• Journal of the Korean Society of Tobacco Science
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• v.20 no.1
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• pp.5-12
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• 1998

Pot experiment was conducted to investigate the effects of fly ash on growth responses and on accumulation of the heavy metals in soil. Two kinds of fly ash, anthracite and bituminous coal, were treated with different levels of 0, 0.4, 0.8, and 1.2 kg/pot(20L). Tobacco growth was better by application of fly ash than that by the control. However, the early stage of growth by application of bituminous coal, 1.2 kg/pot, was decreased due to the boron toxicity occurred by fly ash. Generally, tobacco yield was significantly increased with applying fly ash, showing the highest yield at 1.2 kg/pot for anthracite and at 0.8 kg/pot for bituminous coal. The content of total nitrogen in leaves was higher with fly ash than that of the control, while the content of calcium in leaves was low, Contents of heavy metal and the other minerals were not significantly different between the control and the treatment of fly ash. Soil pH after experiment was linearly increased with application level of fly ash, indicating that the application of bituminous coal was more effective than that of anthracite. Contents of available phosphate, exchangeable $Ca^{2+}$+ and $Mg^{2+}$ in soil were increased by application of fly ash, especially with bituminous coal. Contents of Cu, Cr, and Ni were increased with application level of bituminous coati even if the contents were still lower than critical levels for farming land. The other heavy metals were similar between the control and the application of fly ash.

• Biotechnology and Bioprocess Engineering:BBE
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• v.5 no.6
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• pp.431-435
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• 2000

The goal of this research is to compare the metal binding characteristics of an anoxic selector activated sludge system and a conventional activated sludge system. Metal biosorption by biomass harvested from experimental systems was determined by a series of batch experiments. Heavy metals studied in this research were zinc, cadmium, and nickel. The sorption isotherm showed that the selector sludge had significantly higher sorption capacity than did the control sludge. Metal biosorption behavior closely followed a Freundlich isotherm model for equilibrium concentrations. ECP contents of biomass estimated by alkali extraction technique showed that ECP levels in the selector sludge significantly higher than that in the sludge harvested from the conventional system, indicating that the higher metal sorption capacity of selector sludge may be due to the selection of the ECP-producing bacteria (i.e., Zoogloea sp.) by the selector system.

• Analytical Science and Technology
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• v.23 no.6
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• pp.615-618
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• 2010

An oxygen bomb combustion procedure were studied for determination of heavy metal in polymer materials such as polyvinyl chloride and polypropylene by ICP-AES. This method is proposed as a rapid and simple sample preparation for decomposition of polymer containing certified contents of the analytes by teflon coated oxygen bomb combustion using different absorbing solution. The recoveries of metal were found to be 30~102% from absorbed solution by ICP-AES method using polypropylene certified reference material(PP CRM-As, Ba, Cd, Hg, Pb, Zn). The recoveries of metal using PVC CRM(Cd, Hg, Pb) was found to be 45 ~101% with same procedures.

• Journal of Environmental Health Sciences
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• v.37 no.5
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• pp.348-357
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• 2011

Objectives: This study was conducted in order to examine the relationship between heavy metal concentrations in the soil and the level of heavy metals in the blood or urine of 216 local residents living near abandoned metal mines. Methods: Residents around abandoned metal mines were interviewed about their dietary habits, including seafood consumption, medical history, cigarette smoking, and drug history. Metal concentrations in the soil were determined by atomic absorption spectrophotometer (AA-7000, Shimadzu, Japan). Lead (Pb) and cadmium (Cd) contents in the blood or urine were analyzed by GF-AAS (AA-6800, Shimadzu). Mercury (Hg) contents in the blood were determined by means of a mercury analyzer (SP-3DS, NIC). Arsenic (As) content in the soil and urine were measured by a HG-AAS (hydride vapor generation-atomic absorption spectrophotometer). Results: The heavy metal concentrations in the soil showed a log normal distribution and the geometric means of the four villages were 8.61 mg/kg for Pb, 0.19 mg/kg for Cd, 1.81 mg/kg for As and 0.035 mg/kg for Hg. The heavy metal levels of the 216 local residents showed a regular distribution for Pb, Cd, Hg in the blood and As in the urine. The arithmetic means were 3.37 ${\mu}g$/dl for Pb, 3.07 ${\mu}g$/l for Cd and 2.32 ${\mu}g$/l for Hg, 10.41 ${\mu}g$/l for As, respectively. Conclusions: As a result of multi-variate analysis for the affecting factors on the bodily heavy metal concentrations, gender and concentration in the soil (each, p<0.01) for blood lead levels; gender and smoking status (each, p<0.01) for blood cadmium levels; gender (p<0.01) for urine arsenic levels; gender, age and concentration in the soil (p<0.01) for blood mercury levels were shown to be the affecting factors.

