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Biochemical characterization of cotton stalks biochar suggests its role in soil as amendment and decontamination

  • Younis, Uzma;Athar, Mohammad;Malik, Saeed Ahmad;Bokhari, Tasveer Zahra;Shah, M. Hasnain Raza
    • Advances in environmental research
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    • 제6권2호
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    • pp.127-137
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    • 2017
  • Cotton is the major fiber crop in Pakistan that accounts for 2% of total national gross domestic product (GDP). After picking of cotton, the dry stalks are major organic waste that has no fate except burning to cook food in villages. Present research focuses use of cotton stalks as feedstock for biochar production, its characterization and effects on soil characteristics. Dry cotton stalks collected from agricultural field of Bahauddin Zakariya University, Multan, Pakistan were combusted under anaerobic conditions at $450^{\circ}C$. The physicochemical analysis of biochar and cotton stalks show higher values of % total carbon, phosphorus and potassium concentrations in biochar as compared to cotton stalks. The concentration of nitrogen was decreased in biochar. Similarly biochar had greater values of fixed carbon that suggest its role for carbon sequestration and as a soil amendment. The fourier transformation infrared spectroscopic spectra (FTIR) of cotton stalks and biochar exposed more acidic groups in biochar as compared to cotton stalks. The newly developed functional groups in biochar have vital role in increasing surface properties, cation exchange capacity, and water holding capacity, and are responsible for heavy metal remediation in contaminated soil. In a further test, results show increase in the water holding capacity and nutrient retention by a sandy soil amended with biochar. It is concluded that cotton stalks can be effectively used to prepare biochar.

Monitoring in-service performance of fibre-reinforced foamed urethane sleepers/bearers in railway urban turnout systems

  • Kaewunruen, Sakdirat
    • Structural Monitoring and Maintenance
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    • 제1권1호
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    • pp.131-157
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    • 2014
  • Special track systems used to divert a train to other directions or other tracks are generally called 'railway turnout'. A traditional turnout system consists of steel rails, switches, crossings, steel plates, fasteners, screw spikes, timber bearers, ballast and formation. The wheel rail contact over the crossing transfer zone has a dip-like shape and can often cause detrimental impact loads on the railway track and its components. The large impact also emits disturbing noises (either impact or ground-borne noise) to railway neighbors. In a brown-field railway track where an existing aged infrastructure requires renewal or maintenance, some physical constraints and construction complexities may dominate the choice of track forms or certain components. With the difficulty to seek for high-quality timbers with dimensional stability, a methodology to replace aged timber bearers in harsh dynamic environments is to adopt an alternative material that could mimic responses and characteristics of timber in both static and dynamic loading conditions. A critical review has suggested an application of an alternative material called fibre-reinforced foamed urethane (FFU). The full-scale capacity design makes use of its comparable engineering characteristics to timber, high-impact attenuation, high damping property, and a longer service life. A field trial to investigate in-situ behaviours of a turnout grillage system using an alternative material, 'fibre-reinforced foamed urethane (FFU)' bearers, has been carried out at a complex turnout junction under heavy mixed traffics at Hornsby, New South Wales, Australia. The turnout junction was renewed using the FFU bearers altogether with new special track components. Influences of the FFU bearers on track geometry (recorded by track inspection vehicle 'AK Car'), track settlement (based on survey data), track dynamics, and acoustic characteristics have been measured. Operational train pass-by measurements have been analysed to evaluate the effectiveness of the replacement methodology. Comparative studies show that the use of FFU bearers generates higher rail and sleeper accelerations but the damping capacity of the FFU help suppress vibration transferring onto other track components. The survey data analysis suggests a small vertical settlement and negligible lateral movement of the turnout system. The static and dynamic behaviours of FFU bearers appear to equate that of natural timber but its service life is superior.

