• Title/Summary/Keyword: Heavy Metal Pollution

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A Study on the Method for Ecological Restoration on Abandoned Concrete-paved Road - Focused on the Experimental Construction Site in Young Dong Province of GyungBu Express Highway(227.24~229.04km) - (콘크리트 폐도의 생태복원 방안 모색에 관한 연구 - 경부선 영동군 황간지역 시험시공지를 중심으로(경부고속도로 227.24~229.04km 지점) -)

  • Kim, Nam Choon;Ann, Phil Gun;No, Su Dae;Kim, Do Hee
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.15 no.4
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    • pp.119-132
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    • 2012
  • The unmanaged abandoned concrete roads are vulnerable toward the issues on soil and water pollution, which requires flexible managing method such as eco-corridor after the process of ecological restoration. Among various alternations of abandoned concrete-paved roads, ecological restoration technique may be the most suitable method in sites including high quality of natural environment. Therefore, as in Young dong province, GyungBu express highway (227.24~229.04km), which is near to Hwang-gan IC, the survey to measure its effect of soil under the paving and water pollution by abandoned concrete roads was discussed. Then, the restoration method of plantings of landscape trees and hydro-seeding methods of artificial soil media was appraised through consecutive monitoring. The soil adequacy analysis shows lower percentage of heavy metal substance in each depth level compared to standard limit stated by the Ministry of Environment, along with low concerns raised after the analysis on heavy metal content of the spilled water on the concrete roads. Meanwhile, Korean Weigela (Weigela subsessilis L.H. Baily) was found to be withered in small-scale landscape trees planting sites. Among the seeding plants. the family of leguminosae, Silene armeria, Dendranthema boreale, Caryopteris incana and Aster yomena show good establishment results. Overall studies on planting of small and large landscape trees, planting method of container plants, planting method of ground cover plants, and germination and development trend of seeding plants of the experimental restoration site on abandoned concrete roads are revealing specific trends in the way landscape woody plants establishment and growth. Finally, this study suggests further studies and survey on varied plant restoration methods on abandoned concrete-roads for developed design guidelines of their methods.

UNLEADED GASOLINE AND LEAD LEVEL IN HUMAN BLOOD

  • Kim, Dae-Seon;Cha, Joung-Hoon
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2001.11a
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    • pp.30-41
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    • 2001
  • Rapid economic development and industrialization has been accompanied by an increase of energy demand and environmental pollution. The consumption of gasoline has increased totally, but decreased in use of leaded gasoline after 1988 in Korea. On the other hand, risk assessment of environmental pollutants requires reliable dose estimates. Source oriented monitoring is not providing adequate information to estimate human exposure. The Health Surveillance Project has been launched in Korea from 1980, which questioned their symptoms based on questionnaires and medical examinations for inhabitants in the vicinity of 13 industrial areas and 2 non-industrial areas. 10, 598 inhabitants living in these 15 areas had medical checkups and donated their blood f3r heavy metal analysis from 1980 to 2000 through this project. Especially lead levels in inhabitants' blood of these areas were determined and monitored. Totally 4, 967 samples in target areas were used to review the trend of blood lead level in this paper. Average lead concentrations by areas were from 15.2 to 21.0 ug/dl in 1981 and 22.3 to 34.3 ug/dl in 1988, but were 8.8 to 11.1 ug/dl in 1992 and 4.4 to 4.8 ug/dl in 1995. On the other hand, the consumption of leaded gasoline was at a peak in 1958. Blood lead level showed a very close relationship with the consumption of leaded gasoline in the change pattern(p<0.01) and showed a rapid declining trend since the use of unleaded gasoline, especially from 1988 when Seoul held the olympic games. For example, the blood lead levels were 15.2 ug/dl in 1981, 20.2 ug/dl in 1955. 24.3 ug/dl in 1988 and 3.9 ug/dl in 1993 in Yochon area. China also had monitored blood lead levels of general population. 7, 015 inhabitants living in 28 areas donated their blood far heavy metal analysis from 1981 to 1988. Average lead concentrations by areas were from 5.1 to 5.6 ug/dl before. 1984 but were form 2.8 to 11.2 ug/dl after 1984. Average lead concentration in blood showed increasing trends clearly in most of the areas. The recent policy of unleaded gasoline use for automobile will be a very beneficial policy for the management of atmospheric lead pollution & health risk assessment for the general population in China. It is recommended that it should be propelled more widely and rapidly to the entire country.

