• Title/Summary/Keyword: Heated glass

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Improved Magnetic Anisotropy of YMn1-$xCrxO_3 $ Compounds

  • Yoo, Y.J.;Park, J.S.;Kang, J.H.;Kim, J.;Lee, B.W.;Kim, K.W.;Lee, Y.P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.218-218
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    • 2012
  • Recently, hexagonal manganites have attracted much attention because of the coexistence of ferroelectricity and antiferromagnetic (AFM) order. The crystal structure of hexagonal manganites consists of $MnO_5$ polyhedra in which $Mn^{3+}$ ion is surrounded by three oxygen atoms in plane and two apical oxygen ions. The Mn ions within Mn-O plane form a triangular lattice and couple the spins through the AFM superexchange interaction. Due to incomplete AFM coupling between neighboring Mn ions in the triangular lattice, the system forms a geometrically-frustrated magnetic state. Among hexagonal manganites, $YMnO_3$, in particular, is the best known experimentally since the f states are empty. In addition, for applications, $YMnO_3$ thin films have been known as promising candidates for non-volatile ferroelectric random access memories. However, $YMnO_3$ has low magnetic order temperature (~70 K) and A-type AFM structure, which hinders its applications. We have synthesized $YMn1_{-x}Cr_xO_3$ (x = 0, 0.05 and 0.1) samples by the conventional solid-state reaction. The powders of stoichiometric proportions were mixed, and calcined at $900^{\circ}C$ for $YMn1_{-x}Cr_xO_3$ for 24 h. The obtained powders were ground, and pressed into 5-mm-thick disks of 1/2-inch diameter. The disks were directly put into the oven, and heated up to $1,300^{\circ}C$ and sintered in air for 24 h. The phase of samples was checked at room temperature by powder x-ray diffraction using a Rigaku Miniflex diffractometer with Cu $K{\alpha}$ radiation. All the magnetization measurements were carried out with a superconducting quantum-interference-device magnetometer. Our experiments point out that the Cr-doped samples show the characteristics of a spin-glass state at low temperatures.

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A Black Mold of Pepper Fruites Caused by Alternaria alternata (Alternaria alternata에 의한 고추 열매의 검은곰팡이병)

  • Kim Wan Gyu;Yu Seung Hun
    • Korean Journal Plant Pathology
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    • v.1 no.1
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    • pp.67-71
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    • 1985
  • A severe infection on pepper fruits by a black mold fungus was observed in the fields, Suweon. Conidia of Alternaria sp. were isolated from the infected fruits. Based on the morphological characters and size of the conidia, the fungus was identified as Alrernaria alternata (Fries) Keissler. The single spore isolates of A. alternata were weakly or not pathogenic on non-wounded pepper fruits, but highly virulent on fruits wounded with sandpaper or heated-glass rod. The infection on the wounded fruits were more severe on red fruits than on immature green ones. No visible infection was found on leaves and stems when 60-day-old plants of pepper were inoculated with the fungus. In July of 1984, the field losses of pepper fruits caused by black mold were $2.0\~22.5\%$ in Suweon.

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Preparation of Silica Sol by Partial Hydrolysis of TEOS and High Purity Silica Glass Fiber (TEOS의 부분가수분해에 의한 실리카 졸의 합성과 유리섬유 제조)

  • Yang, Hyun S.;Kwon, Oh H.;Lee, Jae D.;Rho, Jae S.;Kim, Young H.
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.823-831
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    • 1996
  • At the ratio [$H_2O$]/[TEOS]=1.7, the silica sol was synthesized by partial hydrolysis in the presence of acid catalyst. After stabilizing the silica sol by trimethylsilylation, the molecular weight and viscosity of the sol obtained at various reaction times were examined to determine a best spinnability of the sol. Gel fibers were prepared from the sol solution after removing solvent in the solution, and the gel fibers were heated at $1,000^{\circ}C$. The prepared silica fibers were in the shape of circular cross-section and their tensile strength and $SiO_2$ purity were $83{\pm}20kg/mm^2$ and about 99.997%, respectively.

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Development of Intravascular Micro Active Endoscope(II) -System Design, Fabrication and In-vitro Evaluation- (혈관 삽입용 초소형 작동형 내시경의 개발(II) - 시스템 설계, 제작 및 체외 성능 분석 -)

  • Chang, Jun-Keun;Chung, Seok;Lee, Yong-Ku
    • Tribology and Lubricants
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    • v.15 no.3
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    • pp.278-286
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    • 1999
  • To predict the behavior of the intravascular micro active endoscope in the real human vascular system, a human mock circulation system was developed. The intravascular micro active endoscope which consists of micro active bending catheter and micro drug infusion catheter was driven in the velocity, Re number and temperature controlled flow. The three SMA (Shape Memory Alloy) zigzag type spring in the micro active bending catheter was heated by the electric current generated by PWM controller, and the shape memory effect made the actuator bend to any direction. The micro drug infusion catheter was driven through the inner hole of the micro active bending catheter. A mock circulation system is shaped from Ascending Arota to Femoral artery according to a human data (the data contains many vascular sizes and hydrographs of many control points). We developed a vascular model with glass and silicone tubes, and set the flow system with circulation parts, flow settling parts, and lots of valves. The heater and heat-controller was added to the How system to centre! the temperature of the How at 36.5$^{\circ}C$. The result showed that the developed intravascular micro active endoscope could be induced to any point in the vascular model.