• Korean Journal of Soil Science and Fertilizer
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• v.31 no.3
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• pp.225-232
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• 1998

In order to monitor the degree of heavy metal distribution in upland cultivations in Korea, both the cultivated soils and crops were collected from the 854 and 140 sites, respectively. The contents of cadmium (Cd), copper(Cu), lead(Pb), and zinc(Zn) in each sample were measured by Inductively Coupled Plasma(ICP) technique after 1N-HCl extraction. The content of Arsenic(As) was also measured with the same technique after 1N-HCl extraction. The average contents of heavy metal in surface soils(0~15 cm depth) were $0.135mg\;kg^{-1}$ for Cd, $2.77mg\;kg^{-1}$ for Cu, $3.47mg\;kg^{-1}$ for Pb, $10.7mg\;kg^{-1}$ for Zn, and $0.57mg\;kg^{-1}$ for As. Heavy metal contents of soil were similar to those values measured for upland soils in 1989, lower than soils under plastic film house in 1996. However, these contents were lower than "Countermeasure values for soil contamination"(Cd: 4, Cu: 125, Pb: 300, and As: $15mg\;kg^{-1}$ in soil) describled in Soil Environmental Conservation Act in Korea(1996). The contents of heavy metal in fresh vegetable, and root and tuber crops ranged $0.005{\sim}0.019mg\;kg^{-1}$ for Cd, $0.20{\sim}1.03mg\;kg^{-1}$ for Cu, $0.042{\sim}0.104mg\;kg^{-1}$ for Pb, and $2.0{\sim}4.0mg\;kg^{-1}$ for Zn, respectively.

• Ocean and Polar Research
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• v.25 no.4
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• pp.447-457
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• 2003

In order to understand the distribution of changes of geochemical characteristics in surface sediments according to various environmental changes around the artificial Lake Shihwa, surface sediments were sampled at $13{\sim}15$ sites form 1997 to 1999 and analyzed by C/S analyzer, ICP/MS and AAS. The average $S/C_{org}$ ratio was 0.35 in the surface sediments, which is similar to 0.36, the characteristic ratio of marine sediments. Heavy metal contents and enrichment factors in the surface sediments tended to be decreasing from the head to the mouth of the Lake Shihwa. With the deposition of fine-grained sediments in the central part of lake, anoxic water column induced the sulfides compounds with Cu, Cd and Zn. Metals such as Al, Fe, Cr, Co, Ni, Cu, Zn and Cd except for Mn and Pb showed relatively high correlation coefficients among them. The contents of Cr, Co, Ni, Cu, Zn and Cd in the surface sediments of the lake were two to five times higher than those in the lake before dike construction and also in outer part of the dike. These are mainly due to the Input of untreated industrial and municipal waste-waters into the lake, and the accumulation of heavy metals by limitation of physical mixing. Although metal contents of the surface sediments at the sites near the water-gate due to outer seawater inflow tended to be lower than those during the desalination, heavy metals were deposited in areas around the new industrial complex in the evidence of spatial distribution of heavy metals in the sediments. This is mainly due to the input of untreated waste-waters from tributaries.

• Preventive Nutrition and Food Science
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• v.18 no.4
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• pp.249-255
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• 2013

Yam (Dioscorea) has long been used as foods and folk medicine with the approved positive effects for health promotion. Although consumption of yam products is increasing for health promotion, reports for the metal contamination in commercial yam powder products to protect the consumers are lacking. In this study, we aimed to assess whether the commercial yam powder products were heavy metal contaminated or not using the yam products from six commercial products from various places in South Korea. The contents of heavy metals (Cd, Cr, As, Pb, Ni, and Sn) in yam powder products were measured and compared to national and international food standard levels. Also, the metal contamination was monitored during the food manufacturing steps. The study results showed that the contents of heavy metals (Cd, Cr, As, and Pb) in yam powder products are similar to those in national 'roots and tubers' as well as in various crops. In comparison to three international standard levels (EU, Codex and Korea), Cd content in yam powder products was lower but Pb content was 5 times higher. Also, Pb, Ni, and Sn may have the potential to be contaminated during food manufacturing steps. In conclusion, the level of heavy metals (Cd, Cr, As, Ni, and Sn) except Pb is considered relatively safe on comparison to national and international food standard levels.