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Study on Determination of Permissible Soil Concentrations for Explosives and Heavy Metals (화약류 및 중금속의 인체위해성평가 및 생태독성에 기반한 토양허용농도도출에 관한 연구)

  • Kim, Moonkyung;Jung, Jae-Woong;Nam, Kyoungphile;Jeong, Seulki
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.19-27
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    • 2015
  • Permissible soil concentrations for explosives (i.e., TNT and RDX) and heavy metals (i.e., Cu, Zn, Pb, and As) heve been derived from human risk and ecotoxicity, respectively. For TNT and RDX, human risk based-permissible soil concentrations were determined as 460 mg-TNT/kg-soil and 260 mg-RDX/kg-soil. Ecotoxicity based-permissible soil concentrations for Cu and Zn were determined from species sensitivity distribution (SSD) and uncertainty factor of 1 to 5, yielding 18.0-40.0 mg-Cu/kg-soil and 46.0-100 mg-Zn/kg-soil. For Pb and As, ecotoxicity data were not enough to establish SSD so that a deterministic method was used, generating 13.8-30.8 mg-Pb/kg-soil and 2.10-4.60 mg-As/kg-soil. It is worth noting that the methodology used to derive permissible concentrations in soil can differ depending on ecotoxicity data availability and socio-economic situations, which results in different permissible concentrations. The permissible concentrations presented in this study have been derived from conservative assumptions for exposure parameters, and thus should be considered as soil standards. In the light of remediation and pollution management of a site of interest, the site-specific and receptor-specific permissible soil concentrations should be derived considering potential receptors, current and future land use, background concentrations, and socio-economic consultation.

Composition and Structure of Marine Benthic Community Regarding Conditions of Chronic Barbour Pollution

  • Fadeeva, N.P.;Bezverbnaja, I.P.;Tazaki, Kazue;Watanabe, Hiroaki;Fadeev, V.I.
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.21-30
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    • 2003
  • Seasonal fluctuations of physico-chemical and biological aspects of the environment were studied in Vladivostok harbour (Golden Horn Bay, the East Sea/Sea of Japan). The benthic community structure was described with a focus on size-spectra (bacteria, meio- and macrofauna) related with the chemical environment and chemical fluxes in sediment and to reveal their possible ecological role in the process of bioremediation of the environment. Samples from two sites with different concentrations of heavy metals (Fe, Zn, Cu, Pb, Mn, Cr, Ni Cd, Co) and petroleum hydrocarbon were assessed by a number of methods. These included plate counts of culturable bacteria, observation through a scanning electron (SEM) and transmission electron microscope (TEM). These approaches were complemented with microscopic assessments of the diversity of the benthic community. The specific communities had a limited number of species, tolerant to abnormally high levels of toxic compounds. The dominant species were presented by several sho.1-lived small polychaetes (Capitella capitata) and nematodes (Oncholaimium ramosum). The highest population density was recorded in microbenthos, in various diatoms, various physiological groups of bacteria which participate in biomineralization: marine heterotrophic bacteria, which oxidized oil, black oil in addition to groups resistant to heavy metals. They have the entire set of mechanisms for neutralizing the negative effect of those compounds, forming the detrital food web and biogeochemical circulation of material in sediments, which results in the biological self-recycling of sea basins. Macro- and meiobenthic organisms were more sensitive to a greater extent of $H_2S$ and petroleum hydrocarbons than to metal content, but the within-site rankings were the same as those achieved for microbiological analyses.

Experimental Evaluation on Occurrence Possibility of Pollutants from Aggregates (순환골재의 오염물질 발생 가능성에 관한 실험적 평가)

  • Park, Jeong-Ho;Seong, Jin-Uk;Park, Je-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.1-7
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    • 2013
  • This study was on leaching test(KSLT, TCLP) of the aggregate for the products(RA-1) and for the site(RA-2) to evaluate the characteristics of contaminants and the possibility of contamination arising from the aggregate. On the basis pH, conductivity and heavy metal contents in the aggregate, RA-1 indicated higher than RA-2. As a result of the leaching test, the pollutants were eluted from the aggregate increased as the particle size of the aggregate was smaller. The pH in the aggregate had a strong alkali by a pH value of 9.0~12.3, the conductivity was higher in less than 10mm RA-1 due to the leaching of dissolved inorganic ions. The heavy metals satisfied the leaching standards of KSLT and less 10% was eluted from the aggregate. As a result of evaluating water pollution possibility of the aggregate, the pH displayed in items with a very high possibility of contamination, conductivity and turbidity did in item with a low possibility of contamination and on the other hand the heavy metals did in item with a very low possibility of contamination.

