• Mass Spectrometry Letters
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• v.2 no.2
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• pp.41-44
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• 2011

Molecular compositions of two types of heavy oil were studied using positive atmospheric pressure photoionization (APPI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Vacuum gas oil (VGO) was generated from vacuum distillation of atmospheric residual oil (AR), and slurry oil (SLO) was generated from catalytic cracking of AR. These heavy oils have similar boiling point ranges in the range of 210-$650^{\circ}C$, but they showed different mass ranges and double-bond equivalent (DBE) distributions. Using DBE and carbon number distributions, aromatic ring distributions, and the extent of alkyl side chains were estimated. In addition to the main aromatic hydrocarbon compounds, those containing sulfur, nitrogen, and oxygen heteroatoms were identified using simple sample preparation and ultra-high mass resolution FT-ICR MS analysis. VGO is primarily composed of mono- and di-aromatic hydrocarbons as well as sulfur-containing hydrocarbons, whereas SLO contained mainly polyaromatic hydrocarbons and sulfur-containing hydrocarbons. Both heavy oils contain polyaromatic nitrogen components. SLO inludes shorter aromatic alkyl side chains than VGO. This study demonstrates that APPI FT-ICR MS is useful for molecular composition characterization of petroleum heavy oils obtained from different refining processes.

• Journal of Energy Engineering
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• v.17 no.2
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• pp.107-115
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• 2008

The numerical analysis of energy and material balance, and plant performance has been carried out when applying the heavy residual oil instead of heavy oil to the existing heavy oil power station. The performance analysis model has been constructed for A heavy oil power station in Korea, and the modeling results were compared with the design data in order to ensure the validity of the model, and further compared with the plant operation data. With the heavy residual oil, the simulation gave 315 MW in power output, which is higher than that of the heavy oil combustion, but the plant efficiency turned out to be lower. The sensitivity analysis of heat rate for the changes in cooling water and ambient temperature, flue gas recirculation and power output has provided valuable information for the optimal operation of the power station.

• Journal of the Korean Society of Combustion
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• v.14 no.4
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• pp.25-32
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• 2009

In commercial combustion systems, heavy oil is one of main hydrocarbon fuel because of its economical efficiency. Regarding heavy oil combustion, due to increasing concerns over environmental pollutants such as carbon monoxide, unburned hydrocarbon and nitrogen oxides, development of low pollutant emission methods has become an imminent issue for practical application to numerous combustion devices. Also a great amount of effort has been tried to developed effective methods for practical using of biomass. It is also an important issue to reduce carbon tax. In this paper, an experimental study has been conducted to evaluate the effect of biomass reburning on NOx formation in a heavy oil flamed combustion furnace. Experiments were performed in flames stabilized by a multi-staged burner, which was mounted at the front of the furnace. Experimental tests were conducted using air-carried rice husk powder and LNG as the reburn fuel and heavy oil as the main fuel. The paper reports data on flue gas emissions and temperature distribution in the furnace for several kinds of experimental conditions. NOx concentration in the exhaust has decreased considerably due to effect of reburning. The maximum NOx reduction rate was 62% when the rice husk was used by reburn fuel, however it was 59% when the LNG was used by reburn fuel. The result shows the positive possibility of biomass reburning system for optimal NOx reduction.

• Economic and Environmental Geology
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• v.44 no.1
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• pp.83-94
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• 2011

