• 한국세라믹학회지
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• 제33권4호
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• pp.448-454
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• 1996

BaTiO3 세라믹스의 입방정과 육방정간의 상전이에 따른 미세조직 변화를 관찰하였다. 입방정을 육방정영역에서 열처리하는 경우, 시편 표면부터 육방정상이 생성되었고 반대로 육방정을 입방정역에서 열처리하여 상전이 시킬때는 입방정상이 시편이 중심부에서부터 생성되었다. 또한 이러한 상전이 과정 중에는 빠른 입성장과 더불어 불규칙적인 입계형태를 나타내었다. 그 외 낮은 성형압으로 소결체의 밀도가 낮은 육방정 시편을 제조한 경우에는 상대적으로 입방정으로의 상전이가 억제되었다. 이러한 결과들은 육방정의 표면에너지가 입방정보다 상대적으로 낮기 때문으로 해석되었다.

• 한국재료학회지
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• 제16권6호
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• pp.394-399
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• 2006

Ferroelectric $HoMnO_3$ thin films were deposited on the Si(100) substrate at $700^{\circ}C$ for 2 hrs by metalorganic chemical vapor deposition (MOCVD) and post-annealed at 850oC by rapid thermal process (RTP). Electrical properties and crystalline phases of $HoMnO_3$ thin films were investigated as a function of postannealing time. Single phase of hexagonal symmetry with c-axis preferred orientation was obtained from $HoMnO_3$ thin films post-annealed at $850^{\circ}C$ for 5 min, while the c-axis preferred orientation was decreased with the increase of post-annealing time, and the thin films post-annealed at $850^{\circ}C$ for 15 min showed the mixture phases of hexagonal and orthorhombic symmetry. P-E (Polarization-Electric field) hysteresis loop of ferroelectric $HoMnO_3$ thin films was observed only for the single phase of hexagonal symmetry, but that was not observed for the mixture phases of the hexagonal and orthorhombic symmetry, which was discussed with the bond valence of Mn ion of crystalline phase. Leakage current density was dependent on the microstructure of thin films as well as the change of valence of Mn ion.

• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1317-1322
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• 2014

Membrane disruption by an antimicrobial peptide (AMP) was investigated by measuring the $^2H$ solid-state nuclear magnetic resonance spectra of 1-palmitoyl-$d_{31}$-2-oleoyl-sn-glycero-3-phosphatidylcholine (POPC_$d_{31}$) in mixtures of POPC_$d_{31}$/cholesterol and either magainin 2 or aurein 3.3 deposited on thin cover-glass plates. The line shapes of the experimental $^2H$ solid-state nuclear magnetic resonance (SSNMR) spectra were best simulated by assuming the coexistence of a mosaic spread of bilayers containing pore structures and a fasttumbling isotropic phase or a hexagonal phase. Within a few days of incubation in a hydration chamber, an isotropic phase and a pore structure were induced by magainin 2, while in case of aurein 3.3 only an isotopic phase was induced in the presence of a bilayer phase. After an incubation period of over 100 days, alignment of the bilayers increased and the amount of the pore structure decreased in case of magainin 2. In contrast with magainin 2, aurein 3.3 induced a hexagonal phase at the peptide-to-lipid ratio of 1/20 and, interestingly, cholesterol was not found in the hexagonal phase induced by aurein 3.3. The experimental results indicate that magainin 2 is more effective in disrupting lipid bilayers containing cholesterol than aurein 3.3.

• 공업화학
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• 제10권2호
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• pp.231-236
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• 1999

결정상과 분산도가 조절된 $MoO_3$/$SiO_2$ 담지촉매를 제조하여 촉매의 표면특성과 디벤조티오펜 탈황반응의 활성도를 고찰하였다. Mo의 표면담지량은 4 atoms $Mo/nm^2$이었으며, 실리카 표면 위에 형성된 $MoO_3$의 결정상은 sintered hexagonal, sintered orthorhombic, 및 dispersed hexagonal상이었다. XRD, Raman, 및 $O_2$ 흡착 결과 $MoO_3$의 표면분산도는 sintered hexagonal < sintered orthorhombic < dispersed hexagonal 순으로 증가하였다. TPR 결과 $MoO_3$ 결정은 $650^{\circ}C$에서 $MoO_2$로, $1000^{\circ}C$에서 Mo로 환원됨을 알 수 있었다. 디벤조티오펜 탈황반응을 30기압, $350{\sim}500^{\circ}C$ 온도범위에서 수행하였으며, 실험 결과 활성도는 $MoO_3$ 결정체의 $SiO_2$ 표면에서의 분산도에 비례하여 증가함을 알 수 있었다.

• 암석학회지
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• 제3권1호
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• pp.34-40
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• 1994

High pressure X-ray diffraction study was carried out on a graphite to investigate its compressibility as well as any possible phase transition to the hexagonal diamond structure at room temperature. Energy dispersive X-ray diffraction method was introduced using a Mao-Bell type diamond anvil cell with Synchrotron Radiation. Polycrystalline sodium chloride was compressed together with graphite for the high pressure determinations. Because of the poor resolution of the X-ray diffraction pattern of graphite, its compressibility was estimated to be almost same as that of NaCl by graphite (002) X-ray diffraction peak only. An observation of any new peak from a possible hexagonal diamond phase seems very unplausible for its definite identification based on the present data. Alternative approaches such as an Wiggler Radiation source as well as a Large Volume high pressure apparatus will be necessary for the detailed studies on a graphite in future.

