• Title/Summary/Keyword: Heavy metals (Pb, Cd, As)

Search Result 914, Processing Time 0.033 seconds

Available Components of Chajogi (Perilla sikokiana B.) at Different Harvest Periods (차조기(紫蘇葉) 채취시기별 유효성분 함량의 변화)

  • Ahn, Hong
    • Food Science and Preservation
    • /
    • v.13 no.6
    • /
    • pp.703-707
    • /
    • 2006
  • The propose of this study was to investigate the changes of available components in Chajogi (Perilla sikokiana B.) by different harvest periods. The Chajogi samples were divided into four groups by harvest period. The four groups were divided into I (harvesting sample at 14, July, 2005), II (harvesting sample at 25, July, 2005), III (harvesting sample at 15, Aug, 2005) and IV sample (harvesting sample at 2, Sept, 2005), and then analysed with regard to the content of proximate compositions, minerals, amino acids, perillaldehyde and anthocyanin. The contents of reducing sugar increased with increasing harvesting periods, while those of crude protein, crude lipid and total amino acids decreased for IV sample as compared to the other samples. The levels of heavy metals in all samples were not detected. The Zn, Fe and Mg contents of IV sample decreased sharply. The perilladehyde contents were 0.36%, 0.42% 0.45%, and 0.35% for I, II, III, and IV products, respectively. III sample as contented to the other samples was shown to have the highest anthocyanine content (1.21% in dry basis). In conclusion, the date of harvesting Chajogi affects the contents of available components.

Changes in Physical Properties and Its Metal Removal Efficiency for The Yellow Soils by Calcination Process (소성처리에 의한 황토의 물성특성 변화 및 용존 중금속 제거능력)

  • Lee, Jin-Won;Kim, Seokhwi;Hwang, Gab-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.18 no.4
    • /
    • pp.584-591
    • /
    • 2017
  • Metal removal from water has not been explained clearly by either adsorption onto the surface of absorbents or precipitation as metal hydroxides because those occur simultaneously to a certain extent. For a better understanding of the metal removal mechanisms, batch experiments were performed using soil calcined at $850^{\circ}C$ under various pH conditions for Cu, Pb, Zn, Cd, and Cr. The results showed that the metal removal efficiency with the exception of Cr decreased abruptly, even within 5 min, showing more than 90% removal. The pH of each reactant increased gradually from around 7 to 9 with time. The increases in metal removal at higher pH appear to be associated with metal hydroxides precipitation. Comparative experiments, which were carried out changing the pH by reacting with commercial activated carbon (CAC), natural yellow soil (NYS), and calcined yellow soil (CYS), showed that the pH of the CYS only increased with time. Calcination processes might lead to a change in the physical properties of the soil matrix resulting in a high pH when reacted with water. Apart from adsorption onto the surface of the absorbents, these results show that the adsorption and/or precipitation of hydroxides onto the surface of adsorbents also play important roles in regulating the dissolved metals under alkaline conditions.

Characteristics of Wash-off Metal Pollutants from Highway Toll-Gate Area (고속도로 영업소지역의 강우유출수내 중금속 유출 특성)

  • Lee, Soyoung;Lee, Eunju;Kim, Chulmin;Son, Hyungun;Maniquiz, Marla C.;Son, Youngkyu;Kang, Heeman;Kim, Jeehyeong;Kim, Lee-Hyung
    • Journal of Korean Society on Water Environment
    • /
    • v.23 no.6
    • /
    • pp.945-950
    • /
    • 2007
  • The stormwater runoff from paved area are highly polluted because of particulate materials as well as metals from various vehicular activities. The Division of Road Maintenance in Ministry of Construction and Transportation was recently developed the Guidelines of Environment-kindly Road Maintenance. It is actually requiring the BMP construction to control the nonpoint source pollution as based on the TMDL program. This research is carried out in order to define the characteristics of stormwater runoff from the toll-gate of highways since 2006, which is actually one of the main pollutant sources of paved areas. This monitoring is the first phase work for establishing the treatment facilities in the toll-gates. The one of the main characteristics from toll-gate runoff is the first flush phenomenon containing lots of sediments and metal compounds at the beginning of a storm event. Usually it is used to determine the size of treatment facilities and to calculate the reduced pollutant mass in the facility. The research results shows that the mean EMC vaules for heavy metals are determined to $274.3{\mu}g/L$ for Cd, $1,273.4{\mu}g/L$ for Cr, $1,822.0{\mu}g/L$ for Cu, $6,504.9{\mu}g/L$ for Fe, $14,930.3{\mu}g/L$ for Pb, and $714.1{\mu}g/L$ for Zn. Also the metal mass loadings from the toll-gates are calculated using EMC, watershed area and storm duration.