Vanadium(V) removal from aqueous solutions using a new composite adsorbent (BAZLSC): Optimization by response surface methodology

  • Mojiri, Amin;Hui, Wang;Arshad, Ahmad Kamil;Ridzuan, Ahmad Ruslan Mohd;Hamid, Nor Hayati Abdul;Farraji, Hossein;Gholami, Ali;Vakili, Amir Hossein
    • Advances in environmental research
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    • 제6권3호
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    • pp.173-187
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    • 2017
  • Heavy metals, such as vanadium, are some of the most toxic types of water contaminants. In this study, vanadium was removed using a new composite adsorbent called BAZLSC. The impacts of pH and initial concentration of vanadium(V) on the elimination effectiveness of this metal by using BAZLSC were investigated in the first step of the study. Vanadium removal increased as pH increased to 3-3.5, and initial concentration increased to 60-70 mg/L. The removal efficiency then decreased. Central composite design and response surface methodology were employed to examine experimental data. Initial concentration of V ($mg.L^{-1}$), pH, and dosage of adsorbent (g/L) were the independent factors. Based on RSM, the removal effectiveness of vanadium was 86.36% at the optimum of initial concentration (52.69 mg/L), pH (3.49), and adsorbent dosage (1.71 g/L). Also adsorption isotherm investigations displayed that the Freundlich isotherm could explain vanadium adsorption by BAZLSC better than the Langmuir isotherm. Beside them, desorption studies showed sorption was slightly diminished after six continuous cycles.

Removal of Pb(II) from wastewater by biosorption using powdered waste sludge

  • Jang, Hana;Park, Nohback;Bae, Hyokwan
    • Membrane and Water Treatment
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    • 제11권1호
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    • pp.41-48
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    • 2020
  • Lead is a highly toxic heavy metal that causes serious health problems. Nonetheless, it is increasingly being used for industrial applications and is often discharged into the environment without adequate purification. In this study, Pb(II) was removed by powdered waste sludge (PWS) based on the biosorption mechanism. Different PWSs were collected from a submerged moving media intermittent aeration reactor (SMMIAR) and modified Ludzack-Ettinger (MLE) processes. The contents of extracellular polymeric substances were similar, but the surface area of MLE-PWS (2.07 ㎡/g) was higher than that of SMMIAR-PWS (0.82 ㎡/g); this is expected to be the main parameter determining Pb(II) biosorption capacity. The Bacillaceae family was dominant in both PWSs and may serve as the major responsible bacterial group for Pb(II) biosorption. Pb(II) biosorption using PWS was evaluated for reaction time, salinity effect, and isotherm equilibrium. For all experiments, MLE-PWS showed higher removal efficiency. At a fixed initial Pb(II) concentration of 20 mg/L and a reaction time of 180 minutes, the biosorption capacities (qe) for SMMIAR- and MLE-PWSs were 2.86 and 3.07 mg/g, respectively. Pb(II) biosorption using PWS was rapid; over 80% of the maximum biosorption capacity was achieved within 10 minutes. Interestingly, MLE-PWS showed enhanced Pb(II) biosorption with salinity values of up to 30 g NaCl/L. Linear regression of the Freundlich isotherm revealed high regression coefficients (R2 > 0.968). The fundamental Pb(II) biosorption capacity, represented by the KF value, was consistently higher for MLE-PWS than SMMIAR-PWS.

Load carrying capacity of CFRP retrofitted broken concrete arch

  • Wang, Peng;Jiang, Meirong;Chen, Hailong;Jin, Fengnian;Zhou, Jiannan;Zheng, Qing;Fan, Hualin
    • Steel and Composite Structures
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    • 제23권2호
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    • pp.187-194
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    • 2017
  • To reuse a broken plain concrete (PC) arch, a retrofitting method was proposed to ensure excellent structural performances, in which carbon fiber reinforced polymers (CFRPs) were applied to repair and strengthen the damaged PC arch through bonding and wrapping techniques. Experiments were carried out to reveal the deformation and the load carrying capacity of the retrofitted composite arch. Based on the experiments, repairing and strengthening effects of the CFRP retrofitted broken arch were revealed. Simplified analysing model was suggested to predict the peak load of the CFRP retrofitted broken arch. According to the research, it is confirmed that absolutely broken PC arch can be completely repaired and reinforced, and even behaves more excellent than the intact PC arch when bonded together and strengthened with CFRP sheets. Using CFRP bonding/wrapping technique a novel efficient composite PC arch structure can be constructed, the comparison between rebar reinforced concrete (RC) arch and composite PC arch reveals that CFRP reinforcements can replace the function of steel bars in concrete arch.

