• Title/Summary/Keyword: Heat treatment condition

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Power Generating Characteristics of Anode-Supported SOFC fabricated by Uni-Axial Pressing and Screen Printing (일축가압/스크린인쇄 공정에 의해 제조된 음극지지형 SOFC의 출력특성)

  • 정화영;노태욱;김주선;이해원;고행진;이기춘;이종호
    • Journal of the Korean Ceramic Society
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    • v.41 no.6
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    • pp.456-463
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    • 2004
  • To enhance the performance of anode-supported SOFC, single cell fabrication procedure was changed for better and resulting power generating characteristics of single cell were investigated. Liquid condensation process was employed for the granulation of NiO/YSZ powder mixture and the produced powder granules were compacted into anode green substrate by uni-axial pressing. YSZ electrolyte was printed on green substrate via screen-printing method and co-fired at 1400$^{\circ}C$ for 3 h. LSM/YSZ composite cathode of which the composition and heat treatment condition was adjusted to minimize the polarization#resistance with AC-impedance spectroscopy, was screen printed. The final single cell size from this multi-step procedure was 5${\times}$5 $\textrm{cm}^2$ and 10${\times}$10 $\textrm{cm}^2$. The maximum power densities of 5${\times}$5 and 10${\times}$10 single cells were about 0.45 W/$\textrm{cm}^2$ and 0.22 W/$\textrm{cm}^2$ at 800$^{\circ}C$, which are two times superior than those from single cells fabricated by the conventional process in previous our work.

Effects of Culture Condition on Embryogenesis in Microspore Culture of Brassica napus L. Domestic Cultivar 'Tammiyuchae' (국내 육성 품종 '탐미유채'의 소포자 배양 시 배양조건이 배발생에 미치는 영향)

  • Kim, Kwang-Soo;Lee, Yong-Hwa;Cho, Hyeon-Jun;Jang, Young-Seok;Park, Kwang-Geun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.4
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    • pp.317-323
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    • 2012
  • For the establishment of an efficient embryogenesis from microspore culture in Brassica napus L. domestic cultivar 'Tammiyuchae', four different factors affecting microspore embryogenesis and plantlet regeneration were investigated. The highest embryogenesis rate was achieved when microspores at late uninucleate to early binucleate stage were isolated from flower buds with a length of 3.0~3.5 mm. On average, 388 embryos generated from 1 ml of microspores media. The highest number of embryos was obtained when microspores were subjected to $32.5^{\circ}C$ for 2 days. Embryogenesis of 'Tammiyuchae' was increased with increasing microspore culture density up to about $5{\times}10^4ea/mL$. Gradually higher culture density repressed embryogenesis of microspores. Regeneration rate of shoots from microspore-derived embryos was observed in MS solid medium supplemented with $0.5mg{\cdot}L^{-1}$ NAA and $1.0mg{\cdot}L^{-1}$ BA, and grew well in MS solid medium without plant growth regulators.

A Case Study and Analysis of the Causes for Natural Gas Vehicle Accidents (천연가스자동차 사고사례 및 원인분석)

  • Kim, Young-Seob;Cho, Eun-Goo;Kim, Lae-Hyun
    • Journal of the Korean Institute of Gas
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    • v.13 no.2
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    • pp.41-48
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    • 2009
  • I collected the cases of CNG vehicle accidents which had happened for 30 years and analyzed the causes of the accidents according to each type of cylinders. There are about six accidents including three cylinder explosion accidents due to bad heat treatment, one composite damage, one CNG vehicle fire, and one fuel piping accident owing to the poor maintenance. When looking into the cylinder types involved in the accidents and the causes, 29% of the cylinder accidents are Type I and 24% Type IV, 16% Type II, and 14% Type III. 37% of the accidents are caused by the defects of the raw materials and the errors of a manufacturing process, 16% by the stress corrosion cracking as a result of the repetitive use, 15% by the cylinder's explosion on account of the malfunction of PRD(Pressure Relief Device) and the overpressure. The remainders of the causes are fire and unknown causes. Therefore, cylinder manufacturers have to strengthen quality management of raw materials and manufacturing process and painting regardless of each type of cylinder. Also bus operators need to make an effort to keep safety condition through every day check.

