• Title/Summary/Keyword: Heavy Metal Species

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An Equilibrium Analysis to Determine the Speciation of Metals in the Incineration of Waste Containing Chlorine and Sulfur (염소와 황을 함유한 폐기물의 소각시 생성되는 유해 중금속류 결정에 대한 화학평형 계산)

  • Lee, Jung-Jin;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.1 no.1
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    • pp.31-39
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    • 1996
  • An equilibrium analysis was carried out to determine principal species in the incineration of hazardous waste, which was assumed as a compound of hydrocarbon fuel, chlorine, sulfur, and heavy metals, and their behaviors with variation of temperature, chlorine and sulfur concentrations. Calculated results showed that the most important parameter influencing the principal species was temperature. Chlorine concentration affected on mole fractions of the species, especially at high temperature. Existence of sulfur had a significant effect on the species at low temperature, regardless of surfur concentration. Generally, principal species at high temperature were chlorides and oxides, while the principal species at low temperature were sulfides. As temperature increased, mole fractions of the principal species increased at low temperature, however, mole fractions of some metal species decreased at high temperature.

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Toxic Effects of Serpentine Soils on Plant Growth

  • Kim, Jeong-Myeong;Shim, Jae-Kuk
    • Journal of Ecology and Environment
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    • v.31 no.4
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    • pp.327-331
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    • 2008
  • Serpentine soils are distributed in a small area in Korea, and generally exhibit high contents of Ni, Cr, Fe, Mn, Co and Mg. We investigated the growth of woody plants and herbs in the Andong serpentine area, Korea. Pinus densiflora and P. rigida growing on serpentine soils have high contents of Fe, Mg, Ni and Co, with contents approximately twice as high as those of non-serpentine plants. Tree species on serpentine soil also had lower ratios of tree height/DBH than trees in a control area. In greenhouse culture experiments on two bodenvag herb species, Setaria viridis and Cymbopogon tortilis, the biomass of the plants was significantly affected by soil type but not by seed origins. After 66 days, the growth of S. viridis and C. tortilis seedlings was significantly inhibited in serpentine soil, and the dry weight of each species showed significant negative correlations with soil heavy metal contents (Ni, Co and Cr). These results suggest that the growth of plants was inhibited by properties of the serpentine soil, and in particular, their high heavy metal concentration, which induced dwarfing in woody plants and reduction of total plant biomass in herbs.

Experimental Studies on the Cadium and Metallothioneien in Molluscs Collected from Mangyeong River, Korea (만경강 유역 연체동물 내 Cadmium 및 Cadmium-Methallothionein 함량의 실험적 조사)

  • 소진탁;유일수;김숙향;김재진
    • The Korean Journal of Malacology
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    • v.9 no.2
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    • pp.16-22
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    • 1993
  • Contamination of heavy metals in water and sediments along Mangyeong Gang(river) has reached up to critical level The object of the study is to elucidate somed molluscs which inhabit along the river on respect to the modulatory role in reducing the pollution. For the purpose, molluscs which are common in numbers and biomass in the area were collected, and Cadmim(Cd) was subjected as a reference metal in the experiment. The corresponding species were; Cipango;aludina chinensis (muddy snail) and Scapharca subcrenata (seashell). As methods, sample species were kept in laboratory under the natural condition as possible. Soil were brought from the site of the collection, dried autoclaved and wetted with ordinary water. It wad utilized as media to maintain the collected species in vitro all the way of the experiment. CdCI$^{2}$ was mixe in the medium according to experimental design. On the result obtained in the study, it is summarized that molluscs which inhabit along Mangyeong Gang(river)consume heavy mital-containing matters, so far Cd is concerned in the study. The amout of Cd concentration in tissues of the benthic natured invertebrates were dose and time related, and MT-Cd was also similar trend. Thus, Cd may eventually combine with low molecular protein forming metalloprotein, then reduce the toxicity of the heavy metal.

