• 제목/요약/키워드: Heterogeneous transformation

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Naturally Occurring Mediastinal Teratoma with Malignant Transformation in an Adult Male

  • Kim, Ho Jin;Kim, Hyeong Ryul
    • Journal of Chest Surgery
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    • 제46권4호
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    • pp.305-308
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    • 2013
  • We report a rare case of rhabdomyosarcoma spontaneously arising in an anterior mediastinal teratoma in a 47-year-old male. The patient was found to have an anterior mediastinal mass on a chest X-ray, which was taken two months before his presentation to Asan Medical Center. A subsequent computed tomography scan revealed an $8.9{\times}7.1{\times}8.0$ cm heterogeneous mass in the anterior mediastinum. He underwent an excision via median sternotomy. The histopathologic study identified a mature teratoma with embryonal rhabdomyosarcoma.

비균질 도시 지표에서 측정된 에디 공분산 난류 플럭스의 불확실성 분석: 좌표계 편향 영향 (Uncertainty Analysis of the Eddy-Covariance Turbulent Fluxes Measured over a Heterogeneous Urban Area: A Coordinate Tilt Impact)

  • 이두일;이재형;이상현
    • 대기
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    • 제26권3호
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    • pp.473-482
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    • 2016
  • An accurate determination of turbulent fluxes over an urban area is a challenging task due to its morphological diversity and associated flow complexity. In this study, an eddy covariance (EC) method is applied over a highly heterogeneous urban area in a small city (Gongju), South Korea to investigate the quantitative influence of 'coordinate tilt' in determining the turbulent fluxes of sensible heat, latent heat, momentum, and carbon dioxide mass. Two widely-used coordinate transform methods are adopted and applied to eight directional sections centered on the site to analyze a 1-year period EC measurement obtained from the urban site: double rotation (DR) and planar fit (PF) transform. The results show that mean streamline planes determined by the PF method are distinguished from the sections, representing morphological heterogeneity of the site. The sectional pitch angles determined by the DR method also compare well with those in the PF method. Both the PF and DR methods show large variabilities in the determined streamline planes at each directional section, implying that flow patterns may form in a complicate way due to the surface heterogeneity. Resulting relative differences of the turbulent fluxes, defined by $(F_{DR}-F_{PF})/F_{DR}$, are found on average +13% in sensible heat flux, +21% in latent heat flux, +37% in momentum flux, and +26% in carbon dioxide mass flux, which are larger values than those reported previously for fairly homogeneous natural sites. The fractional differences depend significantly on wind direction, showing larger differences in northerly winds at the measurement site. It is also found that the relative fractional differences are negatively correlated with the mean wind speed at both stable/unstable atmospheric conditions. These results imply that EC turbulent fluxes determined over heterogeneous urban areas should be carefully interpreted with considering the uncertainty due to 'coordinate tilt' effect in their applications.

루테늄 지르코니아 불균일 촉매를 이용한 알켄 또는 알킨의 효과적인 산화절단반응 (Efficient Oxidative Scission of Alkenes or Alkynes with Heterogeneous Ruthenium Zirconia Catalyst)

  • 모비나 이르샤드;최봉길;강온유;홍석복;황성연;허영민;김정원
    • 공업화학
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    • 제27권6호
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    • pp.659-663
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    • 2016
  • 알켄 또는 알킨의 산화 반응이 루테늄 지르코니아 불균일 촉매에 의해 매우 선택적이며 효율적으로 전환되었다. 절단반응을 통해, C-C 이중 결합은 알데히드 관능기로, 삼중 결합은 다이케톤 또는 카르복시산으로 전환되었는데, 다양한 기질들이 $30^{\circ}C$에서 $PhI(OAc)_2$ 산화제와 dichloromethane 및 물(각각 5 mL와 0.5 mL)의 혼합 용매 조건에서 반응이 수행되었다. 사용된 촉매 $Ru(OH)_x/ZrO_2$는 이 절단 반응에 대해 기존의 다른 루테늄 기반 불균일 또는 균일 촉매들보다 더 좋은 활성과 선택성을 보였다. 반응이 진행되는 동안, 제조된 촉매의 기계적인 물성은 안정적이었고, 금속의 침출은 전혀 보이지 않았다. 불포화된 탄화수소들의 산화적 절단에 대해, 합성된 촉매는 여러 번 재사용해도 그 촉매의 성능을 그대로 유지하였다.