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Planarization of SUS310 Metal Substrate Used for Coated Conductor Substrate by Chemical Solution Coating Method (화학적인 용액 코팅방법에 의한 박막형 고온초전도체에 사용되는 SUS310 금속모재의 평탄화 연구)

  • Lee, J.B.;Lee, H.J.;Kim, B.J.;Kwon, B.K.;Kim, S.J.;Lee, J.S.;Lee, C.Y.;Moon, S.H.;Lee, H.G.;Hong, G.W.
    • Progress in Superconductivity
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    • v.12 no.2
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    • pp.118-123
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    • 2011
  • The properties of $2^{nd}$ generation high temperature superconducting wire, coated conductor strongly depend on the quality of superconducting oxide layer and property of metal substrate is one of the most important factors affecting the quality of coated conductor. Good mechanical and chemical stability at high temperature are required to maintain the initial integrity during the various process steps required to deposit several layers consisting coated conductor. And substrate need to be nonmagnetic to reduce magnetization loss for ac application. Hastelloy and stainless steel are the most suitable alloys for metal substrate. One of the obstacles in using stainless steel as substrate for coated conductor is its difficulties in making smooth surface inevitable for depositing good IBAD layer. Conventional method involves several steps such as electro polishing, deposition of $Al_2O_3$ and $Y_2O_3$ before IBAD process. Chemical solution deposition method can simplify those steps into one step process having uniformity in large area. In this research, we tried to improve the surface roughness of stainless steel(SUS310). The precursor coating solution was synthesized by using yttrium complex. The viscosity of coating solution and heat treatment condition were optimized for smooth surface. A smooth amorphous $Y_2O_3$ thin film suitable for IBAD process was coated on SUS310 tape. The surface roughness was improved from 40nm to 1.8 nm by 4 coatings. The IBAD-MgO layer deposited on prepared substrate showed good in plane alignment(${\Delta}{\phi}$) of $6.2^{\circ}$.

Physio-ecological Characteristics and Control of Alopecurus aequalis Sobol. var. amurensis (Kom.) Ohwi. - 1. Gernmination and Emergence Under Several Environmental Conditions (뚝새풀(Alopecurus aequalis Sobol. var. amurensis (Kom.) Ohwi.)의 생리생태적(生理生態的) 특성(特性) 및 방제(防除) - 1. 발아(發芽) 및 출아(出芽) 특성(特性))

  • Im, I.B.;Lee, S.Y.;Huh, S.M.
    • Korean Journal of Weed Science
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    • v.14 no.4
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    • pp.239-244
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    • 1994
  • As a fundamental study to control Alopeuclus aequalis Sobol. var. amurensis(Kom.) Ohwi., on dominant weed in barley and dry seeded rice cultivation on paddy fields, several factors which would have closer relations to its germination and emergence, were examined. The results are as follows. The dormancy of seeds were broken at dry-heat treatment of $30^{\circ}C$. The germination rate of the seeds was high in order of 15>10>20> $5^{\circ}C$ and was very low at more than $25^{\circ}C$. The emergence of A. aequalis was influenced little for the light, but had a tendency to be good on the dark condition. The seeds dried on room temperature germinated few but them treated on $30^{\circ}C$ for 24 hours were germinated over 80%. The A. aequalis occured few in the saline soil of salt concentration of more than 0.25% and the germination rate of seeds was very low on the over 0.5% solution of NaCl. On the solution of pH 6.0~12.0, the germination was not effected for pH but was very few on pH 2.0. At the paddy-lowland which have cultivated the soybean for three years A. aequalis emerged a few.

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The Effect of Thermal Annealing and Growth of CdGa2Se4 Single Crystal Thin Film by Hot Wall Epitaxy (Hot Wall Epitaxy(HWE)법에 의한 CdGa2Se4 단결정 박막 성장과 열처리 효과)

  • Hong, Myung-Seok;Hong, Kwang-Joon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.10
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    • pp.829-838
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    • 2007
  • The stochiometric mix of evaporating materials for the $CdGa_2Se_4$ single crystal thin films was prepared from horizontal furnace. To obtain the single crystal thin films, $CdGa_2Se_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperature were $630^{\circ}C$ and $420^{\circ}C$, respectively. The crystalline structure of single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD).The carrier density and mobility of $CdGa_2Se_4$ single crystal thin films measured from Hall effect by van der Pauw method are $8.27{\times}10^{17}\;cm^{-3},\;345\;cm^2/V{\cdot}s$ at 293 K. respectively. The temperature dependence of the energy band gap of the $CdGa_2Se_4$ obtained from the absorption spectra was well described by the Varshni's relation, $Eg(T)\;=\;2.6400\;eV\;-\;(7.721{\times}10^{-4}\;eV/K)T^2/(T+399\;K)$. After the as-grown single crystal $CdGa_2Se_4$ thin films were annealed in Cd-, Se-, and Ga -atmospheres, the origin of point defects of single crystal $CdGa_2Se_4$ thin films has been investigated by PL at 10 K. The native defects of $V_{Cd}$, $V_{Se}$, $Cd_{int}$, and $Se_{int}$ obtained by PL measurements were classified as donors or accepters. We concluded that the heat-treatment in the Cd-atmosphere converted single crystal $CdGa_2Se_4$ thin films to an optical p-type. Also, we confirmed that Ga in $CdGa_2Se_4/GaAs$ did not form the native defects because Ga in single crystal $CdGa_2Se_4$ thin films existed in the form of stable bonds.