The Effect of Promoters Addition on NOx Removal by $NH_3$ over V$V_2O_5/TiO_2$

  • Lee, Keon-Joo
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E1
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    • pp.29-36
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    • 2002
  • The selective catalytic reduction (SCR) reaction of promoter catalysts was investigated in this study. A pure anatase type of TiO$_2$ was used as support. Activation measurement of prepared catalysts was practiced on a fixed reactor packing by the glass bead after filling up catalysts in 1/4 inch stainless tube. The reaction temperature was measured by K-type thermocouple and catalyst was heated by electric furnace. The standard compositions of the simulated flue gas mixture in this study were as follows: NO 1,780ppm, NH$_3$1,780ppm, $O_2$1% and $N_2$ as balance gas. In this study, gas analyzer was used to measure the outgassing gas. Catalyst bed was handled for 1hr at 45$0^{\circ}C$, and the reactivity of the various catalyst was determined in a wide temperature range. Conversion of NH$_3$/NO ratio and of $O_2$ concentration was practiced at 1,1.5 and 2, respectively. The respective space velocity were as follows . 10,000, 15,000 and 17,000 hr-1. It was found that the maximum conversion temperature range was in a 5$0^{\circ}C$. It was also found toi be very sensitive at space velocity, $O_2$ concentration, and NH$_3$/NO ratio. We also noticed that the maximum conversion temperature of (W, Mo, Sn) -V$_2$O$_{5}$/TiO$_2$ catalysts was broad. Specially WO$_3$-V$_2$O$_{5}$TiO$_2$2 catalyst appeared nearly 100% conversion at not only above 30$0^{\circ}C$ ut also below 25$0^{\circ}C$. At over 30$0^{\circ}C$, NH$_3$ oxidation decreased with decrease of surface excess oxygen. In addition, WO$_3$-V$_2$O$_{5}$TiO$_2$ catalyst did not appear to affect space velocity, $O_2$ concentration, and NH$_3$/NO ratio.ratio.

A Visual Study on Nucleate Boiling Phenomena in a Closed Two-Phase Thermosyphon (밀폐형 2상 열사이폰내의 비등현상에 관한 가시화 연구)

  • 강환국;오광헌;김철주;박이동;황영규
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1995.05a
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    • pp.185-198
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    • 1995
  • This is an experimental study conducted to visualize the nucleate boiling phenomena and flow regimes occurring inside the liquid pool in a closed two-phase thermosyphon. To meet this purpose, an annular-type thermosyphon was designed and manufactured using a glass tube and a stainless steel tube, being assembled axisymmetrically. The heat to be supplied to the working fluid is generated within a very thin layer of stainless steel tube wall by applying a high frequency electromagnetic field through the induction coil, axisymmetrically set around the evaporator zone. Some important results were as follows ; 1) Considering the structural complexity of the tested thermosyphon, it showed good performance for the range of heat flux 2< q" <25kW/$m^2$ and saturation vapor pressure, 0.1<Pv<1.1bar 2) different type of nucleating boiling regimes were observed as described below, -Pulse boiling regime : Flow pattern changed cyclically with time during 1 cycle of pulse boiling process. The onset of Nucleation was followed by expulsive growing of vapor bubble, resulting in the so called blow-up phenomenon, massive expulsion of large amount of liquid around the bubble. -Transient : Some spherical vapor bobbles were observed growing out from 2~3 nucleating sites, that was dispersed at the lower part of the heated tube wall in the liquid pool. But the rest upper region above the nucleating sites were filled with churns or bubbles of vapor. -Continuous nucleate boiling regime : The whole zone of evaporator was filled with lots of spherical vapor bubbles, and the bubbles showed tendency to decrease in diameter as the heat flux increased.ased.

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Electrochemical Characteristics of all solid supercapacitor based on DAAQ(1,5-diaminoanthraquinone) and SPEEK(sulfonated polyether ether ketone) (DAAQ와 SPEEK를 이용한 전고상 슈퍼커패시터의 전기화학적 특성)