Extrapolation of extreme traffic load effects on bridges based on long-term SHM data

  • Xia, Y.X.;Ni, Y.Q.
    • Smart Structures and Systems
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    • 제17권6호
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    • pp.995-1015
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    • 2016
  • In the design and condition assessment of bridges, it is usually necessary to take into consideration the extreme conditions which are not expected to occur within a short time period and thus require an extrapolation from observations of limited duration. Long-term structural health monitoring (SHM) provides a rich database to evaluate the extreme conditions. This paper focuses on the extrapolation of extreme traffic load effects on bridges using long-term monitoring data of structural strain. The suspension Tsing Ma Bridge (TMB), which carries both highway and railway traffic and is instrumented with a long-term SHM system, is taken as a testbed for the present study. Two popular extreme value extrapolation methods: the block maxima approach and the peaks-over-threshold approach, are employed to extrapolate the extreme stresses induced by highway traffic and railway traffic, respectively. Characteristic values of the extreme stresses with a return period of 120 years (the design life of the bridge) obtained by the two methods are compared. It is found that the extrapolated extreme stresses are robust to the extrapolation technique. It may owe to the richness and good quality of the long-term strain data acquired. These characteristic extremes are also compared with the design values and found to be much smaller than the design values, indicating conservative design values of traffic loading and a safe traffic-loading condition of the bridge. The results of this study can be used as a reference for the design and condition assessment of similar bridges carrying heavy traffic, analogous to the TMB.

Structural identification of Humber Bridge for performance prognosis

  • Rahbari, R.;Niu, J.;Brownjohn, J.M.W.;Koo, K.Y.
    • Smart Structures and Systems
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    • 제15권3호
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    • pp.665-682
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    • 2015
  • Structural identification or St-Id is 'the parametric correlation of structural response characteristics predicted by a mathematical model with analogous characteristics derived from experimental measurements'. This paper describes a St-Id exercise on Humber Bridge that adopted a novel two-stage approach to first calibrate and then validate a mathematical model. This model was then used to predict effects of wind and temperature loads on global static deformation that would be practically impossible to observe. The first stage of the process was an ambient vibration survey in 2008 that used operational modal analysis to estimate a set of modes classified as vertical, torsional or lateral. In the more recent second stage a finite element model (FEM) was developed with an appropriate level of refinement to provide a corresponding set of modal properties. A series of manual adjustments to modal parameters such as cable tension and bearing stiffness resulted in a FEM that produced excellent correspondence for vertical and torsional modes, along with correspondence for the lower frequency lateral modes. In the third stage traffic, wind and temperature data along with deformation measurements from a sparse structural health monitoring system installed in 2011 were compared with equivalent predictions from the partially validated FEM. The match of static response between FEM and SHM data proved good enough for the FEM to be used to predict the un-measurable global deformed shape of the bridge due to vehicle and temperature effects but the FEM had limited capability to reproduce static effects of wind. In addition the FEM was used to show internal forces due to a heavy vehicle to to estimate the worst-case bearing movements under extreme combinations of wind, traffic and temperature loads. The paper shows that in this case, but with limitations, such a two-stage FEM calibration/validation process can be an effective tool for performance prognosis.