Effect of Preparation Conditions of PAN-based Carbon Fibers on Electrochemical Characteristics of Rechargeable Lithium ion Battery Anode (PAN계 탄소섬유 제조조건에 따른 리튬이온 이차전지 음극의 전기화학적 특성)

  • An K. W.;Lee J. K.;Lee S. W.;Kim Y. D.;Cho W. I.;Ju J. B.;Cho B. W.;Park D. G.;Yun K. S.
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.81-87
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    • 1999
  • Poly-acrylonitrile (PAN) based carbon fibers were stabilized under various tensions in the presence of air at about $200^{\circ}C$ and sequentially carbonized under some different gas environments in the range of 700 to $1500^{\circ}C$. The prepared carbon fibers were used for rechargeable lithium ion battery anode to investigate preparation parameters effects on electrochemical characteristics. It was found that the tension during stabilization, carbonization temperature and gas atmospheres affect the carbon fiber properties such as conductivity, mechanical strength, surface morphology and diffusion coefficient of lithium ion, which are closely related to the on electrolchemical properties as well as the charge/discharge characteristics.

The Preparation of $TiO_2$ Coated Activated Carbon Pellets Driven by LED and Removal Characteristics of VOCs (LED구동 $TiO_2$ 코팅 활성탄소 펠렛 제조 및 VOCs 제거 특성)

  • Kim, Yesol;Kim, Do Young;Jung, Min-Jung;Kim, Min Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.314-319
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    • 2013
  • In this study, nitrogen doped $TiO_2$ ($N-TiO_2$) coated on an activated carbon pellet (ACP) was prepared using sol-gel and the solid state heat treatment of urea to improve the removal property of volatile organic compounds (VOCs). To explore the visible light photocatalytic activity of the ACP under the light emitting diods (LED), the removal property of benzene gas was characterized by gas chromatography. The SEM and BET results show that the increment of titanium tetra isopropoxide contents leads to the increased $TiO_2$ coating amount of ACP surface and decreased specific surface area. From the results of benzene gas removal, the breakthrough time of ACP10 increased about 2 times compared to that of the ACP. The improved performance was attributed to the $N-TiO_2$ coating on ACP surface, which could be more effective to remove benzene gas under the condition of LED lamp.

Preparation and Characterization of Anti-reflective and Anti-static Double Layered Films by Sol-Gel Spin-Coating Method (졸-겔 스핀코팅법에 의한 반사방지 및 정전기방지 복층막의 제조 및 특성)

  • 이준종;최세영
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.79-87
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    • 1997
  • Anti-reflective and anti-static double layered films were prepared on the VDT panel by sol-gel spin-coating method. Their electrical, opticla, and mechanical properties were investigated. The outer SiO2 film with low re-fractive index was coated over the inner ATO(Antimony-doped Tin Oxide)-SiO2 film which was prepared by mixing ATO sol with SiO2 at molar ratio of 68:32 to satisfy the interference condition of double layers. The heat treatment was conducted at 45$0^{\circ}C$ for 30 min where residual organics were completely removed. The sheet resistance of ATO single layer showed the minimum value of 6$\times$107$\Omega$/$\square$ at 3 mol% addition of Sb and that of SiO2/ATO-SiO2 increased slightly with increasing SiO2 mol% up to 30 mol%, and then increased steeply to the value of 3$\times$108$\Omega$/$\square$ at 32 mol%. The reflectance of double layered films was about 0.64% at the wavelength of 550nm and the transmittance increased about 3.20%. The hardness of double layered films was almost the same as that of uncoated VDT panel, 471.4kg.f/mm2.

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Fatigue Analysis for Electro-Mechanical Brake Caliper based on Eccentric Rotating Shaft (편심회전축 기반의 전기기계식 제동장치의 피로수명 해석)

  • Oh, Hyuck Keun;Beak, Seung-Koo;Jeon, Chang-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.9
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    • pp.596-603
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    • 2020
  • 'Electro-Mechanical Brake (EMB) is a novel braking system for automobiles and railway vehicles, and research in this area is actively underway. The current braking system for railway vehicles generates a braking force using a pneumatic cylinder, but the EMB system generates the force through a combination of an electric motor and gears. In this study, the design of an EMB system that meets the domestic standards was conducted through the finite element modeling and fatigue analysis of an eccentric rotating shaft-based EMB system capable of generating a high clamping force. At this time, to improve the accuracy of fatigue analysis, three types of fatigue test specimens, which were subjected to the same heat treatment as the materials used in the prototype, were produced, and the fatigue tests were performed for each material. The fatigue properties (S-N curves) were obtained from the fatigue test results for each material and reflected in the analysis model. The results of fatigue analysis confirmed that the design of the EMB prototype could satisfy the maximum commercial braking/relaxation of 530,000 times, which was the endurance life condition for domestic railway vehicles. In addition, based on this design, a prototype will be manufactured, and endurance testing will be completed to demonstrate the durability characteristics of the developed prototype.