• Korean Journal of Materials Research
• /
• v.10 no.6
• /
• pp.437-444
• /
• 2000

We investigated the effect of substrate temperature, chemical composition and post-deposition heat-treatment on the crystal structure and electrical transport of $La_{1-x}Sr_xMnO_{3-{\delta}}$(0.19${\leq}x{\leq}$0.31) thin films. As-prepared $La_{1-x}Sr_xMnO_{3-{\delta}}$ films grown at $500^{\circ}C$ by sputter techniques were found to have the pseudo-tetragonal system(a/c=0.97) and a highly preferential <001> orientation. The films were changed to be of the cubic system by post-deposition annealing at around $900^{\circ}C$. A main target of $La_{0.67}Sr_{0.33}MnO_3$ as well as auxliary targets of $La_{0.3}Sr_{0.7}MnO_3$ ceramics were co-sputtered to control the chemical composition of the film. The Sr content(x) of the film ranged from 0.19 to 0.31, depending on the number of the auxiliary target. When x increased from 0.19 to 0.31, the electrical resistivity of the film decreased and the transition temperature between metal and semiconductor shifted to higher temperature. With a magnetic field of 0.18 T, the magneto-resistance ratio (MR(%) = (${\rho}_o-{\rho}_H/{\rho}_H$) of the $La_{0.69}Sr_{0.31}MnO_3$ thin film was about 390%.

• Korean Chemical Engineering Research
• /
• v.46 no.3
• /
• pp.451-464
• /
• 2008

Three-phase inverse fluidized bed has been widely adopted with its increasing demand in the fields of bioreactor, fermentation process, wastewater treatment process, absorption and adsorption processes, where the fluidized or suspended particles are small or lower density comparing with that of continuous liquid phase, since the particles are frequently substrate, contacting medium or catalyst carrier. However, there has been little attention on the three-phase inverse fluidized beds even on the hydrodynamics. Needless to say, the information on the hydrodynamics and transport phenomena such as heat and mass transfer in the inverse fluidized beds has been essential for the operation, design and scale-up of various reactors and processes which are employing the three-phase inverse beds. In the present article, thus, the information on the three-phase inverse fluidized beds has been summarized and reorganized to suggest a pre-requisite knowledge for the field work in a sense of engineering point of view. The article is composed of three parts; hydrodynamics, heat and mass transfer characteristics of three-phase inverse fluidized beds. Effects of operating variables on the phase holdup, bubble properties and particle fluctuating frequency and dispersion were discussed in the section of hydrodynamics; effects of operating variables on the heat transfer coefficient and on the heat transfer model were discussed in the section of heat transfer characteristics ; and in the section of mass transfer characteristics, effects of operating variables on the liquid axial dispersion and volumetric liquid phase mass transfer coefficient were examined. In each section, correlations to predict the hydrodynamic characteristics such as minimum fluidization velocity, phase holdup, bubble properties and particle fluctuating frequency and dispersion and heat and mass transfer coefficients were suggested. And finally suggestions have been made for the future study for the application of three-phase inverse fluidized bed in several available fields to meet the increasing demands of this system.

• Journal of the Korean Society of Combustion
• /
• v.21 no.1
• /
• pp.38-45
• /
• 2016

Flame characteristics and NO emission behavior in $CH_4$/air-air premixed counterflow flames with applying FIR and FGR with $CO_2$ and $H_2O$ were investigated numerically by varying the ratios of FIR and FGR as well as global strain rate. Chemical effects of added $CO_2$ and $H_2O$ via FIR and FGR were analyzed through comparing flame characteristics and NO behaviors from real species($CO_2$ and $H_2O$) with those from their artificial species($XCO_2$ and $XH_2O$) which have the same thermochemical, radiative, and transport properties to those for the real species. The results showed that flame temperature and NO emission with FIR varied much more sensitively than that with FGR. Those varied little irrespective of adding $CO_2$, $H_2O$, and their artificial species to the fuel stream via FIR. However, Those were varied complicatedly by chemical effects of added $CO_2$ and $H_2O$ via FGR. Detailed analyses for them were made and discussed.

