• Nuclear Engineering and Technology
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• v.43 no.6
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• pp.583-592
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• 2011

The radiological characteristics for waste classification were assessed for neutron-activated decommissioning wastes from a CANDU reactor. The MCNP/ORIGEN2 code system was used for the source term analysis. The neutron flux and activation cross-section library for each structural component generated by MCNP simulation were used in the radionuclide buildup calculation in ORIGEN2. The specific activities of the relevant radionuclides in the activated metal waste were compared with the specified limits of the specific activities listed in the Korean standard and 10 CFR 61. The time-average full-core model of Wolsong Unit 1 was used as the neutron source for activation of in-core and ex-core structural components. The approximated levels of the neutron flux and cross-section, irradiated fuel composition, and a geometry simplification revealing good reliability in a previous study were used in the source term calculation as well. The results revealed the radioactivity, decay heat, hazard index, mass, and solid volume for the activated decommissioning waste to be $1.04{\times}10^{16}$ Bq, $2.09{\times}10^3$ W, $5.31{\times}10^{14}\;m^3$-water, $4.69{\times}10^5$ kg, and $7.38{\times}10^1\;m^3$, respectively. According to both Korean and US standards, the activated waste of the pressure tubes, calandria tubes, reactivity devices, and reactivity device supporters was greater than Class C, which should be disposed of in a deep geological disposal repository, whereas the side structural components were classified as low- and intermediate-level waste, which can be disposed of in a land disposal repository. Finally, this study confirmed that, regardless of the cooling time of the waste, 15% of the decommissioning waste cannot be disposed of in a land disposal repository. It is expected that the source terms and waste classification evaluated through this study can be widely used to establish a decommissioning/disposal strategy and fuel cycle analysis for CANDU reactors.

• Korean Journal of Materials Research
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• v.8 no.4
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• pp.299-303
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• 1998

We examined, using thermoanalytical methods, the effects of $2000^{\circ}C$ heat-treated graphite powders and heating rate of cure after impregnation on the thermal stability and carbon yield of furfuryl alcohol, which is frequently used not only as an impregnant but also as a matrix precursor for carbon fiber-reinforced carbon composites. It was founded that the addition of 30wt% graphite powders to furfuryl alcohol and the heating rate of $35^{\circ}C$/min showed the highest thermal stability of furfuryl alcohol/graphite powder mixture. The carbon yield above $1000^{\circ}C$ was enhanced more than 10% in comparison with the absence of graphite powders. It would be expected that this result can contribute to some extent to reduce the repeating number of processing cycle (carbonization-impregnation-cure-re-carbonization) required to densify a carbonaceous composite.

• Journal of the Korean Electrochemical Society
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• v.22 no.4
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• pp.172-176
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• 2019

The first commercialized cathode material, $LiCoO_2$, suffers from disadvantages such as high cost and toxicity and also possesses safety problems. The nickel-rich $LiNi_{0.9}Mn_{0.1}O_2$ cathode material, used as an alternative to $LiCoO_2$, has highly reversible capacity and high energy density. So, the nickel-rich $LiNi_{0.9}Mn_{0.1}O_2$ cathode material is widely used as an alternative to $LiCoO_2$ due to its highly reversible capacity and high energy density. However, $LiNi_{0.9}Mn_{0.1}O_2$ has several disadvantages as well, such as poor cycle performance and poor thermal instability. To address these problems, we synthesized a new material, $LiNi_{0.5}Mn_{0.5}O_2$, as a shell on the surface of a core to suppress the surface degradation. The new material showed high structural and thermal stabilities and could also maintain a high capacity. The capacity retention of the core-shell cathode (87.7%) was better than that of the core cathode (76.9%) after 50 cycles. Analysis using differential scanning calorimetry revealed that the heat generation in the core-shell cathode ($65.9Jg^{-1}$) was lower than that in the core cathode ($559.7Jg^{-1}$).

