• Journal of Hydrogen and New Energy
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• v.23 no.1
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• pp.73-82
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• 2012

A 2-dimensional heterogeneous reactor model was developed and simulated for a tube reactor of packed bed where the steam-$CO_2$ combined reforming reaction of natural gas proceeded to produce synthesis gas. Under the reactor feeding rate, 45 $Nm^3$/h, of the reactant gas stream, the 2-dimensional heterogeneous reactor model showed the similar results to those from the ASPEN simulator although there were some discrepancies between the two in the temperature and the $H_2$/CO ratio of the reformed gas at the reactor exit. The calculated enthalpy difference between the reformed gas at the reactor exit and the reactant gas fed to the reactor was closely correspondent to the total amount of heat transferred to the reactor interior from the furnace. This supports that the 2-dimensional heterogeneous reactor model was reasonably established and the numerical solution was properly obtained.

• Nuclear Engineering and Technology
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• v.43 no.6
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• pp.523-530
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• 2011

In a previous study, the stochastic space-dependent kinetics model (SSKM) based on the forward stochastic model in stochastic kinetics theory and the Ito stochastic differential equations was proposed for treating monoenergetic space-time nuclear reactor kinetics in one dimension. The SSKM was tested against analog Monte Carlo calculations, however, for exemplary cases of homogeneous slab reactors with only one delayed-neutron precursor group. In this paper, the SSKM is improved and evaluated with more realistic and complicated cases regarding several delayed-neutron precursor groups and heterogeneous slab reactors in which the extraneous source or reactivity can be introduced locally. Furthermore, the source level and the initial conditions will also be adjusted to investigate the trends in the variances of the neutron population and fission product levels across the reactor. The results indicate that the improved SSKM is in good agreement with the Monte Carlo method and show how the variances in population dynamics can be controlled.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.340-343
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• 2006

In this paper, heat and mass transfer characteristics through experimental and numerical study are extensively investigated in steam reform ins reactor under given operating conditions. In order to get simulated data at outlet of the reformer, heterogeneous reactor model is incorporated. As the reaction also takes place in porous media, two medium approach is used to take into account thermally non-equilibrium phenomena between catalyst and bulk gas. In steam reforming reaction, heat transfer issue is so significant that geometrical configuration study is also conducted.

• Korean Chemical Engineering Research
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• v.47 no.3
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• pp.287-291
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• 2009

The heterogeneous decomposition of ammonia on a quartz surface in an inverted, stagnation-point flow reactor was investigated using a measurement reactor and a numerical model of the reactor. In the experiments, 8 mole% of ammonia in nitrogen was used and the temperature of an electric heater was set in the range $300{\sim}900^{\circ}C$ to heat the quartz surface where the decomposition took place. Gas temperatures and ammonia concentrations in the reactor obtained using in situ Raman spectroscopy were analyzed with the numerical model and it was revealed that, depending on the heater temperature, the temperature of the quartz surface was estimated to be in the range $235{\sim}619^{\circ}C$ and the activation energy of the decomposition on the surface was in the range 10.9~15.8 kcal/mol.

• Nuclear Engineering and Technology
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• v.49 no.7
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• pp.1379-1387
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• 2017

This paper presents a comparison of homogenization techniques implemented in the APOLLO3 platform for transport core calculations: standard scalar flux weighting and new flux-moment homogenization, in different combinations with (or without) leakage models. Besides the historical B1-homogeneous model, a new B-heterogeneous one has indeed been implemented recently in the two/three-dimensional-transport solver using the method of characteristics. First analyses have been performed on a very simple Sodium Fast Reactor core with a regular hexagonal lattice. They show that using the heterogeneous leakage model in association with flux-moment homogenization strongly improves the prediction of $k_{eff}$ and void reactivity effects. These good results are confirmed when the application is done to the fissile assemblies of the more complex CFV (Low Void Effect) core of the ASTRID (Advanced Sodium Technological Reactor for Industrial Demonstration) project of sodium-cooled fast breeder reactor (Generation IV).