  • Kim, Jin-Yong;Kim, Hong-Il;Kim, Han-Joo;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.371-372
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    • 2005
  • Supercapacitors are promising devices for delivering high power density. Digital communications, electric vehicles and other devices that require electrical energy at high power levels in relatively short pulses have prompted considerable research on supercapacitors. In recent years, solid electrolytes have been investigated for supercapacitors. Solid electrolytes are advantageous over liquid electrolytes in respect of easy handling and reliability without electrolyte leakage. In this preliminary study, an electrochemical supercapacitor in all solid configuration has been fabricated using CNF-DAAQ and poly-vinylidenefluoride(PVdF). A new type of Supercapacitor was constructed by using carbon nanofibers(CNFs) and DAAQ(l,5-diaminoanthraquinone) monomer. DAAQ was deposited on the carbon nanofibers by chemical polymerization with $(NH_4)_2S_2O_8$ as oxidant in the 0.1M $H_2SO_4$. Dried SPEEK powder was mixed with N-methyl pyrrolidone to make 10 wt.% solution in an ultrasonic bath, the slurry was cast over a glass substrate heated to $70^{\circ}C$ for solvent evaporation. And then we used solid electrolyte of SPEEK. The unit cell consist of DAAQ-CNF/electrolyte/Pt. From the analysis, it is clear that surface of carbon nanofibers was quite uniformly coated with DAAQ. The performance characteristics of the supercapacitors have been evaluated using Cyclic Voltammetry.

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Heat transfer characteristics with materials of the filler and flow path in vehicle washer heater system (차량워셔액 가열시스템에서 충전재 및 유로의 재질에 따른 열전달 특성 연구)

  • Cha, Woo Sub;Kim, Tae Kwon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.2628-2634
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    • 2014
  • Vehicle washer heater system is more widely adopted to defrost a window or to clear the windshield glass in winter season. The washer heater system should be designed to heat up washer fluid rapidly to the target temperature for only a short time. A numerical analysis has been carried out to analyze the heat transfer characteristics with materials of inside parts in vehicle washer heater system with filler and flow path. ANSYS - FLUENT software is employed for the analysis. The axial symmetry model is three-dimensional and unsteady. It applies to the coupled method which is one of pressure based. Through this result, it was obtained to find the optimal material condition for the filler and flow path in washer system. For material of filler, the air with lower density was heated more rapidly rather than silicon carbide(SiC). For material of flow path, copper with the heat transfer coefficient of approximately four times greater than the nickel gives us higher efficiency. That is the reason why the heating time of methanol was reduced to make uniform temperature in washer heater system.

A study on the residual stress and spring back of thermoformed films (열성형 공정에서 발생하는 필름의 잔류응력 및 스프링 백에 관한 연구)

  • Park, Du-Yong;Park, Dong-Hyun;Lee, Ho-Sang
    • Design & Manufacturing
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    • v.16 no.1
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    • pp.27-35
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    • 2022
  • Thermoforming is a plastic manufacturing process that applies a force to stretch a film of heated thermoplastic material over an engineered mold to create a 3-dimensional shape. After forming, the shaped part can then be trimmed and finished to specification to meet an end-user's requirements. The process and thermoplastic materials are extremely versatile and can be utilized to manufacture parts for a very wide range of applications. In this study, based on K-BKZ nonlinear viscoelastic model, thermoforming process analysis was performed for an interior room-lamp. The predicted thickness was minimum at the corner of a molded film, and maximum at the center of the bottom. By using the Taguchi method of design of experiments, the effects of process conditions on residual stresses were investigated. The dominant factors were the liner thickness and the film heating time. As the thickness of the liner increased, the residual stress decreased. And it was found that the residual stress decreased significantly when the film heating temperature was higher than the glass transition temperature. A thermoforming mold and a trimming mold were manufactured, and the spring back was investigated through experiments. The dominant factors were film heating time, liner thickness, and lower mold temperature. As the film heating time and liner thickness increased, the spring back decreased. In addition, it was found that the spring back decreased as the lower mold temperature increased.

Characteristics of Electrospun Ag Nanofibers for Transparent Electrodes (전기방사법으로 제조된 Ag 나노섬유의 투명전극 특성)

  • Hyeon, Jae-Young;Choi, Jung-Mi;Park, Youn-Sun;Kang, Jiehun;Sok, Junghyun
    • Journal of the Korean Vacuum Society
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    • v.22 no.3
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    • pp.156-161
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    • 2013
  • We fabricated transparent conductive electrodes with silver (Ag) nanofibers by electrospinning process. Ag nanofibers have high aspect ratio and fused junctions which result in low sheet resistance. Electrospinning is a fast and efficient process to fabricate continuous one-dimensional (1D) nanofibers. Ag/polymer ink were prepared in polymer matrix solution by a sol-gel method. Then, Ag/polymer nanofibers precursors are heated at $200{\sim}500^{\circ}C$ in air for 2 h to eliminate partially the polymers. The topographical features of the Ag nanofibers were characterized by FE-SEM, and the electrical property was analyzed through I-V measurement system. Finally, optical property was measured using UV/VIS spectroscopy. The transparent conductive electrodes with Ag nanofibers exhibited a sheet resistance (Rs) of $250{\Omega}/sq$ at a transparency (T) of 83%. Transparent conductive films, contain the Ag nanofibers as conductive materials, have good electrical, optical, and mechanical properties. Therefore, it is expected to be useful for the application of flexible display in the future.