Chemical properties of liquid swine manure for fermentation step in public livestock recycling center

  • Lee, Dong Sung;Lee, Jae-Bong;Lee, Myoung-Yun;Joo, Ri-Na;Lee, Kyo-Suk;Min, Se-Won;Hong, Byeong-deok;Chung, Doug-Young
    • Korean Journal of Agricultural Science
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    • v.43 no.3
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    • pp.424-431
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    • 2016
  • The nutrients in livestock manure produced during fermentation processes in public livestock recycling centers are used as fertilizers. However, the large amounts of swine manure produced in intensive livestock farms can be a nonpoint source of pollution. In this experiment, we investigated the chemical properties, inorganic components, and heavy metal contents in 101 samples of liquid swine manure collected from 28 public livestock recycling centers throughout the nation. Results showed that the average pH of the samples was alkaline (pH range 5.18 to 9.54), and their maximum EC was $53.2dS\;m^{-1}$. The amounts of total nitrogen and total phosphorus were in the range of 1000 - 2000 and $200-800mg\;L^{-1}$ while potassium, which constituted 47% of the total inorganic ions recovered from the liquid swine manure, amounted to $1500mg\;L^{-1}$. The most distinctive heavy metals recovered from the liquid swine manure were copper and zinc although the amounts of both heavy metals were much lesser than those of the standards as livestock liquid fertilizer set by the Rural Development Administration. On the other hand, the amount of nitrogen decreased rapidly with an increasing fermentation period from immature to mature, assumed to be lost as volatile compounds, such as ammonia, which are the major odor components during the fermentation process.

Assessment of the Naktong River Pollution after Phenol Spillage from the Kumi Industrial Estates II, Korea (페놀오염사건 이후의 낙동강수 오염평가)

  • Kim, Doo-Hie;Jang, Bong-Ki;Hong, Sung-Chul;Moon, Hyo-Jung;Lee, Duck-Hee;Oh, Hae-Ju
    • Journal of Preventive Medicine and Public Health
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    • v.26 no.2 s.42
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    • pp.268-281
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    • 1993
  • The aquatic quality of the Naktong river after two or three months in June, 1991 with phenol spillage from a electrical factory in Kumi was investigated. The samples were collected at six sites of the Naktong river basin and Kachang and Kongsan lakes. Phenol was not detected from all water samples. Turbidity was very much increased to the down stream in the Naktong river. The BOD and COD values exceeded the 2nd grade(3mg/l) of the Korean standard quality of Environmenal Water Act at the all sampling sites of the Naktong river. Especially, the value of COD at Kaejin (12.5mg/l) was poorly classified as to the 5th grade of water class for the environmental quality standards. Organophosphorous pesticides such as parathion, malathion, fenitrothion and diazinon were investigated but not detected. Diazinon was only detected at the Ilsan bridge(1.42ppb), Okkye stream(6.95ppb), Waekwan bridge(0.32ppb), Gangjung reservior(0.13ppb), Kaejin (0.05ppb). Of the carbamates such as carbanyl, isoprocarb and cabofuran, the carbofuran was detected all sites except tap water, and Kachang and Kongsan lakes. The content of heavy metals such as Cd, Pb, Zn, Fe, Mn, Hg were not exceeding for drinking water standards at the all sampling region, but only mecury was detected from Okkye stream(0.018ppb) and Kaejin (0.09ppb). In the regions of Kachang and Kongsan lakes, the content of heavy meatals were lower than that of reservior of Naktong river.

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Study of the Performance of a Dry Cleaning Method for Polluted Ballast Gravel of Railroad Fields (철도부지 오염도상자갈의 건식 정화 기술 성능 연구)

  • Cho, Youngmin;Park, Duckshin;Kwon, Tae-Soon;Lee, Jae-Young
    • Journal of the Korean Society for Railway
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    • v.18 no.6
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    • pp.552-557
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    • 2015
  • Ballast gravel in a railroad field is often polluted by grease and heavy metals. In this paper, the performances of a dry cleaning method for polluted ballast gravel in which pollutants on the gravel surface can be physically removed was extensively studied. A polluted ballast cleaning device able to shoot emery blasting media onto the surface using compressed air was prepared. Polluted ballast gravel was put into this device for cleaning, with the treatment time varied from 1 to 10 min. The cleaning efficiency of the total petroleum hydrocarbons and heavy metals were studied. The total petroleum hydrocarbon removal efficiency was 70-80% for gravels sampled from a locomotive waiting line, while it was 40-60% for gravels sampled from a turnout area. The heavy metal removal efficiency exceeded 90% for copper and lead, while it was 65-80% for nickel and zinc. This system was found to be effective for the remediation of polluted ballast gravels.