Statistical calibration of safety factors for flexural stiffness of composite columns

  • Aslani, Farhad;Lloyd, Ryan;Uy, Brian;Kang, Won-Hee;Hicks, Stephen
    • Steel and Composite Structures
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    • 제20권1호
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    • pp.127-145
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    • 2016
  • Composite column design is strongly influenced by the computation of the critical buckling load, which is very sensitive to the effective flexural stiffness (EI) of the column. Because of this, the behaviour of a composite column under lateral loading and its response to deflection is largely determined by the EI of the member. Thus, prediction models used for composite member design should accurately mirror this behaviour. However, EI varies due to several design parameters, and the implementation of high-strength materials, which are not considered by the current composite design codes of practice. The reliability of the design methods from six codes of practice (i.e., AS 5100, AS/NZS 2327, Eurocode 4, AISC 2010, ACI 318, and AIJ) for composite columns is studied in this paper. Also, the reliability of these codes of practice against a serviceability limit state criterion are estimated based on the combined use of the test-based statistical procedure proposed by Johnson and Huang (1997) and Monte Carlo simulations. The composite columns database includes 100 tests of circular concrete-filled tubes, rectangular concrete-filled tubes, and concrete-encased steel composite columns. A summary of the reliability analysis procedure and the evaluated reliability indices are provided. The reasons for the reliability analysis results are discussed to provide useful insight and supporting information for a possible revision of available codes of practice.

Computational analysis and design formula development for the design of curved plates for ships and offshore structures

  • Kim, Joo-Hyun;Park, Joo-Shin;Lee, Kyung-Hun;Kim, Jeong-Hyeon;Kim, Myung-Hyun;Lee, Jae-Myung
    • Structural Engineering and Mechanics
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    • 제49권6호
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    • pp.705-726
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    • 2014
  • In general, cylindrically curved plates are used in ships and offshore structures such as wind towers, spa structures, fore and aft side shell plating, and bilge circle parts in merchant vessels. In a number of studies, it has been shown that curvature increases the buckling strength of a plate under compressive loading, and the ultimate load-carrying capacity is also expected to increase. In the present paper, a series of elastic and elastoplastic large deflection analyses were performed using the commercial finite element analysis program (MSC.NASTRAN/PATRAN) in order to clarify and examine the fundamental buckling and collapse behaviors of curved plates subjected to combined axial compression and lateral pressure. On the basis of the numerical results, the effects of curvature, the magnitude of the initial deflection, the slenderness ratio, and the aspect ratio on the characteristics of the buckling and collapse behavior of the curved plates are discussed. On the basis of the calculated results, the design formula was developed to predict the buckling and ultimate strengths of curved plates subjected to combined loads in an analytical manner. The buckling strength behaviors were simulated by performing elastic large deflection analyses. The newly developed formulations were applied in order to perform verification analyses for the curved plates by comparing the numerical results, and then, the usefulness of the proposed method was demonstrated.

The influence of anthropogenic disturbances and watershed morphological characteristics on Hg dynamics in Northern Quebec large boreal lakes

  • Moingt, M.;Lucotte, M.;Paquet, S.;Beaulne, J.S.
    • Advances in environmental research
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    • 제2권2호
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    • pp.81-98
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    • 2013
  • Mercury (Hg) dynamics in the boreal environment have been a subject of concern in recent decades, due to the exposure of local populations to the contaminant. Land use, because of its impact on mercury inputs, has been highlighted as a key player in the sources and eventual concentrations of the heavy metal. In order to evaluate the impact of watershed disturbances on Hg dynamics in frequently fished, large boreal lakes, we studied sediment cores retrieved at the focal point of eight large lakes of Qu$\acute{e}$bec (Canada), six with watersheds affected by land uses such as logging and/or mining, and two with pristine watersheds, considered as reference lakes. Using a Geographical Information System (GIS), we correlated the recent evolution of land uses (e.g., logging and mining activities) and morphological characteristics of the watershed (e.g., mean slope of the drainage area, vegetation cover) to total Hg concentrations (THg) in sedimentary records. In each core, THg gradually increased over recent years with maximum values between 70 and 370 ng/g, the lowest mercury concentrations corresponding to the pristine lake cores. The Hg Anthropogenic Sedimentary Enrichment Factor (ASEF) values range from 2 to 15. Surprisingly, we noticed that the presence of intense land uses in the watershed does not necessarily correspond to noticeable increases of THg in lake sediments, beyond the normal increment that can be attributed to Hg atmospheric deposition since the beginning of the industrial era. Rather, the terrestrial Hg inputs of boreal lakes appear to be influenced by watershed characteristics such as mean slopes and vegetation cover.