• Title/Summary/Keyword: Hazardous Gas

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Influence of Mixture Non-uniformity on Methane Explosion Characteristics in a Horizontal Duct (수평 배관의 메탄 폭발특성에 있어서 불균일성 혼합기의 영향)

  • Ou-Sup Han;Yi-Rac Choi;HyeongHk Kim;JinHo Lim
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.27-35
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    • 2024
  • Fuel gases such as methane and propane are used in explosion hazardous area of domestic plants and can form non-uniform mixtures with the influence of process conditions due to leakage. The fire-explosion risk assessment using literature data measured under uniform mixtures, damage prediction can be obtained the different results from actual explosion accidents by gas leaks. An explosion characteristics such as explosion pressure and flame velocity of non-uniform gas mixtures with concentration change similar to that of facility leak were examined. The experiments were conducted in a closed 0.82 m long stainless steel duct with observation recorded by color high speed camera and piezo pressure sensor. Also we proposed the quantification method of non-uniform mixtures from a regression analysis model on the change of concentration difference with time in explosion duct. For the non-uniform condition of this study, the area of flame surface enlarged with increasing the concentration non-uniform in the flame propagation of methane and was similar to the wrinkled flame structure existing in a turbulent flame. The time to peak pressure of methane decreased as the non-uniform increased and the explosion pressure increased with increasing the non-uniform. The ranges of KG (Deflagration index) of methane with the concentration non-uniform were 1.30 to 1.58 [MPa·m/s] and the increase rate of KG was 17.7% in methane with changing from uniform to non-uniform.

Identification of Quaternary Faults and shallow gas pockets through high-resolution reprocessing in the East Sea, Korea (탄성파 자료 고해상도 재처리를 통한 동해해역의 제4기 단층 및 천부 가스 인지)

  • Jeong, Mi Suk;Kim, Gi Yeong;Heo, Sik;Kim, Han Jun
    • Journal of the Korean Geophysical Society
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    • v.2 no.1
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    • pp.39-44
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    • 1999
  • High-resolution images are drawn from existing seismic data which were originally obtained by Korea Ocean Research & Development Institute (KORDI) during 1994-1997 for deep seismic studies on the East Sea of Korea. These images are analyzed for mapping Quaternary faults and near-bottom gas pockets. First 12 channels are selected from shot gathers for reprocessing. The processing sequence adopted for high-resolution seismic images comprises data copy, trace editing, true amplitude recovery, common-midpoint sorting, initial muting, prestack deconvolution, bandpass filtering, stacking, highpass filtering, poststack deconvolution, f-x migration, and automatic gain control (AGC). Among these processing steps, predictive deconvolution, highpass filtering, and short window AGC are the most significant in enhancement of resolution. More than 200 Quaternanry faults are interpreted on the migrated sections in the shallow depths beneath the seafloor. Although numerous faults are found mostly at the western continental slope and boundaries of the Ulleung Basin, significant amount of the faults are also indicated within the basin. Many of these faults are believed to be formed with reactivation of basement, from geotectonic activities including volcanism, and often originated in Tertiary, indicating that the tectonic regime of the East Sea might be unstable. Existence of shallow gas pockets casts real hazardous warnings to deep-sea drillings and/or to underwater constructions such as inter-island cables and gas pipelines. On the other hand, discovery of these gas pockets heightens the interests in developing natural resources in the East Sea. Reprocessed seismic sections, however, show no typical seismic characteristics for gas hydrates such as bottom-simulating reflectors in the western continental slope and ocean floor.

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Development of Permanent Reference Electrode for Corrosion Monitoring of Underground Metallic Structures (지중 금속구조물 부식감시를 위한 영구매설용 기준전극 개발)

  • Ha, Y.C.;Bae, J.H.;Ha, T.H.;Lee, H.G.;Lee, J.D.;Kim, D.K.
    • Proceedings of the KIEE Conference
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    • 2004.11c
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    • pp.532-534
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    • 2004
  • The advancement of electronics and telecommunication technologies has forced the risk management system for underground metallic structures to evolve into the remote monitoring and control system. Especially, facilities such as gas pipelines, oil pipelines and water distribution lines might make hazardous effect on human safety without continuous monitoring and control. As a result, pipeline engineers have applied cathodic protection system to prevent the degradation of their facilities by corrosion and carried out a periodic monitoring of the pipe-to-soil (P/S) potentials at numberous test boxes along their pipelines. The latter action on a road in downtowns, however, is so much dangerous that the inspectors should be ready to suffer the threatening of their lives and maintenance. In order to minimize these social costs and hazards, a stand-alone type corrosion monitoring equipment which can be installed in test box, store the P/S data for given Belied and send the data by wired/wireless telecommunications is under development. In order to obtain the exact P/S data, however, a reference electrode should be located as close to the pipeline as possible. Actually, the measured potential by a conventional portable reference electrode contain inevitably an IR drop portion caused by the current flow from the cathodic protection rectifier or the subway railroad. To minimize this error, it is recommended that the reference electrode should be buried within 10 cm from the pipeline. In this paper, we describe the design parameters for fabricating the permanent type reference electrode and the characteristics of the developed reference electrode.