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Mathematical modeling to simulate the adsorption and internalization of copper in two freshwater algae species, Pseudokirchneriella subcapitata and Chlorella vulgaris

  • Kim, Yongeun;Lee, Minyoung;Hong, Jinsol;Cho, Kijong
    • Korean Journal of Environmental Biology
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    • v.39 no.3
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    • pp.298-310
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    • 2021
  • Prediction of the behavior of heavy metals over time is important to evaluate the heavy metal toxicity in algae species. Various modeling studies have been well established, but there is a need for an improved model for predicting the chronic effects of metals on algae species to combine the metal kinetics and biological response of algal cells. In this study, a kinetic dynamics model was developed to predict the copper behavior(5 ㎍ L-1, 10 ㎍ L-1, and 15 ㎍ L-1) for two freshwater algae (Pseudokirchneriella subcapitata and Chlorella vulgaris) in the chronic exposure experiments (8 d and 21 d). In the experimental observations, the rapid change in copper mass between the solutions, extracellular and intracellular sites occurred within initial exposure periods, and then it was slower although the algal density changed with time. Our model showed a good agreement with the measured copper mass in each part for all tested conditions with an elapsed time (R2 for P. subcapitata: 0.928, R2 for C. vulgaris: 0.943). This study provides a novel kinetic dynamics model that is compromised between practical simplicity and realistic complexity, and it can be used to investigate the chronic effects of heavy metals on the algal population.

Foliar Transfer of Dust and Heavy Metals on Roadside Plants in a Subtropical Environment

  • Gajbhiye, Triratnesh;Kim, Ki-Hyun;Pandey, Sudhir Kumar;Brown, Richard J.C.
    • Asian Journal of Atmospheric Environment
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    • v.10 no.3
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    • pp.137-145
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    • 2016
  • In this study, the contents of dust and associated heavy metals on roadside plants were investigated to assess their foliar transfer. The study was conducted at six different locations (four roadside and two industrial) near an industrial area in Bilaspur (Chhattisgarh), India. Six metals (Fe, Mn, Pb, Cu, Cr, and Cd) were examined in this study. The concentrations of heavy metals in foliar dust were found to be in the order of Fe>Mn>Pb>Cu>Cr>Cd. However, this relative order changed in the case of leaf concentrations to Fe>Mn>Cd>Cu>Pb>Cr. The metal concentrations in the dust and leaves can be attributed mainly to industrial and vehicular emissions. In contrast to other metals, Cd showed significant accumulation in the leaves compared to the respective dust samples. This study showed different patterns in the distributions of heavy metals between the dust deposited on the leaves and the metal accumulated in the leaves. These results suggest that the dust retention and heavy metal accumulation in native plant species should be explored in an attempt to manage these hazardous metallic elements.

Effects of Heavy Metals Pollution in Soil and Plant in the Industrial Area, West ALGERIA

  • Tahar, Kebir;Keltoum, Bouhadjera
    • Journal of the Korean Chemical Society
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    • v.55 no.6
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    • pp.1018-1023
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    • 2011
  • Alzinc is a ursine situated in the Ghazaouet town western part of the republic of Algeria. The purpose of this study was to determine the degree of contamination which soil and plants are burdened with some heavy metals: Pb, Zn, Ni, Cu, Cd, Mn, Cr, Fe and As, then the accumulation of heavy metals in the soil and plant adjacent of area the alzinc ursine was detected and the interdependence of pollution among all three regions of the environment determined. This paper analyzes the heavy metal contents within a 2-years period in the soil and plants at the beginning of the vegetation period. The presence of Pb, Zn, Ni, Cu, Cd, Mn, Cr, Fe and As, in the samples were analyzed using Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES). Measurements of heavy metal contents were performed at three locations in soil and vegetative parts of three-plant types (plant alimentary) period during summer. The plant samples from the immediate environment of the dumpsite were highly contaminated with Zn, Cd and Mn. Three plants species: grape, artichoke and pepper, particularly, grape met some of the conditions to be classified as accumulators for Zn, Cu, Cd and Fe, consequently, she revealed a health risk for human and livestock due to the spread of the metal pollution from waste dumpsites to agricultural areas.

Heavy Metal Concentrations of Some Game Species Captured in Kyeongsangnam-do, Korea (경남지역(慶南地域)에 서식(棲息)하는 수렵조수류(狩獵鳥獸類)의 중금속(重金屬) 축적(蓄積))

  • Choi, Jai Sik;Jung, Wee Hyun;Youn, Ki Sick;Lee, Doo Pyo
    • Journal of Korean Society of Forest Science
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    • v.83 no.1
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    • pp.6-11
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    • 1994
  • Three different types of tissue taken from three game birds such as Ring-necked Pheasant, Rufous Turtle Dove, Mallard and a mammal, Korean Water Deer were analyzed for five heavy metals such as iron, zinc, copper, lead and cadmium. The main purpose of this study was to make clear the background levels of the metal concentrations in the tissues of these game species. The metal levels were generally low and could be considered as the background levels. But some markedly high levels of lead were recorded in the muscles of birds shot by the shotgun. The implications of these results were discussed with respect to the health of people.

