• Title/Summary/Keyword: Harmful gas

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A Study on Lean Combustion Characteristics with Hydrogen Addition in a Heavy Duty Natural Gas Engine (대형 천연가스엔진에서의 수소 첨가에 의한 희박연소특성 연구)

  • Park, Cheol-Woong;Kim, Chang-Gi;Choi, Young;Won, Sang-Yeon
    • Journal of the Korean Institute of Gas
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    • v.14 no.4
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    • pp.12-17
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    • 2010
  • Natural gas is one of the most promising alternatives to gasoline and diesel fuels because of its high thermal efficiency and lower harmful emissions, including $CO_2$. However, the possibility of partial burn and misfire makes the benefits of natural gas fueled engine worse under lean burn operation condition, Hydrogen addition can promote the combustion characteristics while reduces emissions extremely. In this study, the effect of hydrogen addition on an engine performance was investigated. The results showed that thermal efficiency was increased due to the expansion of lean operation range under stable operation. NOx emission can be significantly reduced with the small increase in HC or CO emissions.

Gas Migration in Low- and Intermediate-Level Waste (LILW) Disposal Facility in Korea (중·저준위 방사성폐기물 처분시설 폐쇄후 기체이동)

  • Ha, Jaechul;Lee, Jeong-Hwan;Jung, Haeryong;Kim, Juyub;Kim, Juyoul
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.4
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    • pp.267-274
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    • 2014
  • The first Low- and Intermediate-Level Waste (LILW) disposal facility with 6 silos has been constructed in granite host rock saturated with groundwater in Korea. A two-dimensional numerical modeling on gas migration was carried out using TOUGH2 with EOS5 module in the disposal facility. Laboratory-scale experiments were also performed to measure the important properties of silo concrete related with gas migration. The gas entry pressure and relative gas permeability of the concrete was determined to be $0.97{\pm}0.15bar$ and $2.44{\times}10^{-17}m^2$, respectively. The results of the numerical modeling showed that hydrogen gas generated from radioactive wastes was dissolved in groundwater and migrated to biosphere as an aqueous phase. Only a small portion of hydrogen appeared as a gas phase after 1,000 years of gas generation. The results strongly suggested that hydrogen gas does not accumulate inside the disposal facility as a gas phase. Therefore, it is expected that there would be no harmful effects on the integrity of the silo concrete due to gas generation.

Feasibility Study of Microturbine CHP and Greenhouse $CO_2$ Enrichment System as Small Scale LFG Energy Project (소규모 매립가스 자원화를 위한 마이크로터빈 열병합발전 및 유리온실 $CO_2$ 농도 증가 시스템의 타당성 연구)

  • Park, Jung-Keuk;Hur, Kwang-Beom;Rhim, Sang-Gyu;Lee, In-Hwa
    • New & Renewable Energy
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    • v.5 no.2
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    • pp.15-24
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    • 2009
  • As new small scale LFG (landfill gas) energy project model which can improve economic feasibility limited due to the economy of scale, LFG-Microturbine combined heat and power system with $CO_2$ fertilization into greenhouses was proposed and investigated including basic design process prior to the system installation at Gwang-ju metro sanitary landfill. The system features $CH_4$ enrichment for stable microturbine operation, reduction of compressor power consumption and low CO emission, and $CO_2$ supplement into greenhouse for enhancement plant growth. From many other researches, high $CO_2$ concentration was found to enhance $CO_2$ assimilation (also known as photosynthesis reaction) which converts $CO_2$ and $H_2O$ to sugar using light energy. For small scale landfills which produce LFG under $3\;m^3$/min, among currently available prime movers, microturbine is the most suitable power generation system and its low electric efficiency can be improved with heat recovery. Besides, since its exhaust gas contains very low level of harmful contaminants to plant growth such as NOx, CO and SOx, microturbine exhaust gas is a suitable and economically advantageous $CO_2$ source for $CO_2$ fertilization in greenhouse. The LFG-Microturbine combined heat and power generation system with $CO_2$ fertilization into greenhouse gas to enhance plant growth is technologically and economically feasible and improves economical feasibility compared to other small scale LFG energy project model.

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Development of an Environmental Friendly Hybrid Power System and its Application to Agricultural Machines (친환경 하이브리드 동력 시스템 개발 및 농기계 응용)

  • Kim, Sangcheol;Hong, Youngki;Kim, Gookhwan
    • Journal of Institute of Control, Robotics and Systems
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    • v.21 no.5
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    • pp.447-452
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    • 2015
  • A hybrid power system was developed for agricultural machines with a 20kW output capacity, and it was attached to a multi-purpose cultivator to improve the performance of the cultivator. The hybrid system combined heterogeneous sources: an internal-combustion engine and an electric power motor. In addition, a power splitter was developed to simplify the power transmission structure. The cultivator using a hybrid system was designed to have increased fuel efficiency and output power and reduced exhaust gas emissions, while maintaining the functions of existing cultivators. The fuel consumption for driving the cultivator in the hybrid engine vehicle (HEV) mode was 341g/kWh, which was 36% less than the consumption in the engine (ENG) mode for the same load. The maximum power take off output of the hybrid power system was 12.7kW, which was 38% more than the output of the internal-combustion engine. In the HEV mode, harmful exhaust gas emissions were reduced; i.e., CO emissions were reduced by 36~41% and NOx emissions were reduced by 27~51% compared to the corresponding emissions in the ENG mode. The hybrid power system improved the fuel efficiency and reduced exhaust gas emissions in agricultural machinery. The hybrid system's lower exhaust gas emissions have considerable advantages in closed work environments such as crop production facilities. Therefore, agricultural machinery with less exhaust gas emissions should be commercialized.

