• Journal of the Korea Organic Resources Recycling Association
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• v.9 no.2
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• pp.71-76
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• 2001

Recently, sludge disposal becomes one of the most serious environmental problems. Because the landfilling and ocean dumping of sludge materials will be prohibited in the near future, the proper treatment?disposal methods should be investigated. Also, oyster shells, piled at the coast, cause adverse effects in coastal fishery, public water surface, natural landscape, public health and so on. Thus, the purpose of this study is to evaluate the dissolution characteristic of metal compounds during soil application experiment using sewage treatment sludge mixed with oyster shells. The dissolution experiment conducted 100days under artificial rainfall and farming soil, mixed with sewage treatment sludge and oyster shells, was put into the pots(approx. 0.5L). The results from dissolution experiment as follows. 1. K, Na was $5{\sim}20mg/{\ell}$, and Ca was less than $90mg/{\ell}$. 2. Heavy metals such as Cd, Cu, As, Pb, Cr, Hg are dissoluted far less than the soil pollution guideline. The application of sewage sludge mixed with oyster shells increases pH(soil acidity)and buffer capacity(CEC) of farming soil, and heavy metals are thought to be attached to soil as insoluble forms.

• Journal of Korea Foresty Energy
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• v.24 no.2
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• pp.1-9
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• 2005

After manufacturing fermentation system for degrading pig manure using environmentally friendly technique, performance of the system and characteristics of wood chips and pig manure fermented in the system were analyzed. Results from this study shows that proper fermentation temperature($55{\sim}60^{\circ}C$) reached 3days after the system started and degradation rate, which expresses fermentation performance of system, was $180{\iota}$/day. Even as progressing the fermentation of wood chips and pig manure mixture, the amount of extractives drawn out by alkali, and alcohol-benzene and lignin content was not varied. However, ash content in wood was increased. The inorganic compounds in pig manure seem to be transferred into wood chip. On the other hand holocellulose contents in wood were decreased a little. Holocellulose seems to be consumed as the second carbon source in fermentation process. Results through analysis of inorganic- and heavy metal elements contents in wood chips and pig manure fermented in long term process shows that inorganic elements($Ca^{2+},\;Mg^{2+},\;K^+,\;Na^+$ etc.) contents were increased with fermentation time and heavy metal elements(Cd, As, Cu etc.) which cause environmental pollution were not detected. Number of microorganisms including bacteria, actinomycetes, and fungi, the number of C.F.U(Colony Forming Unit) was increased while temperature in fermentation system was abruptly increased.

• Journal of the korean society of oceanography
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• v.33 no.4
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• pp.168-177
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• 1998

Five and a half months after the Keumdong oil spill accident on the 21$^{st}$ of September 1993, 34 seawater samples and 94 sediment samples were collected from Kwangyang Bay and Namhaedo area to assess its environmental impacts. Hydrocarbon concentration in the seawater ranged from 0.8 to 9.2 ${\mu}$g/1 with an average of 3.3 ${\mu}$g/1. This average value was nearly the same as the value(3.7 ${\mu}$g/1) before the oil spill accident. This suggests that by the early March of 1994 majority of the coastal water in the study area restored to its background hydrocarbon concentration before the oil spill accident. Nutrients, heavy metals and other general environmental parameters of the seawater did not show any aggravated seawater quality compared with the previous records. From the regression analysis of time-course observation of hydrocarbon in the seawater, except the sediment environment, the effect of oil spill on the water column was estimated to last at least 4 months in the study area after the oil spill accident. In the shoreline sediments, oil deposits were, however, still found at the high water marks at several stations, and very high values were found in the west of Namhaedo, ranging from 3.7 to 40.1 mg/g of wet sediment. Gas chromatography of these samples showed a very distinct Bunker C chromatogram identical to the Keumdong oil spill. Hydrocarbons in the subtidal bottom sediments in the study area and the reference stations (YB and CB) ranged from 0.45 to 18.08 ${\mu}$g/g of wet sediment with an average of 3.09 ${\mu}$g/g. West of Namhaedo (Stations Bl2-B33) generally showed much higher values than inner Kwangyang Bay and in Chinju Bay. Chinju Bay generally showed the lowest value among the study area. Subtidal bottom sediments in inner Kwangyang Bay and Chinju Bay seemed to be less affected than west of Namhaedo. Heavy metal concentrations in the sediment were relatively higher in the Kwangyang Bay than in the Chinju Bay. However, metal concentrations in the study area were in general comparable to the reference areas.

