• Title/Summary/Keyword: Heat discharge

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Electrochemical Performances of Acid-Treated and Pyrolyzed Cokes According to Acid Treatment Time (산처리 시간별 산화 코크스와 열분해 코크스의 전기화학적 거동)

  • Kim, Ick-Jun;Yang, Sunhye;Jeon, Min-Je;Moon, Seong-In;Kim, Hyun-Soo
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.407-412
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    • 2008
  • As an activation procedure, in this study, the oxidation treatment of needle cokes with a dilute nitric acid and sodium chlorate $(NaClO_3)$, combined with heat treatment, was attempted. The structures of acid-treated and pyrolyzed coke were examined with XRD, FESEM, elemental analyzer, BET, and Raman spectroscopy. The behavior of double layer capacitance was investigated with the analysis of charge and discharge. The structure of needle coke treated with acid was revealed to a single phase of (001) diffraction peak after 24 h. On the other hand, thecoke oxidized by heat treatment was reduced to a graphite structure of (002) at $300^{\circ}C$. The distorted graphene layer structure, derived from the process of oxidation and reduction of the inter-layer, makes the pores by the electric field activation at the first charge, and generates the double layer capacitance from the second charge. The cell using pyrolyzed coke with 24 h acid treatment and $300^{\circ}C$ heat treatment exhibited the maximum capacitance per weight and volume of 33 F/g and 30 F/mL at the two-electrode system in the potential range of 0~2.5 V.

An Experimental Study on the Freezing Protection Valve Using Phase Change Material(PCM) for the Heat Exchanger (상변화물질(PCM)을 이용한 열교환기용 동파방지밸브에 관한 실험적 연구)

  • Yun, Jea-Ho;Kim, Joung-Ha;Jeong, Soon-Young;Yang, Yoon-Sub;Kim, Seong-Hyun;Song, Duk-Yong
    • Journal of the Korean Solar Energy Society
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    • v.32 no.6
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    • pp.127-133
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    • 2012
  • This paper is an experimental study on the freezing protection valve used for solar water heating, air-conditioning systems, and plumbing systems. When the phase change occurs from liquid to solid, most of the substances except water volumetrically shrink. And referred to as PCM(Phase Change Material) a substance with such properties, the phase change temperature varies depending on the material. To prevent the freezing of the plumbing system, such as air-conditioning system in the winter season, we developed a several types of freezing protection valve using PCM whose freezing temperature are $2-4^{\circ}C$. The working principle of the freezing protection valve is that the fluid inside the pipe is released to prevent the system-collapse when fluid temperature reaches the freezing temperature of the PCM. And then the valve is closed and returned to the original position automatically when the temperature of the operating fluid rises. In this paper, the operating temperatures, discharge flow rate and the response characteristics of the valve during the operation are tested and investigated. From the results of this research the freezing protection valves employing PCM are expected to be commercialized in the near future.

Synthesis of Li4/3Mn5/3O4 by Sol-Gel Process and its Electrochemical Properties (졸-겔법에 의한 Li4/3Mn5/3O4의 합성 및 전기화학적 특성)

  • Lee, Jin-Sik;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.80-84
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    • 1999
  • $Li_{4/3}Mn_{5/3}O_4$ having a defect structure was prepared by sol-gel process using lithium acetate and manganese acetate as starting materials, and their electrode characteristics in the lithium secondary battery was investigated. The reaction mole ratio was determined as $AA/Mn(OAc)_2$ of 0.2 and $NH_4OH/Mn(OAc)_2$ to $H_2O/Mn(OAc)_2$ of 0.4. The product was obtained through heat treatment at $350^{\circ}C$ for 12hrs after 1'st heat treatment at $150^{\circ}C$ of xerogel under oxygen atmosphere. When the charge and discharge cycles were performed between 2.0 V and 3.2 V, $Li/Li_{4/3}Mn_{5/3}O_4$ cell showed the dicharge capacity of 84.23 mAh/g and the good cycleability was obtained in the plateau region.

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Inspection of Heat Exchanger Tubing Defects with Ultrasonic Guided Waves (유도초음파를 이용한 열 교환기 튜브 결함 탐상)

  • Shin, Hyeon-Jae;Rose, Joseph L.;Song, Sung-Jin
    • Journal of the Korean Society for Nondestructive Testing
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    • v.20 no.1
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    • pp.1-9
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    • 2000
  • This study shows the defect detection and sizing capability of ultrasonic guided waves in the nondestructive inspection of heat exchanger and steam generator tubing. Phase and group velocity dispersion curves for the longitudinal and flexural modes of a sample Inconel tube were presented for the theoretical analysis. EDM(Electric Discharge Machining) wears in tubing under a tube support plate and circumferential laser notches in tubing were detected by an axisymmetric and a non-axisymmetric transducer set up, respectively. EDM wears were detected with L(0, 2), L(0, 3) and L(0, 4) modes and among them L(0, 4) mode was found to be the most sensitive. It was also found that the flexural modes around L(0, 1) mode could be used for the detection and sizing of laser notches in the tubing.