• Proceedings of the Korea Association of Crystal Growth Conference
• /
• 1996.06b
• /
• pp.285-309
• /
• 1996

Non oxide ceramics such as nitrides of transition metals have shown significant potential for future economic impact, in diverse applications in ceramic, aerospace and electronic industries, as refractory products, abrasives and cutting tools, aircraft components, and semi-conductor substrates amid others. Combustion synthesis has become an attractive alternative to the conventional furnace technology to produce these materials cheaply, faster and at a higher level of purity. However he process os highly exothermic and manifests complex dynamics due to its strongly non-linear nature. In order to develop an understanding of this process and to study the effect of operational parameters on the final outcome, numerical modeling is necessary, which would generated essential knowledge to help scale-up the process. the model is based on a system of parabolic-hyperbolic partial differential equations representing the heat, mass and momentum conservation relations. The model also takes into account structural change due to sintering and volumetric expansion, and their effect on the transport properties of the system. The solutions of these equations exhibit steep moving spatial gradients in the form of reaction fronts, propagating in space with variable velocity, which gives rise to varying time scales. To cope with the possibility of extremely abrupt changes in the values of the solution over very short distances, adaptive mesh techniques can be applied to resolve the high activity regions by ordering grid points in appropriate places. To avoid a control volume formulation of the solution of partial differential equations, a simple orthogonal, adaptive-mesh technique is employed. This involves separate adaptation in the x and y directions. Through simple analysis and numerical examples, the adaptive mesh is shown to give significant increase in accuracy in the computations.

• BMB Reports
• /
• v.55 no.10
• /
• pp.488-493
• /
• 2022

The specific pair of heat shock protein 70 (Hsp70) and Hsp40 constitutes an essential molecular chaperone system involved in numerous cellular processes, including the proper folding/refolding and transport of proteins. Hsp40 family members are characterized by the presence of a conserved J-domain (JD) that functions as a co-chaperone of Hsp70. Tumorous imaginal disc 1 (Tid1) is a tumor suppressor protein belonging to the DNAJA3 subfamily of Hsp40 and functions as a co-chaperone of the mitochondrial Hsp70, mortalin. In this work, we performed nuclear magnetic resonance spectroscopy to determine the solution structure of JD and its interaction with the glycine/phenylalanine-rich region (GF-motif) of human Tid1. Notably, Tid1-JD, whose conformation was consistent with that of the DNAJB1 JD, appeared to stably interact with its subsequent GF-motif region. Collectively with our sequence analysis, the present results demonstrate that the functional and regulatory mode of Tid1 resembles that of the DNAJB1 subfamily members rather than DNAJA1 or DNAJA2 subfamily proteins. Therefore, it is suggested that an allosteric interaction between mortalin and Tid1 is involved in the mitochondrial Hsp70/Hsp40 chaperone system.

• Nuclear Engineering and Technology
• /
• v.17 no.4
• /
• pp.290-301
• /
• 1985

600MW(e) CANDU Primary Heat Transport System (PHTS) is composed of the two “figure-of-eight” loops and is designed to operate with the 4% Reactor Outlet Header (ROH) quality at its rated power. This existence of the two compressible regions and the positive flow-qualitly-void feedbacks are the sources of the PHTS flow instability. To ensure the PHTS stability, ROH-ROH interconnect pipes are installed as passive systems. This paper describes the investigation of the PHTS flow instability at its design full power condition. Also studied are the interconnect effect and the inherent system damping effect on the system stability. The time domain stability analyses are accessed by using the ATHER/MOD-I code which is the improved version of the KAERI developed ATHER code. Under the most adverse system modelling, the “figure-of-eight” symmetric loop shows divergent flow oscillations. Under with the interconnect, the PHTS stability is remarkably enhanced so that the system becomes stable. However, even under the conservative pressurizer modelling, the PHTS shows the more convergent flow oscillations. With the interconnect and the pressurizer modelling, its stability is highly credited. Conclusively, the inherent system damping by pressurizer itself can credit the PHTS stability without the interconnect.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2004.06a
• /
• pp.268-277
• /
• 2004