Study on the Effect of Corrosion Gas and Acidic Falling Materials for Conservational Wax on the Copper based Sculpture (동(銅)이 주종을 이루는 조형물 보존용 왁스의 산성강하물 및 부식 가스에서의 영향성 연구)

  • Oh, Seung-Jun;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.26 no.4
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    • pp.437-443
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    • 2010
  • The influence of noxious corrosive gas, which is the product of fossil fuel, and the acidic descent material, which becomes the reason for such reaction, on wax which protects the cultural assets, and the habitat factor were researched. It could be viewed that corrosion occurred rapidly due to the acidic descent material, which have the long staying on the material, rather than harmful corrosive gas. Also, it could be figured out that such corrosion began from whitening phenomenon of coated wax. As the acidity increased, more whitening phenomenon occurred, and eventually, it could be found out that whitening effect began due to the acidic descent material, corrosive gas and various 0.1 M acid solution, which lead to the exposure of internal metal, and corrosion occurred. The wax with the greatest resistance to the acidity due to its least changing aspect seemed to be Renaissance wax, except sulfuric acid.

Investigation of Emission Gas by using the Intake Manifold Gasket Blade (흡기 매니폴드 가스켓 블레이드 적용에 따른 배출가스 고찰)

  • Lee, Minjung;Kim, Taejung;Shin, Yunchan;Cho, Honghuyn
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.54-61
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    • 2018
  • Incomplete combustion in automotive engines is a major cause of harmful exhaust gases. In this study, to prevent incomplete combustion and reduce exhaust gas emissions, a gasket blade for increasing the air velocity was applied to the intake manifold, and the change in exhaust gas was investigated theoretically and experimentally. First, simulation analysis for flow according to the number and angle of the gasket blade was performed using a 3D flow analysis program. As an analysis result, the internal average velocity of the gasket blade was optimum at 6-blade with an angle of $30^{\circ}$. Based on the simulation results, experiments were conducted to verify the effects of the gasket blades on the exhaust gas in a non-load engine simulation system. As the engine speed was increased from 2000 to 4000 rpm, exhaust gases of HC, CO, and NOx decreased by 23.4%, 16.5%, and 3.8%, respectively, and the emission decreasing effect was reduced.

Influence of the nitrogen gas addition in the Ar shielding gas on the erosion-corrosion of tube-to-tube sheet welds of hyper duplex stainless steel (질소 보호 가스 첨가가 하이퍼 듀플렉스 스테인리스 밀봉용접재의 마모부식 저항성에 미치는 영향)

  • Kim, Hye-Jin;Jeon, Soon-Hyeok;Kim, Soon-Tae;Lee, In-Sung;Park, Yong-Soo
    • Corrosion Science and Technology
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    • v.13 no.2
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    • pp.70-80
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    • 2014
  • Duplex stainless steels with nearly equal fraction of the ferrite(${\alpha}$) phase and austenite(${\gamma}$) phase have been increasingly used for various applications such as power plants, desalination facilities due to their high resistance to corrosion, good weldability, and excellent mechanical properties. Hyper duplex stainless steel (HDSS) is defined as the future duplex stainless steel with a pitting resistance equivalent (PRE=wt.%Cr+3.3(wt.%Mo+0.5wt.%W)+30wt.%N) of above 50. However, when HDSS is welded with gas tungsten arc (GTA), incorporation of nitrogen in the Ar shielding gas are very important because the volume fraction of ${\alpha}$-phase and ${\gamma}$-phase is changed and harmful secondary phases can be formed in the welded zone. In other words, the balance of corrosion resistance between two phases and reduction of $Cr_2N$ are the key points of this study. The primary results of this study are as follows. The addition of $N_2$ to the Ar shielding gas provides phase balance under weld-cooling conditions and increases the transformation temperature of the ${\alpha}$-phase to ${\gamma}$-phase, increasing the fraction of ${\gamma}$-phase as well as decreasing the precipitation of $Cr_2N$. In the anodic polarization test, the addition of nitrogen gas in the Ar shielding gas improved values of the electrochemical parameters, compared to the Pure Ar. Also, in the erosion-corrosion test, the HDSS welded with shielding gas containing $N_2$ decreased the weight loss, compared to HDSS welded with the Ar pure gas. This result showed the resistance of erosion-corrosion was increased due to increasing the fraction of ${\gamma}$-phase and the stability of passive film according to the addition $N_2$ gas to the Ar shielding gas. As a result, the addition of nitrogen gas to the shielding gas improved the resistance of erosion-corrosion.

