• Title/Summary/Keyword: Heat of adsorption

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A study on Blood pigments removal of butchery wastewater by heat processed Eggshell (Heat processed Eggshell에 의한 도축폐수의 혈색소 제거에 관한 연구)

  • 박경식
    • Journal of environmental and Sanitary engineering
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    • v.15 no.3
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    • pp.37-43
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    • 2000
  • The purpose of this experimental study examine characteristics of blood pigments removal of butchery wastewater by heat processed eggshell, compare activated carbon with its efficiency. Calcined eggshell were classified into four kinds of mesh as HPES-32(Heat Processed Eggshell 32 $mesh=500{\mu}m$), HPES-48($300{\mu}m$), HPES-150($180{\mu}m$) and HPES-150($106{\mu}m$). And two contacting process of CMFA(Complete Mixing Float Adsorption) and FLFA(Fixing layer Flow Adsorption) Were used for getting removal efficiency of blood pigments. In case of using CMFA process, the removal efficiency of blood pigments was occurred as HPES-80>HPES-150>HPES-32, but in case of using FLFA process was occurred as HPES-150>HPES-80>HPES-48>HPES-32. The two results between CMFA and FLFA were differ in strength of removal efficiency of blood pigments.

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Investigation of Optimum Condition of Heat Treatment and Flow to Improve H2S Adsorption Capacity for Practical use of an Activated Carbon Tower (활성탄 흡착탑의 실용화를 위한 최적 유동특성 선정 및 열처리 조건에 따른 황화수소 포집능 향상 연구)

  • Jang, Younghee;Kim, Bong-Hwan;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.91-96
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    • 2021
  • This study was conducted to improve the operating conditions of an adsorption tower filled with potassium impregnated activated carbon for high hydrogen sulfide capture capacity. Heat treatment modified the surface properties of activated carbon, and ultimately determined its adsorption capacity. The activated carbon doped with potassium showed 57 times more adsorption at room temperature than that of using the raw adsorbent. It is believed that uniform pore formation and strong bonding of the potassium on the surface of carbon contributed to the chemical and physical absorption of hydrogen sulfide. The SEM analysis on the surface structure of various commercial carbons showed that the modification of surface properties through the heat treatment generated the destruction of pore structures resulted in the decrease of the absorption performance. The pressure drop across the activated carbon bed was closely related with the grain size and shape. The optimum size of irregularly shaped activated carbon granules was 2~4 mesh indicating economical feasibility.

Effects of Saligenin Treatment on Acoustical Properties and Adsorption of Soundboard for Traditional Musical Instruments (전통악기 음향판용재의 살리게닌 처리가 음향성 및 흡습성에 미치는 영향)

  • Jung, Hee-Suk;Yoo, Tae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.3
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    • pp.7-16
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    • 1999
  • This research was carried out to compare structure, equilibrium moisture content(EMC), adsorption and acoustical properties between 4 retention levels of saligenin(o-hydroxybenzyl alcohol) treated, heat-treated and untreated chestnut(Castanea crenata S. et Z.) and paulownia(Paulownia spp.) woods. The cell structures of untreated wood and heat-treated wood were not different but the cell wall of saligenin treated wood was thicker than that of untreated wood for both species. EMC of untreated wood was the highest, next was that of heat-treated wood, and that of saligenin treated wood was the lowest, and among saligenin treated woods, EMC was decreased as retention level increased for both species. Adsorption curves were parabolically increased. Acoustical properties of saligenin treated wood were most improved, and the next were those of heat-treated wood. Comprehensive acoustical property was improved at retention level 20% and 30% for chestnut wood, and at retention level 80% for paulownia wood.

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Variation of Functional Characteristics of Illite with Heat Treatment (소결온도에 따른 일라이트 기능성 변화)

  • Kim, Ho-Soo;Kim, Han-Il;Seo, Pan-Seok;Koo, Kyung-Wan;Han, Sang-Ok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.117-121
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    • 2002
  • In this paper, the proper manufacturing method to the use of Illite with many application was studied. We confirmed merit of manufacturing and forming according as respective temperature. The variety of crystallization and surface was confirmed by X-ray diffraction(XRD) analysis and SEM. Then, we performed the experiments such as a antibiosis, a heavy metal adsorption and a gas deodorizaton to confirm the function of Illite. As a result, the adsorption of gas decreased according as the heat treatment of Illite, but the ability of antibiosis wasn't changed.