• The Korean Journal of Quaternary Research
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• v.22 no.1
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• pp.1-12
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• 2008

We investigated metal concentrations and oceanic environment changes that have occurred over the past several years by studying the hard coral Porites lutea, which inhabits tropical and subtropical areas. Soft X-radiographs clearly showed distinctive annual bands within 71 mm coral sample, which reflect changes in the oceanic environment over this period. There were large fluctuations in the major and minor element concentrations. Considering the physicochemical partition coefficient, some elements accumulated in the aragonite matrix in a mechanical manner, while others were affected by environmental factors. The concentrations of some heavy metals varied over a wide range, implying local environmental effects. The variation of Sr/Ca and Mg/Ca in coral skeleton clearly showed large-scale fluctuation over the specific intervals, implying environmental changes during this period. The concentrations of heavy metals also show high fluctuations, and roughly accord with Mg/Ca variation. In addition, Cu and Zn seem to show cyclicity-like peaks, coincide with Mg/Ca variation over the specific intervals. Such variation might be related to local pollution and oceanographic changes. More detailed investigation is necessary, including the pretreatment of coral skeleton sediment.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.1
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• pp.1-7
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• 2014

This paper aims to explain the safety assessment and remediation mechanism of Granulated Coal Ash (GCA) as a material for the remediation of coastal sediments and to evaluate the improvement of the sediment in Kaita Bay, where GCA was applied. The concentrations of heavy metal contained in GCA and the dissolved amounts of heavy metal from GCA satisfied the criteria for soil and water pollution in Japan. The mechanisms on the remediation of coastal sediments using GCA is summarized as follows; (1) removal of phosphate and hydrogen sulfide (2) neutralization of acidic sediment (3) oxidation of reductive sediment (4) increase of water permeability (5) increase of soil strength (6) material for a base of seagrass. From the results obtained from the field experiment carried out in Kaita Bay, it was clarified that GCA is a promizing material for remediation of coastal sediment. This remediation technology can contribute to promote waste reduction in society and to decrease cost of coastal sediment remediation by applying GCA in other polluted coastal areas.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.16 no.1
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• pp.44-53
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• 2006

This study purposed to investigate air pollution in car shipping yards and, for this purpose, we selected an outdoor open-air yard and an indoor ramp into the ship and measured the concentrations of sulfur dioxide, nitrogen dioxide, carbon monoxide, PM10, PM2.5 and heavy metals in the air. The results of this study are as follows. No significant difference was observed in temperature and humidity between the outdoor and indoor workshop, and the average air flow was 0.52 m/s in the indoor workshop, which is higher than 0.19 m/s in the outdoor workshop(p<0.01). The average concentrations of sulfur dioxide, nitrogen dioxide, carbon monoxide, PM10 and PM2.5 according to workplace were 0.03 ppm(${\pm}0.01$), 0.03 ppm(${\pm}0.01$), 0.46 ppm(${\pm}0.22$), $39.44{\mu}g/m^3$(${\pm}2.45$) and $5.45{\mu}g/m^3$(${\pm}1.15$) respectively in the outdoor workshop, and 0.15 ppm(${\pm}0.05$), 0.22 ppm(${\pm}0.06$), 8.85 ppm(${\pm}3.35$), $236.39{\mu}g/m^3$(${\pm}58.21$) and $152.43{\mu}g/m^3$(${\pm}35.42$) respectively in the indoor workshop. Thus, the concentrations of gaseous substances in the indoor workshop were 4.9-19.2 times higher than those in the outdoor workshop, and the concentrations of fine dusts were 5.9-27.9 times higher(p<0.01). In addition, according to the result of investigating pollutant concentrations according to displacement and the number of car loaded when shipping gasoline cars into the ship, no significant relation between the number of cars loaded and pollutants was observed in shipping passenger cars, but the concentrations of nitrogen dioxide and carbon monoxide got somewhat higher with the increase of the number of cars loaded(p<0.05). In addition, the concentrations of nitrogen dioxide, carbon monoxide, PM10 and PM2.5 in the air were significantly higher when shipping recreational vehicles, the displacement of which is larger than passenger cars, than when shipping passenger cars(p<0.01). On the other hand, the average heavy metal concentrations of the air in indoor workshop were: lead $-0.05{\mu}g/m^3$(${\pm}0.10$); chromium $-0.90{\mu}g/m^3$(${\pm}0.18$); zinc $-0.38{\mu}g/m^3$(${\pm}0.24$); copper $-0.18{\mu}g/m^3$(${\pm}0.22$); and manganese and cadmium not detected. In addition, the complaining rates of 'asthma,' a major symptom of chronic respiratory diseases, were 18.5% and 22.5% respectively in indoor workers and outdoor workers. Thus the rate was somewhat higher in indoor workers but the difference was not statistically significant. The complaining rates of 'chronic cough' and 'chronic phlegm' were very low and little different between indoor and outdoor workers. The results of this study show that the reason for the higher air pollution in indoor than in outdoor workshop is incomplete combustion of fuel due to sudden start and over-speed when cars are driven inside the ship. In order to prevent high air pollution, efficient management measures should be taken including the observance of the optimal speed, the improvement of old ships and the installation of efficient ventilation system.