• Journal of Soil and Groundwater Environment
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• v.8 no.2
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• pp.87-91
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• 2003

This study was carried out to investigate the heavy metal distributions of soils in the vicinity of Shi-Hwa industrial complex region, where the air pollutants from industrial area could affect the soil environment of near residential and green areas. The ranges of contents of As, Cd, Co, Cr, Cu, Hg, Ni, Pb and Zn in soils were 0.58~3.81, ND~0.91, 0.15~6.33, ND~l.86, 0.14~110.27, ND~l.17, 0.04~10.59, 1.16~86.48 and 1.83~212.65 mg/kg, respectively. For all industrial, residential and green areas, the heavy metal contents were much lower than the standard of Korean Soil Environmental Preservation Act or the critical concentration which phytotoxicity is considered to be possible. Mean values of contents of As were similar in industrial, residential and green areas. However, the mean values of contents of Cd and Cr in industrial area were higher 10 and 5 times than those in residential and green area, respectively. And also the mean values of contents of Co, Cu, Hg, Ni, Pb and Zn in industrial area were higher 2~3 times than those in residential and green area.

• The Korean Journal of Ecology
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• v.26 no.3
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• pp.109-114
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• 2003

To investigate ecophysiological characteristics of plants species adapted to moor habitat, we selected 22 species plants and analyzed inorganic cations (K, Ca, Mg), heavy metals (Al, Fe, Mn) and total nitrogen and phosphorus quantitatively. Moojechi moor indicated typical acidic and oligotrophic conditions with pH of 5.0∼5.6 (pH 4.3∼5.1 in soil) and EC of 15∼30μ S/cm, and contained very low contents of soil divalent cation such as Ca and Mg but high contents of heavy metals (esp. Al). With respect to inorganic cation contents, investigated plants species showed remarkable interspecific difference. Plant species belonging to J. effusus var. decipiens, M. japonica, I. globosa, M. sacchariflorus, R. mucronulatum, R. yedoense var. poukhanense, H. micrantha, D. rotundifolia showed very low contents of inorganic cation below 400 μ M/g DW, but plant species of C. palustris var. spontanea, L. sessilifolia, P. mandarinorum, C. lineare, S. austriaca sub. glabra, V. mandshurica, A. decursiva showed high cation contents in leaves. Especially, S. austriaca sub. glabra (Compositae) and V. mandshurica (Violaceae) showed pattern accumulating Ca and Mg with plant growth, but I. ensata var. spontanea (Iridaceae) and S. officinalis (Rosaceae) showed decreasing tendency. Meanwhile, most plant species showed low contents of soluble metal ions in leaves in spite of high heavy metal contents on soil, and indicated remarkable interspecific differences in the total contents and composition of heavy metals accumulated. Despite low contents of N and P on soil, most plant species indicated relatively high contents of N and P in leaves at the early stage of growth, and showed slowly decreasing pattern according to growth. Consequently, it seems that plant species inhabited on Moojechi moor cope with acidic-oligotrophic conditions, accumulating inorganic cations and nitrogen at the early growing stage and reutilizing them in the course of growth, and developing heavy metal excluding mechanism.

• Journal of the Korean Society of Food Science and Nutrition
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• v.22 no.4
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• pp.484-488
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• 1993

The heavy metal contents in Carassius auratus, that were sampled from Nov.1 to Nov. 31, 1991 at 6 areas in Joenlabuk-do. The mercury contents was determined by mercury analyzer using the combustion Goldamal-gamation method. The arsenic contents were determined by spectrophotometry using silver diethyl ditiho carbamate method. The contents of other heavy metals were determined by inductively coupled plasma spectrometer method. The levels of total mercury, arsenic, cadmium, lead, cupper, manganes, and zinc were determined and the results were summarized as follows : The 6 areas over all range(ppm) were Hg : 0.0167~0.0407, As : N.D.~0.0018, Cd : 0.1256~0.1935, Pb : 0.3536~0.6593, Cu : 0.2094~0.3792, Mn : 2.9059~6.9335, Zn : 14.3095~48.1615ppm. Among the seven heavy metals contents, the higest was zinc and the lowest was arsenic. The results show that contents of Hg As, Cd, Pb, Mn and Zn in Carassius auratus were lower than the FAO/WHO maximum allowance.