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.115-121
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• 2008

A core engine for pre-cooled turbojet engines is designed and its component performances are examined both by CFD analyses and experiments. The engine is designed for a flight demonstration of precooled turbojet engine cycle. The engine uses gas hydrogen as fuel. The external boundary including measurement devices is set within $23cm{\times}23cm$ of rectangular cross section, in order to install the engine downstream of the air intake. The rotation speed is 80000 rpm at design point. Mixed flow compressor is selected to attain high pressure ratio and small diameter by single stage. Reverse type main combustor is selected to reduce the engine diameter and the rotating shaft length. The temperature at main combustor is determined by the temperature limit of non-cooled turbine. High loading turbine is designed to attain high pressure ratio by single stage. The firing test of the core engine is conducted using components of small pre-cooled turbojet engine. Gas hydrogen is injected into the main burner and hot gas is generated to drive the turbine. Air flow rate of the compressor can be modulated by a variable geometry exhaust nozzle, which is connected downstream of the core engine. As a result, 75% rotation speed is attained without hazardous vibration and heat damage. Aerodynamic performances of both compressor and turbine are obtained and evaluated independently.

• The Journal of the Petrological Society of Korea
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• v.1 no.2
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• pp.91-103
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• 1992

Eruptive mechanisms and processes at Udo tuff cone can be inferred from indicative characters of products, bedforms and lithofacies, and ring faults. In terms of bedforms and lithofa-cies in particular, massive lapilli tuff beds and chaotic lapilli tuff beds are derived from subaerial falls of aggregated tephra of wet tephra finger jets, occurring dominantly at the lower sequences of proximal part at the tuff cone. Crudely stratified lapilli tuff are derived from subaerial falls of slightly aggregated tephra of less wet tephra finger jets, whereas reversely graded lapilli tuff beds are from slightly disaggregated subaerial falls of continuous uprush. Both beds frequently occur in the middle sequences at proximal and near medial part of the tuff cone. Block and lapilli tephra lenses, ash-coated lapilli tephra beds(lenses) and thin-bedded tuff beds are derived from extremely disaggregated subaerial falls of dry tephra in the continuous uprush, frequently occurring at the upper sequences of medial part at the tuff cone. Udo tuff cone is a basaltic volcano emergent through the sea water surface while water could flood across or into the vent area. Emergence of the tuff cone was from the type-Surtseyan eruption characterized by earlier tephra finger jets and later continuous uprush columns of tephra with copious volumes of steam. Explosions began when boiling of wter produced a bubble column reducing the hydrostatic pres-sure, allowing exsolution of gases from the magma. This expansion of magma into a vesiculating froth fragmented the magma and permitted mixing of magma and water so that a more vigorous generation of steam could proceed. Tephra finger jetting explosions continued to build the crater rims, then remove water from the vent that their deposits flowed like slsurries until the continuous uprush explosion ensued. Continuous uprush explosions were associated with most rapid accumula-tion of tephra. The increasing volume rate led to partial removal of water from the vent area by the newly tephra ring so that more vigorous activity could be attended by a reducing water supply. This might restrain surplus of cold water entering the vent and thus enhance the vigour of the eruption by allowing optimal heat exchange. Eventually the crater became so deep and unsuported that piecemeal sliding, or massive subsidence on indipping ring faults, filled and closed the vent, and the cycle of explosions and collapse began anew.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.20 no.12
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• pp.113-122
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• 2021

Complicated residual stress distributions occur in the vicinity of a deposited region via directed energy deposition (DED) process owing to the rapid heating and cooling cycle of the deposited region and the substrate. The residual stress can cause defects and premature failure in the vicinity of the deposited region. Several heat treatment technologies have been extensively researched and applied on the part deposited by the DED process to relieve the residual stress. The aim of this study was to investigate the residual stress characteristics of a specimen fabricated by DED and a quenching process using thermomechanical analyses. A coupled thermomechanical analysis technique was adopted to predict the residual stress distribution in the vicinity of the deposited region subsequent to the quenching step. The results of the finite element (FE) analyses for the deposition and the cooling measures show that the residual stress in the vicinity of the deposited region significantly increases after the completion of the elastic recovery. The results of the FE analyses for the heating and quenching stages further indicate that the residual stress in the vicinity of the deposited region remarkably increases at the initial stage of quenching. In addition, it is observed that the residual stress for quenching is lesser than that after the elastic recovery, irrespective of the deposited material.

