• Corrosion Science and Technology
• /
• v.18 no.6
• /
• pp.267-276
• /
• 2019

The purpose of this study was to examine the influence of conditions for quenching and/or tempering on the corrosion and hydrogen diffusion behavior of ultra-strong automotive steel in terms of the localized plastic strain related to the dislocation density, and the precipitation of iron carbide. In this study, a range of analytical and experimental methods were deployed, such as field emission-scanning electron microscopy, electron back scatter diffraction, electrochemical permeation technique, slow-strain rate test (SSRT), and electrochemical polarization test. The results showed that the hydrogen diffusion parameters involving the diffusion kinetics and hydrogen solubility, obtained from the permeation experiment, could not be directly indicative of the resistance to hydrogen embrittlement (HE) occurring under the condition with low hydrogen concentration. The SSRT results showed that the partitioning process, leading to decrease in localized plastic strain and dislocation density in the sample, results in a high resistance to HE-induced by aqueous corrosion. Conversely, coarse iron carbide, precipitated during heat treatment, weakened the long-term corrosion resistance. This can also be a controlling factor for the development of ultra-strong steel with superior corrosion and HE resistance.

• Journal of the Korean Society for Heat Treatment
• /
• v.30 no.3
• /
• pp.117-126
• /
• 2017

The variation in microstructure and mechanical properties during heat treatment was examined in a series of 0.27% C-1.5% Mn-1.0% Cr steels with silicon contents in the range of 0 to 1.0 wt%. It was found that addition of 0.5%~1.0% silicon increased both tensile strength and impact toughness through solid solution strengthening and microstructural refinement. 0.27% C-1.0% Si-1.5% Mn-1.0% Cr steel showed tensile strength of 1,700 MPa in the as-quenched condition and the steel revealed a full martensitic structure even after air cooling from $900^{\circ}C$ to room temperature, showing air hardening characteristics. Tempering at $150^{\circ}C$ which corresponds to the typical paint-baking temperature after painting of body in white, slightly decreased the tensile strength and increased elongation, but substantially increased the impact toughness compared to the as-quenched steel.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.17 no.3
• /
• pp.102-108
• /
• 2018

The objective of this study is to develop the mechanical properties of an AlSiCu aluminum alloy using the two-step solution heat treatment. The microstructure of the gravity casting specimen represents a typical dendrite structure with a secondary dendrite arm spacing (SDAS) of 40 um. In addition to the Al matrix, a large amount of coarsen eutectic Si phase, $Al_2Cu$ intermetallic phase, and Fe-rich phases is generated. The eutectic Si phases are fragmented and globularized with the solution heat treatment. The $Al_2Cu$ intermetallic phase is also resolutionized into the Al matrix. The $2^{nd}$ solution temperature at $525^{\circ}C$ may be an optimal condition to enhance the mechanical properties of the AlSiCu aluminum alloy.

• Journal of Ocean Engineering and Technology
• /
• v.23 no.5
• /
• pp.79-84
• /
• 2009

Super duplex stainless steel has long life in severe environments by showing the enough strength and corrosion resistance. Therefore, the fracture mechanics approach needs to support the structural strength integrity for the used material. In this study, fatigue crack propagation behavior was investigated to super duplex stainless steel with 0.2% nitrogen. The various volume fraction and distribution of austenite structure for applied specimen in test were obtained by changing the heat treatment temperature and cycle. From test results, fatigue crack propagation rate showed two kinds of tendency between da/dN and ${\Delta}K$ according to distribution of austenite structure and structure anisotropy.

• YAKHAK HOEJI
• /
• v.56 no.3
• /
• pp.145-151
• /
• 2012

To develop fundamental data of herbal materials with heat treatment, we studied analytical and extraction methods of benzopyrene in black ginseng and validated by HPLC analysis. Benzopyrene was successfully separated in mobile phase of acetonitrile:water (80 : 20) and detection of excitation 294 nm, emission 404 nm. The calibration curve of benzopyrene was linear over the concentration range of 1.17~37.50 ng/ml with correlation coefficient of above 0.999. The limit of detection (LOD) and quantitation (LOQ) of benzopyrene was 0.25 and 0.75 ng/ml, respectively. Hexane extraction method was used as a new extraction method for benzopyren and the efficient of extraction was over 95%. In conclusion, analytical method and extraction method were suitable for the determination of benzopyrene in the black ginseng and could be applied to fundamental study and guideline of herbal materials with heat treatment.