Extra heavy oil reservoirs are distributed over the world but most of them is deposited in the northern part of the Orinoco River in Venezuela, in the area of 5,500 $km^2$, This region, which has been commonly called "the Orinoco Oil Belt", contains estimated 1.3 trillion barrels of original oil-in-place and 250 billion barrels of established reserves. The Venezuela extra heavy oil has an API gravity of less than 10 degree and in situ viscosity of 5,000 cP at reservoir condition. Although the presence of extra heavy oil in the Orinoco Oil Belt has been initially reported in the 1930's, the commercial development using in situ cold production started in the 1990's. The Orinoco heavy oil deposits are clustered into 4 development areas, Boyaco, Junin, Ayachoco, and Carabobo respectively, and they are subdivided into totally 31 production blocks. Nowadays, PDVSA (Petr$\'{o}$leos de Venzuela, S.A.) makes a development of each production block with the international oil companies from more than 20 countries forming a international joint-venture company. The Eastern Venezuela Basin, the Orinoco Oil Belt is included in, is one of the major oil-bearing sedimentary basins in Venezuela and is first formed as a passive margin basin by the Jurassic tectonic plate motion. The major source rock of heavy oil is the late Cretaceous calcareous shale in the central Eastern Venezuela Basin. Hydrocarbon materials migrated an average of 150 km up dip to the southern margin of the basin. During the migration, lighter fractions in the hydrocarbon were removed by biodegradation and the oil changed into heavy and/or extra heavy oil. Miocene Oficina Formation, the main extra heavy oil reservoir, is the unconsolidated sand and shale alternation formed in fluvial-estuarine environment and also has irregularly a large number of the Cenozoic faults induced by basin subsidence and tectonics. Because Oficina Formation has not only complex lithology distribution but also irregular geology structure, geological evolution and characteristics of the reservoirs have to be determined for economical production well design and effective oil recovery. This study introduces geological formation and evolution of the Venezuela extra heavy oil reservoirs and suggest their significant geological characteristics which are (1) thickness and geometry of reservoir pay sands, (2) continuity and thickness of mud beds, (3) geometry of faults, (4) depth and geothermal character of reservoir, (5) in-situ stress field of reservoir, and (6) chemical composition of extra heavy oil. Newly developed exploration techniques, such as 3-D seismic survey and LWD (logging while drilling), can be expected as powerful methods to recognize the geological reservoir characteristics in the Orinoco Oil Belt.

• Applied Chemistry for Engineering
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• v.24 no.1
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• pp.10-17
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• 2013

Heavy oil residue upgrading process was being used in conventional refinery process. Recently, as the importance of non conventional energy development is growing up, the commercial projects of heavy oil upgrading are getting more active than before. For having competitive business model in the resource competition, non conventional energy development should be considered as an important business strategy. In developing oil sands, extra heavy oil, and shale gas, canadian oil sands and extra heavy oil have great importance in substitution of conventional oil consumption. In oil sands development, the bitumen, which is extracted from oil sands, has great value after upgrading or refining process. Similar process is being used current conventional refinery process. The bitumen is highly viscous hydrocarbon. This bitumen includes impurities which can not be treated in conventional refinery process. As this reason, specified process is needed in bitumen or extra heavy oil upgrading process. Moreover, there will be additional specified facilities in the process of production, transportation and marketing. In oil sands, there are various kinds of commercial upgrading process. Extraction, dilution, coking and cracking method were being used commercially.

• Elastomers and Composites
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• v.20 no.2
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• pp.115-131
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• 1985

Heavy residual fuel oils is a mixture of reduced crude from crude unit, bottom products from vacuum and/or catalytic cracking unit with distillate to meet the specification and generally used as heavy fuel oil for large combustion engines, boilers, etc$\cdots$. But this study was made to investigate heavy residual fuel oils for using as industrial raw material and resulted the following possiblities as valuable raw material as well as heavy fuel oil. 1) Production of straight asphalt through vacuum distillation unit. 2) Using straight asphalt from vacuum distillation unit for manufacturing of blown asphalts, cut back asphalts, emulsified asphalts and asphalt compound, rubber/asphalt sheet, etc$\cdots$. 3) Using waxy oil side streams for manufacturing of raw oil to be lube oil base stocks through solvent dewaxing. 4) Production of lube base oils and rubber process oils from dewaxed raw oil through chemical treatments. 5) Manufacturing of paraffine wax from slack wax to be produced as by product of dewaxing process.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.18 no.2
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• pp.70-79
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• 2013