process (ACP), electrochemical properties of high heat-generating alkali and alkali earth oxides in molten salt were measured and the behavior of those elements were analyzed. The reduction potentials of Cs, Sr, and Ba in a molten LiCl-$Li_2O$ system were more cathodic than that of Li and closely located one another. Thus, it is expected that the alkali and alkali earth would not hinder the reaction mechanism which is via lithium reduction. Alkali and alkali earth metals are likely to recycle into molten salt when the process is operated beyond metal reduction potentials and the effect of electric current on the mass transport is also determined by measuring the metal concentrations in the molten salt phase at different current conditions.

• Journal of The Korean Society of Grassland and Forage Science
• /
• v.36 no.3
• /
• pp.237-242
• /
• 2016

Copper (Cu) is a necessary microelement for plants. However, high concentrations of Cu are toxic to plants that change the regulation of several stress-induced proteins. In this study, an annealing control primer (ACP) based approach was used to identify differentially expressed Cu-induced genes in alfalfa leaves. Two-week-old alfalfa plants (Medicago sativa L.) were exposed to Cu for 6 h. Total RNAs were isolated from treated and control leaves followed by ACP-based PCR technique. Using GeneFishing ACPs, we obtained several genes those expression levels were induced by Cu. Finally, we identified several genes including UDP-glucuronic acid decarboxylase, transmembrane protein, small heat shock protein, C-type cytochrome biogenesis protein, mitochondrial 2-oxoglutarate, and trans-2,3-enoyl-CoA reductase in alfalfa leaves. These identified genes have putative functions in cellular processes such as cell wall structural rearrangements, transduction, stress tolerance, heme transport, carbon and nitrogen assimilation, and lipid biosynthesis. Response of Cu-induced genes and their identification in alfalfa would be useful for molecular breeding to improve alfalfa with tolerance to heavy metals.

• Transactions of the Korean Society of Pressure Vessels and Piping
• /
• v.12 no.1
• /
• pp.126-133
• /
• 2016

Recently, the research and development of Sodium-cooled Fast Reactors (SFRs) have made progresses. However, liquid sodium, the coolant of an SFR, is chemically unstable and sodium fire can be occurred when liquid sodium leaks from sodium pipe. To reduce the damage by the sodium fire, many fire walls and fire extinguishers are needed for SFRs. LBB concept in SFR might reduce the scale of sodium fire and decrease or eliminate fire walls and fire extinguishers. Therefore, LBB concept can contribute to improve economic efficiency and to strengthen defense-in depth safety. The LBB assessment procedure has been well established, and has been used significantly in light water reactors (LWRs). However, an LBB assessment of an SFR is more complicated because SFRs are operated in elevated temperature regions. In such a region, because creep damage may occur in a material, thereby growing defects, an LBB assessment of an SFR should consider elevated temperature effects. The procedure and method for this purpose are provided in RCC-MRx A16, which is a French code. In this study, LBB assessment was performed for PGSFR IHTS hot-leg pipe according to RCC-MRx A16 and the applicability of the code was discussed.

• Journal of Energy Engineering
• /
• v.24 no.2
• /
• pp.40-44
• /
• 2015

Sensitivity on the reactor safety was evaluated for the safety margin and time delay applied to the opening pressure of liquid relief valve(LRV) of the primary heat transport system(PHTS) in the pressurized heavy water reactor(PHWR) type nuclear power plant. Since the LRV is the pressure boundary for the PHTS in the safety analysis, the operating of LRV has a significant effect on the safety analysis results. Therefore it is required during the regulatory review of Wolsong Unit 1 safety analysis to find the safety effect of the application of safety margin and time delay to the LRV opening pressure for the safety analysis of PHTS pressurizing events.