• 제목/요약/키워드: Hard template

검색결과 25건 처리시간 0.022초

슈퍼 커패시터용 전극을 위한 Polyvinylidene chloride(PVDC)-resin과 Mg(OH)2 템플릿으로부터 메조기공 탄소의 제조 (Fabrication of Mesoporous Carbon from Polyvinylidene Chloride(PVDC)-resin Precursor with Mg(OH)2 Template for Supercapacitor Electrode)

  • 황버들;전상은
    • 한국표면공학회지
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    • 제52권6호
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    • pp.326-333
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    • 2019
  • The microporous carbon derived from PVDC-resin by a simple heat-treatment under an inert atmosphere exhibits a reasonable specific capacitance for a supercapacitor's electrode. However, the capacitance was rapidly decreased at high charge/discharge rate. The micropores present in an electrode surface hinder the entrance of an electrolyte ion onto the entire surface. To induce the meso-sized pores during the carbonization of PVDC-resin, Mg(OH)2 was utilized as a hard template. The porous carbon made from the mixture of PVD-Cresin and Mg(OH)2 include mesopores as well as micropores. The induced mesopores does not homogeneously distributed on the entire surface of the synthesized carbon. The PVDC-resin and Mg(OH)2 are dissolved in the dimethylformamide for the hard template to evolve the pores on the synthesized carbon uniformly. The carbon made from PVDC-resin with solvent and a hard template contains mostly mesopores resulting in the high power performance. The reduced amount of solvent in the precursor derives the carbon with high specific surface area and high power density.

Preparation of Micro-/Macroporous Carbons and Their Gas Sorption Properties

  • Hwang, Yong-Kyung;Shin, Hye-Seon;Hong, Jin-Yeon;Huh, Seong
    • Bulletin of the Korean Chemical Society
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    • 제35권2호
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    • pp.377-382
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    • 2014
  • Micro-/macroporous carbons (MMCs) were prepared using a hollow mesoporous silica capsule (HMSC) as a sacrificial hard template. The carbonization process after the infiltration of furfuryl alcohol into the template-free HMSC material afforded MMC materials in high yield. The hard template HMSC could be removed by HF etching without deteriorating the structure of MMC. The MMC materials were fully characterized by SEM, TEM, PXRD, XPS, and Raman spectroscopy. The replication processes were so successful that MMCs exhibited a hollow capsular structure with multimodal microporosity. Detailed textural properties of MMC materials were investigated by volumetric $N_2$ adsorption-desorption analysis at 77 K. To explore the gas sorption abilities of MMCs for other gases, $H_2$ and $CO_2$ sorption analyses were also performed at various temperatures. The multimodal MMC materials were found to be good sorbents for both $H_2$ and $CO_2$ at low pressure.

First-fit 전략을 사용하는 템플럿 패킹 문제를 위한 근사 알고리즘 (An Approximation Algorithm based on First-fit Strategy for Template Packing Problem)

  • 송하주;권오흠
    • 한국멀티미디어학회논문지
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    • 제19권2호
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    • pp.443-450
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    • 2016
  • This paper deals with a kind of packing problem of which the goal is to compose one or more templates which will be used to produce the items of different types. Each template consists of a fixed number of slots which are assigned to the different types of items and the production of the items is accomplished by printing the template repeatedly. The objective is to minimize the total number of produced items. This problem is known to be NP-hard. We present a polynomial time approximation algorithm which has a constant approximation ratio. The proposed algorithm is based on the well-known first-fit strategy.

Versatile Strategies for Fabricating Polymer Nanomaterials with Controlled Size and Morphology

  • Yoon, Hyeon-Seok;Choi, Moon-Jung;Lee, Kyung-Jin;Jang, Jyong-Sik
    • Macromolecular Research
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    • 제16권2호
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    • pp.85-102
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    • 2008
  • The development of reliable synthetic routes to polymer nanomaterials with well-defined size and morphology is a critical research topic in contemporary materials science. The ability to generate nanometer-sized polymer materials can offer unprecedented, interesting insights into the physical and chemical properties of the corresponding materials. In addition, control over shape and geometry of polymer nanoparticles affords versatile polymer nanostructures, encompassing nanospheres, core-shell nanoparticles, hollow nanoparticles, nanorods/fibers, nanotubes, and nanoporous materials. This review summarizes a diverse range of synthetic methods (broadly, hard template synthesis, soft template synthesis, and template-free synthesis) for fabricating polymer nanomaterials. The basic concepts and significant issues with respect to the synthetic strategies and tools are briefly introduced, and the examples of some of the outstanding research are highlighted. Our aim is to present a comprehensive review of research activities that concentrate on fabrication of various kinds of polymer nanoparticles.

나노템플레이트 표면처리를 통한 나노패턴이 형성된 PDMS 탄성 스탬프 몰드 제작 (Fabrication of Nanopatterned PDMS Elastic Stamp Mold Using Surface Treatment of Nanotemplate)

  • 박용민;서상현;서영호;김병희
    • 한국생산제조학회지
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    • 제24권1호
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    • pp.38-42
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    • 2015
  • Polydimethylsiloxane (PDMS) is a widely used material for replicating micro-structures because of its transparency, deformability, and easy fabrication. At the nanoscale, however, it is hard to fill a nanohole template with uncured PDMS. This paper introduces several simple methods by changing the surface energy of a nanohole template and PDMS elastomer for replicating 100nm-scale structures. In the case of template, pristine anodic aluminum oxide (AAO), hydrophobically treated AAO, and hydrophillically treated AAO are used. For the surface energy change of the PDMS elastomer, a hydrophilic additive and dilution solvent are added in the PDMS prepolymer. During the molding process, a simple casting method is used for all combinations of the treated template and modified PDMS. The nanostructured PDMS surface was investigated with a scanning electron microscope after the molding process for verification.