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GaAs-Carbon Nanotubes Nanocomposite: Synthesis and Field-Emission Property (갈륨비소-탄소나노튜브 복합체 제작과 전계방출특성)

  • Lim, Hyun-Chul;Chandrasekar, P.V.;Chang, Dong-Mi;Ahn, Se-Yong;Jung, Hyuk;Kim, Do-Jin
    • Korean Journal of Materials Research
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    • v.20 no.4
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    • pp.199-203
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    • 2010
  • Hybridization of semiconductor materials with carbon nanotubes (CNTs) is a recent field of interest in which new nanodevice fabrication and applications are expected. In this work, nanowire type GaAs structures are synthesized on porous single-wall carbon nanotubes (SWCNTs) as templates using the molecular beam epitaxy (MBE) technique. The field emission properties of the as-synthesized products were investigated to suggest their potential applications as cold electron sources, as well. The SWCNT template was synthesized by the arc-discharge method. SWCNT samples were heat-treated at $400^{\circ}C$ under an $N_2/O_2$ atmosphere to remove amorphous carbon. After heat treatment, GaAs was grown on the SWCNT template. The growth conditions of the GaAs in the MBE system were set by changing the growth temperatures from $400^{\circ}C$ to $600^{\circ}C$. The morphology of the GaAs synthesized on the SWCNTs strongly depends on the substrate temperature. Namely, nano-crystalline beads of GaAs are formed on the CNTs under $500^{\circ}C$, while nanowire structures begin to form on the beads above $600^{\circ}C$. The crystal qualities of GaAs and SWCNT were examined by X-ray diffraction and Raman spectra. The field emission properties of the synthesized GaAs nanowires were also investigated and a low turn-on field of $2.0\;V/{\mu}m$ was achieved. But, the turn-on field was increased in the second and third measurements. It is thought that arsenic atoms were evaporated during the measurement of the field emission.

Performance of R1234yf and R1234yf/R134a Mixture under Mobile Air-conditioner Operating Conditions (R1234yf와 R1234yf/R134a의 자동차 에어컨 작동 조건에서의 성능 평가)

  • Park, Ki-Jung;Lee, Yo-Han;Choe, Dae-Seong;Jung, Dong-Soo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.12
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    • pp.837-844
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    • 2010
  • In this study, performance of R1234yf and R1234yf/R134a mixture is measured on a heat pump bench tester in an attempt to substitute R134a used widely in mobile air conditioners (MACs). The bench tester is equipped with a open type compressor providing a nominal capacity of 3.5 kW. All tests are conducted under the summer cooling and winter heating conditions of 7/4 $5^{\circ}C$ and $-7/41^{\circ}C$ in the evaporator and condenser, respectively. For R1234yf/R134a mixture, measurements are made at 5%, 10%, and 15% of R134a by mass. Test results show that the coefficient of performance (COP) and capacity of R1234yf are up to 2.7% and 4.0% lower than those of R134a, respectively. For R1234yf/R134a mixture, the COP and capacity are up to 3.9% lower and 3.6% higher than those of R134a. For R1234yf and R1234yf/R134a mixture, the compressor discharge temperature is $4.1{\sim}6.7^{\circ}C$ lower than that of R134a while the amount of charge is reduced up to 11% as compared to R134a. 90%R1234yf/10%R134a is a better refrigerant than pure R1234yf in that it is less flammable and more compatible with existing R134a system. Based upon the results, it is concluded that R1234yf and R1234yf/R134a mixture are long term environmentally friendly solutions to mobile air-conditioners due to their excellent environmental properties with acceptable performance.

A Study on Application of Radix Asari Main Blended Prescription From Dongeubogam (동의보감(東醫寶鑑) 중(中) 세신(細辛)이 주약(主藥)으로 배오(配伍)된 방제(方劑)의 활용(活用)에 대한 고찰(考察))