• 한국세라믹학회지
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• 제37권7호
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• pp.665-672
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• 2000

The ferroelectric YMnO3 thin films were prepared by MOD(metal-organic decomposition) method with Y- and Mn-acetylacetonate as starting materials. Thin films were grown on various substrates by spin-coating technique. The crystalline phases of the thin films were identified by X-ray diffractometer as a function of heat-treatment temperature, pH of coating solution and substrate. In addition, the effect of Mn/Y molar ratio(0.8~1.2) on the formation of hexagonal-YMnO3 phase was investigated. In forming highly c-axisoriented hexagonal-YMnO3 single phase, the Pt coated Si substrate was more effective than the bare Si substrate, and the optimum heat-treatment condition was at 82$0^{\circ}C$ for 30 min. Higher Mn/Y molar ratio within 0.8~1.2 and pH of YMnO3 precursor solution within 0.5~2.5 favored formation of ferroelectric hexagonal phase rather than orthorhombic phase. Leakage current density of the hexagonal-YMnO3 thin film formed on Pt(111)/TiO2/SiO2/Si substrate was low enough as 0.4~4.0$\times$10-8(A/$\textrm{cm}^2$) at 5 V and its remanent polarization(Pr), calculated from the P-E hysteresis loop, was 3 nC/$\textrm{cm}^2$.

• 센서학회지
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• 제29권1호
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• pp.63-67
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• 2020

This study investigated the influence of various sintering pressures of ZnS nanoparticles prepared by hydrothermal synthesis performed at 220 ℃ for 20 h. The hydrothermally synthesized ZnS nanoparticles formed a cubic phase. The ZnS nanoparticles were sintered using a hot-press process at 850 ℃ for 2 h under pressures of 10, 20, 30, 40, 50, 60, and 70 MPa. The ZnS ceramics indicate the cubic phase is the major phase and the hexagonal phase is the minor phase. In the ZnS ceramics, as the sintering pressure increased, a decrement in the hexagonal phase was confirmed. When the sintering pressure equaled or exceeded 30 MPa, the transmittance and density improved with reductions in porosity and hexagonal phase. A sintering pressure of 60 MPa delivered the highest transmittance (69.7%).

• 한국산학기술학회논문지
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• 제5권6호
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• pp.558-561
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• 2004

암모늄헵타몰리브데이트(ammonium heptamolybdate, AHM)를 전구체로 제조한 실리카 담지 몰리브드늄$(MoO_{3}/SiO_{2})$ 촉매의 구조적 특성을 x-ray 회절기(XRD)를 사용하여 자세히 고찰하였다. 몰리브드늄의 표면담지량은 0.2부터 4.0 atoms $Mo/nm^{2}$로 변화하였으며, 담지촉매의 소성온도는 $300\~500^{\circ}C$로 변화하여 열역학적으로 형성 가능한 모든 몰리브드늄산화물의 구조를 고찰하였다. 담지량이 큰 경우(4 atoms $Mo/nm^{2}$), $300^{\circ}C$소성에서는 뭉쳐있거나 잘 분산된 hexagonal 형태의 결정체가 형성되었으며, $500^{\circ}C$로 소성온도를 증가하면 뭉친 orthorhombic 형태의 $MoO_{3}$ 결정체가 형성되었다. 뭉친 orthorhombic 형태의 결정체는 담지량이 1.1 atom $Mo/nm^{2}$이상이 되면 형성된 반면 잘 분산된 hexagonal 형태의 결정체는 가장 큰 표면 담지량 4.0 atoms $Mo/nm^{2}$에서도 고찰하기가 어려웠다. 이러한 hexagonal 결정체의 담체 표면에서의 높은 분산은 암모니아로 인한 몰리브드늄 산화물($MoO_{3}$)과 실리카($SiO_{2}$) 담체 사이의 강한 표면작용에 기인한 것으로 생각된다.

• 센서학회지
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• 제28권4호
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• pp.256-261
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• 2019

In this study, mid-infrared transparent zinc sulfide (ZnS) ceramics were fabricated through hydrothermal synthesis with different molar ratios of S/Zn (S/Zn = 0.8, 1.0, 1.2, 1.4, and 1.6). The ZnS ceramics were sintered at a relatively low temperature of $850^{\circ}C$ to prevent the occurrence of the hexagonal phase featuring optical anisotropy. The phase composition, microstructure, and optical properties of the ZnS ceramics were subsequently investigated by employing X-ray diffraction, scanning electron microscopy, and Fouriertransform infrared spectroscopy. The results obtained indicate that the ZnS nanoparticles feature the cubic phase, without the hexagonal phase. Moreover, with increasing S, the crystallinity and particle size of the ZnS nanoparticles increased. The crystallinity and density of the ZnS ceramics improved when the molar ratio of S was higher than the molar ratio of Zn, thereby enhancing the transmittance. Furthermore, the ZnS ceramic with an S/Zn value of 1.2 was found to exhibit the highest transmittance of approximately 69% owing to the reduced occurrence of the hexagonal phase and a high density of 99.8%.

• 암석학회지
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• 제6권2호
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• pp.88-95
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• 1997

High pressure X-ray diffraction study was carried out on a polycrystalline graphite to investigate the phase transition(s) at room temperature. Energy dispersive X-ray diffraction method was employed using a Mao-Bell type diamond anvil cell with an Wiggler synchrotron Radiation at the National Synchrotron Light Source. Sodium chloride power was used as the internal pressure sensor for the high pressure determinations as well as the pressure medium for quasihydrostatic pressure environment. Graphite transforms into a hexagonal didose not agree with the previously reported observations and this phase persists when pressure is released down to 0.1 MPa. This result dose not agree with the previously reported observations and this discrepancy would be due to the kinetics in phase transition as well as the uniaxially oriented pressure field in the diamond anvil cell.