• Proceedings of the KIEE Conference
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• 1994.11a
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• pp.212-214
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• 1994

At recent time, superconducting technology makes it possible to develop various devices using strong magnetic fields. As increasing with devices using high magnetic fields, magnetic shielding technology is essential in order to get high efficiency. Therefore it is necessary to establish production method and clear characteristics of suitable shielding materials. Usually, ferromagnetic metal has been used for shielding of high magnetic fields up to the present time. Instead of heavy ferromagnetic metal, we can acquire better upgraded shielding system by using of very light superconducting thin film that has a perfect diamagnetism. We would like to study basic characteristics of NbTi thin film produced by RF sputtering, investigated morphology and crystal structure of NbTi thin film by SEM and XRD, identified superconductivity measuring by critical current.

• Journal of the Korean GEO-environmental Society
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• v.19 no.3
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• pp.15-24
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• 2018

As electromagnetic waves are affected by electrical conductivity or permittivity, they are widely used to evaluate geotechnical characteristics. In this study, a probe for measuring electromagnetic waves using a time domain reflectometry is manufactured to evaluate heavy metal concentration in saline water. In the experiments, a copper is used as a heavy metal, and a probe is demonstrated with the concentration of copper. Solutions were set for 8 different copper concentration (0, 0.01, 0.05, 0.1, 0.5, 1, 5, 10 mg/L) in saline water with 3% salinity. The probe is coated by electrical insulating materials such as epoxy, top-coat, varnish, acrylic paint, heat-shrinkage tube to measure electromagnetic waves in saline water. The measured signals are compared according to coating material. As results, for probes coated with acrylic paint and heat-shrinkage tube, signal variation is not detected. For epoxy, top-coat, and varnish coated probes, the voltage decreases with an increase of copper concentration. Probes coated by epoxy at once and top coat can estimate under 5 mg/L of copper concentration and the probe coated by epoxy twice can estimate over 5 mg/L of copper concentration. This study shows that the probe using the time domain reflectometry can be used to evaluate the concentration of heavy metal in saline water by coating the probe with insulating material.

• Journal of Environmental Health Sciences
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• v.47 no.6
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• pp.530-539
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• 2021

Background: In South Korea, areas around abandoned metal mines are designated as regions with high arsenic (As) contamination. However, studies assessing urinary As exposure, As metabolism, and relevant genetic polymorphisms in residents of these metal mine areas are lacking. Objectives: To identify factors associated with As exposure and evaluate the effects of MTHFR, As3MT, and GSTO1 genetic polymorphisms on As metabolism in residents of abandoned metal mine areas by measuring urinary As species. Methods: Urinary As species (arsenite [As³⁺], arsenate [As⁵⁺], monomethyl arsonic acid, and dimethylarsinic acid) were isolated using high-performance liquid chromatography in combination with inductively coupled plasma mass spectrometry (HPLC-ICP-MS). Four genetic polymorphisms (MTHFR A222V, MTHFR E429A, GSTO1 A140D, As3MT M287T) were analyzed in 144 residents of four areas around abandoned metal mines. Results: The study sample was comprised of 34.7% men and 65.3% women, with a mean age of 70.7±10.9 years. The urinary inorganic As concentration was higher among those consuming more than half locally produced rice (0.31 ㎍/L) than those consuming less than half such rice (0.18 ㎍/L). The urinary dimethylarsinic acid concentration was higher in the group that had consumed seafood in the past day (31.68 ㎍/L) than in those who had not (22.37 ㎍/L). Furthermore, individuals heterozygous in the MTHFR A222V and GSTO1 A140D polymorphism had higher urinary arsenic species concentrations than did individuals with a wild type or homozygous for the variant allele. Conclusions: Consumption of locally produced rice was associated with inorganic As exposure, whereas seafood consumption was associated with organic As exposure among residents of abandoned metal mine areas. There was no clear association between MTHFR A222V and GSTO1 A140D polymorphisms and As metabolism.