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A Study on the Adsorption of Uranium(VI) Ion Using Ion Exchange Resin (이온 교환수지를 이용한 우라늄(VI) 이온의 흡착에 관한 연구)

  • 강영식;김준태
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.114-122
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    • 2000
  • Several new ion exchange resins have been synthesized from chloromethyl styrene-1,4-divinylbenzine with 1%, 2%, 5% and 105-crosslink and macrocyclic ligands of cryptand type by interpolymerization method. The adsorption characteristics and the pH, time, solvents and concentration dependence of the adsorption of uranium ion by this resins were studied. The resins were very stable in both acidic and basic media and have good resistance to heat at $300^{\circ}C$. The uranium ion are not adsorbed on the resins below pH 3.0, but the power of adsorption of it increased rapidly above pH 4.0. The optimum equilibrium time for adsorption of uranium ion was two hours and adsorptive power decreased in proportion to crosslink size of the resins and order of dielectric constants of solvents used and the adsorption for uranium ion was bin the order of $OdienNtn-H_4$ > $OtnNen-H_4$ > $OtnNen-H_4$ > $OenNen-H_4$.

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Cycle Simulation of an Adsorption Chiller Using Silica Gel-water (실리카겔-물계 흡착식 냉동기 사이클 시뮬레이션)

  • Kwon, Oh-Kyung;Yun, Jae-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.2 s.257
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    • pp.116-124
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    • 2007
  • An adsorption chiller is expected to have high energy-efficiency in utilizing the waste heat exhausted from a process. The objective of this paper is to investigate the performance of silica gel-water adsorption chiller from the cycle simulation and to provide a guideline for design of the adsorption chiller. The effect of cycle time, inlet temperature and water flow rate on the cooling capacity and COP is quantified during the cycle operation. It is found that the performance of adsorption chiller is more sensitive to the change of inlet water temperature rather than the water flow rate. It is concluded that the COP is 0.57 in the standard conditions(hot water $80^{\circ}C$, cooling water $30^{\circ}C$, chilled water inlet temperatures $14^{\circ}C$ and cycle time 420sec).

Study on CO Adsorption on in-situ Brass Formed Cu/ZnO

  • Jung, Kwang-Deog;Joo, Oh-Shim
    • Bulletin of the Korean Chemical Society
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    • v.23 no.12
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    • pp.1765-1768
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    • 2002
  • The isotherms of CO adsorption on the Cu/ZnO sample treated with with hydrogen and methanol are investigated. The heats of adsorption of CO on the Cu/ZnO treated with hydrogen at 723K for 3 h are in the range from 25.7 kJ/mol at $\theta=0.8$ to 59.8 at $\theta=0.1$, while those on the Cu/ZnO sample treated with methanol at 523 K for 3 h are in the range 30.3 kJ/mol at $\theta=0.8$ to 99.8kJ/mol at $\theta=0.1.$ The Cu/ZnO samples treated with hydrogen do. The heats of adsorption at q=0.1 increase with the methanol treatment time within 30 min and leveled off afterwards.

Isotherm, Kinetic and Thermodynamic Characteristics for Adsorption of Acenaphthene onto Sylopute (실로퓨트에 의한 아세나프텐 흡착에 관한 등온흡착식, 동역학 및 열역학적 특성)

  • Cho, Da-Nim;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.127-134
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    • 2020
  • The adsorption characteristics of the major tar compound, acenaphthene, derived from Taxus chinensis by the commercial adsorbent Sylopute were investigated using different parameters such as initial acenaphthene concentration, adsorption temperature, and contact time. Out of Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models, adsorption data were best described by Langmuir isotherm. The adsorption kinetics was evaluated by pseudo-first-order, pseudo-second-order and intraparticle diffusion models. The pseudo-second-order model was found to explain the adsorption kinetics most effectively. Thermodynamic parameters revealed the feasibility, nonspontaneity and exothermic nature of adsorption. In addition, the isosteric heat of adsorption was independent of surface loading indicating the Sylopute used as an energetically homogeneous surface.

Adsorption and Thermostability of Antimicrobial compounds on Water-soluble Silica (수용성 Silica에 대한 항균성물질의 흡착 및 내열성)

  • 김현수;성림식;이인선
    • KSBB Journal
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    • v.17 no.4
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    • pp.345-349
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    • 2002
  • The adsorption of the antimicrobial compounds(AMCs) and their heat-resistance were investigated for the packaging film manufacture, wherein, the antimicrobial compounds were adsorbed on a silica component. The naturally source antimicrobial compounds were produced by methylotropic actinomycetes strains MO-16 and MO-17, extracted with ethylacetate. Antimicrobial compounds adsorbed on water-soluble silica had retained activity against Gram(+) and the Gram(-) bacteria after heat treatment at 150$\^{C}$ for 5min. The benzoic acid showed strong antimicrobial activity to fungi and was stable to heat treatment. The combination of antimicrobial compound plus benzoic acid was synergistic against test strains. Therefore, we estimated that the water-soluble silica is suitable for the packaging film manufacture as a adsorbent of the antimicrobial compounds.