• Journal of the Korean Society for Heat Treatment
• /
• v.13 no.5
• /
• pp.303-308
• /
• 2000

The ring gears of automobile parts are manufactured generally process chart of which is as follows : forging ${\rightarrow}$ annealing or normalizing ${\rightarrow}$ rough machining ${\rightarrow}$ hardening(Quenching-Tempering or carburizing process) ${\rightarrow}$ finish machining. Isothermal annealing process after forging is most effective in the side of improvment of machinability. On this study we selected two kinds of steel;SCM415, SCM435 of most universal and investigated microstructures to find out most suitable condition of heat treatment in proportion continuous cooling and isothermal annealing. As the cooling rate is $5^{\circ}C$ per minute in continuous cooling process, martensite and bainite are coexisted with ferrite and pearlite in SCM435 steel. If the cooling rate is slower than $5^{\circ}C$ per minute, microstructure were only ferrite and pearlite but formation of band structure can't be avoid. On the other hand, microstructure is only ferrite and pearlite regardless of cooling rate because carbon content of SCM415 steel is low. Moreover formation of band structure isn't exposed by faster cooling rate. Most optimal temperature of the isothermal annealing is from $650^{\circ}C$ to $680^{\circ}C$ in SCM435 steel. When holding time is 60 minute with $650^{\circ}C$, the identical ferrite and pearlite microstructures can be obtained.

• Journal of the Korean Society for Heat Treatment
• /
• v.30 no.5
• /
• pp.187-196
• /
• 2017

High temperature flow behaviors of AISI 4340 steel were investigated using isothermal compression tests under the temperature range from 850 to $1100^{\circ}C$ and a strain rate from 0.01 to $10s^{-1}$. The flow stress decreased with increasing compression temperature and decreasing strain rate. The dynamic softening related to the dynamic recrystallization was observed during hot deformation. The constitutive model based on Arrheniustyped equation with the Zener-Hollomon parameter was used to simulate the hot deformation behavior of AISI 4340 steel. The modification of the Zener-Hollomon parameter and lnA parameter resulted in the improvement of the calculation accuracy of the proposed constitutive model compared with the experimental flow curves. In addition, the process map of AISI 4340 steel was proposed. The instable process condition for hot deformation was predicted and its reliability was verified with the experimental observation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.07a
• /
• pp.218-221
• /
• 2000

Currently, Bi-2223 HTS tape is capable of being fabricated in longer than 100m length by industrial processes. But there are some problems in heat treatment of the degree of longer than 100m tape, which is in term of volume occupied with specimen in furnace. The effects of ceramic coating with variable slurry states were studied in Bi-2223 high-temperature superconductor. The HTS tapes coated with oxide were prepared by using dip-coating method on slurry state. Critical current(I$_{c}$) of tapes coated with ceramic materials were equal with 11.5A at 77K after first heat treatment as different slurries. For final heat treatment, Critical current of HTS tapes coated with zirconia oxide mixed in PMMA and PVA organic solute were 20.8A at 77K. The breakdown voltage of HTS tapes coated with zirconia oxide were 3kV in air and 4~7kV in L$N_2$.>.

• Journal of the Korean institute of surface engineering
• /
• v.55 no.4
• /
• pp.215-221
• /
• 2022

In the present work, copper oxide thin films were formed by heat-treatment method with different temperatures and atmosphere, e.g., at 200 ~ 400 ℃; in air and Ar atmosphere. The morphological, electrical and optical properties of the thermally fabricated Cu oxide films were analyzed by SEM, XRD, and UV-VIS spectrometer. Thereafter, photoelectrochemical properties of the thermal copper oxide films were analyzed under solar light (AM 1.5, 100 mW/cm²). Conclusively, the highest photocurrent was obtained with Cu₂O formed under the optimum annealing condition at 300 ℃ in air atmosphere. In addition, EIS results of Cu oxide formed in air atmosphere showed relatively low resistance and long electron life-time compared with Cu Oxide fabricated in Ar atmosphere at the same temperature. This is because heat-treatment in Ar atmosphere could not form Cu₂O due to lack of oxygen, and thermally formed CuO at high temperature suppressed stability and conductivity of the Cu oxide.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2005.05a
• /
• pp.277-277
• /
• 2005