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A study on the distribution of organic compounds, nitrogen, phosphorus and heavy metal in Ballast Water (밸러스트수내 유기물, 영양염류 및 중금속 농도 분포에 관한 연구)

  • Cheong, Kwang-Hyun;Ahn, Jong-Gil
    • Proceedings of KOSOMES biannual meeting
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    • 2006.05a
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    • pp.71-77
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    • 2006
  • There is a growing concern about the damage to aquatic ecosystem caused by immigration of non-indigenous species. It is estimated that more than 10,000 million tons of ballast water is transported by shipping activities annually, and ballast water has been recognised as a major vector for the transplant of aquatic species across bio-geographical boundaries. The problem of harmful aquatic organism in ballast water for the control and management of ships' ballast water and sediments was adopted and diplomatic conference of IMO at February 2004. At once ballast water is transported by shipping activities for organic compounds, nitrogen, phosphorus and heavy metal etc. but, It's fixing a focus only for the transported of pathogenic bacteria and non-indigenous species. Hence, this studies on the distribution of organic compounds, nitrogen, phosphorus and heavy metal in ballast water during the shipping activity with the basic data which is necessary to the systemic manage of ballast water.

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Emission Characterization of Particulate Matters According to the Types of Wastes from Industrial Waste Incinerator (산업폐기물 소각시설에서 폐기물 유형에 따른 입자상물질의 배출특성)

  • Park, Jeong-Ho;Suh, Jeong-Min;Jo, Jeong-Gu;Ryu, Jae-Yong;Han, Seong-Jong
    • Journal of Environmental Science International
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    • v.16 no.11
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    • pp.1225-1230
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    • 2007
  • The emissions characteristics of particulate matters(PM) according to the types of wastes from industrial waste incinerator of 800 kg/hr treatment capacity were investigated. For this study, the incinerate waste are as follows; waste resin, waste wood, waste urethane, waste gunny, and waste paper. The particulate samples were collected to be emitted in stack and air pollution control(both cyclone and bag filter). In stack, the concentrations of PM were in the range of 2.61 to $26.51 mg/Sm^3$ and the major chemical species were C, Si, Cl, K, Na, Ca in all the wastes. In cyclone fly ash, the mean content of heavy metal were in the order of Fe > Zn > Pb > Cu > Mn > Cr > Ni > Cd > As > Hg and the heavy metal content of waste resin were Zn 34,197.5 mg/kg, Fe 27,587.6 mg/kg, Pb 6,055.8 mg/kg, respectively. In bag filter fly ash, the mean content of heavy metal were in the order of Zn > Pb > Fe > Cu > Mn > Cd > Cr > Ni > As > Hg and the heavy metal content of waste wood were Pb 36,405.2 mg/kg, Fe 15,762.9 mg/kg, Cu 9,989.5 mg/kg, Cd 2,230.1 mg/kg, respectively. Comparing the heavy metal content of both cyclone and bag filter, in cyclone, the Cr, Fe, Ni content were higher than in bag filter and the Cd, Cu, Hg content were lower than in bag filter.

Accumulation of Heavy Metals in the Antarctic Clam Laternula elliptica

  • Lee, Yong-Seok;Jeong, Kye-Heon
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2004.06a
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    • pp.87-91
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    • 2004
  • Immunohistochemical and ultrastructural experiments were conducted to find out heavy metal accumulation in some selected organs such as the kidney, the hepatopancreas, and the gills of the Antarctic Clam Laternula elliptica According to the immunohistochemical study the subject organs of the clam showed reactions indicating the presence of MT(metallothionein), a metal-binding protein involved in metal detoxifying process. Examination under the transmission electron microscope also revealed that other ligands(e.g. metal-rich granules in the kidney) may play a role in metal accumulating and detoxifying process in L. elliptica. In the artificial exposure of the clam to Cd, it showed immediate subcellular responses, suggesting that this species can be used as rapid and efficient bioindicators for Cd exposure in natural environment.

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