• Title/Summary/Keyword: Heat of hydration Temperature

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Re-hydration of Heat-treated $CaO-SiO_2-H_2O$ System and Their Application under Hydrothermal Condition (열처리한 $CaO-SiO_2-H_2O$계의 수열반응과 이의 응용에 관한 연구)

  • 윤철현;송태웅
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1387-1395
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    • 1994
  • Re-hydration properties of heated and ground CaO-SiO2-H2O system were studied under hydrothermal condition in order to examine the possibility of recycling ALC waste as raw materials of ALC. Powder of calcium silicate hydrates and ALC waste without heat treatment did not show further hydration while those of heat-treated at proper temperature showed re-hydration properties under hydrothermal condition. The lath-like shape of initially synthesized tobermorite was gradually turned into small debris during heating and plate-like tobermorite was crystallized during re-hydration of the heated powders. Heated and ground ALC waste could be added to natural raw mix for ALC at the ammount up to 20% with increased compressive strength and up to 30% with slightly decreased compressive strength. The optimum heating temperature of ALC for recycling was about 50$0^{\circ}C$.

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Generation of Hydration Heat of the Concrete Combined Coarse Particle Cement and Blast Furnace Slag (조분 시멘트와 고로슬래그를 조합 사용한 콘크리트의 수화발열 특성)

  • Noh, Sang-Kyun;Baek, Dae-Hyun;Jang, Duk-Bae;Kim, Young-Pil;Cha, Wan-Ho;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.05a
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    • pp.61-65
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    • 2008
  • This study, having combined and displaced blast furnace slag("BS" hereinafter) known as admixture material that delays hydration reaction with coarse particle cement("CC" hereinafter) collected in particle classification method during ordinary portland cement("OPC" hereinafter), reviewed the hydration heat characteristics affecting the concrete. To reduce hydration heat, the study plain-mixed which used 100% OPC for W/B 50% level 1, displaced CC at level 3 of 25%, 50% and 75% for OPC, and by displacing BS with admixture material at level 5 of 0%, 20%, 40%, 60% and 80% for cement(OPC+CC), experimented totally 16 batches. As a result of experiment, in the case of flow, the more CC displacement rate increased, the more it tended to decrease, and the more BS displacement rate increased, the more it decreased. Also, as for simple adiabatic temperature rise by the CC and BS displacement rates, it decreased as displacement rate increased, and particularly in the case of displaced BS of 80%, It showed temperature reduction effect of about 63% companing with plain. Compressive strength decreased in proportion to displacement rate, however strength reduction increment was shown to decrease with age progress.

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Hydration Heat Properties of High Flowing Self-Compacting Concrete with Normal Strength (보통강도 고유동 자기충전 콘크리트의 수화발열 특성)

  • Choi, Yun-Wang;Kim, Byoung-Kwon;Lee, Jae-Nam;Ryu, Deug-Hyun;Song, Yong-Kyu;Jung, Woo-Yong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.497-500
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    • 2008
  • This research carries out experiments for hydration exothermic rate and adiabatic temperature rise of concrete to examine the characteristics of the hydration heat of high flowing self-compacting concrete with a normal strength. As a result of the hydration exothermic rate experiment, the high flowing self-compacting concrete that used Lime stone powder and fly ash as polymers shows that its hydration heat amount reduces due to the reduction of unit cement. The result measured the adiabatic temperature rise of concrete presents that high flowing self-compacting concrete having lots of binder contents has a good performance in temperature reduction due to the effect of polymer and that triple adding high flowing self-compacting concrete has a similar temperature rise speed with conventional concrete. As a result of the research, high flowing self-compacting concrete shows a better temperature reduction performance for the binder content per unit than conventional concrete. In addition, it is judged that triple adding high flowing self-compacting concrete with a specified concrete strength 30 MPa is more beneficial in temperature reduction and early hydration heat than double adding high flowing self-compacting concrete.

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Field Application of Mass Concrete Using Setting Time Difference of Super Retarding Agent for Reduction of Hydration Heat (초지연제의 응결시간차를 이용한 매스 콘크리트의 수화열 저감을 위한 현장 적용)

  • 전충근;심보길;손성운;신동안;오선교;한천구
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2004.05a
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    • pp.11-14
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    • 2004
  • In this paper, field application of mass concrete using setting time difference of super retarding agent is reported to reduce hydration heat of concrete placed at newly constructed apartment house in Busan. Horizontal placing lift is applied. According to test results. slump and air content meets the requirement of target values. For compressive strength, it exceeds the nominal strength ordered by the costumer. Compressive strength of concrete cured in place is achieved more than the values of nominal strength at l4days. For temperature history, maximum temperature of center at top section shows 58.5$^{\circ}C$, and at bottom section, 62.6$^{\circ}C$. According to naked eye's investigation, no hydration heat crack is observed at the surface of concrete.

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Field Application of Setting Time Difference Method Using SRA for Reduction of Hydration Heat of Mass Concrete (매스콘크리트의 수화열저감을 위한 초지연제 응결시간차 공법의 현장 적용 -대전 가오지구 코오롱 하늘채 아파트 현장-)

  • Jeon Chung-Keun;Kim Jong;Shin Dong-An;Yoon Gi-Won;Oh Seon-Gyo;Han Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.21-24
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    • 2005
  • In this paper, field application of mass concrete using setting time difference of super retarding agent is reported to reduce hydration heat of concrete placed at newly constructed apartment house in Daejeon. Horizontal placing lift is applied. According to test results,: slump and air content meets the requirement of target values. For compressive strength, it exceeds the nominal strength ordered by the costumer. For temperature history, maximum temperature of center at top section shows $25.6^{\circ}C$, and at bottom section, $35.4^{\circ}C$. According to naked eye's investigation, no hydration heat crack is observed at the surface of concrete.