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The Analysis of the Painting Work Clothes Clothing Comfort and Wearer Mobility Considering the Work Environment in the Machine and Shipbuilding Industries

  • Park, Gin-Ah;Park, Hye-Won;Bae, Hyun-Sook
    • Journal of Fashion Business
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    • v.16 no.3
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    • pp.13-31
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    • 2012
  • The purpose of the study was to analyze the work clothes' clothing comfort and wearer mobility of painting workers with the consideration of the work environment features in the machine and shipbuilding industries in South Korea. A questionnaire survey was conducted for the study, which consisted of questions on the clothing comfort and wearer mobility aspects of painting work clothes by clothes types and body parts. The work clothes' clothing comfort and wearer mobility levels were scaled in 5 points i.e. 1(: very tight/very uncomfortable) to 5(: very slack/very comfortable). The painting work environmental hazardous features were considered as high impact levels of workplace temperature, oxygen deficiency, organic solvent, toxic gas factors while metal fragment factor only impacts 'low' in the painting processes with the findings throughout this study. Since the painting work consisted of surface washing and the spray and touch-up painting processes, which was carried out in an outdoor work place, the painting work clothes should meet high performance of waterproofing from the painting material and air permeability specially in summer as well as thermal performance in winter. The subjects painting workers' assessment of the existing work clothes' clothing oppression was in the levels between 3 (i.e. moderate) and 4 (i.e. comfortable) in a range of 1 to 5 points. The existing painting work clothes' wearer mobility was evaluated 'very uncomfortable' in all work clothes parts, especially, armhole length, biacromial breadth, sleeve length of the jumper; and body rise, waist, hip, thigh and knee circumferences of the pants.

A Study on Hazardous Air Pollutant Emissions From Diesel Engines Utilizing DME Fuel (DME를 이용한 경유자동차의 유해대기오염물질 발생 특성 연구)

  • Lim, Yun-Sung;Seo, Choong-Youl;Kwack, Soon-Chul;Lee, Jong-Tae;Park, Jung-Min;Kang, Dae-Il;Kim, Jong-Choon;Lee, Young-Jae;Pyo, Young-Duk;Lim, Yui-Soon;Dong, Jong-In
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.53-61
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    • 2006
  • Recently, lots of researchers have been attracted to develop various alternative fuels and to use renewable fuels in order to solve the exhaust emission problems. DME (Dimethylether) is synthetic fuel, and can be produced from natural gas, coal and biomass. The emission is clean because it contains little sulfur and aromatic components In this study, the fuel was tested to investigate the applicability as an alternative fuel for diesel. This study was carried out by comparing the exhaust emissions and performance of diesel engine with DME, ULSD (ultra low sulfur diesel), LSD (low sulfur diesel) respectively. In order to measure regulated emissions, CO, $NO_{3}$, HC from vehicle different fuel types were used on chassis dynamometer CVS (constant volume sampler)-75 mode and EPA TO-I1A method was chosen for aldehydes analysis.

A Survey on the Management of Chemical Substances and Airborne Concentration in Laundries Exposed to Organic Solvents (일부 세탁소의 유기용제 관리실태 및 공기중 노출농도에 관한 조사)

  • Roh, Young-Man;Kwon, Gi-Bum;Park, Seoung-Hyun;Jeong, Jee-Yeon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.11 no.1
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    • pp.70-77
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    • 2001
  • This study was conducted to identify the current status of occupational safety and health by checklist and to evaluate the airborne exposure to chemicals and to provide the appropriate recommendation for safety and health of laundries. A total of 20 laundries located in tile Gyungi district area were surveyed from July 20 to September 15, 2000. The prevalence of laundries having a stove and gas range were found to be 25 % and 55 %, respectively. Smoking is not allowed in 60 % of the laundries. Only 10 % of dry-cleaners were isolated. Ventilation systems in laundries had not been annually inspected. Most of the workers didn't put on respirators, MSDS were not available, and storage bottles did not contain warning labels. The bulk samples of dry cleaning agent include many chemicals that are not controlled by the MOL in Korea. The detected airborne organic solvents in the laundries were benzene, toluene, p-xylene, m-xylene, o-xylene, perchloroethylene, and 2-butoxy ethanol. The airborne concentrations of organic solvents were much less than the occupational exposure limits proposed by the Ministry of Labor(MOL) in Korea. But the concentrations of benzene exceeded the TLV of ACGIH. This study showed that the current status of occupational safety and health was not appropriate for workers in laundries. It is recommended that laundry workers should be educated for the treatment and storage of hazardous organic solvents to improve the occupational safety and health of the working environment as well as MSDS usage. Also, extended research and survey for the organic solvents that are not controlled by the MOL has to be conducted.