• Journal of Climate Change Research
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• v.7 no.4
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• pp.433-442
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• 2016

In this study, we examine future changes in surface radiation associated with cloud amount and aerosol emission over East Asia. Data in this study is HadGEM2-CC (Hadley Centre Global Environmental Model version 2, Carbon Cycle) simulations of the Representative Concentration Pathways (RCPs) 2.6/4.5/8.5. Results show that temperature and precipitation increase with rising of the atmosphere $CO_2$. At the end of $21^{st}$ century (2070~2099) relative to the end of $20^{st}$ century (1981~2005), changes in temperature and precipitation rate are expected to increase by $+1.85^{\circ}C/+6.6%$ for RCP2.6, $+3.09^{\circ}C/+8.5%$ for RCP4.5, $+5.49^{\circ}C/10%$ for RCP8.5. The warming results from increasing Net Down Surface Long Wave Radiation Flux (LW) and Net Down Surface Short Wave Radiation Flux (SW) as well. SW change increases mainly from reduced total Aerosol Optical Depth (AOD) and low-level cloud amount. LW change is associated with increasing of atmospheric $CO_2$ and total cloud amount, since increasing cloud amounts are related to absorb LW radiation and remit the energy toward the surface. The enhancement of precipitation is attributed by increasing of high-level cloud amount. Such climate conditions are favorable for vegetation growth and extension. Expansion of C3 grass and shrub is distinct over East Asia, inducing large latent heat flux increment.

• Korean Chemical Engineering Research
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• v.57 no.5
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• pp.672-678
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• 2019

The electrochemical properties of pitch-coated natural graphite(NG) were investigated as an anode for lithium-ion batteries. The anode materials were prepared by heat-treatment of mixture of NG and petroleum pitch at $1000^{\circ}C$. The pitches with various softening points were used as carbon precursor. The physical properties of anode materials were analyzed by TGA, SEM, PSA and BET. As the softening point increased, the thickness of the coating layer increased and the specific surface area decreased. The electrochemical performances were investigated by initial charge/discharge efficiency, cycle stability, cyclic voltammetry, rate performance and electrochemical impedance spectroscopy. The carbon-coated NG using pitch with softening points of $250^{\circ}C$ showed an initial discharge capacity of 361 mAh/g and a coulombic efficiency of 92.6%. Also, the rate performance(5 C/0.2 C) was 1.6 times higher than that of NG, and it had a capacity retention (90%) after 50 cycles at 0.5 C.

• Plant Journal
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• v.14 no.4
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• pp.48-54
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• 2018

As the emission limits for NOx in power generation facilities were strengthened, HRSGs installed in the 1990s became necessary to install additional DeNOx system. However, since there is no space in the HRSG for installing the entire the catalyst and ammonia injection grid, as an alternative, the catalyst was installed inside of the HRSG and the ammonia injection device was installed in the exhaust duct of the gas turbine. Experiments were conducted in horizontal HRSG of Incheon combined cycle power plant. Experimental results show that the ammonia injection method in the gas turbine exhaust duct is 1.2 times higher than the HRSG internal ammonia injection method. However when operating a HRSG for 30 years as its life span, ammonia injection method in the gas turbine exhaust duct is more economical than the cost of new HRSG construction.

• Journal of the Korean Electrochemical Society
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• v.24 no.3
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• pp.42-51
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• 2021

Dissociation into Lithium-polysulfide electrolyte due to repeated cycles during the Lithium/Sulfur battery reaction is a major problem of reduced battery lifespan. We searched for a porous carbon with a large specific surface area that infiltrated S to prevent liquid Lithium-polysulfide from being dissolved in electrolyte, induce adsorption of Lithium-polysulfide, and further increase conductivity. In order to obtain porous carbon spheres with a large specific surface area, the carbon spheres of 1939 m²/g were raised to 2200 m²/g through additional KOH treatment. In addition, through heat treatment with S, a carbon sulfur compound containing 75 wt% of S was fabricate and material analysis was conducted on the possibility of using the cathode material. The electrochemical characteristics of the Reference (622; sulfur: 60%, conductive material: 20%, binder: 20%) pouch cell and the pouch cell made using 75wt% of carbon sulfur compound were analyzed. 75wt% of carbon sulfur pouch cell showed a 20% increase in lifespan and 10% improvement in C-rate compared to the Reference pouch cell after 50 cycles.