  • Jeon Ho-Cheol;Rho Euy-Joon;Kim Hyung-Rul;Yun Young-Gab
    • Herbal Formula Science
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    • v.12 no.2
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    • pp.57-76
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    • 2004
  • This report describes the remedial fields, symptoms, pathology, dosage, prescriptional constitution of 69 studies related to the use of Radix Asari main blended prescriptions from Dongeubogam. The following conclusions were reached through investigations on the prescriptions that use Radix Asari as a key ingredient. Radix Asari blended prescriptions are utilized for 14 therapeutic purposes, for example, in symptoms of tooth, eye, paralysis, ear-nose, skin infection and carbuncle. In particular, 14.49% of the prescriptions appear in the chapter of tooth, and 10.14% of those appear in the chapter of eye. Prescriptions that utilize Radix Asari as the main ingredient are used in the treatment of dental disease, othalmology, nose and ear disease, throat disease, common cold, dermothology, paralysis, musculoskeletal disease, disease of the head, asthma, genital disease, the injury of the cuts and they are also used for treating 50 different types of diseases. Radix Asari is used in Six pathogenic factors such as wind, wind-cold, wind-heat, wind-dampness heat, wind-dampness, dampness, paralysis, cold-chill, cold, dryness, in visceral pathogenic factors such as stomach, kidney, liver-kidney, liver and in chi-blood pathogenic factors such as chi-blood deficiency, chi-blood stagnation and in extravasated blood pathogenic factors such as impact injury, an injury such as cuts, blood accumulation as well as weakness-cold and parasites. The actual amount of Radix Asari blended has ranged at a wide variety of amounts from 2.5pun(about 0.94gram) to 3don(about 11.25gram). 26.09% of the prescriptions used 1don(about 3.75gram). The function of Radix Asari is to calm down, to get the consciousness back, to bore through, to warm up the meridians and to run it smoothly, to discharge of phlegm from the combination of drugs and prescriptions.

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Heat load characteristic analysis of conduction cooled 10kJ HTS SMES (전도 냉각형 10kJ 고온 초전도 에너지 저장장치의 열 부하 특성 해석)

  • Kim, Kwang-Min;Kim, A-Rong;Kim, Jin-Geun;Park, Hae-Yong;Park, Min-Won;Yu, In-Keun;Kim, Seok-Ho;Sim, Ki-Deok
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.2219_2220
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    • 2009
  • The characteristics of the Superconducting Magnetic Energy Storage (SMES) system are faster response, longer life time, more economical, and environment friendly than other Uninterruptible Power Supply (UPS) using battery. Fast charge and discharge time of SMES system can provide powerful performance of improving power quality in the grid. In order to demonstrate the effectiveness of SMES, the authors make a 10kJ SMES system for connection with RTDS (Real Time Digital Simulator). Because the characteristics of superconducting magnet are very important in SMES system, the necessary items such as thermal characteristic, mechanical stress and protection circuit should be considered. In this paper, the authors experimented thermal characteristics of the 10kJ SMES system. The experiment was accomplished using a simulation coils made of aluminium. It has same dimension of the 10kJ class HTS SMES coil. The coil was cooled with GM (Gifford -McMahon) cryocooler through the OFHC (Oxgen Free High thermal Conductivity) conduction bar. The test results of cool down and heat loads characteristics of the simulation coils are described in detail.

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Cooling CFD Analysis of a Car Batter Pack with Circular Cells (원통형 셀을 이용한 자동차용 배터리팩 냉각해석)

  • Shin, Hyun Jang;Lee, Joo Sung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.10
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    • pp.693-698
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    • 2017
  • The 18650 battery cell is known to be reliable and cost effective, but it has a design limitation and low electric capacity compared to pouch-type cells. Because its economy is superior, an 18650-cell-type battery pack is chosen. A reliable temperature is very important in automobile battery packs. Therefore, in this study, the temperature stability of the battery pack is predicted using CFD simulation. Following 3C discharge tests, the results for the heat generation of the battery cell are compared to the simulation results. Based on these results, a natural convection condition, forced convection condition, direct cell-cooling condition, cooling condition on the upper and lower surfaces of the battery pack, and cooling condition using air channels are all simulated. The results indicate that the efficiency and the performance of the air-channel-type cooling system is good.

Development and Application of a Computer Program for the Analysis of Heat Transfer and Fluid Flow of Water Body: Lake and Primary Clarifier (水體 熱流動 數値解析 프로그램 개발 및 응용 : 湖沼, 일차침전조)

  • 박병수;김경미
    • Water for future
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    • v.29 no.6
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    • pp.141-154
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    • 1996
  • A computer program is developed in order to investigate the fluid flow and heat ransfer of a water body in a 2-D vertical rectangular coordinate. The specific purpose of this study is to obtain a physical insight of several fluid flow problems which occur in a lake and the water and wastewater treatment facility like a primary clarifier. The performance of computer program developed is successfully evaluated by the comparison of other two experimental and computational data in open literature : the first comparison is made against the numerical data associated with the cooling water discharge and the other is numerical and experimental works for the primary clarifier of Sarina City at Ontario. Further, the computer program is applied to investigate the feature of lake flow, say lake turnover, and 2-D vertical channel flow in terms of temperature, wind velocity and flow rate, etc. The computational results appear to be physically acceptable and consistent. The computer program developed in this study shows the possibility of the viable tool to figure out the flow characteristics of water reservoir.

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