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A Study on the Development of the Mercury Emission Factor from Coal-fired Power Plant (석탄 화력발전시설에서의 수은 배출계수 개발에 관한 연구)

  • Kim, Hyung-Chun;Park, Jung-Min;Jang, Kee-Won;Lee, Sang-Bo;Jung, No-El;Song, Deok-Jong;Hong, Ji-Hyung;Lee, Suk-Jo;Kim, Sang-Kyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.2
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    • pp.172-181
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    • 2012
  • Mercury is one of the most hazardous air pollutants. Recently, mercury has been a concern in domestic and overseas because it has lethal toxicity, long distance transport, persistence and bioaccumulation in the environment. Stationary combustion sources such as coal-fired power plants, waste incinerators, and cement kilns are the major sources of mercury emissions. The objectives of this study were to measure the concentration for mercury from coal-fired power plants and to calculate emission factor to estimate its emission. The results showed that the mercury concentrations in the flue gas were 1.63-3.03 mg/$Sm^3$ in anthracite-fired power plants (average 2.32 mg/$Sm^3$) and 1.95-3.33 mg/$Sm^3$ in bituminous-fired power plants (average 2.6 mg/$Sm^3$). Mercury emission factor was estimated as 25.74 mg/ton for anthracite-fired power plants and 12.48 mg/ton for bituminous-fired power plants. Because actual measurements are limited in quantity, it is desirable to refine our estimates by extending the actual measurements.

Emission Factor of Hazardous Air Pollutants in Gas-phase from Light Commersial Vehicle using PEMS on Real-road Driving (실도로 주행에서 PEMS를 이용한 소형 경유 상용차의 가스 상 유해대기오염물질 배출계수 연구)

  • Lim, Ji Hye;Han, Sang Woo;Kim, Jeong;Jang, Young Kee;Chon, Mun Soo;Hwang, Sung Chul;Kim, Joung Hwa;Jung, Sung Woon;Kim, Jeong Soo;Han, Jin Seok
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.2
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    • pp.191-206
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    • 2018
  • In this study, the HAPs(Harzard Air Pollutants) emission factor level of Starex and Grand Carnival was tested using PEMS (Portable Emissions Measurement System) on real road driving. As a result of RDE (Real Driving Emission test), the overall vehicle speed pattern showed similar characteristics. The real-road driving test at constant speed revealed emission factor is inversely proportional relationship to constant speed. Results of accelerating with speed limit on the real-road were shown as followings; Uran (less than 45 km/h)>Rural (<45 km/h, less than 80 km/h)>Motorway (>80 km/h). Moreover, the sudden acceleration and deceleration in driving at high speed was the increasing factor to the HAPs emission factor. This tendency is considered to be influenced by the operating environment on real roads.

A Study on Workers' Risk-Aware Smart Bands System in Explosive Areas (폭발위험지역 근로자 위험 인지형 스마트밴드시스템에 대한 연구)

  • Lee, Byong-Kwon
    • Journal of Internet of Things and Convergence
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    • v.5 no.2
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    • pp.73-79
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    • 2019
  • Research is underway on services and systems that provide real-time alerts for suffocating gases and potentially explosive materials, but currently smart bend type services are lacking. This study supports real-time identification of explosion hazards due to static electricity in the workplace and immediate elimination of accident occurrence factors, real-time monitoring of worker status and workplace hazards (oxygen, hazardous chemical concentration), and immediate warning and data in case of danger. We propose a method of establishing an accident prevention system through analysis. In this way, various accidents that may occur in industrial sites are monitored using IoT-based intelligent sensor nodes, wireless network technology, data processing middleware, and integrated control system, and real-time risk information at the industrial sites is prevented and accidents are prevented. By supporting a safe working environment, the company can significantly reduce costs compared to post-procurement costs.

Bioreactor Systems for the Cometabolic Biodegradation of Trichloroethlene (트리클로로에틸렌의 공동대사적 생분해를 위한 생물반응기 시스템)

  • 이은열
    • KSBB Journal
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    • v.16 no.6
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    • pp.527-532
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    • 2001
  • Trichlooethylene (TCE) has become a widespread contaminant in air, soil, and underground water due to extensive industrial used and improper disposals. Since TCE is a suspected carcinogen and constitutes public health concerns, many treatment systems have been investigated to remove this hazardous waste. One of the most premising reactor systems for the treatment of TCE is trickling biofilter (TBF), in which monooxygenase (MO), the corresponding enzyme for initiating primary substrate oxidation, fortuitously degrades TCE via cometabolism. TCE, however, is not easily treated by simple TBF. This is mainly due to the toxicities of TCE and its degradation products to microbial film in TBF. In this paper, recent progresses on the development of bioreactor system for the treatment of TCE, especially gas-phase TCE, are reviewed. The potentials of novel biofilm reactor systems were also discussed for the long-term continuous treatment of TCE.

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