• Journal of Environmental Science International
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• v.26 no.8
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• pp.955-966
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• 2017

Amendment of multi-binders was employed for the immobilization of metal(loid)s in field-contaminated soils to reduce the leaching potential. The effect of different types of multi-binders (lime/diammonium phosphate, diammonium phosphate/ladle slag and lime/ladle slag) on the solidification/stabilization of metal(loid)s (Pb, Zn, Cu and As) from the smelter soil and mine tailing soil were investigated. The amended soils were evaluated by measuring Toxicity Characterization Leaching Procedure (TCLP) leaching concentration of metal(loid)s. The results show that the leaching concentration of metal(loid)s decreased with the immobilization using multi-binders. In terms of TCLP extraction, the mixed binder was effective in the order of lime/ladle slag > diammonium phosphate/ladle slag > lime/diammonium phosphate. When the mixed binder amendment (0.15 g lime+0.15 g ladle slag for 1g smelter soil and 0.05 g lime+0.1 g ladle slag for 1 g mine tailing soil, respectively) was used, the leaching concentration of metal(loid)s decreased by 90%. However, As leaching concentration increased with diammonium phosphate/lime and diammonium phosphate/ladle slag amendment competitive anion exchange between arsenic ion and phosphate ion from diammonium phosphate. The Standard, Measurements and Testing programme (SM&T) analysis indicated that fraction 1 (F1, exchangeable fraction) decreased, while fraction 4 (F4, residual fraction) increased. The increased immobilization efficiency was attributed to the increase in the F4 of the SM&T extraction. From this work, it was possible to suggest that both arsenic and heavy metals can be simultaneously immobilized by the amendment of multi-binder such as lime/ladle slag.

• Journal of Soil and Groundwater Environment
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• v.18 no.1
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• pp.102-111
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• 2013

A novel MgO-based binder was developed and applied to treat the anoxic sediment that was collected from Seonakdong river, Korea and was contaminated with heavy metals. The treated sediment was evaluated by measuring compressive strength, expansion, leaching of heavy metals and storage characteristics for $CO_2$. Initially, an optimal blending ratio of lime (L)/fly ash (FA)/blast furnace slag (BFS) that was to be mixed with MgO was screened to be $L_{0.3}-FA_{0.1}-BFS_{0.6}$. Long-term strengths of the sediments that were treated by various mixtures of MgO and $L_{0.3}-FA_{0.1}-BFS_{0.6}$ were then evaluated and the blending ratios between 4 : 6 and 6 : 4 were found optimal, which yielded a compressive strength of 4.09 MPa. On this basis, the optimal MgO-based binder was selected to be a 5 : 5 mixture of MgO and $L_{0.3}-FA_{0.1}-BFS_{0.6}$. The good performance of the MgO-based binder was believed to be due to the formation of Mg $(OH)_2$, which filled the micropores and also increased the density of the solidified matrices. The MgO-based binder exhibited an average stabilizing capacities for heavy metals of 92.9%, which was similar to or higher than that of Portland cement. It was found that 69.1 kg of carbon dioxide could be sequestrated after 365 days of curing when treating a ton of anoxic sediments.

• Analytical Science and Technology
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• v.6 no.5
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• pp.435-442
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• 1993

Carboxymethylated polyamine-polyurea resin loaded with rubeanic acid (RCCPPI resin) was obtained by 1 step chemical reaction between chlorocarboxymethylated polyamine-polyurea(CCPPI) resin as matrix polymer and rebeanic acid. This resin was confirmed with infrared spectrometry, elemental analysis, and thermal analysis(DSC). The adsorption characteristics of the heavy metal's on the resin were studied by measuring distribution coefficient($K_d$) with changing pH of the solutions and frontal chromatography. The enrichment, recovery, and analysis of trace heavy metals, such as cadmium, cerium, copper, nikel, lead, and zinc, in the presence of high concentrations of sodium, calcium, and acetate salts was possible quantitatively by a column packed with the resin at each optimum pH. Preconcentration factors were more than 25. To elute the adsorbed heavy metals on the resin, 0.025M EDTA solution(pH 9.0) was used.