Distribution and remediation design of heavy metal contamination in farm-land soils and river deposits in the vicinity of the Goro abandoned mine (고로폐광산 주변 농경지 토양 및 하천 퇴적토의 중금속 오염 분포 및 복원 대책 설계)

  • 이민희;최정찬;김진원
    • Economic and Environmental Geology
    • /
    • v.36 no.2
    • /
    • pp.89-101
    • /
    • 2003
  • River deposits and farmland soils were analyzed to investigate the pollution level of heavy metals in the vicinity of the Goro abandoned Zn-mine. Surface (0-40 cm) and subsurface (40-100 cm) soils were collected around a main river located at the lower part of the Goro mine, and analyzed by ICP-MS for Cd, Cu, Pb, Zn and Cr after 0. 1N HCI extraction and by AAS for As after IN HCI extraction. Concentrations of cadmium and lead at the surface river deposits close to the mine were over the Soil Pollution Warning Limit (SPWL), and 43% of sample sites (6 of 14 samples) were over SPWL for As suggesting that river deposits were broadly contaminated by arsenic. Results from farmland soil analysis showed that surface soils were contaminated by heavy metals, while only arsenic was over SPWL at 50% of sampling sites. Main pollution mechanism around the Goro mine was the discharge of mine tailing and waste rocks from the storage site to the river and to adjacent farmland during flood season. Pollution Grades for sample locations were prescribed by the Law of Soil Environmental Preservation, suggesting that the pollution level of heavy metals around the Goro mine was serious, and the remediation operation fur arsenic and the isolation of mine tailing and waste rocks from river and farmland should be activated to protect further contamination. The area needed to clean up was estimated from pollution distribution data and the remediation methods such as a soil washing method and a soil improvement method were considered as the further remediation operation for arsenic contaminated soils and river deposits around the Goro abandoned mine.

Solidification and Stabilization of Metal(loid)s-contaminated Soils using Single Binders (단일 고형화제를 이용한 중금속류 오염 토양의 고형화/안정화)

  • Park, Hye Ok;Choi, Jiyeon;Oh, Sanghwa;Shin, Won Sik
    • Journal of Soil and Groundwater Environment
    • /
    • v.20 no.7
    • /
    • pp.135-147
    • /
    • 2015
  • Remediation of metal(loid)s-contaminated sites is crucial to protect human and ecosystem. Solidification and stabilization of metal(loid)s by the binder amendment is one of the cost-effective technologies. In this study, metal (loid)s in various field-contaminated soils obtained from steel-making, metal refinery and mining tillage were immobilized by the application of single binders such as diammonium phosphate (DAP), lime, and ladle slag. The efficiency of solidification and stabilization was evaluated by Toxicity Characteristic Leaching Procedure (TCLP) and the Standard, Measurements and Testing programme of European Union (SM&T) extraction processes. In terms of TCLP extraction, the binder was effective in order of lime > DAP > ladle slag. All binders were highly effective in the immobilization of Pb, Zn, Cu, Ni, and Cd. The increased immobilization efficiency is attributed to the increase in the Step III and IV fractions of the SM&T extraction. Lime and ladle slag were highly effective in the immobilization of the metal(loid)s, however, As release increased with DAP due to competition between the phosphate originated from DAP and arsenate. A further study is needed for the better immobilization of multi metal(loid)s using binary binders.

