• Title/Summary/Keyword: Halogen

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Effects of light direction and exposure times of plasma arc light on shear bond strength of metal brackets (Plasma arc light를 이용한 금속 브라켓의 부착시 광조사 방향과 중합시간이 전단결합강도에 미치는 영향)

  • Roh, Sang-Jeong;Lee, Hyun-Jung;Jeon, Young-Mi;Kim, Jong-Ghee
    • The korean journal of orthodontics
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    • v.34 no.5 s.106
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    • pp.429-438
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    • 2004
  • The purpose of this study was to compare the effects of different light direction exposure times and setting times when using plasma arc light on shear bond strength of metal brackets. 240 extracted human premolars were randomly assigned to one of 16 groups Standardized brackets were bonded to enamel using different light curing units (Plasma arc light and Halogen light), exposure times (Plasma arc light 2. 4, 6 seconds and Halogen light 20 seconds). and light directions [Vertical direction [V] and Oblique direction [O]). 8 groups were tested after 5 minutes and the remaining 8 groups after 24 hours. The metal brackets were bonded with Transbond XT. Shear bond strength was measured by a universal testing machine. The results were as fellows: There were as differences between the shear bond strengths of the Vertical groups (V) and Oblique groups (O). regardless of exposure times and types of light curing units (p>0.05). The shear bond strength of the group with 2 seconds of plasma light were significantly lower than other exposure time groups (P<0.05). The shear bond strength tested after 5 minutes was lower than after 24 hours (p<0.05) The Adhesive Remment Index (ARI) score showed no statistically significant difference among the different groups. The results of this study suggested that the light direction of plasma arc light had no influence on the shear bond strength of metal brackets to enamel. and exposure times more than 4 seconds produced shear bond strengths similar to those Produced with a conventional halogen curing light.

DEVELOPMENT OF OPTICAL CARIES ACTIVITY TEST USING DENTAL CURING LIGHT (광중합기를 이용한 광학적 치아우식활성도 검사법)

  • Lee, Nan-Young;Kim, Mi-Ra;Oh, You-Hyang;Lee, Chang-Seop;Lee, Sang-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.31 no.4
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    • pp.671-679
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    • 2004
  • The purpose of this study was to develop a practical caries activity test by fluorescence using laser, plasma light and halogen light. The subjects of study were 45 children of 7-8 years old Argon laser, plasma light and halogen light were irradiated to buccal or labial surface of all teeth. Fluorescence of initial carious lesion from teeth was observed through barrier filter and the number of teeth showing lesion was counted. Visual examination for the dDfFtT, mutans streptococci screening test and Lactobacilli colony counting were also done. Data analysis was accomplished by Axelsson's method. The result from the present study can be summarized as follows. 1. Laser, plasma light and halogen light could detect the initial carious lesions better than visual examination(p<0.05). 2. There was positive correlation between laser(r=0.42), plasma light(r=0.41), halogen light(r=0.39) and dBfFtT rate(p<0.01). 3. The specificity sensitivity and predictive value was showed highest value in laser, but was showed favorable value in plasma light and halogen light. In regard to above results, laser, plasma light and halogen light all considered to be reliable method for determining individual caries activity. And they were also considered to be practical method because it would be simple, inexpensive, and time saving method.

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Photocatalytic-Photooxidation of Halogen Derivatives of Phenols in Aqueous Solution (방향족 탄화수소 할로겐 유도체의 광촉매-광산화)

  • 김삼혁;권규혁;정오진
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.233-240
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    • 1999
  • Industrial waste which highly loaded by halogenide phenols was photooxidized by laboratory-scale photooxidation of these organic impurities in the presence of aerotropic and titaniumdioxide as photocatalyst. The disapperance of organic compounds was determined as a function of the irradiation time. Some contaminants such as 2-chlorophenol, 2-bromphenol, 3-bromphenol, 4-bromphenol, 2,4-dibromophenol and 2,6-dibromophenol were photodegraded separately to obtain information on the reaction rates, reactivities, and reaction mechanisms of the photooxidation, and on the stoichiometric correlation between organic reactant and inorganic products concentration in the course of the photocatalytic photoreaction.