Synthesized Oil Manufacturing Technology from Natural Gas, GTL (천연가스로부터 합성유 제조 기술, GTL(Gas To Liquids))

  • Bae, Ji-Han;Lee, Won-Su;Lee, Heoung-Yeoun;Kim, Yong-Heon
    • The Korean Journal of Petroleum Geology
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    • v.14 no.1
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    • pp.45-52
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    • 2008
  • The GTL(Gas to Liquids) technology, manufacturing synthesized oil from natural gas, had been developed about 1920 for the military purpose by Fischer and Tropsch, German scientists. And 1960, Sasol company had started commercializing the FT(Fischer-Tropsch) synthesis technology, for the transport fuel in South Africa. Until a recent date, the commercialization of GTL technology had been delayed by low oil price. But concern about depletion of petroleum resources, and development in synthesizing technology lead to spotlight on the GTL businesses. Especially, Qatar, which has rich natural gas fields, aims at utilizing natural gas like conventional oil resources. Therefore, around this nation, GTL plants construction has been promoted. There are mainly 3 processes to make GTL products(Diesel, Naphtha, lube oil, etc) from natural gas. The first is synthesis gas generation unit reforming hydrogen and carbomonoxide from natural gas. The second is FT synthesis unit converting synthesized gas to polymeric chain-hydrocarbon. The third is product upgrading unit making oil products from the FT synthesized oil. There are quite a little sulfur, nitrogen, and aromatic compounds in GTL products. GTL product has environmental premium in discharging less harmful particles than refinery oil products from crude to the human body. In short, the GTL is a clean technology, easier transportation mean, and has higher stability comparing to LNG works.

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Effect of CeO2 Addition on De-CH4 and NOx Performance (CH4와 NOx 저감 성능에 관한 CeO2 첨가의 영향)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.9
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    • pp.473-479
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    • 2017
  • Due to environmental pollution, hazards of the human body, and global warning, changes in the power train of automobiles are intensifying, and the market forelectronic vehicles is rising. Also, in order to meet the stricter emission regulations forautomobiles with internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is increasing gradually. The objective of this study is to investigate the effectsfrom additive ceric oxide ($CeO_2$) loading amounts to improve the methane ($CH_4$) and nitric oxide (NOx) abatement ability of the natural gas oxidation catalysts(NGOC) reducing toxic gases emitted from compressed natural gas (CNG) buses. Three kinds of NGOC were prepared under the following conditions: fresh and $700^{\circ}C$ for 12hr thermal aging, and the reduction performance of toxic gases was evaluated. Fresh $1Pt-3Pd-1Rh-3MgO-6CeO_2/(Al+Z)$ NGOC containing 6wt% $CeO_2$ had the highest dispersivity of palladium (Pd) with high selectivity to $CH_4$ and improved harmful gas reduction performance. The NGOC with 6wt% $CeO_2$ loaded the least decreased in the dispersivity of the noble metal, and showed the highest reduction of harmful gases due to the thermal durability of $CeO_2$.

A STUDY ON THE FLOW CHARACTERISTICS OF AIR-KNIFE USING A CONSTANT EXPANSION RATE NOZZLE (팽창률이 일정한 노즐을 사용한 AIR-KNIFE 유동에 관한 연구)

  • Lee, Dong-Won;Kang, Nam-Cheol;Kim, Guen-Young;Kwon, Young-Doo;Kwon, Soon-Bum
    • Journal of computational fluids engineering
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    • v.13 no.4
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    • pp.1-7
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    • 2008
  • In the process of continuous hot-dip galvanizing, it is well known that the gas wiping through an air knife system is most effective because of its uniformity in coating thickness, possibility of thin coating, workability in high speed, and simplicity of control. However, gas wiping used in the galvanizing process brings about a problem of splashing at the strip edge above a certain high speed of process. It is also known that the problem of edge splashing is more harmful than that at the mid strip surface. For a given liquid(of a certain viscosity and surface tension), the onset of splashing mainly depends upon the strip velocity, the gas-jet pressure, and the nozzle's stand-off distance. In these connections in the present study, we proposed three kinds of air knife system having nozzles of constant expansion rate, and compared the jet structures issuing from newly proposed nozzle systems with the result by a conventional one. In numerical analysis, the governing equations are consisted of two-dimensional time dependent Navier-Stokes equations, and the standard k-${\varepsilon}$ turbulence model is employed to solve turbulence stress and so on. As the result, it is found that we had better use the constant expansion-rate nozzle which can be interpreted from the point view of the energy saving for the same coating thickness. Also, we better reduce the size of separation bubble and enhance the cutting ability at the strip surface, by using an air-knife having constant expansion-rate nozzle.