Preparation of Mesoporous SiCBN Ceramic Templated by Mesoporous Carbon

  • Nghiem, Quoc Dat;Ryoo, Hyang-Im;Kim, Dong-Pyo
    • 한국세라믹학회지
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    • 제44권7호
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    • pp.358-361
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    • 2007
  • Well-ordered mesoporous SiCBN ceramics have been successfully synthesized by infiltrating a polymeric precursor, which was prepared from borazine and 2,4,6-trimethyl-2,4,6-trivinylcyclotrisilazane via a hydroboration reaction, into a mesoporous carbon (CMK-3) as a hard template. This was followed by pyrolysis at $1400^{\circ}C$ under nitrogen gas and subsequent oxidative removal of the carbon template without chemical etching. The prepared mesoporous SiCBN ceramic was characterized by a small-angle XRD, TEM, and BET surface area. The resulting mesoporous SiCBN ceramic revealed a BET surface area of $275 m^2g^{-1}$ and a pore volume of $0.8 cm^3 g$ with no crystallization.

A Secure Decentralized Storage Scheme of Private Information in Blockchain Environments

  • Han, Seungjin
    • 한국컴퓨터정보학회논문지
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    • 제23권1호
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    • pp.111-116
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    • 2018
  • Recently, IoT and Big Data dealing with voluminous and complex sensitive information is one of the key issues in the era of the 4th industrial revolution. There have been a lot of studies to store the collected and processed sensitive information safely in storage data. Especially biometric information, if it is leaked and becomes identity theft, is hard to be corrected and results in serious event. To fix the problem, methods such as FIDO or KFTC have been proposed. In this paper, we propose a modified method of TTAK.KO-12.0098 according to the environment of this paper and propose a method of safely storing the generated disposable template in a block chain. We show that our method is better by comparing the existing method and the security analysis.

템플릿 기반의 상호대화형 전공강의시간표 작성지원시스템 (A Template-based Interactive University Timetabling Support System)

  • 장용식;정예원
    • 지능정보연구
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    • 제16권3호
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    • pp.121-145
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    • 2010
  • 매 학기마다 반복되는 대학의 강의시간표 작성 방법은 대학 상황에 따라 다르며, 교육환경의 변화에 따라 그 복잡도와 문제의 크기가 증가되는 NP-hard 문제로 알려져 있다. 그 동안, 효과적인 강의자원 배분을 위한 강의시간표 자동생성의 필요성으로 대학 강의시간표 작성에 관한 여러 방법의 연구가 진행되어 왔다. 일반적으로 교양과목 강의시간표는 대학행정부서에서, 전공과목은 학과에서 작성하는데 각 학과 단위의 전공강의시간표작성지원시스템은 학생들의 편의를 도모하고 수업의 효과와 전공강의자원의 효과적인 배분를 위해 중요한 역할을 한다. 이를 위하여 본 연구는 한신대학교의 새로운 강의시간표 작성체계에 따라, 사례 기반의 템플릿을 생성하고, 이로부터 규칙 기반의 상호대화형으로 효과적인 강의자원 배분이 가능한 전공강의시간표를 작성하는 두 단계 지원시스템을 제안하였으며, 사례 데이터를 이용한 프로토타입으로 그 효과를 검정하였다. 과거 사례와의 유사도는 학과 평균 41.72%로 템플릿의 유용성을 볼 수 있으며, 민감도 분석 결과에서 동일 시간 개설과목 허용 임계치를 90% 이상 설정한다면 강의시간표가 더 고른 분포를 갖게 됨을 검정하였다.

디지털 카메라를 이용한 구조물의 동특성 추출 (Modal Parameter Extraction Using a Digital Camera)

  • 김병화
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2008년도 추계학술대회논문집
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    • pp.61-68
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    • 2008
  • A set of modal parameters of a stay-cable have been extracted from a moving picture captured by a digital camera supported by shaking hands. It is hard to identify the center of targets attached on the cable surface from the blurred cable motion image, because of the high speed motion of cable, low sampling frequency of camera, and the shaking effect of camera. This study proposes a multi-template matching algorithm to resolve such difficulties. In addition, a sensitivity-based system identification algorithm is introduced to extract the natural frequencies and damping ratios from the ambient cable vibration data. Three sets of vibration tests are conducted to examine the validity of the proposed algorithms. The results show that the proposed technique is pretty feasible for extracting modal parameters from the severely shaking motion pictures.

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Fabrication of Hollow Metal Microcapsules with Mesoporous Shell Structure: Application as Efficient Catalysts Recyclable by Simple Magnetic Separation

  • Jang, Da-Young;Jang, Hyung-Gyu;Kim, Gye-Ryung;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • 제32권9호
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    • pp.3274-3280
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    • 2011
  • Monodispersed porous NiO and $Co_3O_4$ microcapsules with a hollow core were synthesized using SBA-16 silica sol and PS as a hard template. The porous hollow microcapsules were characterized by XRD, TEM and $N_2$ adsorption/desorption analysis. After $H_2$ reduction of metal oxide microspheres, they were conducted as an active catalyst in the reduction of chiral butylronitrile and cyanobenzene. The mesoporous metals having a hollow structure showed a higher activity than a nonporous metal powder and an impregnated metal on the carbon support.