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Kinetic Studies on Halogen Exchanges of 2-Naphthylmethyl Chloride

  • Lee, Ikchoon;Yie, Jae-Eui;Kim, Wang-Ki;Lee, Kae-Soo
    • Nuclear Engineering and Technology
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    • v.8 no.2
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    • pp.77-80
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    • 1976
  • The halogen exchange reactions of 2-naphylmethyl chloride have been investigated in actone and acetonitrile. The results were in good accord with PMO theory and HSAB principle.

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Natural Halogenated Organic Compounds (천연(天然) Halogen 유기화합물(有機化合物)에 대(對)하여)

  • Han, Koo-Dong
    • Korean Journal of Pharmacognosy
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    • v.7 no.3
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    • pp.159-169
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    • 1976
  • The present review records the known structures of more than 80 organic compounds containing halogens, which may be considered naturally occurring. The format of the review is based on the viewpoint of biochemists. Compounds containing one type of halogen atom have been placed in one of four major division, i.e., structures possessing fluorine, chlorine, bromine or iodine covalently bonded to carbon. Within each major division molecular structures are given along with the species from which the compounds have been isolated, The biological significance, if any, is also mentioned.

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Selective Dehalogenative Homocoupling of Haloarylsulfonates by th Use of Palladium Catalyst

  • Lee, Tae Su;An, Jeong Ho;Kim, Jin Hwan;Bae, Jin Yeong
    • Bulletin of the Korean Chemical Society
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    • v.22 no.4
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    • pp.375-378
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    • 2001
  • The palladium catalyzed dehalogenative homocoupling of haloarylsulfonates under reductive conditions has proceeded selectively depending on the type of the halogen. Thus, an iodo or a bromo leaving group of haloarylsulfonates was homocoupled to gi ve symmetrical biaryls in good yields with the sulfonate group intact, whereas a chloro leaving group gave no reaction under the conditions used. When the more reactive nickel catalyst was employed instead of the palladium catalyst in the reaction, both dehalogenative and desulfonative homocouplings of haloarylsulfonates occurred regardless of the type of the halogen used.

Halogen Exchange Reactions of Cinnamyl Halides

  • Lee, Bon-Su;Lee, Ikchoon
    • Nuclear Engineering and Technology
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    • v.1 no.2
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    • pp.87-90
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    • 1969
  • Halogen exchange reactions of trans-cinnnamyl chloride and bromide with radioactive chloride, bromide and iodide ions in acetone have teen studied. Relative nucleophilicity of halide ions and relative leaving ability have been discussed invoking the principle of HSAB.

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Wear Of Dental Restorative Composite Resins Cured by Two Different Light Sources (치아 충전용 복합레진의 광중합 광원 종류에 따른 마멸 비교)

  • Kim H.;Lee K.Y.;Park S. H.;Jung I. Y.;Jeon S. B.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.350-354
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    • 2004
  • In this study, the wear characteristics of five different dental composite resins cured by conventional halogen light and LED light sources were investigated. Five different dental composite resins of Surefil, Z100, Dyract AP, Fuji II LC and Compoglass were worn against a zirconia ceramic ball using a pin-on-disk type wear tester with 15 N contact force in a reciprocal sliding motion of sliding distance of 10 mm/cycle at 1Hz under the room temperature dry condition. The wear variations of dental composite resins were linearly increased as the number of cycles increased. It was observed that the wear resistances of these specimens were in the order of Dyract AP > Surefil > Compoglass > Z100 > Fuji II LC. On the morphological observations by SEM, the large crack formation on the sliding track of Fuji ?LC specimen was the greatest among all resin composites. Dyract AP showed less wear with few surface damage. There is no significant difference in wear performance between conventional halogen light curing and light emitting diodes curing sources. It indicates that a light emitting diodes (LED) source can replace a halogen light source as curing unit for composite resin restorations.

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