3차원 공간 위상 관계 연산자의 설계 (Design of Three Dimensional Spatial Topological Relational Operators)

  • 김상호;강구;류근호
    • 정보처리학회논문지D
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    • 제10D권2호
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    • pp.211-220
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    • 2003
  • 지리정보시스템은 3차원 위상정보를 표현함으로써 사용자에게 정확하고 정교한 서비스를 제공한다. 이 때에 3차원 위상정보연산을 위해 차원변경방식과 서로 이질적인 공간모델을 사용해야 하는데, 이 방식을 사용할 때는 공간 연산이 어려울 뿐 아니라 서로 호환성이 부족한 문제가 발생한다. 따라서 이 논문에서는 이 문제를 해결하기 위하여 2차원 공간 객체 모델을 수용하는 3차원 공간 객체 모델을 제안하였고, 타당성을 보이기 위하여 구현하여, 그 실행을 보였다. 3차원 공간 위상 관계 연산자를 위하여 DE-9IM 방식을 3차원 개념으로 정의한 DE-9IM을 이용해서 설계하였고, 객체지향 개념을 지원하는 컴포넌트 환경에서 3차원 공간 위상 연산자를 구현하였다. 이 논문에서 제안된 3차원 공간 위상 연산자는 타 시스템과의 상호 운용성을 보장하며, 구현된 공간 위상 관계 연산을 이용하여, 3차원 공간 객체에 대한 효율적인 공간 질의를 수행할 수 있다.

Risk Assessment from Heterogeneous Energy Deposition in Tissue. The Problem of Effects from Low Doses of Ionizing Radiation

  • Le, Feinendegen;J, Booz
    • 대한핵의학회지
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    • 제26권1호
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    • pp.8-13
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    • 1992
  • Low doses of ionizing radiation from external or internal sources cause heterogeneous distribution of energy deposition events in the exposed biological system. With the cell being the individual element of the tissue system, the fraction of cells hit, the dose received by the hit, and the biological response of the cell to the dose received eventually determine the effect in tissue. The hit cell may experience detriment, such as change in its DNA leading to a malignant transformation, or it may derive benefit in terms of an adaptive response such as a temporary improvement of DNA repair or temporary prevention of effects from intracellular radicals through enhanced radical detoxification. These responses are protective also to toxic substances that are generated during normal metabolism. Within a multicellular system, the probability of detriment must be weighed against the probability of benefit through adaptive responses with protection against various toxic agents including those produced by normal metabolism. Because irradiation can principally induce both, detriment and adaptive responses, one type of affected cells may not be simply summed up at the expense of cells with other types of effects, in assessing risk to tissue. An inventory of various types of effects in the blood forming system of mammals, even with large ranges of uncertainty, uncovers the possibility of benefit to the system from exposure to low doses of low LET radiation. This experimental approach may complement epidemiological data on individuals exposed to low doses of ionizing radiation and may lead to a more rational appraisal of risk.

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Suzuki-Miyaura Cross-coupling Reaction Catalyzed by Nickel Nanoparticles Supported on Poly(N-vinyl-2-pyrrolidone)/TiO2-ZrO2 Composite

  • Kalbasi, Roozbeh Javad;Mosaddegh, Neda
    • Bulletin of the Korean Chemical Society
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    • 제32권8호
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    • pp.2584-2592
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    • 2011
  • Nickel nanoparticle-poly(N-vinyl-2-pyrrolidone)/$TiO_2-ZrO_2$ composite (Ni-PVP/$TiO_2-ZrO_2$) was prepared by in situ polymerization method. The physical and chemical properties of Ni-PVP/$TiO_2-ZrO_2$ were investigated by XRD, FT-IR, BET, TGA, SEM and TEM techniques. The catalytic performance of this novel heterogeneous catalyst was determined for the Suzuki-Miyaura cross-coupling reaction between aryl halides and phenylboronic acid in the presence of methanol-water mixture as solvent. The effects of reaction temperature, the amount of catalyst, amount of support, solvent, and amount of metal for the synthesis of Ni-PVP/$TiO_2-ZrO_2$, were investigated as well as recyclability of the heterogeneous composite. The catalyst used for this synthetically useful transformation showed considerable level of reusability besides very good activity.

Efficient key generation leveraging wireless channel reciprocity and discrete cosine transform

  • Zhan, Furui;Yao, Nianmin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제11권5호
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    • pp.2701-2722
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    • 2017
  • Key generation is essential for protecting wireless networks. Based on wireless channel reciprocity, transceivers can generate shared secret keys by measuring their communicating channels. However, due to non-simultaneous measurements, asymmetric noises and other interferences, channel measurements collected by different transceivers are highly correlated but not identical and thus might have some discrepancies. Further, these discrepancies might lead to mismatches of bit sequences after quantization. The referred mismatches significantly affect the efficiency of key generation. In this paper, an efficient key generation scheme leveraging wireless channel reciprocity is proposed. To reduce the bit mismatch rate and enhance the efficiency of key generation, the involved transceivers separately apply discrete cosine transform (DCT) and inverse discrete cosine transform (IDCT) to pre-process their measurements. Then, the outputs of IDCT are quantified and encoded to establish the bit sequence. With the implementations of information reconciliation and privacy amplification, the shared secret key can be generated. Several experiments in real environments are conducted to evaluate the proposed scheme. During each experiment, the shared key is established from the received signal strength (RSS) of heterogeneous devices. The results of experiments demonstrate that the proposed scheme can efficiently generate shared secret keys between transceivers.