• Journal of environmental and Sanitary engineering
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• v.24 no.2
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• pp.31-39
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• 2009

In this research, I carried out the adsorption and removal test of Pb, Ni, Co and Cu ions using organic substances spread out any where in the nature which can be obtained easily from our neighbor-such as Paulownia coreana, Pinus densiflora, Juniperus chinesis, Quercus dentata, Magnolia kobus, Platanus occidentalis, Gingko biloba, Diospyros kaki leaves. As the result of the research to find the best optional condition for the adsorption and removal, shows that the adsorption and removal ratio of Pb ion by a Paulownia coreana raw leaves is 99% at $70^{\circ}C$, those of Ni ion and Co ion by Magnolia kobus formalin treatment leaves are 79% at $70^{\circ}C$, 97% at $40^{\circ}C$ respectively. And that of Cu ion by Platanus occidentalis treatment leaves is 97% at $50^{\circ}C$ in mixed solution. As the result of comparing the removal ratio by raw leaves and formalin treatment leaves, the removal ratio of treatment is 30~90% more effective than raw leaves in most cases. And I concluded Pb > Cu > Co > Ni ion in multiple solution and Co > Ni > Cu >Pb ion in single solution after testing adsorption and removal ratio of mixed solution separately as time goes by. In general, the reactions were completed within first 5 minutes. The test result of measuring the hydrolysable tannin content of each leaf shows that an overcup Quercus dentata is 11.36%, a Diospyros kaki is 10.81% and the rest of them are 2.49~4.12% in raw leaves cases. In treatment leaves cases, an overcup Quercus dentata is 3.23% and the others are less than 1%.

• Journal of the Korean Society of Clothing and Textiles
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• v.37 no.4
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• pp.590-597
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• 2013

This study examined the change in the dyeability of natural dyes on cotton fabrics by a PEI (polyethyleneimine) pretreatment instead of mordants. Cotton fabrics were treated with PEI and the changes in the dyeability were shown by measuring the amount of PEI on cotton fabrics. Samples treated with PEI were dyed with two natural polychromatic dyes with a different affinity to cotton fibers: Alizarin Red S and Curcumin. The changes in dyeability by three variables (time, temperature and concentration of dyes) on cotton fabrics were analyzed by the K/S value to define optimum dyeing conditions. Subsequently, the PEI treatment improved the dyeability of cotton fabrics with both dyes of low and high affinity to cotton fibers. Thus, PEI could be a suitable heavy metal mordant replacement.

• Journal of the Korean GEO-environmental Society
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• v.18 no.10
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• pp.23-34
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• 2017

As the electrical property of fully saturated soils is dependent on the pore water, it has been commonly used for the detection of the contamination into the ground. The objective of this study is to investigate the electrical characteristics according to the salinity and the lead concentration in fully saturated soils. Fresh water and saline water with the salinity of 1%, 2% and 3%, which are mixed with 6 different lead solutions with the range of 0~10 mg/L, are prepared in the cylindrical cell incorporated with sensors for measuring electrical resistance and time domain reflectometry signal. Then, the dried sands are water-pluviated into the cell. The electrical resistance and the time domain reflectometry signal are used to estimate the electrical conductivity. Test results show that electrical conductivity determined from electrical resistance at the frequency of 1 kHz continuously increases with an increase in the lead concentration, thus it may be used for the estimation of the contaminant level. In addition, the electrical conductivity estimated by the time domain reflectometry changes even at very low concentration of lead, the variation rate decreases as the lead concentration increases. Thus, the time domain reflectometry can be used for the investigation of the heavy metal leakage. This study demonstrates that complementary characteristics of electrical resistance and time domain reflectometry may be used for the detection of the leakage and contamination of heavy metal in coastal and marine environments.

• Journal of Welding and Joining
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• v.28 no.5
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• pp.51-57
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• 2010

Brittle microstructure created in a heat affected zone (HAZ) during the welding of low alloy steel can be eliminated by post-weld heat treatment (PWHT). If the PWHT is not possible during a repair welding, the controlled bead depositions of multi-pass welding should be applied to obtain tempering effect on the HAZ without PWHT. In order to anticipate and control the tempering effect during the temper bead welding, the definition of temperature curve obtained from the analytical solution was suggested in this research. Because the analytical solution for heat flow is expressed as a mathematical equation of weld parameters, it may be effective in anticipating the effect of each weld parameter on the tempering in HAZ during the successive bead depositions. The reheating effect by the successive bead layer on the brittle coarse grained HAZ formed by earlier bead deposition was estimated by comparing the overlapped distance between the temperature curves in the HAZ. Three layered weld specimens of SA508 base metal with A52 filler were prepared by controlling heat input ratio between layers. The tempering effect anticipated by using the overlapped distance between the temperature curves was verified by measuring the micro-hardness distribution in the HAZ of prepared specimens. The temperature curve obtained from analytical solution was expected as a good tool to find optimal temper bead welding conditions.