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3353-3358
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• 2007

The present paper is devoted to investigate dynamic effect and steady-state performance of methane autothermal reformer theoretically and numerically. In order to simplify the complicated phenomena in the system, axisymmetric heterogeneous reactor model is developed. As autothermal reaction takes places on catalyst surface between bulk gas and catalyst, volume averaging method is incorporated using porous medium approach. To understand the start-up process which occurs in the reactor is highly important. Therefore, in this paper we get various goverining equations to find out transient and steady solutions and time scale for start-up introducing dimensionless variables. Start-up is a significant issue in reforming reaction for automobile system and fueling of SOFC-based auxiliary power units. This paper deals with characteristics of heat and mass transfer and predicted light-off time in the reformer as oxygen to carbon ratio ($O_2$/C) and amount of feeding gas.

• Nuclear Engineering and Technology
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• v.48 no.1
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• pp.33-42
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• 2016

Spacer grids play an important role in maintaining the proper form of the fuel assembly structure and ensuring the safety of reactor core design. This study applies the Monte Carlo method to the analysis of the neutronics effects of spacer grids in a typical pressurized water reactor (PWR). The core problem used to analyze the neutronics effects of spacer grids is a modified version of Korea Advanced Institute of Science and Technology benchmark problem 1B, based on an Advanced Power Reactor 1400 (APR1400) core model. The spacer grids are modeled and added to this test problem in various ways. Then, by running MCNP5 for all cases of spacer grid modeling, some important numerical results, such as the effective multiplication factor, the spatial distributions of neutron flux, and its energy spectrum are obtained. The numerical results of each case of spacer grid modeling are analyzed and compared to assess which type has more advantages in accuracy of numerical results and effectiveness in terms of geometry building. The conclusion is that the most realistic modeling for Monte Carlo calculation is the "volume-preserving" streamlined heterogeneous spacer grids, but the "banded" dissolution spacer grids modeling is a more practical yet accurate model for routine (deterministic) analysis.

• Microbiology and Biotechnology Letters
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• v.23 no.4
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• pp.425-431
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• 1995

A kinetic model of the cyclodextrin formation in a heterogeneous enzyme reaction system using swollen extrusion starch as substrate was derived emphasing the structural features of extrusion starch. The degree of gelatinization, the ratio of accessible and inaccessible portion of extrusion starch, adsorption of CGTase on swollen starch, the structural transformation during reaction, and product inhibition caused by produced CDs were considered in deriving kinetic model. Various kinetic constants were also evaluated. The derived kinetic equation was numerically simulated, which result showed that the derived kinetic equations can be used to predict the experimental data reasonably well under the various experimental conditions. Kinetic model can be utilized for the optimization of enzyme reactor and the process development for CD production from swollen extrusion starch.

• 한국가스학회:학술대회논문집
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• 2007.04a
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• pp.27-32
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• 2007

Dimethyl Ether (DME, $CH_3OCH_3$) is the simplest ether and is considered as one of the leading candidates in the quest for a substitute fur petroleum-based fuels. In this work, we analyzed the one-step synthesis of DME in a shell and tube type fixed bed reactor and carried out a simulation with a one-dimensional, steady state model of a heterogeneous catalyst bed, while taking into consideration the heat and mass transfer between the catalyst pellets and reactants gas and the effectiveness factor of the catalysts, together with the reactor cooling through the reactor tube wall. The reactor simulation was carried out under steady state condition and we compared the simulation results with the experimental data obtained from operations of a pilot-scale reactor and found good agreement between them.

• New & Renewable Energy
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• v.2 no.4 s.8
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• pp.56-63
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• 2006

In this paper, heat and mass transfer characteristics through experimental and numerical study are extensively investigated in steam reforming reactor under given operating conditions. In order to get simulated data at outlet of the reformer, heterogeneous reactor model is incorporated. As the reaction also takes place in porous media, two medium approach is used to take into account thermally non-equilibrium phenomena between catalyst and bulk gas. From various parametric studies, significance of heat transfer is emphasized in steam reforming reaction.