A frame work for heat generation/absorption and modified homogeneous-heterogeneous reaction in flow based on non-Darcy-Forchheimer medium

  • Hayat, Tasawar;Ahmad, Salman;Khan, Muhammad I.;Khan, Muhammad I.;Alsaedi, Ahmed
    • Nuclear Engineering and Technology
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    • 제50권3호
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    • pp.389-395
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    • 2018
  • The present work aims to report the consequences of Darcy-Forchheimer medium in flow of Cross fluid model toward a stretched surface. Flow in porous space is categorized by Darcy-Forchheimer medium. Further heat transfer characteristics are examined via thermal radiation and heat generation/absorption. Transformation procedure is used. The arising system of nonlinear ordinary differential equations is solved numerically by means of shooting method. The effects of different flow variables on velocity, temperature, concentration, skin friction, and heat transfer rate are discussed. The obtained outcomes show that velocity was enhanced with the increase in the Weissenberg number but decays with increase in the porosity parameter and Hartman number. Temperature field is boosted by thermal radiation and heat generation; however, it decays with the increase in the Prandtl number.

Bayberry Tannin as Stabilizer for the Synthesis of Highly Active and Reusable Heterogeneous Pd Catalysts and Their Application in the Catalytic Hydrogenation of Olefins

  • Chen, Chen;Lv, Guang;Huang, Xin;Liao, Xue Pin;Zhang, Wen Hua;Shi, Bi
    • Bulletin of the Korean Chemical Society
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    • 제33권2호
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    • pp.403-408
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    • 2012
  • In this study, the homogenous Pd nanoparticles (Pd NPs) were first prepared with bayberry tannin (BT) as the stabilizers. Subsequently, the obtained bayberry tannin-stabilized Pd nanoparticles (BT-Pd) were immobilized onto ${\gamma}-Al_2O_3$ to prepare heterogeneous ${\gamma}-Al_2O_3$-BT-Pd catalysts. Fourier Transformation Infrared Spectrum (FTIR) and X-ray Photoelectron Spectroscopy (XPS) analyses confirmed that the Pd NPs were well stabilized by the phenolic hydroxyl groups of BT. Transmission Electron Microscopy (TEM) observation indicated that the diameter of the Pd NPs can be effectively controlled in the range of 4.2-16.0 nm by varying the amount of BT. It is found that the ${\gamma}-Al_2O_3$-BT-Pd catalysts exhibit highly activity for various olefin hydrogenations. For example, the initial TOF (turnover frequency) of the ${\gamma}-Al_2O_3$-BT-Pd in the allyl alcohol hydrogenation is as high as $12804 mol{\cdot}mol^{-1}{\cdot}h^{-1}$. Furthermore, the ${\gamma}-Al_2O_3$-BT-Pd can be reused 5 times without significant loss of activity, exhibiting a superior reusability as compared with conventionally prepared ${\gamma}-Al_2O_3$-Pd catalysts.

A Physical-layer Security Scheme Based on Cross-layer Cooperation in Dense Heterogeneous Networks

  • Zhang, Bo;Huang, Kai-zhi;Chen, Ya-jun
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제12권6호
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    • pp.2595-2618
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    • 2018
  • In this paper, we investigate secure communication with the presence of multiple eavesdroppers (Eves) in a two-tier downlink dense heterogeneous network, wherein there is a macrocell base station (MBS) and multiple femtocell base stations (FBSs). Each base station (BS) has multiple users. And Eves attempt to wiretap a macrocell user (MU). To keep Eves ignorant of the confidential message, we propose a physical-layer security scheme based on cross-layer cooperation to exploit interference in the considered network. Under the constraints on the quality of service (QoS) of other legitimate users and transmit power, the secrecy rate of system can be maximized through jointly optimizing the beamforming vectors of MBS and cooperative FBSs. We explore the problem of maximizing secrecy rate in both non-colluding and colluding Eves scenarios, respectively. Firstly, in non-colluding Eves scenario, we approximate the original non-convex problem into a few semi-definite programs (SDPs) by employing the semi-definite relaxation (SDR) technique and conservative convex approximation under perfect channel state information (CSI) case. Furthermore, we extend the frame to imperfect CSI case and use the Lagrangian dual theory to cope with uncertain constraints on CSI. Secondly, in colluding Eves scenario, we transform the original problem into a two-tier optimization problem equivalently. Among them, the outer layer problem is a single variable optimization problem and can be solved by one-dimensional linear search. While the inner-layer optimization problem is transformed into a convex SDP problem with SDR technique and Charnes-Cooper transformation. In the perfect CSI case of both non-colluding and colluding Eves scenarios, we prove that the relaxation of SDR is tight and analyze the complexity of proposed algorithms. Finally, simulation results validate the effectiveness and robustness of proposed scheme.