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Hydration-heat Characteristics of Mortar mixed with Strontium Hydration-heat Reducing Material (스트론튬계 수화열저감재 혼입 모르타르의 수화발열 특성)

  • Kim, Goo-Hwan;Kim, Gyu-Yong;Lee, Sang-Kyu;Hwang, Eui-Chul;Kim, Gyeong-Tae;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.33-34
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    • 2018
  • As a result of measuring the compressive strength and semi-adiabatic temperature rise of the mixed mortar, it was confirmed that the mortar mixed with the hydration heat reducing material is effective. On the other hand, the compressive strength showed similar strength to that of moderate heat Portland cement until the age 7 days, but after that, the tendency of the strength development to be delayed was confirmed.

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Temperature development and cracking characteristics of high strength concrete slab at early age

  • Wu, Chung-Hao;Lin, Yu-Feng;Lin, Shu-Ken;Huang, Chung-Ho
    • Structural Engineering and Mechanics
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    • v.74 no.6
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    • pp.747-756
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    • 2020
  • High-strength concrete (HSC) generally is made with high amount of cement which may release large amount of hydration heat at early age. The hydration heat will increase the internal temperature of slab and may cause potential cracking. In this study, slab specimens with a dimension of 600 × 600 × 100 mm were cast with concrete incorporating silica fume for test. The thermistors were embedded in the slabs therein to investigate the interior temperature development. The test variables include water-to-binder ratio (0.25, 0.35, 0.40), the cement replacement ratio of silica fume (RSF; 5 %, 10 %, 15 %) and fly ash (RFA; 10 %, 20 %, 30 %). Test results show that reducing the W/B ratio of HSC will enhance the temperature of first heat peak by hydration. The increase of W/B decrease the appearance time of second heat peak, but increase the corresponding maximum temperature. Increase the RSF or decrease the RFA may decrease the appearance time of second heat peak and increase the maximum central temperature of slab. HSC slab with the range of W/B ratio of 0.25 to 0.40 may occur cracking within 4 hours after casting. Reducing W/B may lead to intensive cracking damage, such as more crack number, and larger crack width and length.

An Experimental Study on Hydration Heat Characteristics for Thermal Crack Analysis Based on FEM of Urea Mixed Mass Concrete (Urea 혼입 매스콘크리트의 FEM 온도균열 해석을 위한 수화발열특성에 관한 실험적 연구)

  • Mun, Dong-Hwan;Jang, Hyun-O;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.36-37
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    • 2019
  • In domestic construction industry progress, construction and quality control of large structures are considered to be important as the superstructure and mass scale of structures. In the case of mass concrete, high hydration heat caused by cement hydration generates temperature stress by generating internal temperature difference with the concrete surface. These temperature stresses cause cracks to penetrate the concrete structure. A method of lowering the heat generation by incorporating Urea in order to reduce the concrete temperature crack has been proposed. In this study, the heat function coefficient for the FEM temperature crack analysis of the mass concrete containing the element was derived and the adiabatic temperature rise test was carried out according to the incorporation of the element. As a result of this experiment, the maximum temperature of 41 ± 1℃ was obtained irrespective of the amount of urea, and the maximum temperature decreased by 16.9℃ in concrete containing 40kg/㎥ of urea.

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Properties of Autogenous Shrinkage according to Hydration Heat Velocity of High Strength Concrete Considering Mass Member (매스부재를 고려한 고강도콘크리트의 수화발열상승속도 조절에 따른 자기수축 특성)

  • Koo, Kyung-Mo;Kim, Gyu-Yong;Hong, Sung-Hyun;Nam, Jeong-Soo;Shin, Kyoung-Su;Khil, Bae-Su
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.4
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    • pp.369-376
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    • 2012
  • In this study, to reduce the hydration heat velocity (HHV) of high-strength mass concrete at early ages, phase change materials (PCM) that could absorb hydration heat were applied, and the changes in autogenous shrinkage were investigated, as well as the relationship between the hydration temperature and autogenous shrinkage. The acceleration of the cement hydration process by the PCM leads to an early setting and a higher development of the compressive strength and elastic modulus of concrete at very early ages. The function of PCM could be worked below the original melting point due to the eutectic effect, while the hydration temperature and HHV of high-strength mass concrete can be decreased through the use of the PCM. A close relationship was found between the hydration temperature and autogenous shrinkage: the higher the HHV, the greater the ultimate autogenous shrinkage.

A Study on Expedite Heat Transfer in Packed Bed of Hydration Calcined Dolomite for Chemical Heat Pump (소성 Dolomite 수화물 화학열펌프의 고체반응층 전열촉진 연구)

  • Kim, Jong-Shik;Lee, Han-Gyu;Park, Young-Hae
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.434-439
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    • 2005
  • The reaction of hydration proceeded at the same time the vapor was introduced into the reactor that was filled with calcined dolomite. It has shown that the temperature has begun to fall from the bottom of reactor after increase of temperature by the heat of hydration reaction. The reaction initiated at the pipe wall and the heat was transfer to the center of block between the fins. The results show that the use of copper fin in the reactor reducted the hydration reaction time by half when compared to the case without using the fins.