Soil Washing Coupled with the Magnetic Separation to Remediate the Soil Contaminated with Metal Wastes and TPH (자력선별과 토양세척법을 연계하여 금속폐기물과 TPH로 복합 오염된 토양 동시 정화)

  • Han, Yikyeong;Lee, Minhee;Wang, Sookyun;Choi, Wonwoo
    • Economic and Environmental Geology
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    • v.52 no.1
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    • pp.1-12
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    • 2019
  • Batch experiments for the soil washing coupled with the magnetic separation process were performed to remediate the soil contaminated with metal and oil wastes. The soil was seriously contaminated by Zn and TPH (total petroleum hydrocarbon), of which concentrations were 1743.3 mg/kg and 3558.9 mg/kg, respectively, and initial concentrations of Zn, Pb, Cu, and TPH were higher than the 2nd SPWL (soil pollution warning limit: remediation goal). The soil washing with acidic solution was performed to remove heavy metals from the soil, but Pb and Zn concentration of the soil maintained higher than the 2nd SWPL even after the soil washing with acidic solution. The 2nd soil washing was repeated to increase the Pb and Zn removal efficiency and the Zn and Pb removal efficiencies additionally increased by only 8 % and 5 %, respectively, by the 2nd soil washing (> 2nd SPWL). The small particle separation from the soil was conducted to decrease the initial concentration of heavy metals and to increase the washing effectiveness before the soil washing and 4.1 % of the soil were separated as small particles (< 0.075 mm in diameter). The small particle separation lowered down Zn and Pb concentrations of soil to 1256.3 mg/kg (27.9 % decrease) and 325.8 mg/kg (56.3 % decrease). However, the Zn concentration of soil without small particles still was higher than the 2nd SPWL even after the soil washing, suggesting that the additional process is necessary to lower Zn concentration to below the 2nd SPWL after the treatment process. As an alternative process, the magnetic separation process was performed for the soil and 16.4 % of soil mass were removed, because the soil contamination was originated from unreasonable dumping of metal wastes. The Zn and Pb concentrations of soil were lowered down to 637.2 mg/kg (63.4 % decrease) and 139.6 mg/kg (81.5 % decrease) by the magnetic separation, which were much higher than the removal efficiency of the soil washing and the particle separation. The 1st soil washing after the magnetic separation lowered concentration of both TPH and heavy metals to below 2nd SPWL, suggesting that the soil washing conjugated with the magnetic separation can be applied for the heavy metal and TPH contaminated soil including high content of metal wastes.

Water Quality and Heavy Metals in the Surface Seawaters of the Saemangeum Area during the Saemangeum-dike Construction (새만금 방조제 체절 과정 중 새만금 주변해역 표층수의 수질과 중금속 분포 특성)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Kim, Seong-Soo;Park, Jong-Soo;Park, Jun-Kun;Cho, Sung-Rok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.1
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    • pp.35-46
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    • 2009
  • In order to investigate spatial and temporal distributional characteristics of major water qualities in the Saemangeum area during the Saemangeum dike construction, salinity, COD, dissolved nutrients(DIN, Silicate) and heavy metals were analyzed from the surface water collected in April, May, August and November 2002. The overall value of Salinity, COD, DIN, and silicate in surface waters were in the range of $13.08{\sim}31.96\;psu$, $0.12{\sim}3.43\;mg/L$, $0.001{\sim}2.638\;mg/L$, and $0.010{\sim}3.181\;mg/L$, respectively. The COD and DIN in each survey showed the highest concentration at the mouth of Mangyeong river estuary(St. 1) where freshwater flow into the Saemangeum area. The concentrations of nutrients were high in the inner part of the Saemangeum dike with low-salinity, and low nutrients in the outer part of the dike with high-salinity, which strongly indicated that concentrations were adjusted by physical mixing. The ranges of dissolved metals and acid-soluble Hg in surface seawater were $0.006{\sim}0.115{\mu}g/L$ for Co, $0.26{\sim}0.114{\mu}g/L$ for Ni, $0.14{\sim}0.93{\mu}g/L$ for Cu, $0.04{\sim}0.53{\mu}g/L$ for Zn, $0.010{\sim}0.043{\mu}g/L$ for Cd, $0.010{\sim}0.795{\mu}g/L$ for Pb, and $0.25{\sim}4.16{\mu}g/L$ for Hg. The highest concentrations of some metals except for Cd were found at the estuary(Sts. 1 or 3). In most cases, a decreasing order of metal concentrations towards open sea(low-salinity$\rightarrow$high-salinity) was observed and showed positive relationship with DIN and silicate caused by land base pollutants input. On the other hand, due to Cd desorption from suspended solids in saline water, dissolved Cd concentrations were high in high-salinity area and low in low-salinity. In November, Co, Zn, Cu and Pb were relatively high in the northern area of the outer-side of Saemangeum, which was only influenced by the Geum river discharge. The concentrations of most dissolved metals of this study were lower than those of the past data in this area, but higher than those in Lena river estuary under the pristine environment.

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