Removal of As, Cadmium and Lead in Sandy Soil with Sonification-Electrokinetic Remediation (초음파동전기기법을 이용한 비소, 카드뮴, 납으로 오염된 사질토 정화 연구)

  • Oh, SeungJin;Oh, Minah;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
    • /
    • v.18 no.7
    • /
    • pp.1-11
    • /
    • 2013
  • The actively soil pollution by the toxic heavy-metals like the arsenic, cadmium, lead due to the industrialization and economic activity. The uses the electrokinetic remediation of contaminated soil has many researches against the fine soil having a small size in the on going. However, it is the actual condition which the research result that is not effective due to the low surface charge of the particle and high permeability shows in the electrokinetic remediation in comparison with the fine soil in the case of the sandy soil in which the particle size is large. In this research, the electrokinetic remediation and ultrasonic wave fetch strategy is compound applied against the sandy soil polluted by the arsenic, cadmium, and lead removal efficiency of the sandy soil through the comparison with the existing electrokinetic remediation tries to be evaluated. First of all, desorption of contaminants in soil by ultrasonic extraction in the Pre-Test conducted to see desorption effective 5~15%. After that, By conducted Batch-Test results frequency output century 200 Khz, reaction time 30 min, contaminated soil used in experiment was 500 g. Removal efficiency of arsenic, cadmium, lead are 25.55%, 8.01%, 34.90%. But, As, Cd, Pb remediation efficiency less than 1% in EK1(control group).

Cultivation Environment in Relation to Good Agricultural Practices in the Major Cultivation Area of Disocorea batatas (우리나라 주요 산약 재배지 GAP와 관련된 재배환경 실태)

  • Cho, Jae-Young
    • Journal of Applied Biological Chemistry
    • /
    • v.54 no.4
    • /
    • pp.290-295
    • /
    • 2011
  • This study was carried out to investigate the quality of soil, irrigation water, and status of agrochemicals application in relation to good agriculture practices system in the major cultivation area of Disocorea batatas. The concentrations of heavy metals as Cd, Pb, Cu, and Zn in soils and irrigation waters were lower than those of standard level for Environmental Conservation Act of Soil and Water in Korea. The dominant weed have been appeared Digitaria sanguinalis and Portulaca oleraceamite. The dominant insect pests and plant pathogens have been appeared aphid and anthracnose. Average yearly application of pesticide was 2 to 4 times for herbicide and 4 to 6 times for plant pathogens and insect pests. In order to safety production of medicinal crops could be achieved by proper cultivation management such as minimum application of agro-chemicals, effective use of by-product fertilizer, and technology development of organic farming.

Availability Review of Tailings from the Sangdong Tungsten Mine as a Material for Construction (건설용 재료로서 상동광산광미의 활용성 검토)

  • Kim, Yong-Jic;Kim, Young-Jin;Choi, Yun-Wang;Kim, Sang-Chel
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.1 no.3
    • /
    • pp.204-210
    • /
    • 2013
  • This study has focused on the possibility for recycling tailings from the Sangdong tungsten mine (TA) as admixture for concrete. TA has been accumulating for several decades in Sangdong, a region in Korea, and there is a growing demand for alternative uses for this hazardous substance. In particular, the use must be in accordance with the hazardous materials stipulations under the Korean waste control act. This study showed that TA presented pH of 8.0-9.3, 18.7-22.0% of water content, 2.7% of maximum ignition loss. The chemical composition of TA showed minute differences from each depth of sampling that represented approximately 50% of $SiO_2$ and 13% of both $Al_2O_3$ and $Fe_2O_3$. The chemical composition of Cd, Cu, Zn and Pb from mortar incorporating TA showed lower levels of hazardous materials which met the specifications of the waste control act in Korea. The TA mortar also appeared very effective for stabilizing/solidifying heavy metals particularly when used in conjunction with SG.

Quality characteristics and antioxidant activity of fruit dressing using lentil (Lens culinaris Med. cv, Silvina) legume