• Journal of the Korean Society for Marine Environment & Energy
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• v.7 no.2
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• pp.75-81
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• 2004

A large amount 2.1×106 ㎥ of the polluted sediment was dredged from the Masan Bay and deposited in Gapo confined area, Masan. The dissolved metal concentrations of seawater in the dumping site (Gapo area) were observed during one tidal cycle and compared with those of seawater obtained from Jinhae Bay. The sediment was evaluated as from Non polluted to Moderately polluted by USEPA standards. It was judged that toxicological effects of sediment analyzed ranged from ERL to ERM with copper and zinc, and ERL with cadmium, chrome, lead, and nickel by the Adverse Biological Effects. The pollutant concentration was low in surface sediment compared to deeper sediment since the sediments with relatively low concentrations of pollutant were dumped to the surface. The pollutant concentration was low in surface sediment compared to deeper sediment since the sediments with relatively low concentrations of pollutant were dumped to the surface. The benthic organisms in Gapo area had higher concentrations of trace metals (Oyster: Zn 238.96, Cu 5.29 ㎍/g wet wt., Clam: Zn 17.71, Cu 1.00 ㎍/g wet wt., Mussel. Zn 187.98, Pb 0.28, Cr 0.15, Mn 4.23, Sr 1.45 and Fe 100.33 ㎍/g wet wt.) compared to outside of dumping site. However, the trace metal level in the bivalves was less than the NFPQIS (National Fisheries Products Quality Inspection Service) standard.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.5 no.4
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• pp.285-294
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• 2000

In order to determine the horizontal and vertical distributions of metals and prospect the recent metal pollution history in Nakdong Estuary, we took surface and core sediments. Maximum value of organic matter occurs at the upstream site located 4 km from Nakdong barrage, and the concentration of trace metals (Zn, Cu, and Pb etc.) decrease seaward in the estuary. The sedimentation rates, based on $^{210}$Pb$_{ex}$ and $^{137}$Cs activities, were 0.34 cm/yr in inside of barrage (core 1) and 0.25 cm/yr in Changrim (core 4). Sediment mixing layer does not exist in core 1, where anoxic condition is known to be prevail. The topmost sediment layer of core 4 (<3.5 cm) is severely mixed. At sites 1 and 4, concentrations of Cu slowly increased during the period of 1920-1970, rapidly increased during 1970-1990, and followed by slight decrease after 1990. Zn contents increased in early 1960s and peaked in 1993, and followed by decrease after 1990s. Pb has increased continuously since early 1970s. At the downstream of the barrage, Cu and Zn have increased in the topmost layer. The trend of increase of Cu is evident after 1950 (11 cm in sediment depth). Overall trend of heavy metal concentration clearly indicates the pollution has been increasing after the construction of the barrage.

• Journal of Soil and Groundwater Environment
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• v.14 no.3
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• pp.32-39
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• 2009

This study was conducted in order to get the scientific background for soil pollution criteria. The 92 soil samples derived from various geological units were taken and analyzed to survey natural heavy metal background levels using aqua regia digestion method and 0.1N HCl extraction method. From these results, the average natural contents of metals were 0.287 mg/kg for Cd, 15.26 mg/kg for Cu, 18.43 mg/kg for Pb, 25.36 mg/kg for Cr, 54.27 mg/kg for Zn, 17.68 mg/kg for Ni, 6.83 mg/kg for As by the aqua regia method, and 0.040 mg/kg for Cd, 0.48 mg/kg for Cu, 3.06 mg/kg for Pb, 0.09 mg/kg for Cr, 1.54 mg/kg for Zn, 0.27 mg/kg for Ni, 0.089 mg/kg for As by the 0.1N HCl extraction method. Ratios of soluble contents and total contents were Cd 0.14, Cu 0.03, Pb 0.17, Cr 0.004, Zn 0.03, Ni 0.02, As 0.013 and the correlation coefficients of soluble contents and total contents were 0.24(As), 0.88(Cd), 0.43(Cr), 0.65(Cu), 0.70(Pb), 0.61(Ni), 0.24(Zn). The correlation factor decreased in the order of Cd > Pb > Cu > Ni > Cr > Zn $\approx$ As.

• Land and Housing Review
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• v.13 no.3
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• pp.125-140
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• 2022

Road Deposited Sediment (RDS) is the solids formed from the wear of road, wear of vehicles, exhausts, and the input of the emissions from various sources out of the roads. RDS is seriously polluted by organic matter, nutrients, and metals. RDS plays an important role as the sink and the transport medium of the associated pollutants because RDS can be carried to the adjacent water system via stormwater runoff. In this regard, the heavy metals in RDS were investigated based on the publications. The contents of the metals in RDS were highly variable. The concentration of Cr, Ni, Cu, Fe, Zn, As, Cd, and Pb in urban RDS in various regions was in a range of 3.16-3,410, 1.15-1,382, 20.2-9,069, 2,980-124,853, 81-2,550, 2.3-214, 0.19-21.3, and 15.21-1,125 mg/kg, respectively. The anthropogenic enrichment of the metals in RDS was confirmed by the high concentration of Cu, Zn, Cd, and Pb. The contents of the metals were higher in industrial and traffic areas than in residential areas, while they were generally increased with decreasing particle size. It is believed that this study's results would contribute to quantifying the metals' load via RDS and establishing control strategies.