Since crude oil contains various pollutants including heavy metals, the environmental impact should be assessed for heavy metals as well as oil itself. In order to estimate the extent of heavy metal contamination, surface sediments were collected at the intertidal and coastal zone around the Herbei sprit oil spill area during December 2007 and January 2008. Organic carbon, sulfur and heavy metals were determined to assess heavy metal contamination in sediments. The crude oils contained C, S, V and Ni, but little toxic metals such as As, Cd, etc. From organic carbon content, the highest contaminated site was estimated that oils contributed to sediments up to 10%, and this site showed high V concentration. Potentially contaminated sediments by crude oil could be differentiated from unaffected sediments through V/Al and Ni/Al ratios, which can be used as indicators of oil contamination even after the oils were fully degraded.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.99-108
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• 2018

An oil-tolerant and salt-resistant aqueous foam system was screened out as a possible lubricant to enable cold heavy oil transportation. The microstructures and viscoelasticity and effects of heavy oil, salt and temperature on the foam stability were investigated and new rheological and drainage models were established. The results indicate the foam with multilayered shells belongs to a special microcellular foam. The viscoelasticity could be neglected due to its low relaxation time. The drainage process can be divided into three stages. The foam with quality of 67.9% maintains great stability at high oil and salt concentrations and appropriate elevated temperature.

• Journal of the Korean Applied Science and Technology
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• v.35 no.4
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• pp.985-994
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• 2018

Bio-heavy oil for power generation is a product made by mixing animal fat, vegetable oil and fatty acid methyl ester or its residues and is being used as steam heavy fuel(B-C) for power generation in Korea. However, if the fuel supply system of the fuel pump, the flow pump, the injector, etc., which is transferred to the boiler of the generator due to the composition of the raw material of the bio-heavy oi, causes abrasive wear, it can cause serious damage. Therefore, this study evaluates the fuel characteristics and lubricity properties of various raw materials of bio-heavy oil for power generation, and suggests fuel composition of biofuel for power generation to reduce frictional wear of generator. The average value of lubricity (HFRR abrasion) for bio-heavy oil feedstocks for power generation is $137{\mu}m$, and it varies from $60{\mu}m$ to $214{\mu}m$ depending on the raw materials. The order of lubricity is Oleo pitch> BD pitch> CNSL> Animal fat> RBDPO> PAO> Dark oil> Food waste oil. The average lubricity for the five bio-heavy oil samples is $151{\mu}m$ and the distribution is $101{\mu}m$ to $185{\mu}m$. The order of lubricity is Fuel 1> Fuel 3> Fuel 4> Fuel 2> Fuel 5. Bio-heavy oil samples (average $151{\mu}m$) show lower lubricity than heavy oil C ($128{\mu}m$). It is believed that bio-heavy oil for power generation is composed of fatty acid material, which is lower in paraffin and aromatics content than heavy oil(B-C) and has a low viscosity and high acid value, resulting in inhibition of the formation of lubricating film by acidic component. Therefore, in order to reduce friction and abrasion, it is expected to increase the lubrication of fuel when it contains more than 60% Oleo pitch and BD pitch as raw materials of bio-heavy oil for power generation.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.23 no.2
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• pp.72-79
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• 1987

In this paper, an investigation of the property of blended fuel oil, combustion characteristics and engine performance was made, in case blended fuel oil(light oil+heavy oil) was used in a home-made precombustion diesel engine for small-sized fishing boat. The results may be summarized as follows: 1. The specific gravity was linearly increased in accordance with the increase in heavy oil ratio in blended fuel oil, and the relationship between viscosity and temperature was coincided with the formula of Walther-ASTM, and the CCAI, the ignition quality index, was increased nearly as a straight line of the gradient 1.0. 2. The ignition delay was slightly increased below 810 of CCAI(blending ratio to be 60% of heavy oil), but remarkably increased above 810 of CCAI. Therefore, it was considered that the practicable value of CCAI, ignition quality of blended fuel oil, was more than 810. 3. The maximum combustion pressure was increased until blending ratio of heavy oil was raised up to 40%. On the contrary, it came to be decreased at that ratio, with smoke emissions remarkably increasing above 60%. Therefore, it was found in this experiment that the best practicable limit of heavy oil blending ratio was around 50% for saving fuel costs with least smoke emissions.