  • Son, Jin Hwan;Kim, Il Doo;Kim, Hye Ryun;Jeong, Rae Kyo;Kim, Bo Ra;Park, Yong Sung;Do, Hyeon Min;Mun, Ji Hye
    • Proceedings of the Korean Society of Crop Science Conference
    • /
    • 2017.06a
    • /
    • pp.275-275
    • /
    • 2017
  • Dressing is a seasoned mixture usually used as a stuffing in food. Quality characteristics and antioxidant activity of fruit dressing using lentil legume were investigated. The four groups were divided into D-1(fruit dressing purchased from the local market in Deagu, Korea), D-2 (grapefruit-sugaring dressing prepared with grapefruit sugaring and lentil legume paste), D-3 (vinegar dressing purchased from the local market in Deagu, Korea), D-4 (pineapple-vinegar dressing prepared with pineapple vinegar and lentil legume paste), and then they were analyzed with regard to general compositions, Hunter's color value, mineral and free amino acid content and antioxidant activities. The pH and titratable acidity in all samples ranged from 2.9 to 4.6 and from 0.6 to 1.2%, respectively. The crude protein content were 2.29% for D-2 dressing and 4.03 for D-4 sample, while were not detected D-1 and D-3 samples. In case of Hunter's value, The ' L'and 'a' values of all samples ranged from 45.98 to 56.54 and from -1.59 to 3.30, respectively. The D-4 sample exhibited the higher levels of Ca (215.40 mg/kg), K (1,105.83 mg/kg), Mg (233.63 mg/kg) and Fe (13.78 mg/kg). The levels of heavy metals (As, Pb, Cd and Hg) in all samples were not detected. The contents of total amino acid in D-3 and D-4 samples were 8.269 and 3.419 mg/mL, respectively. The highest contents of total phenols($191.13{\mu}g\;GAE/mL$) and DPPH radical scavenging activity(93.69%, Inhibition) were observed in D-4 sample.

  • PDF

Study on the Hygenic Water Quality in Imha Dam (임하댐의 위생학적 수질조사 연구)

  • 이희무
    • Journal of environmental and Sanitary engineering
    • /
    • v.10 no.1
    • /
    • pp.25-34
    • /
    • 1995
  • A Study on environmental Investigation in Imha Dam for the finding the degree of water quality and heavy metals was carried out at 4 sampling station during the period from August 15, 1993 to May 7, 1994. The results were as follows. 1. The ranges of values of pH for water were st. 1-7.56, st.2-7.77, st.3-7.9, st.4-7,7 on the average. Total average of pH values were 7.56-7.9 2. The ranges of values of DO for water were st.1-8.71($mg/{\ell}$), st.2-8.64($mg/{\ell}$), st.3-10. 25($mg/{\ell}$), st.4-9.01($mg/{\ell}$) on the average. Total average of DO of values were 8.64-10.25($mg/{\ell}$). 3. The ranges of values of BOD for water were st.1-1.1($mg/{\ell}$), st.2-1.0($mg/{\ell}$), st.3-0 86($mg/{\ell}$), st.4-0.99($mg/{\ell}$) on the average. Total average of BOD of values were 0.86-1.1($mg/{\ell}$). 4. The ranges of values of COD for water were st.1-1.12($mg/{\ell}$), st.2-1.4($mg/{\ell}$), st.3-0 98($mg/{\ell}$), st.4-1.46($mg/{\ell}$) on the average. Total average of COD of values were 0.98-1.46($mg/{\ell}$). 5, The ranges of values of T- N for water were st.1-0.36($mg/{\ell}$), st.2-0.49($mg/{\ell}$), st.3-0 23($mg/{\ell}$), st.4-0.83($mg/{\ell}$) on the average. Total average of T-N of values were 0.23-0.83($mg/{\ell}$). 6. The ranges of values of T-P for water were st.1-0.053($mg/{\ell}$), st.2-0.06($mg/{\ell}$), st.3-0.02($mg/{\ell}$), st.4-0.07($mg/{\ell}$) on the average. Total average of T-P of values were 0.02-0.07($mg/{\ell}$). 7. In the E. soli group distribution were counted st.1-1130, st.2-1113, st.3-152.3, st.4-1253 by the MPN test. Total distribution of E. soil group were 152.3-1253. 8. The concentration of heavy metals of Cu, Mn, Pb, Zn were measured st.1-0.59, 0.18, 0 04, 74.6( ${\mu}g/{\ell}$), st.2-0.39,0.29,0.03, 54.3(${\mu}g/{\ell}$), st.3-0.1,0.3, ND, 8(${\mu}g/{\ell}$), st.4-0.96, 0 26,0.23,45.6(${\mu}g/{\ell}$) on the average. Cd, Hg, Cr were not detected in the sampling site.

  • PDF