis Suspensions Containing either iron(III) hydroxide or hydroxide oxide and barium ians were subjected to autoclavings at various temperatures from 150 to 30$0^{\circ}C$. A ferromagnetic precipitate BaO.$6Fe_2O_3$ consisting of hexagonal plate-like particle was obtained by suitable combination of temperature and concentration of KOH

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$Fe_2O_3$몰비 및 B\ulcorner첨가가 Sr-Ferrite 특성에 미치는 영향 (Effect of Molar Ratio of $Fe_2O_3$ and BaO Addition on the Characteristics of Sr-Ferrite)

  • 문기훈;심영재;조성걸
    • 한국세라믹학회지
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    • 제34권5호
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    • pp.453-460
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    • 1997
  • Sr-ferrite having magnetoplumbite structure is similar to Ba-ferrite in magnetic characteristics, but better magnetic characteristics for using motor application. To improve remanence magnetic flux density(Br) and coercive force(iHc), it is necessary that sintered ferrites must have high density and grain size less than 1 $\mu$m. By varying n values in SrO.nFe2O3 basic composition, calcination temperature, and BaO addition, Sr-ferrite powder and sintered specimen was prepared. The n values, calcination temperature, and BaO addition affected secondary phase formation, particle size, and particle shape. BaO addition enhanced Fe2O3 secondary phase and hexagonal shape particle. Fe2O3 phase reduced sintered density which greatly decreased Br.

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